| Common Name: | LOCTITE LB 8008 C5-A KNOWN AS C5-A COPPER BASED ANTI-SEIZE, 51008 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 5/11/2022 |
| SDS Format: | No Format Specified |
| Item Number(s): | 45MY40 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 009.0
ISSUE DATE: 05/11/2022
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE LB 8008 C5-A KNOWN AS C5-A(R*) COPPER BASED ANTI-SEIZE
IDH NUMBER: 234204
PRODUCT TYPE/USE: ANTISEIZE
ITEM NUMBER: 51008
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE DAMAGE.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
SERIOUS EYE DAMAGE 1
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 1
PICTOGRAM(S):
HEALTH HAZARD
CORROSION
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY
AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WEAR PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION IF
YOU FEEL UNWELL.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: NOT PRESCRIBED
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL,
STATE/PROVINCIAL AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE
UNITED NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND
LABELING OF CHEMICALS (GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
CALCIUM DIHYDROXIDE 1305-62-0 10 - 30
DISTILLATES (PETROLEUM), HYDROTREATED 64742-52-5 10 - 30
HEAVY NAPHTHENIC
PETROLEUM DISTILLATES, HYDROTREATED, 64742-53-6 10 - 30
LIGHT NAPHTHENIC
COPPER 7440-50-8 10 - 30
GRAPHITE 7782-42-5 5 - 10
QUARTZ (SiO2) "RESPIRABLE PARTICULATES 14808-60-7 1 - 5
(REACHES THE ALVEOLI)" (RCS) <0.1%
QUARTZ (SiO2) RESPIRABLE PARTICULATES 14808-60-7 0.1 - 1
(RCS) >=10%
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE
IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF SYMPTOMS DEVELOP AND
PERSIST, GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
GET MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES: NONE
UNUSUAL FIRE OR EXPLOSION HAZARDS: NONE
HAZARDOUS COMBUSTION PRODUCTS: OXIDES OF CARBON.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEM.
CLEAN-UP METHODS:
SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. CLEAN RESIDUE WITH SOAP AND WATER.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. AVOID CONTACT WITH EYES, SKIN AND
CLOTHING. KEEP CONTAINER CLOSED. WASH THOROUGHLY AFTER HANDLING.
STORAGE: KEEP IN A COOL, WELL VENTILATED AREA.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
CALCIUM DIHYDROXIDE 5 MG/M3 TWA 5 MG/M3 PEL NONE NONE
RESPIRABLE
FRACTION.
15 MG/M3 PEL
TOTAL DUST.
50 MPPCF TWA
TOTAL DUST.
5 MG/M3 TWA
RESPIRABLE
FRACTION.
15 MPPCF TWA
RESPIRABLE
FRACTION.
15 MG/M3 TWA
TOTAL DUST.
DISTILLATES 5 MG/M3 TWA 5 MG/M3 PEL NONE NONE
(PETROLEUM), INHALABLE MIST.
HYDROTREATED HEAVY FRACTION.
NAPHTHENIC 500 PPM
(2,000 MG/M3)
PEL
PETROLEUM DISTILLATES, 5 MG/M3 TWA 5 MG/M3 PEL NONE NONE
HYDROTREATED, LIGHT INHALABLE MIST.
NAPHTHENIC FRACTION.
500 PPM
(2,000 MG/M3)
PEL
COPPER 0.2 MG/M3 1 MG/M3 PEL NONE NONE
TWA (AS Cu) (AS Cu)
FUME. DUST AND
MIST.
1 MG/M3 TWA
(AS Cu) DUST 0.1 MG/M3
AND MIST. PEL (AS
Cu) FUME.
GRAPHITE 2 MG/M3 TWA 5 MG/M3 PEL NONE NONE
RESPIRABLE RESPIRABLE
FRACTION. FRACTION.
15 MG/M3 PEL
TOTAL DUST.
5 MG/M3 PEL
RESPIRABLE
FRACTION.
15 MG/M3 PEL
TOTAL DUST.
QUARTZ (SiO2) 0.025 MG/M3 0.05 MG/M3 NONE NONE
"RESPIRABLE TWA TWA
PARTICULATES RESPIRABLE (RESPIRABLE
(REACHES THE FRACTION. DUST.)
ALVEOLI)" (RCS)
<0.1% 0.025 MG/M3
OSHA_ACT
(RESPIRABLE
DUST.)
0.05 MG/M3
PEL
RESPIRABLE
DUST.
2.4 MPPCF TWA
RESPIRABLE.
0.1 MG/M3 TWA
RESPIRABLE.
QUARTZ (SiO2) 0.025 MG/M3 0.05 MG/M3 NONE NONE
RESPIRABLE TWA TWA
PARTICULATES RESPIRABLE (RESPIRABLE
(RCS) >=10% FRACTION. DUST.)
0.025 MG/M3
OSHA_ACT
(RESPIRABLE
DUST.)
0.05 MG/M3
PEL
RESPIRABLE
DUST.
2.4 MPPCF
TWA
RESPIRABLE.
0.1 MG/M3
TWA
RESPIRABLE.
ENGINEERING CONTROLS:
USE LOCAL VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO MAINTAIN
VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S). OBSERVE OSHA REGULATIONS FOR RESPIRATOR USE (29 CFR 1910.134).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT
SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE
COLOR: COPPER
ODOR: MILD
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: <5.0 MM Hg
BOILING POINT/RANGE: 260 DEG. C (>500 DEG. F)
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.30
VAPOR DENSITY: HEAVIER THAN AIR.
