| Common Name: | TRANSGARD MULTI-PURPOSE ATF |
| Manufacturer: | CITGO PETROLEUM |
| SDS Revision Date: | 4/28/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 45KJ35, 45KJ36, 63DV42, 63DV43 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CITGO(R*)
SAFETY DATA SHEET
TRANSGARD MULTI-PURPOSE ATF
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: TRANSGARD MULTI-PURPOSE ATF
SYNONYMS: AUTOMATIC TRANSMISSION FLUID; DEXRON III / MERCON
CODE: 633135001
SUPPLIER'S DETAILS:
CITGO PETROLEUM CORPORATION
P.O. BOX 4689
HOUSTON, TX 77210
SDSVEND@CITGO.COM
EMERGENCY TELEPHONE NUMBER:
TECHNICAL CONTACT: (800) 248-4684
MEDICAL EMERGENCY: (832) 486-4700
CHEMTREC EMERGENCY: (800) 424-9300 (UNITED STATES ONLY)
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2B
SKIN SENSITIZATION: CATEGORY 1
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
CAUSES EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
INJECTION UNDER THE SKIN CAN CAUSE SEVERE INJURY.
MOST DAMAGE OCCURS IN THE FIRST FEW HOURS.
INITIAL SYMPTOMS MAY BE MINIMAL.
PRECAUTIONARY STATEMENTS:
GENERAL:
READ LABEL BEFORE USE. KEEP OUT OF REACH OF CHILDREN. IF MEDICAL ADVICE
IS NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
PREVENTION:
WEAR PROTECTIVE GLOVES. WEAR EYE OR FACE PROTECTION. AVOID BREATHING VAPOR.
WASH HANDS THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD
NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE:
STORE IN A DRY PLACE AND/OR IN CLOSED CONTAINER. STORE IN ACCORDANCE WITH
ALL LOCAL, REGIONAL, NATIONAL AND INTERNATIONAL REGULATIONS.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED:
INJECTION OF PETROLEUM HYDROCARBONS REQUIRES IMMEDIATE MEDICAL ATTENTION
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION:
AUTOMATIC TRANSMISSION FLUID; DEXRON III / MERCON
CAS NUMBER/OTHER IDENTIFIERS:
CAS NUMBER: NOT APPLICABLE.
INGREDIENT NAME % CAS NUMBER
ALKOXYLATED LONG CHAIN ALKYL AMINE 0.1 - 1 ***
* = VARIOUS
** = MIXTURE
*** = PROPRIETARY
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO PROCESS VARIATION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE
UPPER AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE
TO RINSE FOR AT LEAST 10 MINUTES. IF IRRITATION PERSISTS, GET MEDICAL
ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION IF ADVERSE HEALTH
EFFECTS PERSIST OR ARE SEVERE. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION
AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN
TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
SKIN CONTACT:
WASH WITH PLENTY OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES.
WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING IT, OR
WEAR GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL
ATTENTION. IN THE EVENT OF ANY COMPLAINTS OR SYMPTOMS, AVOID FURTHER
EXPOSURE. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH
AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. DO NOT INDUCE
VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. IF VOMITING OCCURS,
THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT DOES NOT ENTER THE LUNGS. GET
MEDICAL ATTENTION IF ADVERSE HEALTH EFFECTS PERSIST OR ARE SEVERE. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN
RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN
AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT:
MAY CAUSE AN ALLERGIC SKIN REACTION. INJECTION OF PRESSURIZED HYDROCARBONS
CAN CAUSE SEVERE PERMANENT TISSUE DAMAGE. INITIAL SYMPTOMS MAY BE MINOR.
INGESTION: MAY BE IRRITATING TO MOUTH, THROAT AND STOMACH.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
WATERING
REDNESS
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
INGESTION: NO SPECIFIC DATA.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH
WATER BEFORE REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST.
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS: NO SPECIFIC DATA.
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE
ALSO THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH
WATER AND MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE,
ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. APPROACH
RELEASE FROM UPWIND. PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS
OR CONFINED AREAS. WASH SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR
PROCEED AS FOLLOWS. CONTAIN AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE,
ABSORBENT MATERIAL E.G. SAND, EARTH, VERMICULITE OR DIATOMACEOUS EARTH
AND PLACE IN CONTAINER FOR DISPOSAL ACCORDING TO LOCAL REGULATIONS
(SEE SECTION 13). DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
CONTAMINATED ABSORBENT MATERIAL MAY POSE THE SAME HAZARD AS THE SPILLED
PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). PERSONS
WITH A HISTORY OF SKIN SENSITIZATION PROBLEMS SHOULD NOT BE EMPLOYED IN ANY
PROCESS IN WHICH THIS PRODUCT IS USED. DO NOT GET IN EYES OR ON SKIN OR
CLOTHING. DO NOT INGEST. AVOID BREATHING VAPOR OR MIST. KEEP IN THE
ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE MADE FROM A COMPATIBLE
MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE. EMPTY CONTAINERS RETAIN
PRODUCT RESIDUE AND CAN BE HAZARDOUS. DO NOT REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. KEEP
CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT
HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT
LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE APPROPRIATE CONTAINMENT
TO AVOID ENVIRONMENTAL CONTAMINATION.
