| Common Name: | HOMAX 4575, GPSP-4575 |
| Manufacturer: | PPG INDUSTRIES |
| SDS Revision Date: | 9/14/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 45MV56 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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PPG
SAFETY DATA SHEET
DATE OF ISSUE/DATE OF REVISION: 14 SEPTEMBER 2015
VERSION: 2.01
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: HOMAX 4575
PRODUCT CODE: GPSP-4575
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: AEROSOL.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
PRODUCT USE: INDUSTRIAL APPLICATIONS.
USE OF THE SUBSTANCE/MIXTURE: COATING.
USES ADVISED AGAINST: NOT APPLICABLE.
SUPPLIER:
PPG INDUSTRIES, INC.
ONE PPG PLACE
PITTSBURGH, PA 15272
EMERGENCY TELEPHONE NUMBER:
(412) 434-4515 (U.S.)
(514) 645-1320 (CANADA)
01-800-00-21-400 (MEXICO)
TECHNICAL PHONE NUMBER: 1-800-441-9695 (8:00 AM TO 5:00 PM EST)
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE AEROSOLS: CATEGORY 1
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN TOXICITY:
6.3%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CAUSES SERIOUS EYE IRRITATION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
WEAR EYE OR FACE PROTECTION. KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS,
OPEN FLAMES AND OTHER IGNITION SOURCES. NO SMOKING. DO NOT SPRAY ON AN
OPEN FLAME OR OTHER IGNITION SOURCE. WASH HANDS THOROUGHLY AFTER HANDLING.
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
DISPOSAL: NOT APPLICABLE.
SUPPLEMENTAL LABEL ELEMENTS:
CONTENTS UNDER PRESSURE. IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL
OCCUR AND THE CONTAINER MAY BURST OR EXPLODE. DO NOT PUNCTURE OR
INCINERATE. KEEP AWAY FROM HEAT AND DIRECT SUNLIGHT. AVOID CONTACT WITH
SKIN AND CLOTHING. WASH THOROUGHLY AFTER HANDLING. EMITS TOXIC FUMES WHEN
HEATED.
HAZARDS NOT OTHERWISE CLASSIFIED:
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
PRODUCT NAME: HOMAX 4575
INGREDIENT NAME % CAS NUMBER
CALCIUM CARBONATE >/=25 - <50 471-34-1
DIMETHYL ETHER >/=10 - <24 115-10-6
TALC, NOT CONTAINING ASBESTIFORM FIBRES >/=3 - <5 14807-96-6
MAGNESIUM CARBONATE >/=1 - <3 546-93-0
2-METHYLPENTANE-2,4-DIOL >/=1 - <1.9 107-41-5
2,2',2"-(HEXAHYDRO-1,3,5-TRIAZINE- >/=0.1 - <0.3 4719-04-4
1,3,5-TRIYL)TRIETHANOL
SUB CODES REPRESENT SUBSTANCES WITHOUT REGISTERED CAS NUMBERS.
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
IF INGESTION, IRRITATION, ANY TYPE OF OVEREXPOSURE OR SYMPTOMS OF
OVEREXPOSURE OCCUR DURING OR PERSISTS AFTER USE OF THIS PRODUCT, CONTACT
A POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN IMMEDIATELY; HAVE
SAFETY DATA SHEET INFORMATION AVAILABLE. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS OR CONVULSING PERSON.
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
REMOVE CONTACT LENSES, IRRIGATE COPIOUSLY WITH CLEAN, FRESH WATER, HOLDING
THE EYELIDS APART FOR AT LEAST 10 MINUTES AND SEEK IMMEDIATE MEDICAL
ADVICE.
INHALATION:
REMOVE TO FRESH AIR. KEEP PERSON WARM AND AT REST. IF NOT BREATHING, IF
BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS, PROVIDE ARTIFICIAL
RESPIRATION OR OXYGEN BY TRAINED PERSONNEL.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND SHOES. WASH SKIN THOROUGHLY WITH SOAP AND
WATER OR USE RECOGNIZED SKIN CLEANSER. DO NOT USE SOLVENTS OR THINNERS.
