| Common Name: | 100CF |
| Manufacturer: | LENOX TOOLS |
| SDS Revision Date: | 1/29/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 45PE58, 45PE59, 45PE60, 56LU72, 56LU73, 56LU74 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LENOX(R*)
SAFETY DATA SHEET
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: LENOX(R*) 100CF
MATERIAL USES: METALWORKING FLUID
MANUFACTURER:
LENOX TOOLS
301 CHESTNUT STREET
EAST LONGMEADOW, MA 01028
EMERGENCY TELEPHONE NUMBER (WITH HOURS OF OPERATION):
CHEMTREC (U.S. AND CANADA): 1-800-424-9300
CHEMTREC (OUTSIDE THE U.S.): +1-703-527-0585
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
ACUTE TOXICITY (ORAL): CATEGORY 4
ACUTE TOXICITY (DERMAL): CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN TOXICITY:
7.5%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
HARMFUL IF SWALLOWED OR IN CONTACT WITH SKIN.
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
WEAR PROTECTIVE GLOVES. WEAR EYE OR FACE PROTECTION. WEAR PROTECTIVE
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH HANDS
THOROUGHLY AFTER HANDLING.
RESPONSE:
IF SWALLOWED:
CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL. RINSE MOUTH.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. CALL A POISON CENTER OR PHYSICIAN IF
YOU FEEL UNWELL. TAKE OFF CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE: NOT APPLICABLE.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
INGREDIENT NAME % CAS NUMBER
1-AMINOPROPAN-2-OL 2 - 5 78-96-6
2-DIBUTYLAMINOETHANOL 2 - 5 102-81-8
3-IODO-2-PROPYNYL BUTYLCARBAMATE 0.1 - 2 55406-53-6
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION IF ADVERSE HEALTH
EFFECTS PERSIST OR ARE SEVERE. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION
AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN
TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND. IN CASE OF
INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY BE DELAYED.
THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL SURVEILLANCE FOR 48
HOURS.
SKIN CONTACT:
WASH WITH PLENTY OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES.
WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING IT, OR
WEAR GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL
ATTENTION. IF NECESSARY, CALL A POISON CENTER OR PHYSICIAN. WASH CLOTHING
BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH
AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL
HAS BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL
QUANTITIES OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS
VOMITING MAY BE DANGEROUS. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO
BY MEDICAL PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO
THAT VOMIT DOES NOT ENTER THE LUNGS. GET MEDICAL ATTENTION. IF NECESSARY,
CALL A POISON CENTER OR PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET
MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT
CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: HARMFUL IN CONTACT WITH SKIN. CAUSES SKIN IRRITATION.
INGESTION: HARMFUL IF SWALLOWED.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
INGESTION: NO SPECIFIC DATA.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
IN CASE OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY BE
DELAYED. THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL SURVEILLANCE
FOR 48 HOURS.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH
WATER BEFORE REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE, USE WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CO2. USE AN
EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER JET.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
NITROGEN OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL
OR AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH
WATER AND MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE,
ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. APPROACH
RELEASE FROM UPWIND. PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR
CONFINED AREAS. WASH SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED
AS FOLLOWS. CONTAIN AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT
MATERIAL E.G. SAND, EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN
CONTAINER FOR DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13).
DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT
MATERIAL MAY POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT
INGEST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING VAPOR
OR MIST. KEEP IN THE ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE MADE
FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE. EMPTY
CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS. DO NOT REUSE
CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. KEEP
CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT
HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT
LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE APPROPRIATE CONTAINMENT
TO AVOID ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
2-DIBUTYLAMINOETHANOL ACGIH TLV (UNITED STATES, 4/2014).
ABSORBED THROUGH SKIN.
TWA: 0.5 PPM 8 HOURS.
TWA: 3.5 MG/M3 8 HOURS.
OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 2 PPM 8 HOURS.
TWA: 14 MG/M3 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
ABSORBED THROUGH SKIN.
TWA: 2 PPM 10 HOURS.
TWA: 14 MG/M3 10 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A PROPERLY FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH
AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: CLEAR.
ODOR: CHEMICAL.
ODOR THRESHOLD: NOT AVAILABLE.
PH: 8.6 [CONC. (% W/W): 5%]
MELTING POINT: <-17.8 DEG. C (<-0.04 DEG. F)
BOILING POINT: >100 DEG. C (>212 DEG. F)
FLASH POINT:
OPEN CUP: 173.9 DEG. C (345 DEG. F)
BURNING TIME: NOT APPLICABLE.
BURNING RATE: NOT APPLICABLE.
