| Common Name: | PERCHLORIC ACID, 0.100 NORMAL (N/10) IN GLACIAL ACETIC ACID |
| Manufacturer: | RICCA CHEMICAL |
| SDS Revision Date: | 10/6/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 45F245 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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R
RICCA CHEMICAL COMPANY(R*)
SAFETY DATA SHEET
CLASSIFIED ACCORDING TO OSHA HAZARD COMMUNICATION STANDARD (HCS)
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
TRADE NAME OR DESIGNATION:
PERCHLORIC ACID, 0.100 NORMAL (N/10) IN GLACIAL ACETIC ACID
PRODUCT NUMBER: 5515
OTHER IDENTIFYING PRODUCT NUMBERS:
5515-1, 5515-16, 5515-32, 5515-4, 5515-5, 5515-5PT
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE: GENERAL LABORATORY REAGENT
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY: RICCA CHEMICAL COMPANY
ADDRESS:
448 WEST FORK DRIVE
ARLINGTON, TX 76012
USA
TELEPHONE: 888-467-4222
1.4. EMERGENCY TELEPHONE NUMBER (24 HOURS):
CHEMTREC (USA): 800-424-9300
CHEMTREC (INTERNATIONAL): 1+703-527-3887
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FOR THE FULL TEXT OF THE HAZARD AND PRECAUTIONARY STATEMENTS LISTED
BELOW, SEE SECTION 16.
HAZARD CLASS CATEGORY HAZARD PRECAUTIONARY
STATEMENTS STATEMENTS
ACUTE TOXICITY - ORAL CATEGORY 4 H302 P264, P270,
P301+P312, P330,
P501
ACUTE TOXICITY - DERMAL CATEGORY 4 H312 P280, P302+P352,
P312, P321, P362,
P501
ACUTE TOXICITY - INHALATION CATEGORY 4 H332 P261, P271,
P304+P340, P312
SKIN CORROSION / IRRITATION CATEGORY 1A H314 P260, P264, P280,
P301+P330+P331,
P303+P361+P353,
P363, P304+P340,
P310, P321,
P305+P351+P338,
P405, P501
EYE DAMAGE / IRRITATION CATEGORY 1 H318 P280,
P305+P351+P338,
P310
RESPIRATORY SENSITIZER CATEGORY 1 H334 P261, P285,
P304+P341,
P342+P311, P501
SPECIFIC TARGET CATEGORY 1 H370 P260, P264, P270,
ORGANS/SYSTEMIC TOXICITY P307+P311, P321,
FOLLOWING SINGLE EXPOSURE P405, P501
SPECIFIC TARGET CATEGORY 1 H372 P260, P264, P270,
ORGANS/SYSTEMIC TOXICITY P314, P501
FOLLOWING REPEATED EXPOSURE
FLAMMABLE LIQUIDS CATEGORY 3 H226 P210, P233, P240,
P241, P242, P243,
P280,
P303+P361+P353,
P370+P378,
P403+P235, P501
CORROSIVE TO METALS CATEGORY 1 H290 P234, P390, P406
HAZARDOUS TO THE AQUATIC CATEGORY 3 H402 P273, P501
ENVIRONMENT (ACUTE)
2.2. GHS LABEL ELEMENTS:
PICTOGRAMS:
EXCLAMATION MARK
CORROSION
HEALTH HAZARD
FLAME
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
HAZARD NUMBER HAZARD STATEMENT
H226 FLAMMABLE LIQUID AND VAPOR.
H290 MAY BE CORROSIVE TO METALS.
H302 HARMFUL IF SWALLOWED.
H312 HARMFUL IN CONTACT WITH SKIN.
H314 CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H318 CAUSES SERIOUS EYE DAMAGE.
H332 HARMFUL IF INHALED.
H334 MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING
DIFFICULTIES IF INHALED.
H370 CAUSES DAMAGE TO ORGANS.