BULK STORAGE CONDITIONS:
MAINTAIN ALL STORAGE TANKS IN ACCORDANCE WITH APPLICABLE REGULATIONS. USE
NECESSARY CONTROLS TO MONITOR TANK INVENTORIES. INSPECT ALL STORAGE TANKS
ON A PERIODIC BASIS. TEST TANKS AND ASSOCIATED PIPING FOR TIGHTNESS.
MAINTAIN THE AUTOMATIC LEAK DETECTION DEVICES TO ASSURE PROPER WORKING
CONDITION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS: NONE IDENTIFIED.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL WORKER EXPOSURE
TO AIRBORNE CONTAMINANTS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, VAPOR CONTROLS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE THAT
EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION LOCATION.
EYE/FACE PROTECTION:
SAFETY GLASSES EQUIPPED WITH SIDE SHIELDS ARE RECOMMENDED AS MINIMUM
PROTECTION IN INDUSTRIAL SETTINGS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION:
CHEMICAL SPLASH GOGGLES. SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD
SHOULD BE USED WHEN A RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID
EXPOSURE TO LIQUID SPLASHES, MISTS, GASES OR DUSTS. IF INHALATION HAZARDS
EXIST, A FULL-FACE RESPIRATOR MAY BE REQUIRED INSTEAD.
SKIN PROTECTION:
HAND PROTECTION:
AVOID SKIN CONTACT WITH LIQUID. CHEMICAL-RESISTANT GLOVES COMPLYING WITH
AN APPROVED STANDARD SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL
PRODUCTS IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE
PARAMETERS SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE
GLOVES ARE STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED
THAT THE TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR
DIFFERENT GLOVE MANUFACTURERS. LEATHER GLOVES ARE NOT PROTECTIVE FOR LIQUID
CONTACT.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
AVOID SKIN CONTACT WITH LIQUID. APPROPRIATE FOOTWEAR AND ANY ADDITIONAL
SKIN PROTECTION MEASURES SHOULD BE SELECTED BASED ON THE TASK BEING
PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A SPECIALIST
BEFORE HANDLING THIS PRODUCT. LEATHER BOOTS ARE NOT PROTECTIVE FOR LIQUID
CONTACT.
RESPIRATORY PROTECTION:
AVOID INHALATION OF GASES, VAPORS, MISTS OR DUSTS. USE A PROPERLY FITTED,
AIR-PURIFYING OR SUPPLIED-AIR RESPIRATOR COMPLYING WITH AN APPROVED
STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY. RESPIRATOR
SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS, THE
HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID.
COLOR: RED.
ODOR: MILD PETROLEUM ODOR
PH: NOT AVAILABLE.
BOILING POINT/BOILING RANGE: NOT AVAILABLE.
FLASH POINT:
OPEN CUP: 194 DEG. C (381.2 DEG. F) [CLEVELAND.]
EVAPORATION RATE: <1 (N-BUTYL ACETATE. = 1)
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT AVAILABLE.
VAPOR PRESSURE: <0.013 KPA (<0.1 MM Hg) [ROOM TEMPERATURE]
VAPOR DENSITY: >1 [AIR = 1]
RELATIVE DENSITY: 0.86
DENSITY LBS/GAL: 7.15 LBS/GAL
GRAVITY, DEG. API: 32.9 @ 60 F
SOLUBILITY:
INSOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER.
VISCOSITY:
KINEMATIC (ROOM TEMPERATURE): 0.34 CM2/S (34 CST)
KINEMATIC (40 DEG. C (104 DEG. F)): 0.343 CM2/S (34.3 CST)
VISCOSITY SUS: 165 SUS @ 100 F
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NOT EXPECTED TO BE EXPLOSIVE, SELF-REACTIVE, SELF-HEATING, OR AN ORGANIC
PEROXIDE UNDER US GHS DEFINITION(S).
