| Common Name: | MAPP 2211, PROPAN 2209 |
| Manufacturer: | SIEVERT SWEDEN |
| SDS Revision Date: | 12/17/2014 |
| SDS Format: | GHS-EU |
| Item Number(s): | 45MK51, 45MK52, 45MK53 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
IN ACCORDANCE WITH 453/2010 AND 1272/2008
(ALL REFERENCES TO EU REGULATIONS AND DIRECTIVES ARE ABBREVIATED INTO ONLY
THE NUMERIC TERM)
ISSUED: 2014-12-17
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
TRADE NAME: SIEVERT MAPP 2211
SUPPLIER'S PRODUCT NUMBER: 221183, 221184, 400 G, 788 ML
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
IDENTIFIED USES: PROPELLANTS
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY:
SIEVERT AB
BOX 1366
SE-17126 SOLNA
SWEDEN
TELEPHONE: +46 8-629 22 00
E-MAIL: INFO@SIEVERT.SE
1.4. EMERGENCY TELEPHONE NUMBER:
IN CASE OF EMERGENCY CONTACT TOXICOLOGICAL INFORMATION, EMERGENCY TEL 112
(WITHIN EUROPE) OR 1-800-222-1222 (FOR USA). FOR OTHER COUNTRIES, USE THE
BUILT-IN EMERGENCY NUMBER IN YOUR CELL PHONE
FOR NON-EMERGENCY POISON INFORMATION,
SEE HTTP://WWW.WHO.INT/GHO/PHE/CHEMICAL_SAFETY/POISONS_CENTRES/EN/
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION IN ACCORDANCE WITH 1272/2008:
EXTREMELY FLAMMABLE GAS (CATEGORY 1)
COMPRESSED GAS
CLASSIFICATION IN ACCORDANCE WITH 1999/45/EG: EXTREMELY FLAMMABLE; F+; R12.
2.2. LABEL ELEMENTS:
LABEL INFORMATION IN ACCORDANCE WITH 1272/2008:
HAZARD PICTOGRAMS: FLAME
SIGNAL WORDS: DANGER
HAZARD STATEMENTS:
H220: EXTREMELY FLAMMABLE GAS
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
PRECAUTIONARY STATEMENTS:
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING
P377:
LEAKING GAS FIRE: DO NOT EXTINGUISH, UNLESS LEAK CAN BE STOPPED SAFELY
P381: ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO
P410+P403: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE
LABEL INFORMATION IN ACCORDANCE WITH 1999/45/EG: SEE SECTION 16.
2.3. OTHER HAZARDS: NOT RELEVANT.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
THIS PRODUCT IS COMPOSED OF A COMPRESSED GAS MIXTURE.
3.2. MIXTURES:
NOTE THAT THE TABLE SHOWS KNOWN HAZARDS OF THE INGREDIENTS IN A PURE FORM.
THESE HAZARDS ARE REDUCED OR ELIMINATED WHEN MIXED OR DILUTED, SEE SECTION
16D.
CONSTITUENT CLASSIFICATION CONCENTRATION
PROPENE:
CAS NO: 115-07-1 FLAM GAS 1, PRESS GAS P; H220, >=99,5%
EC NO: 204-062-1 H280 F+; R12
INDEX NO: 601-011-00-9
PROPANE:
CAS NO: 74-98-6 FLAM GAS 1, PRESS GAS P; H220, <=0,5%
EC NO: 200-827-9 H280 F+; R12
INDEX NO: 601-003-00-5
EXPLANATIONS TO THE CLASSIFICATION AND LABELLING OF THE INGREDIENTS ARE
GIVEN IN SECTION 16E. OFFICIAL ABBREVIATIONS ARE PRINTED IN NORMAL FONT.
TEXT IN ITALICS ARE SPECIFICATIONS AND/OR COMPLEMENT USED IN THE
CALCULATION OF THE HAZARDS OF THIS MIXTURE, SEE SECTION 16B
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
UPON BREATHING IN:
ALLOW THE INJURED PERSON TO REST IN A WARM PLACE WITH FRESH AIR, IF
SYMPTOMS PERSIST SEEK MEDICAL ADVICE.
UPON CONTACT WITH THE EYES:
REMOVE CONTACT LENSES IMMEDIATELY IF POSSIBLE.
RINSE THE EYE FOR SEVERAL MINUTES WITH LUKEWARM WATER. IF IRRITATION
PERSISTS CALL A DOCTOR/OPHTHALMOLOGIST.
UPON SKIN CONTACT:
REMOVE CONTAMINATED CLOTHES.
WARM UP AFFECTED PARTS OF THE BODY IF FROSTBITE IS APPARENT.
IN CASE OF MAJOR FROST INJURIES, PLEASE CONTACT YOUR DOCTOR.
UPON INGESTION: IF SYMPTOMS PERSIST CONTACT A DOCTOR.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: SYMPTOMATIC TREATMENT.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
RECOMMENDED EXTINGUISHING AGENTS:
EXTINGUISH WITH POWDER, CARBON DIOXIDE OR FOAM.
UNSUITABLE EXTINGUISHING AGENTS: SHOULD NOT BE EXTINGUISHED WITH WATER.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
GASES DETRIMENTAL TO HEALTH (CARBON MONOXIDE AND CARBON DIOXIDE) CAN BE
SPREAD IN CASE OF FIRE.
THE GAS FORMS AN EXPLOSIVE MIXTURE WITH AIR.
IN CASE OF FIRE, HIGH PRESSURE MAY BUILD UP CAUSING THE PACKAGING TO
EXPLODE.
FLAMMABLE GAS.
5.3. ADVICE FOR FIRE-FIGHTERS:
IN CASE OF FIRE USE A RESPIRATOR MASK.
VAPORS ARE HEAVIER THAN AIR AND MAY SPREAD ALONG FLOORS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
CHEMICAL PROTECTION SUITS SHOULD BE WORN FOR ALL SALVAGE AND
DECONTAMINATION WORK.
USE RECOMMENDED SAFETY EQUIPMENT, SEE SECTION 8.
DO NOT INHALE THE GAS.
NOTE, RISK OF IGNITION AND EXPLOSION.
UPON SMALL SPILLAGE <5 KG VACATE THE AREA AND VENTILATE THE FUMES.
SWITCH OFF EQUIPMENT WHICH HAS AN EXPOSED FLAME, GLOWS, OR HAS A HEAT
SOURCE OF SOME OTHER KIND.
NOTE, RISK FOR FORMATION OF SPARKS DUE TO STATIC ELECTRICITY. DO NOT
REMOVE CLOTHING IN A ROOM WHERE SPILLAGE HAS OCCURRED.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO SOIL, WATER OR AIR.
