| Common Name: | HYDROGEN SULFIDE (0.0001% - 0.05 %) IN NITROGEN, 50248 |
| Manufacturer: | CALGAZ |
| SDS Revision Date: | 3/9/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 39GD98, 45GP39, 45GP41, 55PV60, 60JJ75 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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INDUSTRIAL SCIENTIFIC
SAFETY DATA SHEET
50248
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26,
2012 / RULES AND REGULATIONS
HYDROGEN SULFIDE (0.0001% - 0.05 %) IN NITROGEN
DATE OF ISSUE: 03/09/2015
VERSION: 1.0
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
PRODUCT NAME: HYDROGEN SULFIDE (0.0001% - 0.05 %) IN NITROGEN
REPLACES ISC MSDS NO.:
1810-0859, 1810-2245, 1810-2304, 1810-2970, 1810-2988, 1810-4216B,
1810-4984, 1810-6633, 1810-7458, 1810-8274, 1810-9078, 1810-9090,
1810-9096, 1810-9100, 1810-9132
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES
ADVISED AGAINST:
USE OF THE SUBSTANCE/MIXTURE: TEST GAS/CALIBRATION GAS.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
U.S. SUPPLIER:
INDUSTRIAL SCIENTIFIC CORPORATION
1 LIFE WAY
PITTSBURGH, PA 15205-7500
PHONE: (412) 788-4353
TOLL-FREE 800-DETECTS
FAX: (412) 788-8353
MANUFACTURER:
CALGAZ
821 CHESAPEAKE DRIVE
CAMBRIDGE, MD 21613
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300
INTERNATIONALLY: 1-703-527-3887
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION (GHS-US):
COMPRESSED GAS: H280
FULL TEXT OF H-PHRASES: SEE SECTION 16
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS04: GAS CYLINDER
SIGNAL WORD (GHS-US): WARNING
HAZARD STATEMENTS (GHS-US):
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
PRECAUTIONARY STATEMENTS (GHS-US):
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
P313: GET MEDICAL ADVICE/ATTENTION
P403: STORE IN A WELL-VENTILATED PLACE
CGA-PG02:
PROTECT FROM SUNLIGHT WHEN AMBIENT TEMPERATURE EXCEEDS 52 DEG. C (125 DEG.
F)
CGA-PG05: USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING
CGA-PG06: CLOSE VALVE AFTER EACH USE AND WHEN EMPTY
CGA-PG10: USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE
CGA-PG14: APPROACH SUSPECTED LEAK AREA WITH CAUTION
CGA-PG21: OPEN VALVE SLOWLY
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % CLASSIFICATION (GHS-US)
NITROGEN (CAS NO) 7727-37-9 99.95 - COMPRESSED GAS, H280
99.9999
HYDROGEN SULFIDE (CAS NO) 7783-06-4 0.0001 - FLAM. GAS 1, H220
0.05 LIQUEFIED GAS, H280
ACUTE TOX. 2 (INHALATION:
GAS),
H330
STOT SE 3, H335
AQUATIC ACUTE 1, H400
FULL TEXT OF H-PHRASES: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE.
FIRST-AID MEASURES AFTER SKIN CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
FIRST-AID MEASURES AFTER EYE CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
FIRST-AID MEASURES AFTER INGESTION:
INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES AFTER INHALATION:
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION. MAY CAUSE RESPIRATORY
IRRITATION.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
SYMPTOMS/INJURIES AFTER INGESTION:
INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
SYMPTOMS/INJURIES UPON INTRAVENOUS ADMINISTRATION: NOT KNOWN.
CHRONIC SYMPTOMS: ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL
TREATMENT NEEDED:
IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE. IF BREATHING IS DIFFICULT, GIVE
OXYGEN. OBTAIN MEDICAL ATTENTION IF BREATHING DIFFICULTY PERSISTS.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER JET.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: THE PRODUCT IS NOT FLAMMABLE.
