| Common Name: | HH-66 VINYL CEMENT |
| Manufacturer: | RH PRODUCTS |
| SDS Revision Date: | 1/2/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 45JW36 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
HH-66 VINYL CEMENT
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
REVISION DATE: 01/02/2018
DATE OF ISSUE: 01/02/2018
SUPERSEDES DATE: 01/06/2017
VERSION: 1.0
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
PRODUCT NAME: HH-66 VINYL CEMENT
SYNONYMS: THERMOPLASTIC POLYURETHANE ADHESIVE BLEND/COMPOUND
1.2. INTENDED USE OF THE PRODUCT: NO ADDITIONAL INFORMATION AVAILABLE
1.3. NAME, ADDRESS, AND TELEPHONE OF THE RESPONSIBLE PARTY
COMPANY:
RH PRODUCTS CO., INC.
308 OLD HIGH STREET ACTON
MA 01720
USA
INFORMATION TELEPHONE NUMBER: 1-978-897-8000
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
1-800-535-5053 INFOTRAC
1-352-323-3500 INFOTRAC INTERNATIONAL
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION (GHS-US):
FLAM. LIQ. 2: H225
EYE IRRIT. 2A: H319
REPR. 2: H361
STOT SE 3: H336
STOT RE 2: H373
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, OPEN FLAMES, SPARKS. - NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL, LIGHTING, VENTILATING EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P260: DO NOT BREATHE VAPORS, MIST, SPRAY.
P264: WASH HANDS, FOREARMS, AND EXPOSED AREAS THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280: WEAR EYE PROTECTION, PROTECTIVE CLOTHING, PROTECTIVE GLOVES.
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304+P340:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P312: CALL A POISON CENTER IF YOU FEEL UNWELL.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P370+P378:
IN CASE OF FIRE:
USE DRY CHEMICAL POWDER, ALCOHOL-RESISTANT FOAM, CARBON DIOXIDE (CO2)
TO EXTINGUISH.
P403+P233:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P235+P405: KEEP COOL. STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER ACCORDING TO LOCAL, REGIONAL, NATIONAL, AND
INTERNATIONAL REGULATIONS.
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
2.4. UNKNOWN ACUTE TOXICITY (GHS-US): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % CLASSIFICATION (GHS-US)
METHYL ETHYL KETONE (CAS NO) 78-93-3 44 FLAM. LIQ. 2, H225
EYE IRRIT. 2A, H319
STOT SE 3, H336
ACETONE (CAS NO) 67-64-1 34 FLAM. LIQ. 2, H225
EYE IRRIT. 2A, H319
STOT SE 3, H336
PROPRIETARY COMPONENT PROPRIETARY* 14.1 NOT CLASSIFIED
TOLUENE (CAS NO) 108-88-3 7.9 FLAM. LIQ. 2, H225
SKIN IRRIT. 2, H315
REPR. 2, H361
STOT SE 3, H336
STOT RE 2, H373
ASP. TOX. 1, H304
AQUATIC ACUTE 2, H401
AQUATIC CHRONIC 3, H412
* THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
FULL TEXT OF H-PHRASES: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
USING PROPER RESPIRATORY PROTECTION, IMMEDIATELY MOVE THE EXPOSED PERSON
TO FRESH AIR. ASSURE FRESH AIR BREATHING. CALL A PHYSICIAN IF SYMPTOMS
OCCUR.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. GENTLY WASH WITH PLENTY OF SOAP AND WATER
FOLLOWED BY RINSING WITH WATER FOR AT LEAST 15 MINUTES. CALL A POISON
CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR AT LEAST 15 MINUTES. REMOVE CONTACT
LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. OBTAIN MEDICAL
ATTENTION.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. IMMEDIATELY CALL A POISON CENTER OR
DOCTOR/PHYSICIAN.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES:
CAUSES SERIOUS EYE IRRITATION. VAPORS MAY CAUSE DROWSINESS AND DIZZINESS.
SYMPTOMS/INJURIES AFTER INHALATION:
HIGH CONCENTRATION OF VAPOURS MAY INDUCE: HEADACHE, DIZZINESS, DROWSINESS,
NAUSEA AND VOMITING.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION:
INGESTION IS LIKELY TO BE HARMFUL OR HAVE ADVERSE EFFECTS.