AVOID DISCHARGE INTO SEWERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
EVACUATE THE AREA AND VENTILATE FUMES. NOTE, RISK FOR EXPLOSION.
RESIDUES LEFT BEHIND AFTER CLEANING SHALL BE TREATED AS HAZARDOUS WASTE.
FOR FURTHER INFORMATION, CONTACT THE LOCAL AUTHORITY SANITISATION WORKS.
PRESENT THIS SAFETY DATA SHEET.
6.4. REFERENCE TO OTHER SECTIONS: NOT APPLICABLE
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT INHALE FUMES AND AVOID CONTACT WITH SKIN AND EYES.
THE PRODUCT SHOULD BE STORED IN A MANNER WHICH PREVENTS HAZARDS TO HEALTH
AND THE ENVIRONMENT. AVOID EXPOSURE TO HUMANS AND ANIMALS AND DO NOT
DISCHARGE THE PRODUCT IN A SENSITIVE ENVIRONMENT.
STORE TIGHTLY, IN ORIGINAL PACKAGING.
DO NOT EAT, DRINK OR SMOKE IN PREMISES WHERE THIS PRODUCT IS STORED.
OPEN FIRES, HOT OBJECTS, SPARK FORMATION, OR OTHER SOURCES OF IGNITION,
ARE NOT ALLOWED IN THE PREMISES WHERE THIS PRODUCT IS HANDLED.
PREVENT BUILD UP OF STATIC ELECTRICITY BY UTILISING A SEMI-CONDUCTING
FLOOR AND SHOE SOLES AND KEEP HUMIDITY ABOVE 50%.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN A DRY PLACE NOT ABOVE NORMAL ROOM TEMPERATURE.
HANDLE IN A PREMISES WHICH IS WELL VENTILATED.
STORE IN A WELL-VENTILATED SPACE.
AN EVACUATION PLAN SHOULD BE AVAILABLE AND EVACUATION ROUTES MUST NOT BE
BLOCKED.
DO NOT STORE IN DIRECT SUNLIGHT.
CONTACT WITH THE LIQUID PRODUCT CAN CAUSE INJURIES FROM HYPOTHERMIA.
7.3. SPECIFIC END USES: NOT RELEVANT.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
8.1.1. NATIONAL LIMIT VALUES, UNITED KINGDOM:
ALL INGREDIENTS (CF SECTION 3) LACK OCCUPATIONAL EXPOSURE LIMIT VALUES.
8.2. EXPOSURE CONTROLS:
IN TERMS OF MINIMIZING RISKS, ATTENTION MUST BE PAID TO THE PHYSICAL
HAZARDS (SEE SECTIONS 2 AND 10) OF THIS PRODUCT ACCORDING TO EU DIRECTIVES
89/391 AND 98/24 AND NATIONAL OCCUPATIONAL LEGISLATION.
PROTECTIVE GLOVES ARE NORMALLY NOT NEEDED DUE TO THE PROPERTIES OF THIS
PRODUCT, BUT MAY BE NECESSARY FOR OTHER REASONS, E.G. MECHANICAL RISKS,
TEMPERATURE CONDITIONS OR MICROBIOLOGICAL RISKS. VERY SENSITIVE PERSONS
CAN USE GLOVES LABELLED "LOW CHEMICAL RESISTANT" OR "WATERPROOF" OR WITH
THE PICTOGRAM INDICATED HERE.
A RESPIRATORY MASK MAY BE REQUIRED.
FOR LIMITATION OF ENVIRONMENTAL EXPOSURE, SEE SECTION 12.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
A) APPEARANCE:
FORM: COMPRESSED GAS
COLOUR: COLOURLESS
B) ODOUR: SCENTLESS
C) ODOUR THRESHOLD: NOT APPLICABLE
D) PH: NOT APPLICABLE
E) MELTING POINT/FREEZING POINT: -185 DEG. C
F) INITIAL BOILING POINT AND BOILING RANGE:
-48 DEG. C AT ATMOSPHERIC PRESSURE (101325 PA)
G) FLASH POINT: -108 DEG. C
H) EVAPORATION RATE: NOT APPLICABLE
I) FLAMMABILITY (SOLID, GAS): EXTREMELY FLAMMABLE GAS
J) UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER EXPLOSION LIMIT: 2%
UPPER EXPLOSION LIMIT: 11%
K) VAPOUR PRESSURE: 900 KPA (15 DEG. C)
L) VAPOUR DENSITY: 1.50 (0 DEG. C, AIR = 1.0)
M) RELATIVE DENSITY: 0,6 KG/L
N) SOLUBILITY: SOLUBILITY IN WATER VERY SPARSELY SOLUBLE(<0.1%)
O) PARTITION COEFFICIENT N-OCTANOL/WATER: NOT APPLICABLE
P) AUTO-IGNITION TEMPERATURE: 497 DEG. C
Q) DECOMPOSITION TEMPERATURE: NOT APPLICABLE
R) VISCOSITY: NOT APPLICABLE
S) EXPLOSIVE PROPERTIES: NOT APPLICABLE
T) OXIDISING PROPERTIES: NOT APPLICABLE
9.2. OTHER INFORMATION: NO DATA AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THE PRODUCT CONTAINS NO SUBSTANCES WHICH CAN LEAD TO HAZARDOUS REACTIONS
AT NORMAL USE.
10.2. CHEMICAL STABILITY:
THE PRODUCT IS STABLE AT NORMAL STORAGE AND HANDLING CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NO HAZARDOUS REACTIONS KNOWN.
10.4. CONDITIONS TO AVOID: AVOID HEAT, SPARKS AND OPEN FLAMES.
10.5. INCOMPATIBLE MATERIALS: AVOID CONTACT WITH OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: NONE UNDER NORMAL CONDITIONS.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
GENERAL OR UNSPECIFIC TOXICITY:
THIS PRODUCT'S MAIN RISK IS ITS FLAMMABILITY.
ACUTE EFFECTS: NOT CLASSIFIED AS AN ACUTELY TOXIC SUBSTANCE.
HARMFULNESS: THE PRODUCT IS NOT CLASSIFIED AS HARMFUL TO HEALTH.
CORROSIVE AND IRRITATING EFFECTS:
CONTACT WITH LIQUEFIED GAS MAY CAUSE FROSTBITE ON SKIN AND EYES.
EFFECT ON JUDGEMENT AND OTHER PSYCHOLOGICAL EFFECTS:
AT HIGH CONCENTRATIONS THERE IS AN ANESTHETIC OR NARCOTIC EFFECT.
