| Common Name: | LOCTITE SIL GM 120 GRIT KNOWN AS CLOVER SIL CARBIDE GRS MIX 120, 39598_79504000, |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 5/13/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 45JT32 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 003.0
ISSUE DATE: 05/13/2014
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE SIL GM 120 GRIT KNOWN AS CLOVER SIL CARBIDE GRS MIX 120.
IDH NUMBER: 702079
PRODUCT TYPE: SHARPENING COMPOUND
ITEM NUMBER: 39598_79504000
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH THOROUGHLY AFTER HANDLING. USE
ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR EYE AND FACE PROTECTION.
WEAR PROTECTIVE GLOVES.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING. CALL A POISON CONTROL CENTER
OR PHYSICIAN IF YOU FEEL UNWELL.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
DISTILLATES (PETROLEUM), HYDROTREATED 64742-52-5 30 - 60
HEAVY NAPHTHENIC
SILICON CARBIDE 409-21-2 30 - 60
TALLOW, CALCIUM SALT 68309-87-5 10 - 30
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
INGESTION:
IF CONSCIOUS, DRINK PLENTY OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: CARBON DIOXIDE, FOAM, POWDER
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON, OXIDES OF NITROGEN, IRRITATING ORGANIC VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER,
UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED MATERIAL AND PLACE IN A
CLOSED CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING VAPORS OR MISTS
OF THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT:
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA OTHER
WEEL
DISTILLATES (PETROLEUM), 5 MG/M3 TWA 5 MG/M3 TWA MIST NONE NONE
HYDROTREATED MIST 10 MG/M3 500 PPM (2,000
HEAVY NAPHTHENIC STEL MIST MG/M3) PEL
5 MG/M3 PEL
MIST.
SILICON CARBIDE 10 MG/M3 TWA 5 MG/M3 PEL NONE NONE
INHALABLE RESPIRABLE
FRACTION. FRACTION.
3 MG/M3 TWA 15 MG/M3 PEL
RESPIRABLE TOTAL DUST.
FRACTION.
0.1 FIBERS/CM3
TWA FIBER.
TALLOW, CALCIUM SALT NONE NONE NONE NONE
ENGINEERING CONTROLS:
LOCAL EXHAUST VENTILATION IS RECOMMENDED WHEN GENERAL VENTILATION IS NOT
SUFFICIENT TO CONTROL AIRBORNE CONTAMINATION. LOCAL EXHAUST VENTILATION IS
RECOMMENDED WHEN GENERAL VENTILATION IS NOT SUFFICIENT TO CONTROL AIRBORNE
CONTAMINATION.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID, PASTE
COLOR: GRAY
ODOR: MILD, PETROLEUM
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE. NOT AVAILABLE.
BOILING POINT/RANGE: 141 - 482 DEG. C (285.8 - 899.6 DEG. F)
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.3548
VAPOR DENSITY: HEAVIER THAN AIR.
FLASH POINT:
>93 DEG. C (>199.4 DEG. F) HST-US D09F; FLASH/FIRE POINT BY CLEVELAND OPEN
CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: LESS THAN BUTYL ACETATE.
SOLUBILITY IN WATER: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0%; 0 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. HYDROCARBONS ACRID SMOKE AND FUMES.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: STABLE
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: NOT EXPECTED TO BE HARMFUL BY INGESTION.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND
DELAYED HEALTH
EFFECTS
DISTILLATES (PETROLEUM), HYDROTREATED NONE IRRITANT
HEAVY NAPHTHENIC
SILICON CARBIDE NONE NUISANCE DUST
TALLOW, CALCIUM SALT NONE NO RECORDS
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
DISTILLATES (PETROLEUM), NO NO NO
HYDROTREATED HEAVY
NAPHTHENIC
SILICON CARBIDE NO NO NO
TALLOW, CALCIUM SALT NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
DO NOT EMPTY INTO DRAINS / SURFACE WATER / GROUND WATER.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: LOU FABRIZIO, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 05/13/2014
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 003.0
ISSUE DATE: 08/06/2014
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: SILICON GM 280 GRIT 2 OZ CN
IDH NUMBER: 234968
PRODUCT TYPE: SHARPENING COMPOUND
ITEM NUMBER: 30569
RESTRICTION OF USE: NONE
IDENTIFIED REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH THOROUGHLY AFTER HANDLING. USE
ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR EYE AND FACE PROTECTION.