CHRONIC SYMPTOMS:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. MAY
CAUSE DAMAGE TO CENTRAL NERVOUS SYSTEM, LIVER, AND KIDNEYS. SUSPECTED
OF DAMAGING FERTILITY OR THE UNBORN CHILD.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
IF EXPOSED OR CONCERNED, GET MEDICAL ADVICE AND ATTENTION.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL POWDER, ALCOHOL-RESISTANT FOAM, CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A HEAVY WATER STREAM. USE OF HEAVY STREAM OF WATER MAY SPREAD
FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: HIGHLY FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD:
MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE. HEAT MAY BUILD PRESSURE,
RUPTURING CLOSED CONTAINERS, SPREADING FIRE AND INCREASING RISK OF BURNS
AND INJURIES.
REACTIVITY:
REACTS VIOLENTLY WITH OXIDANTS CAUSING FIRE AND EXPLOSION HAZARD.
5.3. ADVICE FOR FIREFIGHTERS:
PRECAUTIONARY MEASURES FIRE:
EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE.
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. DO NOT GET WATER
INSIDE CONTAINERS. DO NOT APPLY WATER STREAM DIRECTLY AT SOURCE OF LEAK.
FIGHT FIRE FROM SAFE DISTANCE AND PROTECTED LOCATION.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
OTHER INFORMATION: REFER TO SECTION 9 FOR FLAMMABILITY PROPERTIES.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES. KEEP AWAY FROM
HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT GET IN EYES,
ON SKIN, OR ON CLOTHING. DO NOT BREATHE VAPOUR OR MIST.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: USE APPROPRIATE PERSONAL PROTECTION EQUIPMENT (PPE).
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES:
VENTILATE AREA. ELIMINATE IGNITION SOURCES. STOP LEAK IF SAFE TO DO SO.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT: ABSORB AND/OR CONTAIN SPILL WITH INERT MATERIAL, THEN
PLACE IN SUITABLE CONTAINER.
DO NOT TAKE UP IN COMBUSTIBLE MATERIAL SUCH AS:
SAW DUST OR CELLULOSIC MATERIAL.
METHODS FOR CLEANING UP:
CLEAR UP SPILLS IMMEDIATELY AND DISPOSE OF WASTE SAFELY. USE ONLY
NON-SPARKING TOOLS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION. CONCERNING
DISPOSAL ELIMINATION AFTER CLEANING, SEE ITEM 13.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PROCEDURES.
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING, OR SMOKING AND AGAIN WHEN LEAVING WORK.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE
FOLLOWED.
STORAGE CONDITIONS:
STORE IN A DRY, COOL AND WELL-VENTILATED PLACE. KEEP CONTAINER CLOSED WHEN
NOT IN USE. KEEP IN FIREPROOF PLACE.
INCOMPATIBLE PRODUCTS: STRONG ACIDS. STRONG BASES. STRONG OXIDIZERS.
7.3. SPECIFIC END USE(S) NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
TOLUENE (108-88-3):
USA ACGIH:
ACGIH TWA (PPM): 20 PPM
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 375 MG/M3
USA NIOSH:
NIOSH REL (TWA) (PPM): 100 PPM
USA NIOSH:
NIOSH REL (STEL) (MG/M3): 560 MG/M3
USA NIOSH:
NIOSH REL (STEL) (PPM): 150 PPM
USA IDLH:
US IDLH (PPM): 500 PPM
USA OSHA:
OSHA PEL (TWA) (PPM): 200 PPM
USA OSHA:
OSHA PEL (CEILING) (PPM): 300 PPM
ACETONE (67-64-1):
USA ACGIH:
ACGIH TWA (PPM): 500 PPM
USA ACGIH:
ACGIH STEL (PPM): 750 PPM
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 590 MG/M3
USA NIOSH:
NIOSH REL (TWA) (PPM): 250 PPM
USA IDLH:
US IDLH (PPM): 2500 PPM (10% LEL)
USA OSHA:
OSHA PEL (TWA) (MG/M3): 2400 MG/M3
USA OSHA:
OSHA PEL (TWA) (PPM): 1000 PPM
METHYL ETHYL KETONE (78-93-3):
USA ACGIH:
ACGIH TWA (PPM): 200 PPM
USA ACGIH:
ACGIH STEL (PPM): 300 PPM
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 590 MG/M3
USA NIOSH:
NIOSH REL (TWA) (PPM): 200 PPM
USA NIOSH:
NIOSH REL (STEL) (MG/M3): 885 MG/M3
USA NIOSH:
NIOSH REL (STEL) (PPM): 300 PPM
USA IDLH:
US IDLH (PPM): 3000 PPM
USA OSHA:
OSHA PEL (TWA) (MG/M3): 590 MG/M3
USA OSHA:
OSHA PEL (TWA) (PPM): 200 PPM
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN
THE IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. GAS DETECTORS SHOULD
BE USED WHEN FLAMMABLE GASES/VAPORS MAY BE RELEASED. PROVIDE EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP THE AIRBORNE
CONCENTRATIONS OF VAPOR OR MISTS BELOW THE APPLICABLE WORKPLACE
EXPOSURE LIMITS INDICATED ABOVE. ALL ELECTRICAL EQUIPMENT SHOULD
COMPLY WITH THE NATIONAL ELECTRIC CODE. ENSURE ALL NATIONAL/LOCAL
REGULATIONS ARE OBSERVED.