PROLONGED INHALATION CAN CAUSE LOSS OF CONSCIOUSNESS AND/OR DEATH.
RELEVANT TOXICOLOGICAL PROPERTIES:
PROPANE:
LC50 RAT (INHALATION) 4H: 658 MG/L INHALATION
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
PROPANE:
LC50 FRESHWATER WATER FLEA (DAPHNIA MAGNA) 48H: 16,3 MG/L
LC50 FISH 96H: 16,1 MG/L
IC50 ALGAE 72H: 11,3 MG/L
IN THE QUANTITIES WITH WHICH THIS PRODUCT IS USED, EFFECTS ON THE
ENVIRONMENT ARE NEGLIGIBLE. NOTE HOWEVER, THAT THE LOCAL ENVIRONMENT MAY
BE AFFECTED, AND ALL DISCHARGE TO THE NATURAL ENVIRONMENT MAY IMPACT
ECOSYSTEMS.
12.2. PERSISTENCE AND DEGRADABILITY:
THE PRODUCT DEGRADES EASILY IN THE NATURAL ENVIRONMENT.
12.3. BIOACCUMULATIVE POTENTIAL:
NEITHER THIS PRODUCT, NOR ITS CONTENTS, ACCUMULATES IN NATURE.
12.4. MOBILITY IN SOIL:
NO INFORMATION ABOUT MOBILITY IN THE NATURE EXISTS BUT THERE IS NO REASON
TO SUPPOSE THE PRODUCT TO BE ECOLOGICALLY HARMFUL BECAUSE OF THIS.
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES THAT ARE ASSESSED TO BE A PBT
OR A VPVB.
12.6. OTHER ADVERSE EFFECTS: NONE KNOWN EFFECTS OR HAZARDS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE HANDLING FOR THE PRODUCT:
PRODUCT AS WELL AS PACKAGING MUST BE DISPOSED AS HAZARDOUS WASTE.
ALSO TAKE LOCAL REGULATIONS FOR DEALING WITH WASTE INTO ACCOUNT.
CF ALSO NATIONAL WASTE REGULATIONS.
SPECIAL ADVISES FOR WASTE HANDLING: 16 05 04.
RECYCLING OF THE PRODUCT: THIS PRODUCT IS NOT USUALLY RECYCLED.
TRANSPORTATION OF WASTE: NOT INDICATED
| SECTION 14: TRANSPORT INFORMATION | |
THIS PRODUCT IS ONLY SUPPOSED TO BE TRANSPORTED BY ROAD OR RAILWAY AND
JUST THE TRANSPORT REGULATIONS ADR/RID THUS APPLY.
14.1. UN NUMBER: 1077
14.2. UN PROPER SHIPPING NAME: PROPYLENE
14.3. TRANSPORT HAZARD CLASS(ES):
CLASS:
2: GASES
CLASSIFICATION CODE (ADR/RID):
2F:
SUBSIDIARY RISK (IMDG):
LABELS: CLASS 2.1 - FLAMMABLE GASES
14.4. PACKING GROUP:
PACKING GROUP: NOT APPLICABLE
14.5. ENVIRONMENTAL HAZARDS: NOT APPLICABLE
14.6. SPECIAL PRECAUTIONS FOR USER:
TUNNEL RESTRICTIONS:
TUNNEL CATEGORY: B/D.
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT APPLICABLE
14.8 OTHER TRANSPORT INFORMATION:
TRANSPORT CATEGORY:
2; HIGHEST TOTAL QUANTITY PER TRANSPORTED UNIT 333 KG OR LITERS.
| SECTION 15: REGULATORY INFORMATION | |
15.1. SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC
FOR THE SUBSTANCE OR MIXTURE: NOT APPLICABLE.
15.2. CHEMICAL SAFETY ASSESSMENT:
CHEMICAL SAFETY REPORT ACCORDING TO 1907/2006 ANNEX I IS NOT REQUIRED
FOR THIS PRODUCT.
| SECTION 16: OTHER INFORMATION | |
16A. INDICATION OF WHERE CHANGES HAVE BEEN MADE TO THE PREVIOUS VERSION
OF THE SAFETY DATA SHEET:
REVISIONS OF THIS DOCUMENT: THIS IS THE FIRST VERSION.
16B. LEGEND TO ABBREVIATIONS AND ACRONYMS USED IN THE SAFETY DATA SHEET:
FULL TEXTS FOR HAZARD CLASS AND CATEGORY CODE MENTIONED IN SECTION 3:
FLAM GAS 1: EXTREMELY FLAMMABLE GAS (CATEGORY 1)
PRESS GAS P: COMPRESSED GAS
COMPREHENSIVE DEFINITION OF THE HAZARDS MENTIONED IN SECTION 2:
FLAM GAS 1:
GASES, WHICH AT 20 DEG. C AND A STANDARD PRESSURE OF 101,3 KPA:
(A) ARE IGNITABLE WHEN IN A MIXTURE OF 13% OR LESS BY VOLUME IN AIR; OR
(B) HAVE A FLAMMABLE RANGE WITH AIR OF AT LEAST 12 PERCENTAGE POINTS
REGARDLESS OF THE LOWER FLAMMABLE LIMIT.
PRESS GAS P:
A GAS WHICH WHEN PACKAGED UNDER PRESSURE IS ENTIRELY GASEOUS AT -50 C
INCLUDING ALL GASES WITH A CRITICAL TEMPERATURE <=-50 C
EXPLANATIONS OF THE ABBREVIATIONS IN SECTION 14:
ADR EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS
GOODS BY ROAD
RID REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS GOODS
BY RAIL
TUNNEL RESTRICTION CODE:
B/D; TRANSPORT IN TANKS: PASSAGE NOT PERMITTED THROUGH TUNNELS OF CATEGORY
B, C, D AND E.
OTHER TRANSPORT: PASSAGE NOT PERMITTED THROUGH TUNNELS OF CATEGORY D AND E.
TRANSPORT CATEGORY:
2; HIGHEST TOTAL QUANTITY PER TRANSPORTED UNIT 333 KG OR LITERS.
16C. KEY LITERATURE REFERENCES AND SOURCES FOR DATA:
SOURCES FOR DATA:
PRIMARY DATA FOR THE CALCULATION OF THE HAZARDS HAS PREFERENTIALLY BEEN
TAKEN FROM THE OFFICIAL EUROPEAN CLASSIFICATION LIST, 1272/2008 ANNEX I,
AS UPDATED TO 2014-12-17.