FLASH POINT: >93 DEG. C (>199.4 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT DETERMINED
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT DETERMINED
AUTOIGNITION TEMPERATURE: NOT DETERMINED
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: SLOWER THAN ETHER.
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED
VOC CONTENT: <3 % ESTIMATED
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE AT NORMAL CONDITIONS.
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS: HYDROCARBONS. OXIDES OF CARBON.
INCOMPATIBLE MATERIALS: STRONG ACIDS AND STRONG BASES. OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: PROLONGED EXPOSURE TO HEAT.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF COPPER FUMES MAY RESULT IN METAL FUME FEVER. SYMPTOMS
INCLUDE METALLIC TASTE, DISCOLORATION OF SKIN OR HAIR. MAY CAUSE
RESPIRATORY TRACT IRRITATION. CONTAINS CRYSTALLINE SILICA (QUARTZ),
WHICH IS CLASSIFIED AS A POSSIBLE CARCINOGEN. HOWEVER, THE CRYSTALLINE
SILICA PRESENT IN THIS PRODUCT IS ENCAPSULATED IN THE LIQUID AND WILL
ONLY BE LIBERATED IF THE PRODUCT IS SANDED OR ABRADED, AND EVEN THEN
WHAT IS LIBERATED WILL NOT BE PURE CRYSTALLINE SILICA. APPROPRIATE
PRECAUTIONS, HOWEVER, SHOULD BE TAKEN IF THE PRODUCT IS SANDED OR
ABRADED TO PREVENT PERSONNEL FROM BREATHING THE DUST.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
CALCIUM DIHYDROXIDE ORAL LD50 (RAT): IRRITANT, CORROSIVE
7,340 MG/KG
DISTILLATES INHALATION LC50 IRRITANT
(PETROLEUM), (RAT, 4 H):
HYDROTREATED HEAVY >4.026 MG/L
NAPHTHENIC
INHALATION LC50
(RAT, 4 H):
2.18 MG/L
INHALATION LC50
(RAT, 4 H):
10.5 MG/L
INHALATION LC50
(RAT, 4 H):
>5.2 MG/L
INHALATION LC50
(RAT, 4 H):
<5.7 MG/L
PETROLEUM DISTILLATES, INHALATION LC50 IRRITANT
HYDROTREATED, LIGHT (RAT, 4 H):
NAPHTHENIC 10.5 MG/L
INHALATION LC50
(RAT, 4 H):
>4.026 MG/L
INHALATION LC50
(RAT, 4 H):
>5.2 MG/L
INHALATION LC50
(RAT, 4 H):
9.6 MG/L
INHALATION LC50
(RAT, 4 H):
2.18 MG/L
INHALATION LC50
(RAT, 4 H):
>5 MG/L
INHALATION LC50
(RAT, 4 H):
<5.7 MG/L
COPPER INHALATION LC50 ALLERGEN, BLOOD,
(RAT, 4 H): CENTRAL NERVOUS
>5.11 MG/L SYSTEM,
DEVELOPMENTAL,
GASTROINTESTINAL,
IMMUNE SYSTEM,
IRRITANT, KIDNEY,
LIVER, MUTAGEN,
SENSORY, SKIN
GRAPHITE INHALATION LC50 LUNG
(RAT, 4 H):
>2,000 MG/M3
INHALATION LC50
(RAT, 4 H):
>2,000 MG/M3
QUARTZ (SiO2) NONE NO DATA
"RESPIRABLE
PARTICULATES
(REACHES THE ALVEOLI)"
(RCS) <0.1%
QUARTZ (SiO2) NONE NO DATA
RESPIRABLE PARTICULATES
(RCS) >=10%
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
CALCIUM DIHYDROXIDE NO NO NO
DISTILLATES NO NO NO
(PETROLEUM),
HYDROTREATED HEAVY
NAPHTHENIC
PETROLEUM DISTILLATES, NO NO NO
HYDROTREATED, LIGHT
NAPHTHENIC
COPPER NO NO NO
GRAPHITE NO NO NO
QUARTZ (SiO2) KNOWN TO BE GROUP 1 YES
"RESPIRABLE HUMAN
PARTICULATES CARCINOGEN.
(REACHES THE ALVEOLI)"
(RCS) <0.1%
QUARTZ (SiO2) KNOWN TO BE GROUP 1 YES
RESPIRABLE PARTICULATES HUMAN
(RCS) >=10% CARCINOGEN.
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO
THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY PACKAGE/
CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (COPPER)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
MARINE POLLUTANT: COPPER
DOT HAZARDOUS SUBSTANCE(S): COPPER
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (COPPER)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
MARINE POLLUTANT: COPPER
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED AS ACTIVE OR ARE EXEMPT FROM LISTING ON THE
TOXIC SUBSTANCES CONTROL ACT (TSCA) INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). COPPER (CAS# 7440-50-8).
CERCLA REPORTABLE QUANTITY:
COPPER (CAS# 7440-50-8) 5,000 LBS. (2,270 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 15
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 05/11/2022
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO
ADOPT SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY
AND PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND
USE OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL
SPECIFICALLY DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING
WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE,
ARISING FROM SALE OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS
ANY LIABILITY FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND,
INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION
IN ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION
OF ANY KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF
ANY OTHER JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION
PROVIDED HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY
OTHER JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY
AND REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.