| Common Name: | CLOVER SILICON CARBIDE GREASE MIX, 39549 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 3/3/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 45JT13 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 004.0
ISSUE DATE: 03/03/2017
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: CLOVER SILICON CARBIDE GREASE MIX
PRODUCT TYPE: SHARPENING COMPOUND
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 233169
ITEM NUMBER: 39549
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE CANCER.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
CARCINOGENICITY 1A
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S):
HEALTH HAZARD
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING VAPORS, MIST, OR
SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR
IN A WELL-VENTILATED AREA. WEAR PROTECTIVE GLOVES, CLOTHING, EYE AND FACE
PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
SILICON CARBIDE 409-21-2 20 - 30
DISTILLATES (PETROLEUM), 64742-52-5 20 - 30
HYDROTREATED
HEAVY NAPHTHENIC
PETROLEUM DISTILLATES, 64742-53-6 20 - 30
HYDROTREATED, LIGHT
NAPHTHENIC
CRISTOBALITE 14464-46-1 0.1 - 1
*EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
INGESTION:
IF CONSCIOUS, DRINK PLENTY OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SILICON. TOXIC AND IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER,
UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED MATERIAL AND PLACE IN A
CLOSED CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING VAPORS OR MISTS
OF THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
FOR INFORMATION ON PRODUCT SHELF LIFE, PLEASE REVIEW LABELS ON CONTAINER OR
CHECK THE TECHNICAL DATA SHEET.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA OTHER
WEEL
SILICON CARBIDE 3 MG/M3 TWA 5 MG/M3 PEL NONE NONE
RESPIRABLE RESPIRABLE
FRACTION. FRACTION.
10 MG/M3 TWA 15 MG/M3 PEL
INHALABLE TOTAL DUST.
FRACTION. 5 MG/M3 TWA
0.1 FIBERS/CM3 RESPIRABLE
TWA FIBER. FRACTION.
15 MPPCF TWA
RESPIRABLE
FRACTION.
15 MG/M3 TWA
TOTAL DUST.
50 MPPCF TWA
TOTAL DUST.
DISTILLATES 5 MG/M3 TWA 5 MG/M3 TWA MIST NONE NONE
(PETROLEUM), INHALABLE 500 PPM (2,000
HYDROTREATED FRACTION. MG/M3) PEL
HEAVY NAPHTHENIC 5 MG/M3 TWA 5 MG/M3 PEL MIST.
MIST
10 MG/M3 STEL
MIST
PETROLEUM 5 MG/M3 TWA 5 MG/M3 PEL MIST. NONE NONE
DISTILLATES, INHALABLE 500 PPM (2,000
HYDROTREATED, FRACTION. MG/M3) PEL
LIGHT NAPHTHENIC
CRISTOBALITE 0.025 MG/M3 1.2 MPPCF TWA NONE NONE
TWA RESPIRABLE.
RESPIRABLE 0.05 MG/M3 TWA
FRACTION. RESPIRABLE.
0.05 MG/M3 TWA
(RESPIRABLE
DUST.)
(RESPIRABLE
DUST.)
0.025 MG/M3
OSHA_ACT
(RESPIRABLE
DUST.)
0.05 MG/M3 PEL
RESPIRABLE
DUST.
ENGINEERING CONTROLS:
LOCAL EXHAUST VENTILATION IS RECOMMENDED WHEN GENERAL VENTILATION IS NOT
SUFFICIENT TO CONTROL AIRBORNE CONTAMINATION.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID, PASTE
COLOR: GRAY
ODOR: MILD, PETROLEUM
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: 285 - 900 DEG. F (140.6 - 482.2 DEG. C)
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.3548
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: >93 DEG. C (>199.4 DEG. F) CLEVELAND OPEN CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0%; 0 G/L ESTIMATED
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NOT AVAILABLE.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. HYDROCARBONS. IRRITATING ORGANIC FRAGMENTS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: STABLE
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION. CHRONIC EXPOSURE TO DUST CONTAINING
QUARTZ SILICA IN EXCESS OF EXPOSURE LIMITS CAN CAUSE SILICOSIS.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
SILICON CARBIDE NONE NUISANCE DUST
DISTILLATES (PETROLEUM), NONE IRRITANT
HYDROTREATED
HEAVY NAPHTHENIC
PETROLEUM DISTILLATES, NONE IRRITANT
HYDROTREATED, LIGHT
NAPHTHENIC
CRISTOBALITE NONE CARCINOGEN, IMMUNE SYSTEM,
KIDNEY, LUNG
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
SILICON CARBIDE NO GROUP 2A NO
DISTILLATES (PETROLEUM), NO NO NO
HYDROTREATED
HEAVY NAPHTHENIC
PETROLEUM DISTILLATES, NO NO NO
HYDROTREATED, LIGHT
NAPHTHENIC
CRISTOBALITE KNOWN TO BE GROUP 1 YES
HUMAN
CARCINOGEN.
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES
TO THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: TIMOTHY PRATT, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 03/03/2017
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.