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
ALKOXYLATED LONG CHAIN LD50 ORAL RAT 960 MG/KG
ALKYL AMINE
CONCLUSION/SUMMARY:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC:
MINERAL OIL MISTS DERIVED FROM HIGHLY REFINED OILS ARE REPORTED TO HAVE
LOW ACUTE AND SUB-ACUTE TOXICITIES IN ANIMALS. EFFECTS FROM SINGLE AND
SHORT-TERM REPEATED EXPOSURES TO HIGH CONCENTRATIONS OF MINERAL OIL MISTS
WELL ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS INCLUDE LUNG INFLAMMATORY
REACTION, LIPOID GRANULOMA FORMATION AND LIPOID PNEUMONIA. IN ACUTE AND
SUB-ACUTE STUDIES INVOLVING EXPOSURES TO LOWER CONCENTRATIONS OF MINERAL
OIL MISTS AT OR NEAR CURRENT WORK PLACE EXPOSURE LEVELS PRODUCED NO
SIGNIFICANT TOXICOLOGICAL EFFECTS.
DISTILLATES (PETROLEUM), SOLVENT-REFINED HEAVY PARAFFINIC:
MINERAL OIL MISTS DERIVED FROM HIGHLY REFINED OILS ARE REPORTED TO HAVE
LOW ACUTE AND SUB-ACUTE TOXICITIES IN ANIMALS. EFFECTS FROM SINGLE AND
SHORT-TERM REPEATED EXPOSURES TO HIGH CONCENTRATIONS OF MINERAL OIL MISTS
WELL ABOVE APPLICABLE WORKPLACE EXPOSURE LEVELS INCLUDE LUNG INFLAMMATORY
REACTION, LIPOID GRANULOMA FORMATION AND LIPOID PNEUMONIA. IN ACUTE AND
SUB-ACUTE STUDIES INVOLVING EXPOSURES TO LOWER CONCENTRATIONS OF MINERAL
OIL MISTS AT OR NEAR CURRENT WORK PLACE EXPOSURE LEVELS PRODUCED NO
SIGNIFICANT TOXICOLOGICAL EFFECTS.
IRRITATION/CORROSION:
SKIN: NO ADDITIONAL INFORMATION.
EYES: NO ADDITIONAL INFORMATION.
RESPIRATORY: NO ADDITIONAL INFORMATION.
SENSITIZATION:
SKIN: NO ADDITIONAL INFORMATION.
RESPIRATORY: NO ADDITIONAL INFORMATION.
MUTAGENICITY:
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
CARCINOGENICITY:
CONCLUSION/SUMMARY:
DISTILLATES (PETROLEUM), SOLVENT-REFINED HEAVY PARAFFINIC:
IN LONG TERM STUDIES (UP TO TWO YEARS) NO CARCINOGENIC EFFECTS HAVE BEEN
REPORTED IN ANY ANIMAL SPECIES TESTED.
REPRODUCTIVE TOXICITY:
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
TERATOGENICITY:
CONCLUSION/SUMMARY: NO ADDITIONAL INFORMATION.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT AVAILABLE.
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
ROUTES OF ENTRY ANTICIPATED: DERMAL.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT:
MAY CAUSE AN ALLERGIC SKIN REACTION. INJECTION OF PRESSURIZED HYDROCARBONS
CAN CAUSE SEVERE PERMANENT TISSUE DAMAGE. INITIAL SYMPTOMS MAY BE MINOR.
INGESTION: MAY BE IRRITATING TO MOUTH, THROAT AND STOMACH.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
WATERING
REDNESS
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
INGESTION: NO SPECIFIC DATA.
POTENTIAL CHRONIC HEALTH EFFECTS:
GENERAL:
ONCE SENSITIZED, A SEVERE ALLERGIC REACTION MAY OCCUR WHEN SUBSEQUENTLY
EXPOSED TO VERY LOW LEVELS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
CONCLUSION/SUMMARY: NOT AVAILABLE.
PERSISTENCE AND DEGRADABILITY:
CONCLUSION/SUMMARY: NOT AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NOT AVAILABLE.
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL
TIMES COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE
DISPOSAL LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE
OF SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. THIS MATERIAL AND ITS CONTAINER MUST
BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING EMPTIED
CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY CONTAINERS OR
LINERS MAY RETAIN SOME PRODUCT RESIDUES. AVOID DISPERSAL OF SPILLED
MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT CLASSIFICATION IMDG IATA
UN NUMBER NOT REGULATED. NOT REGULATED. NOT REGULATED.
UN PROPER SHIPPING
NAME
TRANSPORT HAZARD
CLASS(ES)
PACKING GROUP
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL
INFORMATION
OIL:
THE PRODUCT(S) REPRESENTED BY THIS MSDS IS (ARE) REGULATED AS "OIL" UNDER
49 CFR PART 130. SHIPMENTS BY RAIL OR HIGHWAY IN PACKAGING HAVING A
CAPACITY OF 3500 GALLONS OR MORE OR IN A QUANTITY GREATER 42,000 GALLONS
ARE SUBJECT TO THESE REQUIREMENTS. IN ADDITION, MIXTURES CONTAINING 10% OR
MORE OF THIS PRODUCT MAY BE SUBJECT TO THESE REQUIREMENTS.