WHERE SUCH DATA WAS LACKING, ON THE SECOND HAND THE DOCUMENTATION ON WHICH
THIS OFFICIAL CLASSIFICATION IS BASED WAS USED, E.G. IUCLID (INTERNATIONAL
UNIFORM CHEMICAL INFORMATION DATABASE). ON THE THIRD HAND, INFORMATION WAS
USED FROM REPUTABLE INTERNATIONAL CHEMICAL SUPPLIERS, AND ON THE FOURTH
HAND FROM OTHER AVAILABLE INFORMATION, E.G. SAFETY DATA SHEETS FROM OTHER
SUPPLIERS OR INFORMATION FROM NON-PROFIT ASSOCIATIONS, WHEREBY THE
RELIABILITY OF THE SOURCE WAS JUDGED BY AN EXPERT. IF, IN SPITE OF THIS,
RELIABLE INFORMATION WAS NOT FOUND, THE HAZARDS WERE JUDGED BY EXPERT
OPINIONS BASED ON THE KNOWN PROPERTIES OF SIMILAR SUBSTANCES, AND ACCORDING
TO THE PRINCIPLES IN 1907/2006 AND 1272/2008.
FULL TEXTS FOR REGULATIONS MENTIONED IN THIS SAFETY DATA SHEET:
453/2010:
COMMISSION REGULATION (EU) NO 453/2010 OF 20 MAY 2010 AMENDING REGULATION
(EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL ON THE
REGISTRATION, EVALUATION, AUTHORISATION AND RESTRICTION OF CHEMICALS
(REACH)
1272/2008:
REGULATION (EC) NO 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 16 DECEMBER 2008 ON CLASSIFICATION, LABELLING AND PACKAGING OF
SUBSTANCES AND MIXTURES, AMENDING AND REPEALING DIRECTIVES 67/548/EEC AND
1999/45/EC, AND AMENDING REGULATION (EC) NO 1907/2006
1999/45/EG:
DIRECTIVE 1999/45/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL OF
31 MAY 1999 CONCERNING THE APPROXIMATION OF THE LAWS, REGULATIONS AND
ADMINISTRATIVE PROVISIONS OF THE MEMBER STATES RELATING TO THE
CLASSIFICATION, PACKAGING AND LABELLING OF DANGEROUS PREPARATIONS
89/391:
COUNCIL DIRECTIVE (89/391/EEC OF 12 JUNE 1989 ON THE INTRODUCTION OF
MEASURES TO ENCOURAGE IMPROVEMENTS IN THE SAFETY AND HEALTH OF WORKERS
AT WORK
98/24:
COUNCIL DIRECTIVE 98/24/EC OF 7 APRIL 1998 ON THE PROTECTION OF THE HEALTH
AND SAFETY OF WORKERS FROM THE RISKS RELATED TO CHEMICAL AGENTS AT WORK
(FOURTEENTH INDIVIDUAL DIRECTIVE WITHIN THE MEANING OF ARTICLE 16(1) OF
DIRECTIVE 89/391/EEC)
1907/2006:
REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 18 DECEMBER 2006 CONCERNING THE REGISTRATION, EVALUATION, AUTHORISATION
AND RESTRICTION OF CHEMICALS (REACH), ESTABLISHING A EUROPEAN CHEMICALS
AGENCY, AMENDING DIRECTIVE 1999/45/EC AND REPEALING COUNCIL REGULATION
(EEC) NO 793/93 AND COMMISSION REGULATION (EC) NO 1488/94 AS WELL AS
COUNCIL DIRECTIVE 76/769/EEC AND COMMISSION DIRECTIVES 91/155/EEC,
93/67/EEC, 93/105/EC AND 2000/21/EC ANNEX I
16D. METHODS OF EVALUATING INFORMATION REFERRED TO IN 1272/2008 ARTICLE 9
WHICH WAS USED FOR THE PURPOSE OF CLASSIFICATION:
THE CALCULATION OF THE HAZARDS OF THIS MIXTURE HAS BEEN PERFORMED AS AN
EVALUATION BY APPLYING A WEIGHT OF EVIDENCE DETERMINATION USING EXPERT
JUDGEMENT IN ACCORDANCE WITH 1272/2008 ANNEX I, WEIGHING ALL AVAILABLE
INFORMATION HAVING A BEARING ON THE DETERMINATION OF THE HAZARDS OF THE
MIXTURE, AND IN ACCORDANCE WITH 1907/2006 ANNEX XI.
16E. LIST OF RELEVANT R PHRASES, HAZARD STATEMENTS, SAFETY PHRASES AND/OR
PRECAUTIONARY STATEMENTS:
FULL TEXT FOR RISK PHRASES MENTIONED IN SECTION 3:
R12: EXTREMELY FLAMMABLE
FULL TEXTS FOR HAZARD STATEMENTS MENTIONED IN SECTION 3:
H220: EXTREMELY FLAMMABLE GAS
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
16F. ADVICE ON ANY TRAINING APPROPRIATE FOR WORKERS TO ENSURE PROTECTION
OF HUMAN HEALTH AND THE ENVIRONMENT WARNING FOR MISUSE:
THIS PRODUCT CAN CAUSE INJURIES IF NOT USED PROPERLY. THE MANUFACTURER, THE
DISTRIBUTOR OR THE SUPPLIER ARE NOT RESPONSIBLE FOR ADVERSE EFFECTS IF THE
PRODUCT IS NOT HANDLED IN ACCORDANCE WITH ITS INTENDED USE.
OTHER RELEVANT INFORMATION:
LABEL INFORMATION IN ACCORDANCE WITH 1999/45/EG:
HAZARD SYMBOL: EXTREMELY FLAMMABLE
R-PHRASES:
R12: EXTREMELY FLAMMABLE
S-PHRASES:
S9: KEEP CONTAINER IN A WELL-VENTILATED PLACE
S16: KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING
EDITORIAL INFORMATION:
THIS SAFETY DATA SHEET HAS BEEN GENERATED BY THE PROGRAM KEMRISK(R*),
KEMRISK SWEDEN AB, TEKNIKRINGEN 10, SE-583 30 LINKOPING, SWEDEN.