H372 CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE.
H402 HARMFUL TO AQUATIC LIFE.
PRECAUTIONARY STATEMENTS:
PRECAUTIONARY NUMBER PRECAUTIONARY STATEMENT
P210 KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. NO
SMOKING.
P233 KEEP CONTAINER TIGHTLY CLOSED.
P234 KEEP ONLY IN ORIGINAL CONTAINER.
P240 GROUND CONTAINER AND RECEIVING EQUIPMENT.
P241 USE EXPLOSION-PROOF EQUIPMENT.
P242 USE ONLY NON-SPARKING TOOLS.
P243 TAKE PRECAUTIONARY MEASURES AGAINST STATIC
DISCHARGE.
P260 DO NOT BREATHE FUMES, MIST, VAPORS, OR SPRAY.
P261 AVOID BREATHING FUMES, MIST, VAPORS, OR SPRAY.
P264 WASH ARMS, HANDS AND FACE THOROUGHLY AFTER
HANDLING.
P270 DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT.
P271 USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P273 AVOID RELEASE TO THE ENVIRONMENT.
P280 WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
P285 IN CASE OF INADEQUATE VENTILATION WEAR
RESPIRATORY PROTECTION.
P301+P312 IF SWALLOWED:
CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL
UNWELL.
P301+P330+P331 IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING.
P302+P352 IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P303+P361+P353 IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
RINSE SKIN WITH WATER.
P304+P340 IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
P304+P341 IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO
FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338 IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO
DO. CONTINUE RINSING.
P307+P311 IF EXPOSED: CALL A POISON CENTER OR PHYSICIAN.
P310 IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
P312 CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL
UNWELL.
P314 GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
P321 SPECIFIC TREATMENT (WASH AREAS OF CONTACT
WITH WATER).
P330 RINSE MOUTH.
P342+P311 IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR PHYSICIAN.
P362 TAKE OFF CONTAMINATED CLOTHING AND WASH IT
BEFORE REUSE.
P363 WASH CONTAMINATED CLOTHING BEFORE REUSE.
P370+P378 IN CASE OF FIRE:
USE DRY CHEMICAL, FOAM OR CARBON DIOXIDE TO
EXTINGUISH.
P390 ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE.
P403+P235 STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405 STORE LOCKED UP.
P406 STORE IN CORROSIVE RESISTANT CONTAINER WITH A
RESISTANT INNER LINER.
P501 DISPOSE OF CONTENTS IN ACCORDANCE WITH LOCAL,
STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
2.4. HAZARDS NOT OTHERWISE CLASSIFIED OR COVERED BY GHS:
DATA NOT AVAILABLE.
| SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS | |
3.1. COMPONENTS OF SUBSTANCE OR MIXTURE:
CHEMICAL NAME FORMULA MOLECULAR WEIGHT CAS NUMBER WEIGHT%
ACETIC ACID CH3COOH 60.05 G/MOL 64-19-7 96.18
ACETIC ANHYDRIDE (CH3CO)2O 102.08 G/MOL 108-24-7 2.47
PERCHLORIC ACID HClO4 100.45 G/MOL 7601-90-3 0.95
WATER H2O 18.01 G/MOL 7732-18-5 0.41
| SECTION 4: FIRST-AID MEASURES | |
4.1. GENERAL FIRST AID INFORMATION:
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. EYE CONTACT MAY CAUSE SEVERE
EYE DAMAGE FOLLOWED BY LOSS OF SIGHT. VAPOR EXPOSURE MAY CAUSE WATERING
AND IRRITATION TO EYES.
INHALATION:
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
SKIN CONTACT:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER.
MAY CAUSE SERIOUS DAMAGE TO THE SKIN. EFFECTS MAY INCLUDE REDNESS, PAIN,
SKIN BURNS.