EXPLOSION HAZARD:
PRODUCT IS NOT EXPLOSIVE. HEAT MAY BUILD PRESSURE, RUPTURING CLOSED
CONTAINERS, SPREADING FIRE AND INCREASING RISK OF BURNS AND INJURIES.
REACTIVITY: NONE KNOWN.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
IN CASE OF FIRE:
EVACUATE AREA. FIGHT FIRE REMOTELY DUE TO THE RISK OF EXPLOSION. USE WATER
SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION WHEN
FIGHTING ANY CHEMICAL FIRE.
PROTECTION DURING FIREFIGHTING:
STANDARD PROTECTIVE CLOTHING AND EQUIPMENT (E.G., SELF CONTAINED BREATHING
APPARATUS) FOR FIRE FIGHTERS. DO NOT ENTER FIRE AREA WITHOUT PROPER
PROTECTIVE
EQUIPMENT, INCLUDING RESPIRATORY PROTECTION.
SPECIFIC METHODS:
EXPOSURE TO FIRE MAY CAUSE CONTAINERS TO RUPTURE/EXPLODE. CONTINUE WATER
SPRAY FROM PROTECTED POSITION UNTIL CONTAINER STAYS COOL. MOVE CONTAINERS
AWAY
FROM
THE FIRE AREA IF THIS CAN BE DONE WITHOUT RISK.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES: ENSURE ADEQUATE VENTILATION.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
WEAR PROTECTIVE EQUIPMENT CONSISTENT WITH THE SITE EMERGENCY PLAN.
EMERGENCY PROCEDURES:
ESCAPE THE DANGER AREA BY THE CLOSEST SAFE ROUTE. CLOSE DOORS AND WINDOWS
OF ADJACENT PREMISES. KEEP CONTAINERS CLOSED. MARK THE DANGER AREA. SEAL
OFF LOW-LYING AREAS. KEEP UPWIND.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
STANDARD PROTECTIVE CLOTHING AND EQUIPMENT (E.G., SELF CONTAINED BREATHING
APPARATUS) FOR FIRE FIGHTERS. EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: EVACUATE AND LIMIT ACCESS. VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS: TRY TO STOP RELEASE IF SAFE TO DO SO.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT: TRY TO STOP RELEASE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
DISPOSE OF THIS MATERIAL AND ITS CONTAINER IN ACCORDANCE WITH LOCAL
REGULATIONS.
6.4. REFERENCE TO OTHER SECTIONS: SEE ALSO SECTIONS 8 AND 13.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. USE EQUIPMENT RATED FOR CYLINDER
PRESSURE.
PRECAUTIONS FOR SAFE HANDLING:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
SAFE HANDLING OF THE GAS RECEPTACLE:
PROTECT CYLINDERS FROM PHYSICAL DAMAGE; DO NOT DRAG, ROLL, SLIDE OR DROP. DO
NOT REMOVE OR DEFACE LABELS PROVIDED BY THE SUPPLIER FOR THE IDENTIFICATION
OF THE CYLINDER CONTENTS.
SAFE USE OF THE PRODUCT:
THE SUBSTANCE MUST BE HANDLED IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE
AND SAFETY PROCEDURES. ONLY EXPERIENCED AND PROPERLY INSTRUCTED PERSONS
SHOULD HANDLE GASES UNDER PRESSURE. CONSIDER PRESSURE RELIEF DEVICE(S) IN
GAS INSTALLATIONS. ENSURE THE COMPLETE GAS SYSTEM WAS (OR IS REGULARILY)
CHECKED FOR LEAKS BEFORE USE. DO NOT REMOVE OR DEFACE LABELS PROVIDED BY
THE SUPPLIER FOR THE IDENTIFICATION OF THE CYLINDER CONTENTS. USE ONLY
PROPERLY SPECIFIED EQUIPMENT WHICH IS SUITABLE FOR THIS PRODUCT, ITS
SUPPLY PRESSURE AND TEMPERATURE. CONTACT YOUR GAS SUPPLIER IF IN DOUBT.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. OBSERVE VERY STRICT
HYGIENE - AVOID CONTACT.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES: COMPLY WITH APPLICABLE REGULATIONS.