WEAR PROTECTIVE GLOVES.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING. CALL A POISON CONTROL CENTER
OR PHYSICIAN IF YOU FEEL UNWELL.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
DISTILLATES (PETROLEUM), HYDROTREATED 64742-52-5 30 - 60
HEAVY NAPHTHENIC
SILICON CARBIDE 409-21-2 30 - 60
TALLOW, CALCIUM SALT 68309-87-5 10 - 30
SILICON 7440-21-3 0.1 - 1
CRISTOBALITE 14464-46-1 0.1 - 1
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
INGESTION:
IF CONSCIOUS, DRINK PLENTY OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: CARBON DIOXIDE, FOAM, POWDER
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON, OXIDES OF NITROGEN, IRRITATING ORGANIC VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER,
UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED MATERIAL AND PLACE IN A
CLOSED CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING VAPORS OR MISTS
OF THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT:
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA OTHER
WEEL
DISTILLATES (PETROLEUM), 5 MG/M3 TWA MIST 5 MG/M3 TWA MIST NONE NONE
HYDROTREATED 10 MG/M3 STEL 500 PPM (2,000
HEAVY NAPHTHENIC MIST MG/M3) PEL
5 MG/M3 PEL
MIST.
SILICON CARBIDE 10 MG/M3 TWA 5 MG/M3 PEL NONE NONE
INHALABLE RESPIRABLE
FRACTION. FRACTION.
3 MG/M3 TWA 15 MG/M3 PEL
RESPIRABLE TOTAL DUST.
FRACTION.
0.1 FIBERS/CM3
TWA FIBER.
TALLOW, CALCIUM SALT NONE NONE NONE NONE
SILICON NONE 5 MG/M3 PEL NONE NONE
RESPIRABLE
FRACTION.
15 MG/M3 PEL
TOTAL DUST.
CRISTOBALITE 0.025 MG/M3 TWA 0.05 MG/M3 TWA NONE NONE
RESPIRABLE RESPIRABLE.
FRACTION. 0.15 MG/M3 TWA
TOTAL DUST.
1.2 MPPCF TWA
RESPIRABLE.
ENGINEERING CONTROLS:
LOCAL EXHAUST VENTILATION IS RECOMMENDED WHEN GENERAL VENTILATION IS NOT
SUFFICIENT TO CONTROL AIRBORNE CONTAMINATION.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID, PASTE
COLOR: GRAY
ODOR: MILD, PETROLEUM
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: 285 - 900 DEG. F (140.6 - 482.2 DEG. C) NONE
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.3548
VAPOR DENSITY: HEAVIER THAN AIR.
FLASH POINT: >93 DEG. C (>199.4 DEG. F) CLEVELAND OPEN CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: LESS THAN BUTYL ACETATE.
SOLUBILITY IN WATER: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0%; 0 G/L ESSENTIALLY ZERO
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. HYDROCARBONS ACRID SMOKE AND FUMES.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: STABLE
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION: CAUSES RESPIRATORY TRACT IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: NOT EXPECTED TO BE HARMFUL BY INGESTION.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
DISTILLATES (PETROLEUM), NONE IRRITANT
HYDROTREATED
HEAVY NAPHTHENIC
SILICON CARBIDE NONE NUISANCE DUST
TALLOW, CALCIUM SALT NONE NO RECORDS
SILICON NONE IRRITANT, NUISANCE DUST
CRISTOBALITE NONE CARCINOGEN, IMMUNE SYSTEM,
KIDNEY, LUNG
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
DISTILLATES (PETROLEUM), NO NO NO
HYDROTREATED
HEAVY NAPHTHENIC
SILICON CARBIDE NO NO NO
TALLOW, CALCIUM SALT NO NO NO
SILICON NO NO NO
CRISTOBALITE KNOWN TO BE GROUP 1 NO
HUMAN
CARCINOGEN.