INGESTION:
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. DO NOT INDUCE VOMITING. GIVE LARGE
QUANTITY OF WATER. CALL A PHYSICIAN IMMEDIATELY.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, ACUTE AND DELAYED:
HARMFUL IF SWALLOWED. HARMFUL IN CONTACT WITH SKIN. CAUSES SEVERE SKIN
BURNS AND EYE DAMAGE. CAUSES SERIOUS EYE DAMAGE. HARMFUL IF INHALED. MAY
CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
CAUSES DAMAGE TO ORGANS. CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR
REPEATED EXPOSURE.
DANGER!
CORROSIVE LIQUID. MAY BE FATAL IF SWALLOWED. CAUSES SEVERE BURNS TO ALL
AREAS OF CONTACT. HARMFUL IF INHALED. INHALATION MAY CAUSE LUNG AND TOOTH
DAMAGE. IMMEDIATELY WASH AREAS OF CONTACT WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES. IF INGESTED, GIVE LARGE QUANTITY OF WATER. DO NOT
INDUCE VOMITING.
EYE CONTACT:
EYE CONTACT MAY CAUSE SEVERE EYE DAMAGE FOLLOWED BY LOSS OF SIGHT. VAPOR
EXPOSURE MAY CAUSE WATERING AND IRRITATION TO EYES.
SKIN CONTACT:
MAY CAUSE SERIOUS DAMAGE TO THE SKIN. EFFECTS MAY INCLUDE REDNESS, PAIN,
SKIN BURNS.
CHRONIC EFFECTS / CARCINOGENICITY:
REPEATED EXPOSURES MAY CAUSE EROSION OF EXPOSED FRONT TEETH, DARKENING
OF SKIN AND CHRONIC INFLAMMATION OF THE NOSE, THROAT AND BRONCHIAL TUBES.
4.3. MEDICAL ATTENTION OR SPECIAL TREATMENT NEEDED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. SPECIFIC TREATMENT (WASH
AREAS OF CONTACT WITH WATER). IRRIGATE IMMEDIATELY WITH LARGE QUANTITY OF
WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IMMEDIATELY. REMOVE
TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NECESSARY. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
CALL A PHYSICIAN IF IRRITATION DEVELOPS. DO NOT INDUCE VOMITING. GIVE
LARGE QUANTITY OF WATER. CALL A PHYSICIAN IMMEDIATELY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE DRY CHEMICAL, FOAM OR CARBON DIOXIDE TO EXTINGUISH. WATER SPRAY, DRY
CHEMICAL, ALCOHOL FOAM, CARBON DIOXIDE
5.2. SPECIFIC HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FLAMMABLE LIQUID AND VAPOR. COMBUSTIBLE LIQUID. COMBUSTION MAY PRODUCE
IRRITANTS AND TOXIC GASES.
5.3. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
WEAR SPECIAL PROTECTIVE CLOTHING AND POSITIVE PRESSURE SELF-CONTAINED
BREATHING APPARATUS. BUTYL RUBBER, TEFLON, VITON, OR SARANEX BARRIER
RECOMMENDED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GROUND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF EQUIPMENT.
USE ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST STATIC
DISCHARGE. WEAR PROTECTIVE GLOVES AND EYE PROTECTION. IN CASE OF INADEQUATE
VENTILATION WEAR RESPIRATORY PROTECTION.
6.2. CLEANUP AND CONTAINMENT METHODS AND MATERIALS:
USE WATER SPRAY TO COOL AND DISPERSE VAPORS, PROTECT PERSONNEL, AND
DILUTE SPILLS TO FORM NONFLAMMABLE MIXTURES. USE SODA ASH TO NEUTRALIZE
SPILLS. CONTROL RUNOFF AND ISOLATE DISCHARGED MATERIAL FOR PROPER DISPOSAL.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING AND STORAGE CONDITIONS:
STORE IN CORROSIVE RESISTANT CONTAINER WITH A RESISTANT INNER LINER. AS
WITH ALL CHEMICALS, WASH HANDS THOROUGHLY AFTER HANDLING. AVOID CONTACT
WITH EYES AND SKIN. PROTECT FROM FREEZING AND PHYSICAL DAMAGE.
| SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
CHEMICAL NAME LIMIT COUNTRY EXPOSURE INFORMATION SOURCE
TYPE LIMIT
ACETIC ANHYDRIDE TWA USA 5 PPM TWA U.S. - OSHA -
(108-24-7) 20 MG/M3 TWA FINAL PELS - TIME
WEIGHTED AVERAGES
(TWAS)
ACETIC ANHYDRIDE TLV-STEL USA 3 PPM STEL ACGIH - THRESHOLD
(108-24-7) LIMIT VALUES -
SHORT TERM
EXPOSURE LIMITS
(TLV-STEL)
ACETIC ANHYDRIDE TLV-TWA USA 1 PPM TWA ACGIH - THRESHOLD
(108-24-7) LIMIT VALUES -
TIME WEIGHTED
AVERAGES (TLV-TWA)
ACETIC ACID TWA USA 10 PPM TWA U.S. - OSHA -
(64-19-7) 25 MG/M3 TWA FINAL PELS - TIME
WEIGHTED AVERAGES
(TWAS)
ACETIC ACID TLV-STEL USA 15 PPM STEL ACGIH - THRESHOLD
(64-19-7) LIMIT VALUES -
SHORT TERM
EXPOSURE LIMITS
(TLV-STEL)
ACETIC ACID TLV-TWA USA 10 PPM TWA ACGIH - THRESHOLD
(64-19-7) LIMIT VALUES -
TIME WEIGHTED
AVERAGES (TLV-TWA)
8.2. EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. A SYSTEM OF LOCAL AND/OR
GENERAL EXHAUST IS RECOMMENDED TO KEEP EMPLOYEE EXPOSURES BELOW THE
AIRBORNE EXPOSURE LIMIT.
RESPIRATORY PROTECTION:
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION. WORK WITH
ADEQUATE VENTILATION OR WEAR RESPIRATOR WITH ACID GAS/ORGANIC VAPOR
CARTRIDGE.
SKIN PROTECTION:
WEAR PROTECTIVE GLOVES AND EYE PROTECTION. CHEMICAL RESISTANT GLOVES.
EYE PROTECTION:
WEAR PROTECTIVE GLOVES AND EYE PROTECTION. SAFETY GLASSES OR GOGGLES.
8.3. PERSONAL PROTECTIVE EQUIPMENT:
WEAR PROTECTIVE GLOVES AND EYE PROTECTION. IN CASE OF INADEQUATE
VENTILATION WEAR RESPIRATORY PROTECTION. WORK WITH ADEQUATE VENTILATION OR
WEAR RESPIRATOR WITH ACID GAS/ORGANIC VAPOR CARTRIDGE. CHEMICAL RESISTANT
GLOVES. SAFETY GLASSES OR GOGGLES.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: COLORLESS TO LIGHT YELLOW LIQUID
PHYSICAL STATE: LIQUID
ODOR: DATA NOT AVAILABLE.
ODOR THRESHOLD: DATA NOT AVAILABLE.
PH: <2
MELTING/FREEZING POINT: DATA NOT AVAILABLE.
INITIAL BOILING POINT/RANGE:
APPROXIMATELY 118 DEG. C - APPROXIMATELY 118 DEG. C
FLASH POINT: 39 DEG. C (ACETIC ACID)
EVAPORATION RATE: 0.97 (BUTYL ACETATE = 1)
FLAMMABILITY: DATA NOT AVAILABLE.
FLAMMABILITY/EXPLOSIVE LIMITS: DATA NOT AVAILABLE.
VAPOR PRESSURE: DATA NOT AVAILABLE.
VAPOR DENSITY: DATA NOT AVAILABLE.