INGESTION:
IF SWALLOWED, SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THIS CONTAINER OR
LABEL. KEEP PERSON WARM AND AT REST. DO NOT INDUCE VOMITING.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: DEFATTING TO THE SKIN. MAY CAUSE SKIN DRYNESS AND IRRITATION.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
DRYNESS
CRACKING
INGESTION: NO SPECIFIC DATA.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY
IF LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
EXTREMELY FLAMMABLE AEROSOL. IN A FIRE OR IF HEATED, A PRESSURE INCREASE
WILL OCCUR AND THE CONTAINER MAY BURST, WITH THE RISK OF A SUBSEQUENT
EXPLOSION. GAS MAY ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL A
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK, CAUSING
FIRE OR EXPLOSION. BURSTING AEROSOL CONTAINERS MAY BE PROPELLED FROM A
FIRE AT HIGH SPEED. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. IN THE CASE OF AEROSOLS BEING RUPTURED, CARE
SHOULD BE TAKEN DUE TO THE RAPID ESCAPE OF THE PRESSURIZED CONTENTS AND
PROPELLANT. IF A LARGE NUMBER OF CONTAINERS ARE RUPTURED, TREAT AS A BULK
MATERIAL SPILLAGE ACCORDING TO THE INSTRUCTIONS IN THE CLEAN-UP SECTION.
DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. SHUT OFF ALL IGNITION
SOURCES. NO FLARES, SMOKING OR FLAMES IN HAZARD AREA. AVOID BREATHING
VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR
WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALISED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS.
SEE ALSO THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL
OR AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE
SPARK-PROOF TOOLS AND EXPLOSION-PROOF EQUIPMENT. DILUTE WITH WATER AND
MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE, ABSORB
WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL
CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE
SPARK-PROOF TOOLS AND EXPLOSION-PROOF EQUIPMENT. APPROACH RELEASE FROM
UPWIND. PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED
AREAS. WASH SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS
FOLLOWS. CONTAIN AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT
MATERIAL E.G. SAND, EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE
IN CONTAINER FOR DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13).
DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED
ABSORBENT MATERIAL MAY POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8).
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER US E. DO NOT INGEST. AVOID
CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING GAS. AVOID BREATHING
VAPOR OR MIST. USE ONLY WITH ADEQUATE VENTILATION. WEAR APPROPRIATE
RESPIRATOR WHEN VENTILATION IS INADEQUATE. STORE AND USE AWAY FROM HEAT,
SPARKS, OPEN FLAME OR ANY OTHER IGNITION SOURCE. USE EXPLOSION-PROOF
ELECTRICAL (VENTILATING, LIGHTING AND MATERIAL HANDLING) EQUIPMENT. USE
ONLY NON-SPARKING TOOLS. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND
CAN BE HAZARDOUS.
SPECIAL PRECAUTIONS:
| IF THIS MATERIAL IS PART OF A MULTIPLE COMPONENT SYSTEM, READ THE SAFETY
| DATA SHEET(S) FOR THE OTHER COMPONENT OR COMPONENTS BEFORE BLENDING AS
| THE RESULTING MIXTURE MAY HAVE THE HAZARDS OF ALL OF ITS PARTS.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING
AND PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8
FOR ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
| STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE AWAY FROM DIRECT
| SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE
| MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. ELIMINATE ALL IGNITION
| SOURCES. USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL
| CONTAMINATION.
| DO NOT STORE BELOW THE FOLLOWING TEMPERATURE: 0 C / 32 F.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
CALCIUM CARBONATE ACGIH TLV (UNITED STATES).
TWA: 3 MG/M3
FORM: RESPIRABLE
TWA: 10 MG/M3
FORM: TOTAL DUST
OSHA PEL (UNITED STATES).
TWA: 5 MG/M3
FORM: RESPIRABLE
TWA: 15 MG/M3
OSHA PEL (UNITED STATES, 2/2013).
TWA: 5 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
DIMETHYL ETHER NONE.
TALC, NOT CONTAINING ASBESTIFORM ACGIH TLV (UNITED STATES, 4/2014).