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
THIS MATERIAL IS CLASSIFIED AS AN OIL UNDER SECTION 311 OF THE CLEAN WATER
ACT (CWA) AND THE OIL POLLUTION ACT OF 1990 (OPA). DISCHARGES OR SPILLS
WHICH PRODUCE A VISIBLE SHEEN ON WATERS OF THE UNITED STATES, THEIR
ADJOINING SHORELINES, OR INTO CONDUITS LEADING TO SURFACE WATERS MUST BE
REPORTED TO THE EPA'S NATIONAL RESPONSE CENTER AT (800) 424-8802.
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS:
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION: IMMEDIATE (ACUTE) HEALTH HAZARD
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE OF (ACUTE) (CHRONIC)
PRESSURE HEALTH HEALTH
HAZARD HAZARD
ALKOXYLATED LONG NO. NO. NO. YES. NO.
CHAIN ALKYL AMINE
STATE REGULATIONS:
MASSACHUSETTS: NONE OF THE COMPONENTS ARE LISTED.
NEW YORK: NONE OF THE COMPONENTS ARE LISTED.
NEW JERSEY: NONE OF THE COMPONENTS ARE LISTED.
PENNSYLVANIA: NONE OF THE COMPONENTS ARE LISTED.
INTERNATIONAL REGULATIONS:
INTERNATIONAL LISTS:
AUSTRALIA INVENTORY (AICS): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHINA INVENTORY (IECSC): ALL COMPONENTS ARE LISTED OR EXEMPTED.
JAPAN INVENTORY: AT LEAST ONE COMPONENT IS NOT LISTED.
KOREA INVENTORY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
MALAYSIA INVENTORY (EHS REGISTER): NOT DETERMINED.
NEW ZEALAND INVENTORY OF CHEMICALS (NZIOC):
ALL COMPONENTS ARE LISTED OR EXEMPTED.
PHILIPPINES INVENTORY (PICCS): ALL COMPONENTS ARE LISTED OR EXEMPTED.
TAIWAN INVENTORY (CSNN): NOT DETERMINED.
CANADA INVENTORY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
EU INVENTORY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
WHMIS (CANADA): NOT CONTROLLED UNDER WHMIS (CANADA).
| SECTION 16. OTHER INFORMATION | |
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 0
FLAMMABILITY 1
INSTABILITY/REACTIVITY 0
SPECIAL
REPRINTED WITH PERMISSION FROM NFPA 704-2001, IDENTIFICATION OF THE
HAZARDS OF MATERIALS FOR EMERGENCY RESPONSE COPYRIGHT (C)1997, NATIONAL
FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269. THIS REPRINTED MATERIAL IS
NOT THE COMPLETE AND OFFICIAL POSITION OF THE NATIONAL FIRE PROTECTION
ASSOCIATION, ON THE REFERENCED SUBJECT WHICH IS REPRESENTED ONLY BY THE
STANDARD IN ITS ENTIRETY.
COPYRIGHT (C)2001, NATIONAL FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269.
THIS WARNING SYSTEM IS INTENDED TO BE INTERPRETED AND APPLIED ONLY BY
PROPERLY TRAINED INDIVIDUALS TO IDENTIFY FIRE, HEALTH AND REACTIVITY
HAZARDS OF CHEMICALS. THE USER IS REFERRED TO CERTAIN LIMITED NUMBER OF
CHEMICALS WITH RECOMMENDED CLASSIFICATIONS IN NFPA 49 AND NFPA 325, WHICH
WOULD BE USED AS A GUIDELINE ONLY. WHETHER THE CHEMICALS ARE CLASSIFIED BY
NFPA OR NOT, ANYONE USING THE 704 SYSTEMS TO CLASSIFY CHEMICALS DOES SO AT
THEIR OWN RISK.
HISTORY:
DATE OF ISSUE/DATE OF REVISION: 4/28/2015.
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL 73/78:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
NOTICE TO READER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) WAS OBTAINED FROM SOURCES
WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT
ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS OR ACCURACY.
SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES
OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS SDS WAS PREPARED
AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A
COMPONENT IN ANOTHER PRODUCT, THIS SDS INFORMATION MAY NOT BE APPLICABLE.
USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF
THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE OR APPLICATION.
THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND/OR DISPOSAL OF
THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR
THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY
DISCLAIM LIABILITY FOR ANY LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN
ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT.
CITGO IS A REGISTERED TRADEMARK OF CITGO PETROLEUM CORPORATION