RELATIVE DENSITY: 1.05
SOLUBILITY: MISCIBLE
PARTITION COEFFICIENT: DATA NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: DATA NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: DATA NOT AVAILABLE.
VISCOSITY: DATA NOT AVAILABLE.
EXPLOSIVE PROPERTIES: DATA NOT AVAILABLE.
OXIDIZING PROPERTIES: DATA NOT AVAILABLE.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY AND CHEMICAL STABILITY:
STABLE UNDER NORMAL CONDITIONS OF USE AND STORAGE. ACETIC ACID CONTRACTS
SLIGHTLY UPON FREEZING WHICH MAY CAUSE THE CONTAINER TO BURST.
10.2. POSSIBILITY OF HAZARDOUS REACTIONS: DATA NOT AVAILABLE.
10.3. CONDITIONS TO AVOID AND INCOMPATIBLE MATERIALS:
KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. NO SMOKING. KEEP CONTAINER
TIGHTLY CLOSED. KEEP ONLY IN ORIGINAL CONTAINER. STRONG BASES, STRONG
OXIDIZERS, CHROMIC ACID, SODIUM PEROXIDE, NITRIC ACID, PERCHLORIC ACID.
10.4. HAZARDOUS DECOMPOSITION PRODUCTS: WILL NOT OCCUR.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY - ORAL EXPOSURE:
HARMFUL IF SWALLOWED. WASH ARMS, HANDS AND FACE THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
IF SWALLOWED:
CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL. RINSE MOUTH. DISPOSE
OF CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL
REGULATIONS.
ACUTE TOXICITY - DERMAL EXPOSURE:
HARMFUL IN CONTACT WITH SKIN. WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. CALL A POISON CENTER OR PHYSICIAN IF
YOU FEEL UNWELL. SPECIFIC TREATMENT (WASH AREAS OF CONTACT WITH WATER).
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE. DISPOSE OF
CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL
REGULATIONS.
ACUTE TOXICITY - INHALATION EXPOSURE:
HARMFUL IF INHALED. AVOID BREATHING FUMES, MIST, VAPORS, OR SPRAY. USE
ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
ACUTE TOXICITY - OTHER INFORMATION:
LD50, ORAL, RAT (ACETIC ACID):
3310 MG/KG, (ACETIC ANHYDRIDE) 1780 MG/KG
LD50, DERMAL, RABBIT (ACETIC ACID):
1.06 G/KG, DETAILS OF TOXIC EFFECTS NOT REPORTED OTHER THAN LETHAL DOSE
VALUE
LC50, INHALATION, MOUSE (ACETIC ACID):
5620 PPM/1 HR., EYE AND BLOOD EFFECTS NOTED
LD50, ORAL, RAT (PERCHLORIC ACID):
1100 MG/KG, BEHAVIORAL, NUTRITIONAL AND RESPIRATORY EFFECTS NOTED.
SKIN CORROSION AND IRRITATION:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. DO NOT BREATHE FUMES, MIST,
VAPORS, OR SPRAY. WASH ARMS, HANDS AND FACE THOROUGHLY AFTER HANDLING.
WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. IMMEDIATELY
CALL A POISON CENTER OR PHYSICIAN. SPECIFIC TREATMENT (WASH AREAS OF
CONTACT WITH WATER).
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. STORE LOCKED UP. DISPOSE OF
CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL
REGULATIONS.
SERIOUS EYE DAMAGE AND IRRITATION:
CAUSES SERIOUS EYE DAMAGE. WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER OR PHYSICIAN.
RESPIRATORY SENSITIZATION:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
AVOID BREATHING FUMES, MIST, VAPORS, OR SPRAY. IN CASE OF INADEQUATE
VENTILATION WEAR RESPIRATORY PROTECTION.
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR PHYSICIAN. DISPOSE OF CONTENTS IN ACCORDANCE WITH
LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
SKIN SENSITIZATION: NOT APPLICABLE.
