| Common Name: | LOCTITE LB 8012 LOW FRICTION LUBRICANT KNOWN AS MOLY PASTE, 51145 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 5/17/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 45MY48 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 005.0
ISSUE DATE: 05/17/2019
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE LB 8012 LOW FRICTION LUBRICANT KNOWN AS MOLY PASTE
PRODUCT TYPE/USE: LUBRICANT
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 226801
ITEM NUMBER: 51145
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 1
PICTOGRAM(S):
HEALTH HAZARD
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER
HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WEAR
PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION IF YOU FEEL
UNWELL.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: NOT PRESCRIBED
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
MOLYBDENUM DISULPHIDE 1317-33-5 60 - 80
RESIDUAL OIL, SOLVENT-DEWAXED, 64742-62-7 10 - 30
<3% DMSO
QUARTZ (SIO2), <1% RESPIRABLE 14808-60-7 1 - 5
DISTILLATES (PETROLEUM), 64742-52-5 1 - 5
HYDROTREATED HEAVY NAPHTHENIC
PETROLEUM DISTILLATES, HYDROTREATED, 64742-53-6 1 - 5
LIGHT NAPHTHENIC
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. IMMEDIATELY FLUSH SKIN WITH
PLENTY OF WATER (USING SOAP, IF AVAILABLE). IF SYMPTOMS DEVELOP AND
PERSIST, GET MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF EYE IRRITATION PERSISTS, CONSULT A SPECIALIST.
INGESTION:
DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS. IN CASE OF FIRE, KEEP CONTAINERS
COOL WITH WATER SPRAY.
UNUSUAL FIRE OR EXPLOSION HAZARDS: NONE
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. TOXIC AND IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEM.
CLEAN-UP METHODS:
REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN
UP. SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. CLEAN RESIDUE WITH SOAP AND
WATER. STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
KEEP CONTAINER CLOSED.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL
MOLYBDENUM DISULPHIDE 10 MG/M3 TWA 15 MG/M3 PEL (AS Mo)
(AS Mo) INHALABLE TOTAL DUST.
FRACTION.
3 MG/M3 TWA (AS Mo)
RESPIRABLE FRACTION.
RESIDUAL OIL, 5 MG/M3 TWA MIST 5 MG/M3 TWA MIST
SOLVENT-DEWAXED, EXPOSURE BY ALL
<3% DMSO ROUTES SHOULD BE
CAREFULLY CONTROLLED
TO LEVELS AS LOW AS
POSSIBLE.
10 MG/M3 STEL MIST
5 MG/M3 TWA
INHALABLE FRACTION.
INCLUDED IN THE
REGULATION BUT WITH NO
DATA VALUES. SEE
REGULATION FOR FURTHER
DETAILS
QUARTZ (SIO2), 0.025 MG/M3 TWA 2.4 MPPCF TWA
<1% RESPIRABLE RESPIRABLE FRACTION. RESPIRABLE.
0.1 MG/M3 TWA
RESPIRABLE.
0.05 MG/M3 TWA
(RESPIRABLE DUST.)
0.025 MG/M3
OSHA_ACT
(RESPIRABLE DUST.)
0.05 MG/M3 PEL
RESPIRABLE DUST.
DISTILLATES (PETROLEUM), 5 MG/M3 TWA 500 PPM
HYDROTREATED INHALABLE FRACTION. (2,000 MG/M3) PEL
HEAVY NAPHTHENIC 5 MG/M3 PEL MIST.
PETROLEUM DISTILLATES, 5 MG/M3 TWA 500 PPM
HYDROTREATED, LIGHT INHALABLE FRACTION. (2,000 MG/M3) PEL
NAPHTHENIC 5 MG/M3 PEL MIST.
HAZARDOUS COMPONENT(S) AIHA WEEL OTHER
MOLYBDENUM DISULPHIDE NONE NONE
RESIDUAL OIL, SOLVENT-DEWAXED, <3% DMSO NONE NONE
QUARTZ (SIO2), <1% RESPIRABLE NONE NONE
DISTILLATES (PETROLEUM), HYDROTREATED NONE NONE
HEAVY NAPHTHENIC
PETROLEUM DISTILLATES, HYDROTREATED, LIGHT NONE NONE
NAPHTHENIC
ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. LOCAL EXHAUST VENTILATION IS
RECOMMENDED WHEN GENERAL VENTILATION IS NOT SUFFICIENT TO CONTROL
AIRBORNE CONTAMINATION BELOW OCCUPATIONAL EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S). OBSERVE OSHA REGULATIONS FOR RESPIRATOR USE (29 CFR 1910.134).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. SAFETY SHOWERS AND EYE
WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
CHEMICAL RESISTANT, IMPERMEABLE GLOVES. USE OF BUTYL OR NITRILE RUBBER
GLOVES IS RECOMMENDED.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE
COLOR: GRAY
ODOR: MILD, PETROLEUM
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.9614
VAPOR DENSITY: HEAVIER THAN AIR.
FLASH POINT: 160 DEG. C (320 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT DETERMINED
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT DETERMINED
AUTOIGNITION TEMPERATURE: NOT DETERMINED
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: LESS THAN BUTYL ACETATE.
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED
VOC CONTENT: 5.08 %; 102.3 G/L EPA METHOD 24
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON. HYDROCARBONS.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION. CONTAINS CRYSTALLINE SILICA
(QUARTZ), WHICH IS CLASSIFIED AS A POSSIBLE CARCINOGEN. HOWEVER, THE
CRYSTALLINE SILICA PRESENT IN THIS PRODUCT IS ENCAPSULATED IN THE LIQUID
AND WILL ONLY BE LIBERATED IF THE PRODUCT IS SANDED OR ABRADED, AND EVEN
THEN WHAT IS LIBERATED WILL NOT BE PURE CRYSTALLINE SILICA. APPROPRIATE
PRECAUTIONS, HOWEVER, SHOULD BE TAKEN IF THE PRODUCT IS SANDED OR ABRADED
TO PREVENT PERSONNEL FROM BREATHING THE DUST.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY CAUSE GASTROINTESTINAL DISTURBANCES.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
MOLYBDENUM DISULPHIDE NONE NO TARGET ORGANS
RESIDUAL OIL, SOLVENT-DEWAXED, NONE IRRITANT
<3% DMSO
QUARTZ (SIO2), <1% RESPIRABLE NONE IMMUNE SYSTEM, LUNG,
SOME EVIDENCE OF
CARCINOGENICITY
DISTILLATES (PETROLEUM), NONE IRRITANT
HYDROTREATED HEAVY NAPHTHENIC
PETROLEUM DISTILLATES, NONE IRRITANT
HYDROTREATED, LIGHT NAPHTHENIC
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY REGULATED)
MOLYBDENUM DISULPHIDE NO NO NO
RESIDUAL OIL, NO NO NO
SOLVENT-DEWAXED, <3%
DMSO
QUARTZ (SIO2), <1% KNOWN TO GROUP 1 YES
RESPIRABLE BE HUMAN
CARCINOGEN.
DISTILLATES (PETROLEUM), NO NO NO
HYDROTREATED
HEAVY NAPHTHENIC
PETROLEUM DISTILLATES, NO NO NO
HYDROTREATED, LIGHT
NAPHTHENIC
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: D005. BARIUM.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 2
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 05/17/2019
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN
ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION OF ANY
KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF ANY OTHER
JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION PROVIDED
HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY OTHER
JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY AND
REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.