SAFETY DATA SHEET FOR SIEVERT MAPP 2211. EDITION 2014-12-17
SAFETY DATA SHEET
IN ACCORDANCE WITH 453/2010 AND 1272/2008
(ALL REFERENCES TO EU REGULATIONS AND DIRECTIVES ARE ABBREVIATED INTO
ONLY THE NUMERIC TERM)
ISSUED: 2014-12-17
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE | |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
TRADE NAME: SIEVERT PROPAN 2209
SUPPLIER'S PRODUCT NUMBER: 220983, 220984, 400G, 788ML
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
IDENTIFIED USES: PROPELLANTS
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY:
SIEVERT AB
BOX 1366
SE-17126 SOLNA
SWEDEN
TELEPHONE: +46 8-629 22 00
E-MAIL: INFO@SIEVERT.SE
1.4. EMERGENCY TELEPHONE NUMBER:
IN CASE OF EMERGENCY CONTACT TOXICOLOGICAL INFORMATION, EMERGENCY TEL 112
(WITHIN EUROPE) OR 1-800-222-1222 (FOR USA). FOR OTHER COUNTRIES, USE THE
BUILT-IN EMERGENCY NUMBER IN YOUR CELL PHONE
FOR NON-EMERGENCY POISON INFORMATION, SEE
HTTP://WWW.WHO.INT/GHO/PHE/CHEMICAL_SAFETY/POISONS_CENTRES/EN/
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION IN ACCORDANCE WITH 1272/2008:
EXTREMELY FLAMMABLE GAS (CATEGORY 1)
COMPRESSED GAS
CLASSIFICATION IN ACCORDANCE WITH 1999/45/EG: EXTREMELY FLAMMABLE; F+; R12.
2.2. LABEL ELEMENTS:
LABEL INFORMATION IN ACCORDANCE WITH 1272/2008:
HAZARD PICTOGRAMS: FLAME
SIGNAL WORDS: DANGER
HAZARD STATEMENTS:
H220: EXTREMELY FLAMMABLE GAS
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
PRECAUTIONARY STATEMENTS:
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING
P377:
LEAKING GAS FIRE: DO NOT EXTINGUISH, UNLESS LEAK CAN BE STOPPED SAFELY
P381: ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO
P410+P403: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE
LABEL INFORMATION IN ACCORDANCE WITH 1999/45/EG: SEE SECTION 16.
2.3. OTHER HAZARDS: NOT RELEVANT.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
THIS PRODUCT IS COMPOSED OF A GAS MIXTURE.
3.2. MIXTURES:
NOTE THAT THE TABLE SHOWS KNOWN HAZARDS OF THE INGREDIENTS IN A PURE FORM.
THESE HAZARDS ARE REDUCED OR ELIMINATED WHEN MIXED OR DILUTED, SEE SECTION
16D.
CONSTITUENT CLASSIFICATION CONCENTRATION
PROPANE:
CAS NO: 74-98-6 FLAM GAS 1, PRESS GAS P; H220, 87,5 - 100%
EC NO: 200-827-9 H280 F+; R12
INDEX NO: 601-003-00-5
ETHANE COMPRESSED:
CAS NO: 74-84-0 FLAM GAS 1A; H220 10 - 7%
EC NO: 200-814-8 F+; R12
INDEX NO: 601-002-00-X
PROPENE:
CAS NO: 115-07-1 FLAM GAS 1, PRESS GAS P; H220, 0 - 5%
EC NO: 204-062-1 H280 F+; R12
INDEX NO: 601-011-00-9
BUTANE <0.1% BUTADIENE:
CAS NO: 106-97-8 FLAM GAS 1, PRESS GAS P; H220, 0 - 2,5%
EC NO: 203-448-7 H280 F+; R12
INDEX NO: 601-004-00-0
EXPLANATIONS TO THE CLASSIFICATION AND LABELLING OF THE INGREDIENTS ARE
GIVEN IN SECTION 16E. OFFICIAL ABBREVIATIONS ARE PRINTED IN NORMAL FONT.
TEXT IN ITALICS ARE SPECIFICATIONS AND/OR COMPLEMENT USED IN THE
CALCULATION OF THE HAZARDS OF THIS MIXTURE, SEE SECTION 16B ALSO CONTAINS
COMPONENT(S) NOT NECESSARY TO LABEL.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
UPON BREATHING IN:
ALLOW THE INJURED PERSON TO REST IN A WARM PLACE WITH FRESH AIR, IF
SYMPTOMS PERSIST SEEK MEDICAL ADVICE.
UPON CONTACT WITH THE EYES:
REMOVE CONTACT LENSES IMMEDIATELY IF POSSIBLE.
RINSE THE EYE FOR SEVERAL MINUTES WITH LUKEWARM WATER. IF IRRITATION
PERSISTS CALL A DOCTOR/OPHTHALMOLOGIST.
UPON SKIN CONTACT:
REMOVE CONTAMINATED CLOTHES.
WARM UP AFFECTED PARTS OF THE BODY IF FROSTBITE IS APPARENT.
IN CASE OF MAJOR FROST INJURIES, PLEASE CONTACT YOUR DOCTOR.
UPON INGESTION: IF SYMPTOMS PERSIST CONTACT A DOCTOR.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: SYMPTOMATIC TREATMENT.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
RECOMMENDED EXTINGUISHING AGENTS:
EXTINGUISH WITH POWDER, CARBON DIOXIDE OR FOAM.
UNSUITABLE EXTINGUISHING AGENTS: SHOULD NOT BE EXTINGUISHED WITH WATER.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
GASES DETRIMENTAL TO HEALTH (CARBON MONOXIDE AND CARBON DIOXIDE) CAN BE
SPREAD IN CASE OF FIRE.
THE GAS FORMS AN EXPLOSIVE MIXTURE WITH AIR.
IN CASE OF FIRE, HIGH PRESSURE MAY BUILD UP CAUSING THE PACKAGING TO
EXPLODE.
FLAMMABLE GAS.
5.3. ADVICE FOR FIRE-FIGHTERS: IN CASE OF FIRE USE A RESPIRATOR MASK.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
CHEMICAL PROTECTION SUITS SHOULD BE WORN FOR ALL SALVAGE AND
DECONTAMINATION WORK.
USE RECOMMENDED SAFETY EQUIPMENT, SEE SECTION 8.
DO NOT INHALE THE GAS.
NOTE, RISK OF IGNITION AND EXPLOSION.
UPON SMALL SPILLAGE <5 KG VACATE THE AREA AND VENTILATE THE FUMES.
SWITCH OFF EQUIPMENT WHICH HAS AN EXPOSED FLAME, GLOWS, OR HAS A HEAT
SOURCE OF SOME OTHER KIND.
NOTE, RISK FOR FORMATION OF SPARKS DUE TO STATIC ELECTRICITY. DO NOT REMOVE
CLOTHING IN A ROOM WHERE SPILLAGE HAS OCCURRED.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO SOIL, WATER OR AIR.
AVOID DISCHARGE INTO SEWERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
EVACUATE THE AREA AND VENTILATE FUMES. NOTE, RISK FOR EXPLOSION.