FIBRES TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE
OSHA PEL Z3 (UNITED STATES, 2/2013).
TWA: 20 MPPCF 8 HOURS.
FORM: NOT CONTAINING ASBESTOS
MAGNESIUM CARBONATE OSHA PEL (UNITED STATES, 2/2013).
TWA: 5 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
2-METHYLPENTANE-2,4-DIOL ACGIH TLV (UNITED STATES, 4/2014).
C: 121 MG/M3
C: 25 PPM
2,2',2"-(HEXAHYDRO-1,3,5- NONE.
TRIAZINE-1,3,5-TRIYL)TRIETHANOL
KEY TO ABBREVIATIONS:
A = ACCEPTABLE MAXIMUM PEAK
ACGIH = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS.
C = CEILING LIMIT
F = FUME
IPEL = INTERNAL PERMISSIBLE EXPOSURE LIMIT
OSHA = OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION.
R = RESPIRABLE
S = POTENTIAL SKIN ABSORPTION
SR = RESPIRATORY SENSITIZATION
SS = SKIN SENSITIZATION
STEL = SHORT TERM EXPOSURE LIMIT VALUES
TD = TOTAL DUST
TLV = THRESHOLD LIMIT VALUE
TWA = TIME WEIGHTED AVERAGE
Z = OSHA 29CFR 1910.1200 SUBPART Z - TOXIC AND HAZARDOUS SUBSTANCES
CONSULT LOCAL AUTHORITIES FOR ACCEPTABLE EXPOSURE LIMITS.
RECOMMENDED MONITORING PROCEDURES:
IF THIS PRODUCT CONTAINS INGREDIENTS WITH EXPOSURE LIMITS, PERSONAL,
WORKPLACE ATMOSPHERE OR BIOLOGICAL MONITORING MAY BE REQUIRED TO DETERMINE
THE EFFECTIVENESS OF THE VENTILATION OR OTHER CONTROL MEASURES AND/OR THE
NECESSITY TO USE RESPIRATORY PROTECTIVE EQUIPMENT. REFERENCE SHOULD BE
MADE TO APPROPRIATE MONITORING STANDARDS. REFERENCE TO NATIONAL GUIDANCE
DOCUMENTS FOR METHODS FOR THE DETERMINATION OF HAZARDOUS SUBSTANCES WILL
ALSO BE REQUIRED.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. IF USER OPERATIONS GENERATE DUST,
FUMES, GAS, VAPOR OR MIST, USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE
WORKING PERIOD.
APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY CONTAMINATED
CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE THAT EYEWASH
STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION LOCATION.
EYE/FACE PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTISTATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR. IF WORKERS ARE EXPOSED TO CONCENTRATIONS ABOVE THE EXPOSURE
LIMIT, THEY MUST USE APPROPRIATE, CERTIFIED RESPIRATORS. USE A PROPERLY
FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH AN APPROVED
STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: NOT AVAILABLE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT: NOT AVAILABLE.
BOILING POINT: >37.78 DEG. C (>100 DEG. F)
FLASH POINT:
CLOSED CUP: -41.11 DEG. C (-42 DEG. F)
MATERIAL SUPPORTS COMBUSTION.: YES.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: 1.6
DENSITY (LBS/GAL ): 13.35
SOLUBILITY:
SOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (40 DEG. C (104 DEG. F)): >0.21 CM2/S (>21 CST)
VOLATILITY: 50% (W/W)
% SOLID. (W/W): 50
AEROSOL PRODUCT:
TYPE OF AEROSOL: SPRAY
| HEAT OF COMBUSTION: 5.691 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
WHEN EXPOSED TO HIGH TEMPERATURES MAY PRODUCE HAZARDOUS DECOMPOSITION
PRODUCTS.
REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8.
INCOMPATIBLE MATERIALS:
KEEP AWAY FROM THE FOLLOWING MATERIALS TO PREVENT STRONG EXOTHERMIC
REACTIONS: OXIDIZING AGENTS, STRONG ALKALIS, STRONG ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON MONOXIDE, CARBON DIOXIDE, SMOKE, OXIDES OF NITROGEN.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
CALCIUM CARBONATE LD50 ORAL RAT 6450 MG/KG
DIMETHYL ETHER LC50 INHALATION RAT 164000 PPM 4 HOURS
GAS.