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
DO NOT EMPTY INTO DRAINS / SURFACE WATER / GROUND WATER.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: LOU FABRIZIO, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 08/06/2014
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 003.0
ISSUE DATE: 08/06/2014
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: LOCTITE CLOVER 280 KNOWN AS CLOVER SIL CARBIDE GRS MIX 280.
IDH NUMBER: 702080
PRODUCT TYPE: SHARPENING COMPOUND
ITEM NUMBER: 39598_79509000
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH THOROUGHLY AFTER HANDLING. USE
ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR EYE AND FACE PROTECTION.
WEAR PROTECTIVE GLOVES.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING. CALL A POISON CONTROL CENTER
OR PHYSICIAN IF YOU FEEL UNWELL.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
DISTILLATES (PETROLEUM), HYDROTREATED 64742-52-5 30 - 60
HEAVY NAPHTHENIC
SILICON CARBIDE 409-21-2 30 - 60
TALLOW, CALCIUM SALT 68309-87-5 10 - 30
SILICON 7440-21-3 0.1 - 1
CRISTOBALITE 14464-46-1 0.1 - 1
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
INGESTION:
IF CONSCIOUS, DRINK PLENTY OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: CARBON DIOXIDE, FOAM, POWDER
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON, OXIDES OF NITROGEN, IRRITATING ORGANIC VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER,
UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED MATERIAL AND PLACE IN A
CLOSED CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING VAPORS OR MISTS
OF THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT:
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA OTHER
WEEL
DISTILLATES (PETROLEUM), 5 MG/M3 TWA MIST 5 MG/M3 TWA MIST NONE NONE
HYDROTREATED 10 MG/M3 STEL 500 PPM (2,000
HEAVY NAPHTHENIC MIST MG/M3) PEL
5 MG/M3 PEL
MIST.
SILICON CARBIDE 10 MG/M3 TWA 5 MG/M3 PEL NONE NONE
INHALABLE RESPIRABLE
FRACTION. FRACTION.
3 MG/M3 TWA 15 MG/M3 PEL
RESPIRABLE TOTAL DUST.
FRACTION.
0.1 FIBERS/CM3
TWA FIBER.
TALLOW, CALCIUM SALT NONE NONE NONE NONE
SILICON NONE 5 MG/M3 PEL NONE NONE
RESPIRABLE
FRACTION.
15 MG/M3 PEL
TOTAL DUST.
CRISTOBALITE 0.025 MG/M3 TWA 0.05 MG/M3 TWA NONE NONE
RESPIRABLE RESPIRABLE.
FRACTION. 0.15 MG/M3 TWA
TOTAL DUST.
1.2 MPPCF TWA
RESPIRABLE.
ENGINEERING CONTROLS:
LOCAL EXHAUST VENTILATION IS RECOMMENDED WHEN GENERAL VENTILATION IS NOT
SUFFICIENT TO CONTROL AIRBORNE CONTAMINATION.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID, PASTE
COLOR: GRAY
ODOR: MILD, PETROLEUM
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: 285 - 900 DEG. F (140.6 - 482.2 DEG. C) NONE
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.3548
VAPOR DENSITY: HEAVIER THAN AIR.
FLASH POINT: >93 DEG. C (>199.4 DEG. F) CLEVELAND OPEN CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: LESS THAN BUTYL ACETATE.
SOLUBILITY IN WATER: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0%; 0 G/L ESSENTIALLY ZERO
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. HYDROCARBONS ACRID SMOKE AND FUMES.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: STABLE
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION: CAUSES RESPIRATORY TRACT IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: NOT EXPECTED TO BE HARMFUL BY INGESTION.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
DISTILLATES (PETROLEUM), NONE IRRITANT
HYDROTREATED
HEAVY NAPHTHENIC
SILICON CARBIDE NONE NUISANCE DUST
TALLOW, CALCIUM SALT NONE NO RECORDS
SILICON NONE IRRITANT, NUISANCE DUST
CRISTOBALITE NONE CARCINOGEN, IMMUNE SYSTEM,
KIDNEY, LUNG
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
DISTILLATES (PETROLEUM), NO NO NO
HYDROTREATED
HEAVY NAPHTHENIC
SILICON CARBIDE NO NO NO
TALLOW, CALCIUM SALT NO NO NO
SILICON NO NO NO
CRISTOBALITE KNOWN TO BE GROUP 1 NO
HUMAN
CARCINOGEN.