GERM CELL MUTAGENICITY: NOT APPLICABLE.
CARCINOGENICITY: NOT APPLICABLE.
REPRODUCTIVE TOXICITY: NOT APPLICABLE.
SPECIFIC TARGET ORGAN TOXICITY FROM SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS. DO NOT BREATHE FUMES, MIST, VAPORS, OR SPRAY.
WASH ARMS, HANDS AND FACE THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK
OR SMOKE WHEN USING THIS PRODUCT.
IF EXPOSED:
CALL A POISON CENTER OR PHYSICIAN. SPECIFIC TREATMENT (WASH AREAS OF
CONTACT WITH WATER). STORE LOCKED UP. DISPOSE OF CONTENTS IN ACCORDANCE
WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
SPECIFIC TARGET ORGAN TOXICITY FROM REPEATED EXPOSURE:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. DO NOT
BREATHE FUMES, MIST, VAPORS, OR SPRAY. WASH ARMS, HANDS AND FACE
THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. GET MEDICAL ATTENTION IF YOU FEEL UNWELL. DISPOSE OF CONTENTS IN
ACCORDANCE WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL REGULATIONS.
ASPIRATION HAZARD: NOT APPLICABLE.
ADDITIONAL TOXICOLOGY INFORMATION: DATA NOT AVAILABLE.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. ECOTOXICITY:
HARMFUL TO AQUATIC LIFE. AVOID RELEASE TO THE ENVIRONMENT. DISPOSE OF
CONTENTS IN ACCORDANCE WITH LOCAL, STATE, FEDERAL AND INTERNATIONAL
REGULATIONS.
12.2. PERSISTENCE AND DEGRADABILITY: DATA NOT AVAILABLE.
12.3. BIOACCUMULATIVE POTENTIAL: DATA NOT AVAILABLE.
12.4. MOBILITY IN SOIL: DATA NOT AVAILABLE.
12.5. OTHER ADVERSE ECOLOGICAL EFFECTS: DATA NOT AVAILABLE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS: DATA NOT AVAILABLE.
| SECTION 14: TRANSPORTATION INFORMATION | |
14.1. TRANSPORTATION BY LAND-DEPARTMENT OF TRANSPORTATION (DOT, UNITED
STATES OF AMERICA):
SIZES: 1 L, 2.5 L, 4 L, 20 L, 120 ML, 500 ML
UN NUMBER: UN2789
PROPER SHIPPING NAME: ACETIC ACID SOLUTION
HAZARD CLASS: 8 (3)
PACKING GROUP: II
HAZARD LABEL(S):
CORROSIVE, CLASS/DIVISION 8
FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
14.2. TRANSPORTATION BY AIR - INTERNATIONAL AIR TRANSPORT ASSOCIATION
(IATA):
SIZES: 1 L, 2.5 L, 4 L, 20 L, 120 ML, 500 ML
UN NUMBER: UN2789
PROPER SHIPPING NAME: ACETIC ACID SOLUTION
HAZARD CLASS: 8 (3)
PACKING GROUP: II
HAZARD LABEL(S):
CORROSIVE, CLASS/DIVISION 8
FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
14.3 TRANSPORTATION OF DANGEROUS GOODS (TDG, CANADA):
SIZES: 1 L, 2.5 L, 4 L, 20 L, 120 ML, 500 ML
UN NUMBER: UN2789
PROPER SHIPPING NAME: ACETIC ACID SOLUTION
HAZARD CLASS: 8 (3)
PACKING GROUP: II
HAZARD LABEL(S):
CLASS 8, CORROSIVES
CLASS 3, FLAMMABLE LIQUIDS
| SECTION 15: REGULATORY INFORMATION | |
15.1. OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA) HAZARDS:
NOT LISTED.
15.2. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) 302 EXTREMELY
HAZARDOUS SUBSTANCES: NOT LISTED.