LC50 INHALATION RAT 309 G/M3 4 HOURS
VAPOR
MAGNESIUM CARBONATE LD50 ORAL RAT 8000 MG/KG
2-METHYLPENTANE- LD50 DERMAL RABBIT 8.56 G/KG
2,4-DIOL LD50 ORAL RAT 3.7 G/KG
2,2',2"-(HEXAHYDRO- LD50 DERMAL RABBIT >2 G/KG
1,3,5-TRIAZINE-1,3,5- LD50 ORAL RAT 0.535 G/KG
TRIYL)TRIETHANOL
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
IRRITATION/CORROSION:
CONCLUSION/SUMMARY SKIN: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
EYES: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
RESPIRATORY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
SENSITIZATION:
CONCLUSION/SUMMARY:
SKIN: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
RESPIRATORY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
MUTAGENICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
CARCINOGENICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
REPRODUCTIVE TOXICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
TERATOGENICITY:
CONCLUSION/SUMMARY: THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY
TALC, NOT CONTAINING ASBESTIFORM FIBRES CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT AVAILABLE.
TARGET ORGANS:
CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS: BRAIN.
CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS:
LUNGS, CARDIOVASCULAR SYSTEM, UPPER RESPIRATORY TRACT, SKIN, CENTRAL
NERVOUS SYSTEM (CNS), EYE, LENS OR CORNEA.
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: DEFATTING TO THE SKIN. MAY CAUSE SKIN DRYNESS AND IRRITATION.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
DRYNESS
CRACKING
INGESTION: NO SPECIFIC DATA.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND
LONG TERM EXPOSURE:
CONCLUSION/SUMMARY:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF. EXPOSURE TO COMPONENT
SOLVENT VAPOR CONCENTRATIONS IN EXCESS OF THE STATED OCCUPATIONAL EXPOSURE
LIMIT MAY RESULT IN ADVERSE HEALTH EFFECTS SUCH AS MUCOUS MEMBRANE AND
RESPIRATORY SYSTEM IRRITATION AND ADVERSE EFFECTS ON THE KIDNEYS, LIVER
AND CENTRAL NERVOUS SYSTEM. SYMPTOMS AND SIGNS INCLUDE HEADACHE, DIZZINESS,
FATIGUE, MUSCULAR WEAKNESS, DROWSINESS AND, IN EXTREME CASES, LOSS OF
CONSCIOUSNESS. SOLVENTS MAY CAUSE SOME OF THE ABOVE EFFECTS BY ABSORPTION
THROUGH THE SKIN. THERE IS SOME EVIDENCE THAT REPEATED EXPOSURE TO ORGANIC
SOLVENT VAPORS IN COMBINATION WITH CONSTANT LOUD NOISE CAN CAUSE GREATER
HEARING LOSS THAN EXPECTED FROM EXPOSURE TO NOISE ALONE. IF SPLASHED IN
THE EYES, THE LIQUID MAY CAUSE IRRITATION AND REVERSIBLE DAMAGE. INGESTION
MAY CAUSE NAUSEA, DIARRHEA AND VOMITING. THIS TAKES INTO ACCOUNT, WHERE
KNOWN, DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS OF COMPONENTS
FROM SHORT-TERM AND LONG-TERM EXPOSURE BY ORAL, INHALATION AND DERMAL
ROUTES OF EXPOSURE AND EYE CONTACT.
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
POTENTIAL DELAYED EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
POTENTIAL DELAYED EFFECTS:
THERE ARE NO DATA AVAILABLE ON THE MIXTURE ITSELF.
POTENTIAL CHRONIC HEALTH EFFECTS:
GENERAL:
PROLONGED OR REPEATED CONTACT CAN DEFAT THE SKIN AND LEAD TO IRRITATION,
CRACKING AND/OR DERMATITIS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 3115.7 MG/KG
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY: NOT AVAILABLE.