RESIDUES LEFT BEHIND AFTER CLEANING SHALL BE TREATED AS HAZARDOUS WASTE.
FOR FURTHER INFORMATION, CONTACT THE LOCAL AUTHORITY SANITISATION WORKS.
PRESENT THIS SAFETY DATA SHEET.
6.4. REFERENCE TO OTHER SECTIONS: NOT APPLICABLE
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT INHALE FUMES AND AVOID CONTACT WITH SKIN AND EYES.
THE PRODUCT SHOULD BE STORED IN A MANNER WHICH PREVENTS HAZARDS TO HEALTH
AND THE ENVIRONMENT. AVOID EXPOSURE TO HUMANS AND ANIMALS AND DO NOT
DISCHARGE THE PRODUCT IN A SENSITIVE ENVIRONMENT.
STORE TIGHTLY, IN ORIGINAL PACKAGING.
STORE THIS PRODUCT SEPARATELY FROM FOOD ITEMS AND KEEP IT OUT OF THE REACH
OF CHILDREN AND PETS.
DO NOT EAT, DRINK OR SMOKE IN PREMISES WHERE THIS PRODUCT IS STORED.
OPEN FIRES, HOT OBJECTS, SPARK FORMATION, OR OTHER SOURCES OF IGNITION,
ARE NOT ALLOWED IN THE PREMISES WHERE THIS PRODUCT IS HANDLED.
PREVENT BUILD UP OF STATIC ELECTRICITY BY UTILISING A SEMI-CONDUCTING FLOOR
AND SHOE SOLES AND KEEP HUMIDITY ABOVE 50%.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN A DRY PLACE NOT ABOVE NORMAL ROOM TEMPERATURE.
HANDLE IN A PREMISES WHICH IS WELL VENTILATED.
STORE IN A WELL-VENTILATED SPACE.
AN EVACUATION PLAN SHOULD BE AVAILABLE AND EVACUATION ROUTES MUST NOT BE
BLOCKED.
DO NOT STORE IN DIRECT SUNLIGHT.
CONTACT WITH THE LIQUID PRODUCT CAN CAUSE INJURIES FROM HYPOTHERMIA.
7.3. SPECIFIC END USES: NOT RELEVANT.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
8.1.1. NATIONAL LIMIT VALUES, UNITED KINGDOM:
BUTANE <0.1% BUTADIENE:
TIME-WEIGHTED-AVERAGE EXPOSURE LIMIT (TWA): 600 PPM / 1450 MG/M3
SHORT TERM EXPOSURE LIMIT (STEL): 750 PPM / 1810 MG/M3
OTHER INGREDIENTS (CF SECTION 3) HAVE NO OCCUPATIONAL EXPOSURE LIMIT
VALUES.
8.2. EXPOSURE CONTROLS:
IN TERMS OF MINIMIZING RISKS, ATTENTION MUST BE PAID TO THE PHYSICAL
HAZARDS (SEE SECTIONS 2 AND 10) OF THIS PRODUCT ACCORDING TO EU DIRECTIVES
89/391 AND 98/24 AND NATIONAL OCCUPATIONAL LEGISLATION.
PROTECTIVE GLOVES ARE NORMALLY NOT NEEDED DUE TO THE PROPERTIES OF THIS
PRODUCT, BUT MAY BE NECESSARY FOR OTHER REASONS, E.G. MECHANICAL RISKS,
TEMPERATURE CONDITIONS OR MICROBIOLOGICAL RISKS. VERY SENSITIVE PERSONS CAN
USE GLOVES LABELLED "LOW CHEMICAL RESISTANT" OR "WATERPROOF" OR WITH THE
PICTOGRAM INDICATED HERE.
A RESPIRATORY MASK MAY BE REQUIRED.
FOR LIMITATION OF ENVIRONMENTAL EXPOSURE, SEE SECTION 12.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
A) APPEARANCE:
FORM: COMPRESSED GAS
COLOUR: COLOURLESS
B) ODOUR: UNPLEASANTLY
C) ODOUR THRESHOLD: NOT APPLICABLE
D) PH: NOT APPLICABLE
E) MELTING POINT/FREEZING POINT: -188 DEG. C
F) INITIAL BOILING POINT AND BOILING RANGE:
CA -42 DEG. C AT ATMOSPHERIC PRESSURE (101325 PA)
G) FLASH POINT: -104 DEG. C
H) EVAPORATION RATE: NOT APPLICABLE
I) FLAMMABILITY (SOLID, GAS): EXTREMELY FLAMMABLE GAS
J) UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER EXPLOSION LIMIT: 2.2%
UPPER EXPLOSION LIMIT: 9.6%
K) VAPOUR PRESSURE: 740 KPA (15 DEG. C)
L) VAPOUR DENSITY: NOT APPLICABLE
M) RELATIVE DENSITY: 0,5 KG/L
N) SOLUBILITY: SOLUBILITY IN WATER VERY SPARSELY SOLUBLE(<0.1%)
O) PARTITION COEFFICIENT N-OCTANOL/WATER: NOT APPLICABLE
P) AUTO-IGNITION TEMPERATURE: NOT APPLICABLE
Q) DECOMPOSITION TEMPERATURE: NOT APPLICABLE
R) VISCOSITY: NOT APPLICABLE
S) EXPLOSIVE PROPERTIES: NOT APPLICABLE
T) OXIDISING PROPERTIES: NOT APPLICABLE
9.2. OTHER INFORMATION: NO DATA AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THE PRODUCT CONTAINS NO SUBSTANCES WHICH CAN LEAD TO HAZARDOUS REACTIONS
AT NORMAL USE.
10.2. CHEMICAL STABILITY:
THE PRODUCT IS STABLE AT NORMAL STORAGE AND HANDLING CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NO HAZARDOUS REACTIONS KNOWN.
10.4. CONDITIONS TO AVOID: AVOID HEAT, SPARKS AND OPEN FLAMES.
10.5. INCOMPATIBLE MATERIALS: AVOID CONTACT WITH OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: NONE UNDER NORMAL CONDITIONS.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
GENERAL OR UNSPECIFIC TOXICITY:
THIS PRODUCT'S MAIN RISK IS ITS FLAMMABILITY.
ACUTE EFFECTS: NOT CLASSIFIED AS AN ACUTELY TOXIC SUBSTANCE.
HARMFULNESS: THE PRODUCT IS NOT CLASSIFIED AS HARMFUL TO HEALTH.
CORROSIVE AND IRRITATING EFFECTS:
CONTACT WITH LIQUEFIED GAS MAY CAUSE FROSTBITE ON SKIN AND EYES.