STORAGE CONDITIONS:
DO NOT EXPOSE TO TEMPERATURES EXCEEDING 52 DEG. C (125 DEG. F). KEEP
CONTAINER CLOSED WHEN NOT IN USE. PROTECT CYLINDER FROM PHYSICAL DAMAGE.
STORE IN WELL VENTILATED AREA.
INCOMPATIBLE PRODUCTS: NONE KNOWN.
INCOMPATIBLE MATERIALS: NONE KNOWN. NITRIC ACID.
STORAGE AREA: STORE AWAY FROM HEAT. STORE IN A WELL-VENTILATED PLACE.
7.3. SPECIFIC END USE(S): SEE SECTION 1.2.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
HYDROGEN SULFIDE (0.0001% - 0.05 %) IN NITROGEN:
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
NITROGEN (7727-37-9):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
HYDROGEN SULFIDE (7783-06-4):
ACGIH:
ACGIH TWA (PPM): 1 PPM
ACGIH:
ACGIH STEL (PPM): 5 PPM
OSHA:
OSHA PEL (CEILING) (PPM): 20 PPM
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
ALARM DETECTORS SHOULD BE USED WHEN TOXIC GASES MAY BE RELEASED. OXYGEN
DETECTORS SHOULD BE USED WHEN ASPHYXIATING GASES MAY BE RELEASED. PROVIDE
ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION. SYSTEMS UNDER PRESSURE
SHOULD BE REGULARLY CHECKED FOR LEAKAGES. CONSIDER WORK PERMIT SYSTEM E.G.
FOR MAINTENANCE ACTIVITIES. ENSURE EXPOSURE IS BELOW OCCUPATIONAL EXPOSURE
LIMITS.
HAND PROTECTION:
WEAR WORKING GLOVES WHEN HANDLING GAS CONTAINERS. 29 CFR 1910.138:
HAND PROTECTION.
EYE PROTECTION:
WEAR SAFETY GLASSES WITH SIDE SHIELDS. 29 CFR 1910.133:
EYE AND FACE PROTECTION.
SKIN AND BODY PROTECTION:
WEAR SUITABLE PROTECTIVE CLOTHING, E.G. - LAB COATS, COVERALLS OR FLAME
RESISTANT CLOTHING.
RESPIRATORY PROTECTION:
NONE NECESSARY DURING NORMAL AND ROUTINE OPERATIONS. SEE SECTIONS 5 & 6.
THERMAL HAZARD PROTECTION:
NONE NECESSARY DURING NORMAL AND ROUTINE OPERATIONS.
ENVIRONMENTAL EXPOSURE CONTROLS:
REFER TO LOCAL REGULATIONS FOR RESTRICTION OF EMISSIONS TO THE ATMOSPHERE.
SEE SECTION 13 FOR SPECIFIC METHODS FOR WASTE GAS TREATMENT.
OTHER INFORMATION:
WEAR SAFETY SHOES WHILE HANDLING CONTAINERS. 29 CFR 1910.136: FOOT
PROTECTION.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: GAS
APPEARANCE: CLEAR, COLORLESS GAS.
COLOR: COLORLESS
ODOR: SULFIDE-LIKE ROTTEN EGGS
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE FOR GAS-MIXTURES.
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (ETHER=1): NOT APPLICABLE FOR GAS-MIXTURES.
FLAMMABILITY (SOLID, GAS): SEE SECT. 2.1 & 2.2
EXPLOSION LIMITS: NOT APPLICABLE - NOT FLAMMABLE
EXPLOSIVE PROPERTIES: NOT APPLICABLE - NOT FLAMMABLE.
OXIDIZING PROPERTIES: NONE.
VAPOR PRESSURE: NOT APPLICABLE.
RELATIVE DENSITY: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
MOLECULAR MASS: NOT APPLICABLE FOR GAS-MIXTURES.
RELATIVE GAS DENSITY: LIGHTER OR SIMILAR TO AIR.