PERSISTENCE AND DEGRADABILITY: NOT AVAILABLE.
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
DIMETHYL ETHER 0.1 LOW
2-METHYLPENTANE-2,4-DIOL 0.58 LOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. EMPTY CONTAINERS OR LINERS MAY RETAIN
SOME PRODUCT RESIDUES. DO NOT PUNCTURE OR INCINERATE CONTAINER.
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
REFER TO SECTION 7:
HANDLING AND STORAGE AND SECTION 8:
EXPOSURE CONTROLS/PERSONAL PROTECTION FOR ADDITIONAL HANDLING INFORMATION
AND PROTECTION OF EMPLOYEES. SECTION 6. ACCIDENTAL RELEASE MEASURES
| SECTION 14. TRANSPORT INFORMATION | |
DOT IMDG IATA
UN NUMBER UN1950 UN1950 UN1950
UN PROPER SHIPPING NAME AEROSOLS AEROSOLS AEROSOLS
TRANSPORT HAZARD CLASS(ES) 2.1 2.1 2.1
PACKING GROUP
ENVIRONMENTAL HAZARDS NO. NO. NO.
MARINE POLLUTANT SUBSTANCES NOT NOT NOT
APPLICABLE. APPLICABLE. APPLICABLE.
ADDITIONAL INFORMATION:
DOT: NONE IDENTIFIED.
IMDG: NONE IDENTIFIED.
IATA: NONE IDENTIFIED.
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
| SECTION 15. REGULATORY INFORMATION | |
UNITED STATES:
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
UNITED STATES - TSCA 5(A)2 - FINAL SIGNIFICANT NEW USE RULES:
SODIUM NITRITE: LISTED
SARA 302/304:
SARA 304 RQ: NOT APPLICABLE.
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 311/312:
CLASSIFICATION:
FIRE HAZARD
IMMEDIATE (ACUTE) HEALTH HAZARD
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE OF (ACUTE) (CHRONIC)
PRESSURE HEALTH HEALTH
HAZARD HAZARD
DIMETHYL ETHER YES. YES. NO. YES. NO.
TALC, NOT NO. NO. NO. YES. NO.
CONTAINING
ASBESTIFORM
FIBRES
2-METHYLPENTANE- NO. NO. NO. YES. NO.
2,4-DIOL
2,2',2"-(HEXAHYDRO- NO. NO. NO. YES. NO.
1,3,5-TRIAZINE-
1,3,5-TRIYL)
TRIETHANOL
ADDITIONAL ENVIRONMENTAL INFORMATION IS CONTAINED ON THE ENVIRONMENTAL DATA
SHEET FOR THIS PRODUCT, WHICH CAN BE OBTAINED FROM YOUR PPG REPRESENTATIVE.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 3
FLAMMABILITY 4
PHYSICAL HAZARDS 1
(*) - CHRONIC EFFECTS
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON MSDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK
OF THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS
MAY BE PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 3
FLAMMABILITY 4
INSTABILITY 1
DATE OF PREVIOUS ISSUE: 8/20/2015
ORGANIZATION THAT PREPARED THE MSDS: EHS
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL 73/78:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
DISCLAIMER:
THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON PRESENT SCIENTIFIC
AND TECHNICAL KNOWLEDGE. THE PURPOSE OF THIS INFORMATION IS TO DRAW
ATTENTION TO THE HEALTH AND SAFETY ASPECTS CONCERNING THE PRODUCTS SUPPLIED
BY PPG, AND TO RECOMMEND PRECAUTIONARY MEASURES FOR THE STORAGE AND
HANDLING OF THE PRODUCTS. NO WARRANTY OR GUARANTEE IS GIVEN IN RESPECT OF
THE PROPERTIES OF THE PRODUCTS. NO LIABILITY CAN BE ACCEPTED FOR ANY
FAILURE TO OBSERVE THE PRECAUTIONARY MEASURES DESCRIBED IN THIS DATA SHEET
OR FOR ANY MISUSE OF THE PRODUCTS.
UNITED STATES