EFFECT ON JUDGEMENT AND OTHER PSYCHOLOGICAL EFFECTS:
AT HIGH CONCENTRATIONS THERE IS AN ANESTHETIC OR NARCOTIC EFFECT.
PROLONGED INHALATION CAN CAUSE LOSS OF CONSCIOUSNESS AND/OR DEATH.
RELEVANT TOXICOLOGICAL PROPERTIES:
PROPANE:
LC50 RAT (INHALATION) 4H: 658 MG/L INHALATION
BUTANE <0.1% BUTADIENE:
LC50 RAT (INHALATION) 4H: 658 MG/L INHALATION
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
PROPANE:
LC50 FRESHWATER WATER FLEA (DAPHNIA MAGNA) 48H: 16,3 MG/L
LC50 FISH 96H: 16,1 MG/L
IC50 ALGAE 72H: 11,3 MG/L
IN THE QUANTITIES WITH WHICH THIS PRODUCT IS USED, EFFECTS ON THE
ENVIRONMENT ARE NEGLIGIBLE. NOTE HOWEVER, THAT THE LOCAL ENVIRONMENT MAY
BE AFFECTED, AND ALL DISCHARGE TO THE NATURAL ENVIRONMENT MAY IMPACT
ECOSYSTEMS.
12.2. PERSISTENCE AND DEGRADABILITY:
THE PRODUCT DEGRADES IN THE NATURAL ENVIRONMENT.
12.3. BIOACCUMULATIVE POTENTIAL:
NEITHER THIS PRODUCT, NOR ITS CONTENTS, ACCUMULATES IN NATURE.
12.4. MOBILITY IN SOIL:
NO INFORMATION ABOUT MOBILITY IN THE NATURE EXISTS BUT THERE IS NO REASON
TO SUPPOSE THE PRODUCT TO BE ECOLOGICALLY HARMFUL BECAUSE OF THIS.
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES THAT ARE ASSESSED TO BE A PBT
OR A VPVB.
12.6. OTHER ADVERSE EFFECTS: NONE KNOWN EFFECTS OR HAZARDS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE HANDLING FOR THE PRODUCT:
PRODUCT AS WELL AS PACKAGING MUST BE DISPOSED AS HAZARDOUS WASTE.
ALSO TAKE LOCAL REGULATIONS FOR DEALING WITH WASTE INTO ACCOUNT.
CF ALSO NATIONAL WASTE REGULATIONS.
SPECIAL ADVISES FOR WASTE HANDLING: 16 05 04.
RECYCLING OF THE PRODUCT: THIS PRODUCT IS NOT USUALLY RECYCLED.
TRANSPORTATION OF WASTE: NOT INDICATED
| SECTION 14: TRANSPORT INFORMATION | |
THIS PRODUCT IS ONLY SUPPOSED TO BE TRANSPORTED BY ROAD OR RAILWAY AND
JUST THE TRANSPORT REGULATIONS ADR/RID THUS APPLY.
14.1. UN NUMBER: 1978
14.2. UN PROPER SHIPPING NAME: PROPANE
14.3. TRANSPORT HAZARD CLASS(ES):
CLASS:
2: GASES
CLASSIFICATION CODE (ADR/RID):
2F:
SUBSIDIARY RISK (IMDG):
LABELS: CLASS 2.1 - FLAMMABLE GASES
14.4. PACKING GROUP:
PACKING GROUP: NOT APPLICABLE
14.5. ENVIRONMENTAL HAZARDS: NOT APPLICABLE
14.6. SPECIAL PRECAUTIONS FOR USER:
TUNNEL RESTRICTIONS:
TUNNEL CATEGORY: B/D.
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC
CODE: NOT APPLICABLE
14.8 OTHER TRANSPORT INFORMATION:
TRANSPORT CATEGORY:
2; HIGHEST TOTAL QUANTITY PER TRANSPORTED UNIT 333 KG OR LITERS.
| SECTION 15: REGULATORY INFORMATION | |
15.1. SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE: NOT APPLICABLE.
15.2. CHEMICAL SAFETY ASSESSMENT:
CHEMICAL SAFETY REPORT ACCORDING TO 1907/2006 ANNEX I IS NOT REQUIRED FOR
THIS PRODUCT.
| SECTION 16: OTHER INFORMATION | |
16A. INDICATION OF WHERE CHANGES HAVE BEEN MADE TO THE PREVIOUS VERSION
OF THE SAFETY DATA SHEET:
REVISIONS OF THIS DOCUMENT: THIS IS THE FIRST VERSION.
16B. LEGEND TO ABBREVIATIONS AND ACRONYMS USED IN THE SAFETY DATA SHEET:
FULL TEXTS FOR HAZARD CLASS AND CATEGORY CODE MENTIONED IN SECTION 3:
FLAM GAS 1: EXTREMELY FLAMMABLE GAS (CATEGORY 1)
PRESS GAS P: COMPRESSED GAS
FLAM GAS 1A: EXTREMELY FLAMMABLE GAS, IGNITABLE <13% (CATEGORY 1 A)
NO TOX HAZ: NOT CLASSIFIED AS TOXIC
COMPREHENSIVE DEFINITION OF THE HAZARDS MENTIONED IN SECTION 2:
FLAM GAS 1:
GASES, WHICH AT 20 DEG. C AND A STANDARD PRESSURE OF 101,3 KPA:
(A) ARE IGNITABLE WHEN IN A MIXTURE OF 13% OR LESS BY VOLUME IN AIR; OR
(B) HAVE A FLAMMABLE RANGE WITH AIR OF AT LEAST 12 PERCENTAGE POINTS
REGARDLESS OF THE LOWER FLAMMABLE LIMIT.
PRESS GAS P:
A GAS WHICH WHEN PACKAGED UNDER PRESSURE IS ENTIRELY GASEOUS AT -50 C
INCLUDING ALL GASES WITH A CRITICAL TEMPERATURE <=-50 C
EXPLANATIONS OF THE ABBREVIATIONS IN SECTION 14:
ADR EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS
GOODS BY ROAD
RID REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS GOODS
BY RAIL
TUNNEL RESTRICTION CODE:
B/D; TRANSPORT IN TANKS: PASSAGE NOT PERMITTED THROUGH TUNNELS OF
CATEGORY B, C, D AND E.
OTHER TRANSPORT: PASSAGE NOT PERMITTED THROUGH TUNNELS OF CATEGORY D AND E.
TRANSPORT CATEGORY:
2; HIGHEST TOTAL QUANTITY PER TRANSPORTED UNIT 333 KG OR LITERS.