SOLUBILITY:
WATER:
SOLUBILITY IN WATER OF COMPONENT(S) OF THE MIXTURE:
20 MG/L
3980 MG/L
LOG POW : NOT APPLICABLE FOR GAS-MIXTURES.
LOG KOW : NOT APPLICABLE FOR GAS-MIXTURES.
AUTO-IGNITION TEMPERATURE : NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE : NO DATA AVAILABLE
VISCOSITY : NO DATA AVAILABLE
VISCOSITY, KINEMATIC : NOT APPLICABLE.
VISCOSITY, DYNAMIC : NOT APPLICABLE.
9.2. OTHER INFORMATION:
ADDITIONAL INFORMATION: NONE.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NONE KNOWN.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
NONE KNOWN. HYDROGEN SULFIDE CAN FORM EXPLOSIVE COMPOUNDS WITH NITRIC ACID.
10.4. CONDITIONS TO AVOID:
NONE UNDER RECOMMENDED STORAGE AND HANDLING CONDITIONS (SEE SECTION 7).
STORAGE NEAR NITRIC ACID.
10.5. INCOMPATIBLE MATERIALS: NONE KNOWN.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE HAZARDOUS DECOMPOSITION PRODUCTS
SHOULD NOT BE PRODUCED.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
NITROGEN (7727-37-9):
LC50 INHALATION RAT (PPM): 820000 PPM/4H
HYDROGEN SULFIDE (7783-06-4):
LC50 INHALATION RAT (MG/L): 0.99 MG/L (EXPOSURE TIME: 1 H)
LC50 INHALATION RAT (PPM): 356 PPM/4H
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE FOR GAS-MIXTURES.
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE FOR GAS-MIXTURES.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
SYMPTOMS/INJURIES AFTER INHALATION:
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION. MAY CAUSE RESPIRATORY
IRRITATION.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
SYMPTOMS/INJURIES AFTER INGESTION:
INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
SYMPTOMS/INJURIES UPON INTRAVENOUS ADMINISTRATION: NOT KNOWN.
CHRONIC SYMPTOMS: ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL: CLASSIFICATION CRITERIA ARE NOT MET.
HYDROGEN SULFIDE (7783-06-4):
LC50 FISH 1:
0.0448 MG/L (EXPOSURE TIME:
96 H - SPECIES: LEPOMIS MACROCHIRUS [FLOW-THROUGH])
EC50 DAPHNIA 1:
0.022 MG/L (EXPOSURE TIME:
96 H - SPECIES: GAMMARUS PSEUDOLIMNAEUS)
LC50 FISH 2:
0.016 MG/L (EXPOSURE TIME:
96 H - SPECIES: PIMEPHALES PROMELAS [FLOW-THROUGH])
12.2. PERSISTENCE AND DEGRADABILITY:
HYDROGEN SULFIDE (0.0001% - 0.05 %) IN NITROGEN:
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE.
NITROGEN (7727-37-9)
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
HYDROGEN SULFIDE (7783-06-4):
PERSISTENCE AND DEGRADABILITY: NOT APPLICABLE FOR INORGANIC GASES.
12.3. BIOACCUMULATIVE POTENTIAL:
HYDROGEN SULFIDE (0.0001% - 0.05 %) IN NITROGEN:
LOG POW: NOT APPLICABLE FOR GAS-MIXTURES.
LOG KOW: NOT APPLICABLE FOR GAS-MIXTURES.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
NITROGEN (7727-37-9):
LOG POW: NOT APPLICABLE FOR INORGANIC GASES.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
HYDROGEN SULFIDE (7783-06-4):
BCF FISH 1: (NO BIOACCUMULATION EXPECTED)
LOG POW: NOT APPLICABLE FOR INORGANIC GASES.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
12.4. MOBILITY IN SOIL:
HYDROGEN SULFIDE (0.0001% - 0.05 %) IN NITROGEN:
MOBILITY IN SOIL: NO DATA AVAILABLE.