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
DO NOT EMPTY INTO DRAINS / SURFACE WATER / GROUND WATER.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: LOU FABRIZIO, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 08/06/2014
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 003.0
ISSUE DATE: 05/13/2014
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: SILICON GM 120 GRIT 2 OZ CN
IDH NUMBER: 234970
PRODUCT TYPE: SHARPENING COMPOUND
ITEM NUMBER: 30571
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH THOROUGHLY AFTER HANDLING. USE
ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR EYE AND FACE PROTECTION.
WEAR PROTECTIVE GLOVES.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING. CALL A POISON CONTROL CENTER
OR PHYSICIAN IF YOU FEEL UNWELL.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
DISTILLATES (PETROLEUM), HYDROTREATED 64742-52-5 30 - 60
HEAVY NAPHTHENIC
SILICON CARBIDE 409-21-2 30 - 60
TALLOW, CALCIUM SALT 68309-87-5 10 - 30
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
INGESTION:
IF CONSCIOUS, DRINK PLENTY OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: CARBON DIOXIDE, FOAM, POWDER
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON, OXIDES OF NITROGEN, IRRITATING ORGANIC VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER,
UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED MATERIAL AND PLACE IN A
CLOSED CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING VAPORS OR MISTS
OF THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT:
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA OTHER
WEEL
DISTILLATES (PETROLEUM), 5 MG/M3 TWA MIST 5 MG/M3 TWA MIST NONE NONE
HYDROTREATED 10 MG/M3 STEL 500 PPM (2,000
HEAVY NAPHTHENIC MIST MG/M3) PEL
5 MG/M3 PEL
MIST.
SILICON CARBIDE 10 MG/M3 TWA 5 MG/M3 PEL NONE NONE
INHALABLE RESPIRABLE
FRACTION. FRACTION.
3 MG/M3 TWA 15 MG/M3 PEL
RESPIRABLE TOTAL DUST.
FRACTION.
0.1 FIBERS/CM3
TWA FIBER.
TALLOW, CALCIUM SALT NONE NONE NONE NONE
ENGINEERING CONTROLS:
LOCAL EXHAUST VENTILATION IS RECOMMENDED WHEN GENERAL VENTILATION IS NOT
SUFFICIENT TO CONTROL AIRBORNE CONTAMINATION. LOCAL EXHAUST VENTILATION IS
RECOMMENDED WHEN GENERAL VENTILATION IS NOT SUFFICIENT TO CONTROL AIRBORNE
CONTAMINATION.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID, PASTE
COLOR: GRAY
ODOR: MILD, PETROLEUM
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE. NOT AVAILABLE.
BOILING POINT/RANGE: 141 - 482 DEG. C (285.8 - 899.6 DEG. F)
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.3548
VAPOR DENSITY: HEAVIER THAN AIR.
FLASH POINT:
>93 DEG. C (>199.4 DEG. F) HST-US D09F; FLASH/FIRE POINT BY CLEVELAND OPEN
CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: LESS THAN BUTYL ACETATE.
SOLUBILITY IN WATER: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0%; 0 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. HYDROCARBONS ACRID SMOKE AND FUMES.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: STABLE
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: NOT EXPECTED TO BE HARMFUL BY INGESTION.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
DISTILLATES (PETROLEUM), NONE IRRITANT
HYDROTREATED
HEAVY NAPHTHENIC
SILICON CARBIDE NONE NUISANCE DUST
TALLOW, CALCIUM SALT NONE NO RECORDS
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
DISTILLATES (PETROLEUM), NO NO NO
HYDROTREATED
HEAVY NAPHTHENIC
SILICON CARBIDE NO NO NO
TALLOW, CALCIUM SALT NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
DO NOT EMPTY INTO DRAINS / SURFACE WATER / GROUND WATER.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: LOU FABRIZIO, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 05/13/2014
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.