| Common Name: | TOUGH GUY VINEGAR CLEANER |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 12/2/2016 |
| SDS Format: | No Format Specified |
| Item Number(s): | 325JA3, 45TW63 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
ISSUE DATE: APRIL 1 2016
REVISION DATE: 02-DEC-2014
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: TOUGH GUY VINEGAR CLEANER
OTHER MEANS OF IDENTIFICATION:
SDS #: TGV-023
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: CLEANING AGENT.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER ADDRESS:
WW GRAINGER
100 GRAINGER PARKWAY
LAKE FOREST, IL 60045
EMERGENCY TELEPHONE NUMBER:
COMPANY PHONE NUMBER: 800-535-1000
EMERGENCY TELEPHONE (24 HR):
INFOTRAC:
1-352-323-3500 (INTERNATIONAL)
1-800-535-5053 (NORTH AMERICA)
| 2. HAZARDS IDENTIFICATION | |
APPEARANCE: CLEAR LIQUID
PHYSICAL STATE: LIQUID
ODOR: FRESH
CLASSIFICATION:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE DAMAGE
CORROSION
PRECAUTIONARY STATEMENTS - PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING IMMEDIATELY CALL A POISON
CENTER OR DOCTOR/PHYSICIAN
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER WASH CONTAMINATED CLOTHING BEFORE REUSE
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE
FOR BREATHING IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING
PRECAUTIONARY STATEMENTS - STORAGE: STORE LOCKED UP
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NO WEIGHT-%
ACETIC ACID 64-19-7 1-10
IF CHEMICAL NAME/CAS NO IS "PROPRIETARY" AND/OR WEIGHT-% IS LISTED AS A
RANGE, THE SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION
HAS BEEN WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
EYE CONTACT:
REMOVE CONTACT LENSES, FLUSH EYES WITH COOL RUNNING WATER HOLDING EYELIDS
APART TO ENSURE THOROUGH RINSING FOR 15 MINUTES. IMMEDIATELY CALL A POISON
CENTER OR DOCTOR/PHYSICIAN.
SKIN CONTACT: WASH WITH SOAP AND WATER.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE
FOR BREATHING. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF BREATHING HAS
STOPPED, GIVE ARTIFICIAL RESPIRATION. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN.
INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. DRINK LARGE AMOUNTS OF WATER. NEVER
GIVE ANYTHING BY MOUTH TO A PERSON WHO IS UNCONSCIOUS OR CONVULSING. SEEK
MEDICAL ATTENTION IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS:
SYMPTOMS: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER. CARBON DIOXIDE (CO2). DRY CHEMICAL. FOAM.
UNSUITABLE EXTINGUISHING MEDIA: NOT DETERMINED.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NOT DETERMINED.
HAZARDOUS COMBUSTION PRODUCTS: OXIDES OF CARBON.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEAN-UP:
FOR SMALL SPILLS: WIPE UP OR MOP UP.
FOR LARGE SPILLS:
CONTROL SPILL WITH ABSORBENT; TRANSFER TO NON-LEAKING CONTAINERS. RINSE
AREA THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. WASH FACE, HANDS, AND ANY
EXPOSED SKIN THOROUGHLY AFTER HANDLING. WEAR PROTECTIVE GLOVES/PROTECTIVE
CLOTHING AND EYE/FACE PROTECTION.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
STORE LOCKED UP. STORE IN A COOL, DRY AND WELL-VENTILATED AREA.
INCOMPATIBLE MATERIALS: STRONG ACIDS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
ACETIC ACID STEL: 15 PPM TWA: 10 PPM IDLH: 50 PPM
64-19-7
TWA: 10 PPM TWA: 25 MG/M3 TWA: 10 PPM
(VACATED) TWA: 10 PPM TWA: 25 MG/M3
(VACATED) TWA: 25 MG/M3 STEL: 15 PPM
STEL: 37 MG/M3
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS:
APPLY TECHNICAL MEASURES TO COMPLY WITH THE OCCUPATIONAL EXPOSURE LIMITS.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: SAFETY GLASSES.
SKIN AND BODY PROTECTION: WEAR GLOVES FOR PROLONGED EXPOSURE.
RESPIRATORY PROTECTION:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: CLEAR LIQUID
ODOR: FRESH
COLOR: COLORLESS
ODOR THRESHOLD: NOT DETERMINED
PROPERTY VALUES REMARKS - METHOD
PH 2.88
MELTING POINT/FREEZING POINT NOT DETERMINED
BOILING POINT/BOILING RANGE NOT AVAILABLE
FLASH POINT 95 DEG. C / 203 DEG. F TAG CLOSED CUP
EVAPORATION RATE NOT DETERMINED
FLAMMABILITY (SOLID, GAS) LIQUID-NOT APPLICABLE
UPPER FLAMMABILITY LIMITS NOT DETERMINED
LOWER FLAMMABILITY LIMIT NOT DETERMINED
VAPOR PRESSURE NOT AVAILABLE
VAPOR DENSITY NOT DETERMINED
SPECIFIC GRAVITY 1.00-1.010
WATER SOLUBILITY 100% SOLUBLE
SOLUBILITY IN OTHER SOLVENTS NOT DETERMINED
PARTITION COEFFICIENT NOT DETERMINED
AUTO-IGNITION TEMPERATURE NOT DETERMINED
DECOMPOSITION TEMPERATURE NOT DETERMINED
KINEMATIC VISCOSITY NOT DETERMINED
DYNAMIC VISCOSITY NOT DETERMINED
EXPLOSIVE PROPERTIES NOT DETERMINED
OXIDIZING PROPERTIES NOT DETERMINED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT REACTIVE UNDER NORMAL CONDITIONS.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: EXCESSIVE HEAT AND FIRE. INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: STRONG ACIDS.
HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SKIN CONTACT: CAUSES SKIN IRRITATION.
INHALATION: DO NOT INHALE.
INGESTION: DO NOT INGEST.
COMPONENT INFORMATION:
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
ACETIC ACID = 3310 MG/KG = 1060 MG/KG = 11.4 MG/L (RAT) 4 H
64-19-7 (RAT) (RABBIT)
INFORMATION ON PHYSICAL, CHEMICAL AND TOXICOLOGICAL EFFECTS:
SYMPTOMS: PLEASE SEE SECTION 4 OF THIS SDS FOR SYMPTOMS.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
CARCINOGENICITY:
THIS PRODUCT DOES NOT CONTAIN ANY CARCINOGENS OR POTENTIAL CARCINOGENS AS
LISTED BY OSHA, IARC OR NTP.
NUMERICAL MEASURES OF TOXICITY: NOT DETERMINED
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT CLASSIFIED AS ENVIRONMENTALLY HAZARDOUS. HOWEVER, THIS
DOES NOT EXCLUDE THE POSSIBILITY THAT LARGE OR FREQUENT SPILLS CAN HAVE A
HARMFUL OR DAMAGING EFFECT ON THE ENVIRONMENT.
COMPONENT INFORMATION:
CHEMICAL NAME ALGAE/AQUATIC FISH TOXICITY TO CRUSTACEA
PLANTS MICROORGANISMS
ACETIC ACID 79: 96 H EC50: 47: 24 H
64-19-7 PIMEPHALES 8.8 MG/L 15 MIN DAPHNIA MAGNA
PROMELAS MG/L EC50
MG/L LC50 EC50:
STATIC 8.8 MG/L 25 MIN 65: 48 H
DAPHNIA MAGNA
75: 96 H EC50: MG/L EC50
LEPOMIS 8.8 MG/L 5 MIN STATIC
MACROCHIRUS
MG/L LC50
STATIC
PERSISTENCE/DEGRADABILITY: NOT DETERMINED.
BIOACCUMULATION: NOT DETERMINED.
MOBILITY:
CHEMICAL NAME PARTITION COEFFICIENT
ACETIC ACID -0.31
64-19-7
OTHER ADVERSE EFFECTS: NOT DETERMINED
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DISPOSAL OF WASTES:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CALIFORNIA HAZARDOUS WASTE STATUS:
CHEMICAL NAME CALIFORNIA HAZARDOUS WASTE STATUS
ACETIC ACID TOXIC
64-19-7 CORROSIVE
IGNITABLE
| 14. TRANSPORT INFORMATION | |
NOTE:
PLEASE SEE CURRENT SHIPPING PAPER FOR MOST UP TO DATE SHIPPING
INFORMATION, INCLUDING EXEMPTIONS AND SPECIAL CIRCUMSTANCES.
DOT: NOT REGULATED
IATA: NOT REGULATED
IMDG: NOT REGULATED
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
CHEMICAL NAME TSCA DSL NDSL EINECS
ACETIC ACID PRESENT X PRESENT
CHEMICAL NAME ELINCS ENCS IECSC KECL PICCS AICS
ACETIC ACID PRESENT X PRESENT X X
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
EINECS/ELINCS:
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST OF
NOTIFIED CHEMICAL SUBSTANCES
ENCS: JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES
IECSC: CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES
KECL: KOREAN EXISTING AND EVALUATED CHEMICAL SUBSTANCES
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
AICS: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES
US FEDERAL REGULATIONS:
CERCLA:
CHEMICAL NAME HAZARDOUS SUBSTANCES CERCLA/SARA REPORTABLE QUANTITY
RQS RQ (RQ)
ACETIC ACID 5000 LB RQ 5000 LB FINAL RQ
64-19-7 RQ 2270 KG FINAL RQ
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
CWA (CLEAN WATER ACT):
CHEMICAL NAME CWA - REPORTABLE CWA - TOXIC CWA - PRIORITY CWA -
QUANTITIES POLLUTANTS POLLUTANTS HAZARDOUS
SUBSTANCES
ACETIC ACID 5000 LB X
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS.
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
CHEMICAL NAME NEW JERSEY MASSACHUSETTS PENNSYLVANIA
ACETIC ACID X X X
64-19-7
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARDS NOT DETERMINED
FLAMMABILITY NOT DETERMINED
INSTABILITY NOT DETERMINED
SPECIAL HAZARDS NOT DETERMINED
HMIS:
HEALTH HAZARDS 1
FLAMMABILITY 0
PHYSICAL HAZARDS 0
PERSONAL PROTECTION B
ISSUE DATE: 01-APRIL-2015
REVISION DATE: 02-DEC-2014
REVISION NOTE: NEW FORMAT
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID
FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN
ANY PROCESS, UNLESS SPECIFIED IN THE TEXT.