NITROGEN (7727-37-9):
ECOLOGY - SOIL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
HYDROGEN SULFIDE (7783-06-4):
ECOLOGY - SOIL:
BECAUSE OF ITS HIGH VOLATILITY, THE PRODUCT IS UNLIKELY TO CAUSE GROUND OR
WATER POLLUTION.
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON OZONE LAYER: NONE.
EFFECT ON THE GLOBAL WARMING:
NO KNOWN ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE TREATMENT METHODS:
CONTACT SUPPLIER IF GUIDANCE IS REQUIRED. DO NOT DISCHARGE INTO ANY PLACE
WHERE ITS ACCUMULATION COULD BE DANGEROUS. ENSURE THAT THE EMISSION LEVELS
FROM LOCAL REGULATIONS OR OPERATING PERMITS ARE NOT EXCEEDED.
WASTE DISPOSAL RECOMMENDATIONS:
REFER TO THE CGA PAMPHLET P-63 "DISPOSAL OF GASES" AVAILABLE AT WWW.CGANET
.COM
FOR MORE GUIDANCE ON SUITABLE DISPOSAL METHODS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1956 COMPRESSED GAS, N.O.S.
UN-NO.(DOT): UN1956
PROPER SHIPPING NAME (DOT): COMPRESSED GAS, N.O.S.
HAZARD LABELS (DOT): 2.2 - NON-FLAMMABLE GAS
DOT PACKAGING NON BULK (49 CFR 173.XXX): 302; 305
DOT PACKAGING BULK (49 CFR 173.XXX): 314; 315
DOT SYMBOLS: G - IDENTIFIES PSN REQUIRING A TECHNICAL NAME
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 306; 307
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 75 KG
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 150 KG
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
ADDITIONAL INFORMATION:
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
SPECIAL TRANSPORT PRECAUTIONS:
AVOID TRANSPORT ON VEHICLES WHERE THE LOAD SPACE IS NOT SEPARATED FROM THE
DRIVER'S COMPARTMENT. ENSURE VEHICLE DRIVER IS AWARE OF THE POTENTIAL
HAZARDS OF THE LOAD AND KNOWS WHAT TO DO IN THE EVENT OF AN ACCIDENT OR AN
EMERGENCY.
BEFORE TRANSPORTING PRODUCT CONTAINERS:
ENSURE THERE IS ADEQUATE VENTILATION.
ENSURE THAT CONTAINERS ARE FIRMLY SECURED.
ENSURE CYLINDER VALVE IS CLOSED AND NOT LEAKING.
ENSURE VALVE OUTLET CAP NUT OR PLUG (WHERE PROVIDED) IS CORRECTLY FITTED.
ENSURE VALVE PROTECTION DEVICE (WHERE PROVIDED) IS CORRECTLY FITTED.
ADR:
TRANSPORT DOCUMENT DESCRIPTION: UN 1956 COMPRESSED GAS, N.O.S., 2.2
CLASS (ADR): 2 - GASES
HAZARD LABELS (ADR): 2.2 - NON-FLAMMABLE COMPRESSED GAS
TRANSPORT BY SEA:
UN-NO. (IMDG): 1956
PROPER SHIPPING NAME (IMDG): COMPRESSED GAS, N.O.S.
CLASS (IMDG): 2.2 - NON-FLAMMABLE, NON-TOXIC GASES
AIR TRANSPORT:
UN-NO.(IATA): 1956
PROPER SHIPPING NAME (IATA): COMPRESSED GAS, N.O.S.