15.3. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) 311/312
HAZARDOUS CHEMICALS:
ACETIC ANHYDRIDE (CAS # 108-24-7):
5000 LB FINAL RQ
2270 KG FINAL RQ
ACETIC ACID (CAS # 64-19-7):
5000 LB FINAL RQ
2270 KG FINAL RQ
15.4. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) 313 TOXIC
RELEASE INVENTORY (TRI): NOT LISTED.
15.5. MASSACHUSETTS RIGHT-TO-KNOW SUBSTANCE LIST:
ACETIC ANHYDRIDE (CAS # 108-24-7): PRESENT
ACETIC ACID (CAS # 64-19-7): PRESENT
PERCHLORIC ACID (CAS # 7601-90-3): PRESENT
15.6. PENNSYLVANIA RIGHT-TO-KNOW HAZARDOUS SUBSTANCES:
ACETIC ANHYDRIDE (CAS # 108-24-7): ENVIRONMENTAL HAZARD
ACETIC ANHYDRIDE (CAS # 108-24-7): PRESENT
ACETIC ACID (CAS # 64-19-7): ENVIRONMENTAL HAZARD
ACETIC ACID (CAS # 64-19-7): PRESENT
PERCHLORIC ACID (CAS # 7601-90-3): PRESENT
WATER (CAS # 7732-18-5): PRESENT
15.7. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW COMPONENTS:
ACETIC ANHYDRIDE (CAS # 108-24-7): CORROSIVE
ACETIC ANHYDRIDE (CAS # 108-24-7): SN 0005
ACETIC ACID (CAS # 64-19-7): CORROSIVE
ACETIC ACID (CAS # 64-19-7): SN 0004
PERCHLORIC ACID (CAS # 7601-90-3): REACTIVE - THIRD DEGREE
PERCHLORIC ACID (CAS # 7601-90-3): SN 2637
15.8. CALIFORNIA PROPOSITION 65: NOT LISTED.
15.9. CANADA DOMESTIC SUBSTANCES LIST / NON-DOMESTIC SUBSTANCES LIST
(DSL/NDSL):
ACETIC ANHYDRIDE (CAS # 108-24-7): PRESENT (DSL)
ACETIC ACID (CAS # 64-19-7): PRESENT (DSL)
ACETIC ACID (CAS # 64-19-7): PRESENT (NDSL)
PERCHLORIC ACID (CAS # 7601-90-3): PRESENT (DSL)
WATER (CAS # 7732-18-5): PRESENT (DSL)
15.10. UNITED STATES OF AMERICA TOXIC SUBSTANCES CONTROL ACT (TSCA) LIST:
ALL COMPONENTS OF THIS SOLUTION ARE LISTED AS ACTIVE ON THE TSCA INVENTORY
OR ARE MIXTURES (HYDRATES) OF ACTIVE ITEMS LISTED ON THE TSCA INVENTORY.
ACETIC ANHYDRIDE (CAS # 108-24-7): PRESENT
ACETIC ACID (CAS # 64-19-7): PRESENT
PERCHLORIC ACID (CAS # 7601-90-3): PRESENT
WATER (CAS # 7732-18-5): PRESENT
15.11. EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
(EINECS), EUROPEAN:
LIST OF NOTIFIED CHEMICAL SUBSTANCES (ELINCS), AND NO LONGER POLYMERS
(NLP):
ACETIC ANHYDRIDE (CAS # 108-24-7): 203-564-8
ACETIC ANHYDRIDE (CAS # 108-24-7): 240-697-0
ACETIC ACID (CAS # 64-19-7): 200-580-7
ACETIC ACID (CAS # 64-19-7): 212-059-1
ACETIC ACID (CAS # 64-19-7): 214-693-4
ACETIC ACID (CAS # 64-19-7): 273-079-4
PERCHLORIC ACID (CAS # 7601-90-3): 231-512-4
WATER (CAS # 7732-18-5): 231-791-2
WATER (CAS # 7732-18-5): 232-148-9
| SECTION 16: OTHER INFORMATION | |
16.1. FULL TEXT OF HAZARD STATEMENTS AND PRECAUTIONARY STATEMENTS:
FLAMMABLE LIQUID AND VAPOR. MAY BE CORROSIVE TO METALS. HARMFUL IF
SWALLOWED. HARMFUL IN CONTACT WITH SKIN. CAUSES SEVERE SKIN BURNS AND EYE
DAMAGE. CAUSES SERIOUS EYE DAMAGE. HARMFUL IF INHALED. MAY CAUSE ALLERGY
OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED. CAUSES DAMAGE TO
ORGANS. CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
HARMFUL TO AQUATIC LIFE.
KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. NO SMOKING. KEEP CONTAINER
TIGHTLY CLOSED. KEEP ONLY IN ORIGINAL CONTAINER. GROUND CONTAINER AND
RECEIVING EQUIPMENT. USE EXPLOSION-PROOF EQUIPMENT. USE ONLY NON-SPARKING
TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. DO NOT
BREATHE FUMES, MIST, VAPORS, OR SPRAY. WASH ARMS, HANDS AND FACE THOROUGHLY
AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. USE
ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. AVOID RELEASE TO THE
ENVIRONMENT. WEAR PROTECTIVE GLOVES AND EYE PROTECTION. IN CASE OF
INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
IF SWALLOWED: CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED:
CALL A POISON CENTER OR PHYSICIAN. GET MEDICAL ATTENTION IF YOU FEEL
UNWELL. SPECIFIC TREATMENT (WASH AREAS OF CONTACT WITH WATER).
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR PHYSICIAN. TAKE OFF CONTAMINATED CLOTHING AND WASH
IT BEFORE REUSE.
IN CASE OF FIRE:
USE DRY CHEMICAL, FOAM OR CARBON DIOXIDE TO EXTINGUISH. ABSORB SPILLAGE
TO PREVENT MATERIAL DAMAGE.
STORE IN A WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP. STORE
IN CORROSIVE RESISTANT CONTAINER WITH A RESISTANT INNER LINER.
16.2. MISCELLANEOUS HAZARD CLASSES:
CANADIAN CARCINOGENICITY HAZARD CLASS: NOT APPLICABLE.
PHYSICAL HAZARDS NOT OTHERWISE CLASSIFIED (PHNOC): NOT APPLICABLE.
HEALTH HAZARDS NOT OTHERWISE CLASSIFIED (HHNOC): NOT APPLICABLE.
BIOHAZARDOUS INFECTIOUS MATERIALS HAZARD CLASS: NOT APPLICABLE.
16.3. NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RATING:
HEALTH 3
FLAMMABILITY 2
REACTIVITY 0
SPECIAL HAZARD
16.4. DOCUMENT REVISION:
LAST REVISION DATE: 2021-10-06
DISCLAIMER:
WHEN HANDLED PROPERLY BY QUALIFIED PERSONNEL, THE PRODUCT DESCRIBED HEREIN
DOES NOT PRESENT A SIGNIFICANT HEALTH OR SAFETY HAZARD. ALTERATION OF
ITS CHARACTERISTICS BY CONCENTRATION, EVAPORATION, ADDITION OF OTHER
SUBSTANCES, OR OTHER MEANS MAY PRESENT HAZARDS NOT SPECIFICALLY ADDRESSED
HEREIN AND WHICH MUST BE EVALUATED BY THE USER. THE INFORMATION FURNISHED
HEREIN IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST DATA CURRENTLY
AVAILABLE TO US. NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE AND RICCA
CHEMICAL COMPANY ASSUMES NO LEGAL RESPONSIBILITY OR LIABILITY WHATSOEVER
RESULTING FROM ITS USE.