16C. KEY LITERATURE REFERENCES AND SOURCES FOR DATA:
SOURCES FOR DATA:
PRIMARY DATA FOR THE CALCULATION OF THE HAZARDS HAS PREFERENTIALLY BEEN
TAKEN FROM THE OFFICIAL EUROPEAN CLASSIFICATION LIST, 1272/2008 ANNEX I,
AS UPDATED TO 2014-12-17.
WHERE SUCH DATA WAS LACKING, ON THE SECOND HAND THE DOCUMENTATION ON WHICH
THIS OFFICIAL CLASSIFICATION IS BASED WAS USED, E.G. IUCLID (INTERNATIONAL
UNIFORM CHEMICAL INFORMATION DATABASE). ON THE THIRD HAND, INFORMATION WAS
USED FROM REPUTABLE INTERNATIONAL CHEMICAL SUPPLIERS, AND ON THE FOURTH
HAND FROM OTHER AVAILABLE INFORMATION, E.G. SAFETY DATA SHEETS FROM OTHER
SUPPLIERS OR INFORMATION FROM NON-PROFIT ASSOCIATIONS, WHEREBY THE
RELIABILITY OF THE SOURCE WAS JUDGED BY AN EXPERT. IF, IN SPITE OF THIS,
RELIABLE INFORMATION WAS NOT FOUND, THE HAZARDS WERE JUDGED BY EXPERT
OPINIONS BASED ON THE KNOWN PROPERTIES OF SIMILAR SUBSTANCES, AND ACCORDING
TO THE PRINCIPLES IN 1907/2006 AND 1272/2008.
FULL TEXTS FOR REGULATIONS MENTIONED IN THIS SAFETY DATA SHEET:
453/2010:
COMMISSION REGULATION (EU) NO 453/2010 OF 20 MAY 2010 AMENDING REGULATION
(EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL ON THE
REGISTRATION, EVALUATION, AUTHORISATION AND RESTRICTION OF CHEMICALS
(REACH)
1272/2008:
REGULATION (EC) NO 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 16 DECEMBER 2008 ON CLASSIFICATION, LABELLING AND PACKAGING OF
SUBSTANCES AND MIXTURES, AMENDING AND REPEALING DIRECTIVES 67/548/EEC AND
1999/45/EC, AND AMENDING REGULATION (EC) NO 1907/2006
1999/45/EG:
DIRECTIVE 1999/45/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL OF
31 MAY 1999 CONCERNING THE APPROXIMATION OF THE LAWS, REGULATIONS AND
ADMINISTRATIVE PROVISIONS OF THE MEMBER STATES RELATING TO THE
CLASSIFICATION, PACKAGING AND LABELLING OF DANGEROUS PREPARATIONS
89/391:
COUNCIL DIRECTIVE (89/391/EEC OF 12 JUNE 1989 ON THE INTRODUCTION OF
MEASURES TO ENCOURAGE IMPROVEMENTS IN THE SAFETY AND HEALTH OF WORKERS
AT WORK
98/24:
COUNCIL DIRECTIVE 98/24/EC OF 7 APRIL 1998 ON THE PROTECTION OF THE HEALTH
AND SAFETY OF WORKERS FROM THE RISKS RELATED TO CHEMICAL AGENTS AT WORK
(FOURTEENTH INDIVIDUAL DIRECTIVE WITHIN THE MEANING OF ARTICLE 16(1) OF
DIRECTIVE 89/391/EEC)
1907/2006:
REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
OF 18 DECEMBER 2006 CONCERNING THE REGISTRATION, EVALUATION, AUTHORISATION
AND RESTRICTION OF CHEMICALS (REACH), ESTABLISHING A EUROPEAN CHEMICALS
AGENCY, AMENDING DIRECTIVE 1999/45/EC AND REPEALING COUNCIL REGULATION
(EEC) NO 793/93 AND COMMISSION REGULATION (EC) NO 1488/94 AS WELL AS
COUNCIL DIRECTIVE 76/769/EEC AND COMMISSION DIRECTIVES 91/155/EEC,
93/67/EEC, 93/105/EC AND 2000/21/EC ANNEX I
16D. METHODS OF EVALUATING INFORMATION REFERRED TO IN 1272/2008 ARTICLE 9
WHICH WAS USED FOR THE PURPOSE OF CLASSIFICATION:
THE CALCULATION OF THE HAZARDS OF THIS MIXTURE HAS BEEN PERFORMED AS AN
EVALUATION BY APPLYING A WEIGHT OF EVIDENCE DETERMINATION USING EXPERT
JUDGEMENT IN ACCORDANCE WITH 1272/2008 ANNEX I, WEIGHING ALL AVAILABLE
INFORMATION HAVING A BEARING ON THE DETERMINATION OF THE HAZARDS OF THE
MIXTURE, AND IN ACCORDANCE WITH 1907/2006 ANNEX XI.
16E. LIST OF RELEVANT R PHRASES, HAZARD STATEMENTS, SAFETY PHRASES AND/OR
PRECAUTIONARY STATEMENTS:
FULL TEXT FOR RISK PHRASES MENTIONED IN SECTION 3:
R12: EXTREMELY FLAMMABLE
FULL TEXTS FOR HAZARD STATEMENTS MENTIONED IN SECTION 3:
H220: EXTREMELY FLAMMABLE GAS
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
16F. ADVICE ON ANY TRAINING APPROPRIATE FOR WORKERS TO ENSURE PROTECTION
OF HUMAN HEALTH AND THE ENVIRONMENT:
WARNING FOR MISUSE:
THIS PRODUCT CAN CAUSE INJURIES IF NOT USED PROPERLY. THE MANUFACTURER,
THE DISTRIBUTOR OR THE SUPPLIER ARE NOT RESPONSIBLE FOR ADVERSE EFFECTS IF
THE PRODUCT IS NOT HANDLED IN ACCORDANCE WITH ITS INTENDED USE.
OTHER RELEVANT INFORMATION:
LABEL INFORMATION IN ACCORDANCE WITH 1999/45/EG:
HAZARD SYMBOL: EXTREMELY FLAMMABLE
R-PHRASES:
R12: EXTREMELY FLAMMABLE
S-PHRASES:
S9: KEEP CONTAINER IN A WELL-VENTILATED PLACE
S16: KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING
EDITORIAL INFORMATION:
THIS SAFETY DATA SHEET HAS BEEN GENERATED BY THE PROGRAM KEMRISK(R*),
KEMRISK SWEDEN AB, TEKNIKRINGEN 10, SE-583 30 LINKPOING, SWEDEN.
SAFETY DATA SHEET FOR SIEVERT PROPAN 2209. EDITION 2014-12-17