PERSONAL PROTECTIVE EQUIPMENT:
FULL PROTECTIVE FLAMEPROOF CLOTHING. PROTECTIVE GOGGLES. GLOVES.
INSUFFICIENT VENTILATION: WEAR RESPIRATORY PROTECTION.
MATERIALS FOR PROTECTIVE CLOTHING:
WEAR FIRE/FLAME RESISTANT/RETARDANT CLOTHING.
HAND PROTECTION: WEAR CHEMICALLY RESISTANT PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES.
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
USE NIOSH-APPROVED AIR-PURIFYING OR SUPPLIED-AIR RESPIRATOR WHERE AIRBORNE
CONCENTRATIONS OF VAPOR OR MIST ARE EXPECTED TO EXCEED EXPOSURE LIMITS.
OTHER INFORMATION: WHEN USING, DO NOT EAT, DRINK OR SMOKE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: CLEAR
ODOR: STRONG AROMATIC ODOR/SHARP MINT LIKE FRAGRANCE
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
EVAPORATION RATE: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: >35 DEG. C (95.00 DEG. F)
FLASH POINT: -14 DEG. C ASTM D-56 (6.80 DEG. F)
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: >1 (HEAVIER THAN AIR)
RELATIVE DENSITY: 0.88 (WATER = 1)
SOLUBILITY: INSOLUBLE IN WATER.
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
LOWER FLAMMABLE LIMIT: 1 %
UPPER FLAMMABLE LIMIT: 12 %
9.2. OTHER INFORMATION:
VOC CONTENT: 51.9 % (3.59 LBS/GAL OR 430 G/L)
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
REACTS VIOLENTLY WITH OXIDANTS CAUSING FIRE AND EXPLOSION HAZARD.
10.2. CHEMICAL STABILITY:
STABLE UNDER RECOMMENDED HANDLING AND STORAGE CONDITIONS (SEE SECTION 7).
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME. IGNITION
SOURCES.
10.5. INCOMPATIBLE MATERIALS:
STRONG ACIDS. STRONG BASES. STRONG OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES (CO, CO2).
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
TOLUENE (108-88-3):
LD50 ORAL RAT: 5580 MG/KG
LD50 DERMAL RABBIT: 8390 MG/KG
ATE (VAPORS): 25.70 MG/L/4H
ACETONE (67-64-1):
LD50 ORAL RAT: 5800 MG/KG
LD50 DERMAL RABBIT: 15688 MG/KG
LC50 INHALATION RAT: 44 G/M3
METHYL ETHYL KETONE (78-93-3):
LD50 ORAL RAT: 2054 MG/KG
LD50 DERMAL RAT: >10 ML/KG
LC50 INHALATION RAT: 23500 MG/M3 (EXPOSURE TIME: 8 H)
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
TOLUENE (108-88-3):
IARC GROUP: 3
REPRODUCTIVE TOXICITY:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
MAY CAUSE DROWSINESS OR DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD: NOT CLASSIFIED
SYMPTOMS/INJURIES AFTER INHALATION:
HIGH CONCENTRATION OF VAPOURS MAY INDUCE:
HEADACHE, DIZZINESS, DROWSINESS, NAUSEA AND VOMITING.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION:
INGESTION IS LIKELY TO BE HARMFUL OR HAVE ADVERSE EFFECTS.
CHRONIC SYMPTOMS:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. MAY
CAUSE DAMAGE TO CENTRAL NERVOUS SYSTEM, LIVER, AND KIDNEYS. SUSPECTED
OF DAMAGING FERTILITY OR THE UNBORN CHILD.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
TOLUENE (108-88-3):
LC50 FISH 1:
15.22 - 19.05 MG/L
(EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS [FLOW-THROUGH])
EC50 DAPHNIA 1:
5.46 - 9.83 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA [STATIC])
LC 50 FISH 2:
12.6 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS [STATIC])
EC50 DAPHNIA 2:
11.5 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
NOEC CHRONIC CRUSTACEA: 0.74 MG/L (CERIODAPHNIA DUBIA)
ACETONE (67-64-1):
LC50 FISH 1:
4144.846 MG/L (EXPOSURE TIME: 96 H - SPECIES: ONCORHYNCHUS MYKISS)
EC50 DAPHNIA 1:
1679.66 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA [STATIC])
LC 50 FISH 2:
6210 (6210 - 8120) MG/L
(EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS [STATIC])
EC50 DAPHNIA 2:
12600 (12600 - 12700) MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
METHYL ETHYL KETONE (78-93-3):
LC50 FISH 1:
3130 (3130 - 3320) MG/L
(EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS [FLOW-THROUGH])
EC50 DAPHNIA 1:
520 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
EC50 DAPHNIA 2:
5091 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
12.2. PERSISTENCE AND DEGRADABILITY:
ACETONE (67-64-1):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE IN WATER.