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: 0.925
SOLUBILITY:
EASILY SOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
SADT: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS
INCOMPATIBLE MATERIALS:
SODIUM NITRITE KEEP AWAY FROM STRONG ACIDS. STRONG OXIDIZING MATERIALS KEEP
AWAY FROM REDUCING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
1-AMINOPROPAN-2-OL LD50 ORAL RAT 1715 MG/KG
2-DIBUTYLAMINOETHANOL LD50 ORAL RAT 1070 MG/KG
3-IODO-2-PROPYNYL LD50 ORAL RAT 1470 MG/KG
BUTYLCARBAMATE
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVA-
NAME TION
1-AMINOPROPAN-2-OL EYES - SEVERE RABBIT 24 HOURS
IRRITANT 250 MICROGRAMS
EYES - SEVERE RABBIT 970 MICROGRAMS
IRRITANT
SKIN - MILD RABBIT 24 HOURS
IRRITANT 500 MILLIGRAMS
SKIN - RABBIT 485 MILLIGRAMS
MODERATE
IRRITANT
2-DIBUTYLAMINO- SKIN - SEVERE RABBIT 24 HOURS
ETHANOL IRRITANT 5 MILLIGRAMS
SKIN - SEVERE RABBIT 500 MILLIGRAMS
IRRITANT
SENSITIZATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
REPRODUCTIVE TOXICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF TARGET ORGANS
EXPOSURE
3-IODO-2-PROPYNYL BUTYLCARBAMATE CATEGORY 1 NOT DETERMINED TRACHEA
ASPIRATION HAZARD: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
HARMFUL IF SWALLOWED. HARMFUL IN CONTACT WITH SKIN. CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS:
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
1-AMINOPROPAN-2-OL ACUTE LC50: FISH - CARASSIUS 96 HOURS
210000 (MICRO)G/L AURATUS
FRESH WATER
2-DIBUTYLAMINOETHANOL ACUTE EC50: DAPHNIA - DAPHNIA MAGNA 48 HOURS
73.7 MG/L FRESH
WATER
3-IODO-2-PROPYNYL ACUTE LC50: CRUSTACEANS - HYALELLA 48 HOURS
BUTYLCARBAMATE 500 PPB FRESH AZTECA
WATER
ACUTE LC50: DAPHNIA - DAPHNIA 48 HOURS
40 PPB FRESH MAGNA
WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
67 (MICRO)G/L MYKISS - JUVENILE
FRESH WATER (FLEDGLING, HATCHLING,
WEANLING)
CHRONIC NOEC: FISH - PIMEPHALES 35 DAYS
8.4 PPB PROMELAS
PERSISTENCE AND DEGRADABILITY:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
1-AMINOPROPAN-2-OL -0.96 0.11 LOW
2-DIBUTYLAMINOETHANOL <39 LOW
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING
EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. AVOID DISPERSAL OF
SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND
SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO IMDG IATA
CLASSIFICA- CLASSIFICA- CLASSIFICA-
TION TION TION
UN NUMBER NOT NOT NOT NOT NOT
REGULATED. REGULATED. REGULATED. REGULATED. REGULA-
TED.
UN PROPER
SHIPPING
NAME
TRANSPORT
HAZARD
CLASS(ES)
PACKING
GROUP
ENVIRONMENTAL NO. NO. NO. NO. NO.
HAZARDS
ADDITIONAL
INFORMATION
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
SARA 311/312:
CLASSIFICATION: IMMEDIATE (ACUTE) HEALTH HAZARD
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE (ACUTE) (CHRO-
OF HEALTH NIC)
PRESSURE HAZARD HEALTH
HAZARD
1-AMINOPROPAN-2-OL 2 - 5 YES. NO. NO. YES. NO.
2-DIBUTYLAMINO- 2 - 5 NO. NO. NO. YES. NO.
ETHANOL
3-IODO-2-PROPYNYL 0.1 - 2 NO. NO. NO. YES. YES.
BUTYLCARBAMATE
CALIFORNIA PROP. 65:
THIS PRODUCT DOES NOT CONTAIN CHEMICALS KNOWN TO STATE OF CALIFORNIA TO
CAUSE CANCER, BIRTH DEFECTS, OR REPRODUCTIVE HARM.
CANADA:
CANADIAN LISTS:
CANADIAN NPRI: NONE OF THE COMPONENTS ARE LISTED.
CEPA TOXIC SUBSTANCES: NONE OF THE COMPONENTS ARE LISTED.
CANADA INVENTORY: ALL COMPONENTS ARE LISTED OR EXEMPTED.
| SECTION 16. OTHER INFORMATION | |
HISTORY:
DATE OF ISSUE/DATE OF REVISION: 3/13/2015.
DATE OF PREVIOUS ISSUE: NO PREVIOUS VALIDATION.
VERSION: 1
PREPARED BY: PRODUCT SAFETY.
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS: GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
UN: UNITED NATIONS
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
SINCE THE USER'S WORKING CONDITIONS ARE NOT KNOWN BY US, THE INFORMATION
SUPPLIED ON THIS SAFETY DATA SHEET IS BASED ON OUR CURRENT LEVEL OF
KNOWLEDGE AND ON NATIONAL AND COMMUNITY REGULATIONS. THE MIXTURE MUST NOT
BE USED FOR OTHER USES THAN THOSE SPECIFIED IN SECTION 1 WITHOUT HAVING
FIRST OBTAINED WRITTEN HANDLING INSTRUCTIONS. IT IS AT ALL TIMES THE
RESPONSIBILITY OF THE USER TO TAKE ALL NECESSARY MEASURES TO COMPLY WITH
LEGAL REQUIREMENTS AND LOCAL REGULATIONS. THE INFORMATION IN THIS SAFETY
DATA SHEET MUST BE REGARDED AS A DESCRIPTION OF THE SAFETY REQUIREMENTS
RELATING TO THE MIXTURE AND NOT AS A GUARANTEE OF THE PROPERTIES THEREOF.
DATE OF ISSUE/DATE OF REVISION: 1/29/2019.