CLASS (IATA): 2
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
NITROGEN (7727-37-9):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
HYDROGEN SULFIDE (7783-06-4):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
LISTED ON THE UNITED STATES SARA SECTION 302
LISTED ON UNITED STATES SARA SECTION 313
SARA SECTION 302 THRESHOLD PLANNING QUANTITY (TPQ): 500
SARA SECTION 313 - EMISSION REPORTING: 1.0%
15.2. INTERNATIONAL REGULATIONS:
CANADA:
NITROGEN (7727-37-9):
LISTED ON THE CANADIAN DSL (DOMESTIC SUSTANCES LIST):
WHMIS CLASSIFICATION: CLASS A - COMPRESSED GAS
HYDROGEN SULFIDE (7783-06-4):
LISTED ON THE CANADIAN DSL (DOMESTIC SUSTANCES LIST):
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS B DIVISION 1 - FLAMMABLE GAS
CLASS D DIVISION 1 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING IMMEDIATE AND
SERIOUS TOXIC EFFECTS
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
EU-REGULATIONS:
NITROGEN (7727-37-9):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL
CHEMICAL SUBSTANCES)
HYDROGEN SULFIDE (7783-06-4):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL
CHEMICAL SUBSTANCES)
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]: NOT
CLASSIFIED
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC [DSD] OR 1999/45/EC [DPD]:
NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
NITROGEN (7727-37-9):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES)
HYDROGEN SULFIDE (7783-06-4):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICAL SUBSTANCES) INVENTORY
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES)
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
NITROGEN (7727-37-9):
U.S. - MASSACHUSETTS: RIGHT TO KNOW LIST
U.S. - NEW JERSEY: RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA: RTK (RIGHT TO KNOW) LIST
HYDROGEN SULFIDE (7783-06-4):
U.S. - MASSACHUSETTS: RIGHT TO KNOW LIST
U.S. - NEW JERSEY: RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA: RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA: RTK (RIGHT TO KNOW) LIST
| SECTION 16: OTHER INFORMATION | |
INDICATION OF CHANGES:
REVISED SAFETY DATA SHEET IN ACCORDANCE WITH OSHA FINAL RULE ON GHS
IMPLEMENTATION PROMULGATED MARCH 26, 2012.
OTHER INFORMATION:
THIS SAFETY DATA SHEET IS OFFERED PURSUANT TO OSHA'S HAZARD COMMUNICATION
STANDARD, 29 CFR, 1910.1200. OTHER GOVERNMENT REGULATIONS MUST BE REVIEWED
FOR APPLICABILITY TO THIS PRODUCT.
FULL TEXT OF H-PHRASES:
ACUTE TOX. 2 (INHALATION:GAS): ACUTE TOXICITY (INHALATION:GAS) CATEGORY 2
AQUATIC ACUTE 1: HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD
CATEGORY 1
COMPRESSED GAS: GASES UNDER PRESSURE COMPRESSED GAS
FLAM. GAS 1: FLAMMABLE GASES CATEGORY 1
LIQUEFIED GAS: GASES UNDER PRESSURE LIQUEFIED GAS
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3
H220: EXTREMELY FLAMMABLE GAS
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H330: FATAL IF INHALED
H335: MAY CAUSE RESPIRATORY IRRITATION
H400 VERY TOXIC TO AQUATIC LIFE
SDS US (GHS HAZCOM 2012)
THIS SAFETY DATA SHEET IS OFFERED PURSUANT TO OSHA'S HAZARD COMMUNICATION
STANDARD, 29 CFR, 1910.1200. OTHER GOVERNMENT REGULATIONS MUST BE REVIEWED
FOR APPLICABILITY TO THIS GAS MIXTURE. TO THE BEST OF CALGAZ'S KNOWLEDGE,
THE INFORMATION CONTAINED HEREIN IS RELIABLE AND ACCURATE AS OF THIS DATE;
HOWEVER, ACCRUACY, SUITABILITY OR COMPLETENESS ARE NOT GUARANTEED AND NO
WARRANTIES OF ANY TYPE, EITHER EXPRESS OR IMPLIED, ARE PROVIDED. THE
INFORMATION CONTAINED HEREIN RELATES ONLY TO THIS SPECIFIC PRODUCT. IF
THIS GAS MIXTURE IS COMBINED WITH OTHER MATERIALS, ALL COMPONENT PROPERTIES
MUST BE CONSIDERED. DATA MAY BE CHANGED FROM TIME TO TIME. BE SURE TO
CONSULT
THE LATEST EDITION.
04/27/2015
SDS ID: 50248 / P/N 3602
EN (ENGLISH US)