12.3. BIOACCUMULATIVE POTENTIAL:
TOLUENE (108-88-3):
LOG POW: 2.65
ACETONE (67-64-1):
BCF FISH 1: 0.69
LOG KOW: -0.24
METHYL ETHYL KETONE (78-93-3):
LOG POW: 0.29
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE OF WASTE MATERIAL IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL, AND INTERNATIONAL REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
RCRA WASTE NUMBER: D001.
| SECTION 14: TRANSPORT INFORMATION | |
14.1. IN ACCORDANCE WITH DOT:
PROPER SHIPPING NAME: ADHESIVES CONTAINING A FLAMMABLE LIQUID
HAZARD CLASS: 3
IDENTIFICATION NUMBER: UN1133
LABEL CODES: 3
PACKING GROUP: II
ERG NUMBER: 128
FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
14.2. IN ACCORDANCE WITH IMDG:
PROPER SHIPPING NAME: ADHESIVES
HAZARD CLASS: 3
IDENTIFICATION NUMBER: UN1133
PACKING GROUP: II
LABEL CODES: 3
EMS-NO. (FIRE): F-E
EMS-NO. (SPILLAGE): S-D
MFAG NUMBER: 127
CLASS 3 - FLAMMABLE LIQUIDS
14.3. IN ACCORDANCE WITH IATA:
PROPER SHIPPING NAME: ADHESIVES
PACKING GROUP: II
IDENTIFICATION NUMBER: UN1133
HAZARD CLASS: 3
LABEL CODES: 3
ERG CODE (IATA): 3L
CLASS 3, FLAMMABLE LIQUIDS
| SECTION 15: REGULATORY INFORMATION | |
15.1 US FEDERAL REGULATIONS:
HH-66 VINYL CEMENT:
SARA SECTION 311/312 HAZARD CLASSES:
FIRE HAZARD
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
TOLUENE (108-88-3):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
LISTED ON UNITED STATES SARA SECTION 313
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS) : 1000 LB
SARA SECTION 313 - EMISSION REPORTING: 1.0 %
ACETONE (67-64-1):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
EPA TSCA REGULATORY FLAG:
T - INDICATES A SUBSTANCE THAT IS THE SUBJECT OF A SECTION 4 TEST RULE
UNDER TSCA.
METHYL ETHYL KETONE (78-93-3):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
FIRE HAZARD
PROPRIETARY COMPONENT:
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2 US STATE REGULATIONS:
TOLUENE (108-88-3):
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS.
TOLUENE (108-88-3):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
ACETONE (67-64-1):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
METHYL ETHYL KETONE (78-93-3):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
| SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
REVISION DATE: 01/02/2018
OTHER INFORMATION:
THIS DOCUMENT HAS BEEN PREPARED IN ACCORDANCE WITH THE SDS REQUIREMENTS OF
THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200.
GHS FULL TEXT PHRASES:
AQUATIC ACUTE 2:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 2
AQUATIC CHRONIC 3:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 3
ASP. TOX. 1: ASPIRATION HAZARD CATEGORY 1
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2A
FLAM. LIQ. 2: FLAMMABLE LIQUIDS CATEGORY 2
REPR. 2: REPRODUCTIVE TOXICITY CATEGORY 2
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION CATEGORY 2
STOT RE 2: SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) CATEGORY 2
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS
H315: CAUSES SKIN IRRITATION
H319: CAUSES SERIOUS EYE IRRITATION
H336: MAY CAUSE DROWSINESS OR DIZZINESS
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
H401: TOXIC TO AQUATIC LIFE
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS
THE INFORMATION ABOVE IS BELIEVED TO BE ACCURATE AND REPRESENTS THE
INFORMATION CURRENTLY AVAILABLE TO US. WE HOWEVER, MAKE NO WARRANTY
OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH
RESPECT TO THIS INFORMATION, AND WE ASSUME NO LIABILITY RESULTING
FROM ITS USE.
SDS US (GHS HAZCOM)
EN (ENGLISH US)
MSD-V275 NEWPIG