| Common Name: | PYROIL LOW VOC NON-CHLR BPC PL 5 GA |
| Manufacturer: | NITEO PRODUCTS |
| SDS Revision Date: | 9/6/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 45VH10 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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NITEO(TM) PRODUCTS
SAFETY DATA SHEET
PYROIL(TM) LOW VOC NON-CHLORINATED BRAKE PARTS CLEANER (TM) TRADEMARK,
NITEO PRODUCTS, LLC
VERSION: 4.0
REVISION DATE: 09/06/2018
SDS NUMBER: 600000000075
DATE OF LAST ISSUE: 06/19/2018
DATE OF FIRST ISSUE: 05/23/2016
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: PYROIL LOW VOC NON-CHLR BPC PL 5 GA
PRODUCT CODE: PYNCBPC5
MANUFACTURER OR SUPPLIER'S DETAILS:
COMPANY NAME OF SUPPLIER: NITEO PRODUCTS, LLC
ADDRESS: DALLAS TX 75225
EMAIL ADDRESS: EHS@NITEOPRODUCTS.COM
TELEPHONE: 1-844-696-4836
EMERGENCY TELEPHONE NUMBER: 1-800-424-9300 / 1-703-741-5970
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: CLEANER
RESTRICTIONS ON USE: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910.1200:
FLAMMABLE LIQUIDS: CATEGORY 2
ACUTE TOXICITY (ORAL): CATEGORY 4
ACUTE TOXICITY (INHALATION): CATEGORY 3
ACUTE TOXICITY (DERMAL): CATEGORY 4
SKIN IRRITATION: CATEGORY 2
EYE IRRITATION: CATEGORY 2A
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CATEGORY 1 (CENTRAL NERVOUS SYSTEM, EYES)
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CATEGORY 3 (RESPIRATORY SYSTEM, CENTRAL NERVOUS SYSTEM)
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
CATEGORY 2 (AUDITORY SYSTEM)
ASPIRATION HAZARD: CATEGORY 1
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
SKULLS AND CROSSBONES
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOUR.
HARMFUL IF SWALLOWED OR IN CONTACT WITH SKIN.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
TOXIC IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, EYES).
MAY CAUSE DAMAGE TO ORGANS (AUDITORY SYSTEM) THROUGH PROLONGED OR REPEATED
EXPOSURE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
KEEP CONTAINER TIGHTLY CLOSED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
WASH SKIN THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER/DOCTOR.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
DO NOT INDUCE VOMITING.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
IN CASE OF FIRE: USE DRY SAND, DRY CHEMICAL OR ALCOHOL-RESISTANT FOAM TO
EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: STATIC-ACCUMULATING FLAMMABLE LIQUID.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
HAZARDOUS COMPONENTS:
CHEMICAL NAME CAS-NO. CONCENTRATION (% W/W)
ACETONE 67-64-1 >/= 50 - <70
METHANOL 67-56-1 >/= 20 - <30
XYLENE 1330-20-7 >/= 20 - <30
ETHYLBENZENE 100-41-4 >/= 5 - <10
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
MOVE OUT OF DANGEROUS AREA.
CONSULT A PHYSICIAN.
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
SYMPTOMS OF POISONING MAY APPEAR SEVERAL HOURS LATER.
DO NOT LEAVE THE VICTIM UNATTENDED.
IF INHALED:
MOVE TO FRESH AIR.
CALL A PHYSICIAN OR POISON CONTROL CENTRE IMMEDIATELY.
IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND SEEK MEDICAL ADVICE.
KEEP PATIENT WARM AND AT REST.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
IN CASE OF SKIN CONTACT:
IF ON CLOTHES, REMOVE CLOTHES.
CALL A PHYSICIAN OR POISON CONTROL CENTRE IMMEDIATELY.
REMOVE CONTAMINATED CLOTHING. IF IRRITATION DEVELOPS, GET MEDICAL
ATTENTION.
IF ON SKIN, RINSE WELL WITH WATER.
WASH CONTAMINATED CLOTHING BEFORE RE-USE.
IF SKIN IRRITATION PERSISTS, CALL A PHYSICIAN.
IN CASE OF EYE CONTACT:
IMMEDIATELY FLUSH EYE(S) WITH PLENTY OF WATER.
REMOVE CONTACT LENSES.
PROTECT UNHARMED EYE.
KEEP EYE WIDE OPEN WHILE RINSING.
IF EYE IRRITATION PERSISTS, CONSULT A SPECIALIST.
IF SWALLOWED:
OBTAIN MEDICAL ATTENTION.
DO NOT INDUCE VOMITING.
RINSE MOUTH WITH WATER.
DO NOT GIVE MILK OR ALCOHOLIC BEVERAGES.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
HARMFUL IF SWALLOWED OR IN CONTACT WITH SKIN.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
TOXIC IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
CAUSES DAMAGE TO ORGANS.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
INHALATION OF HIGH CONCENTRATIONS OF THIS MATERIAL, AS COULD OCCUR IN
ENCLOSED SPACES OR DURING DELIBERATE ABUSE, MAY BE ASSOCIATED WITH CARDIAC
ARRHYTHMIAS. SYMPATHOMIMETIC DRUGS MAY INITIATE CARDIAC ARRHYTHMIAS IN
PERSONS EXPOSED TO THIS MATERIAL.
THIS PRODUCT CONTAINS METHANOL WHICH CAN CAUSE INTOXICATION AND CENTRAL
NERVOUS SYSTEM DEPRESSION. METHANOL IS METABOLIZED TO FORMIC ACID AND
FORMALDEHYDE. THESE METABOLITES CAN CAUSE METABOLIC ACIDOSIS, VISUAL
DISTURBANCES AND BLINDNESS. SINCE METABOLISM IS REQUIRED FOR THESE TOXIC
SYMPTOMS, THEIR ONSET MAY BE DELAYED FROM 6 TO 30 HOURS FOLLOWING
INGESTION. ETHANOL COMPETES FOR THE SAME METABOLIC PATHWAY AND HAS BEEN
USED TO PREVENT METHANOL METABOLISM. ETHANOL ADMINISTRATION IS INDICATED IN
SYMPTOMATIC PATIENTS OR AT BLOOD METHANOL CONCENTRATIONS ABOVE 20 UG/DL.
METHANOL IS EFFECTIVELY REMOVED BY HEMODIALYSIS.
THIS MATERIAL (OR A COMPONENT) HAS PRODUCED HYPERGLYCEMIA AND KETOSIS
FOLLOWING SUBSTANTIAL INGESTION.
| SECTION 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY
CARBON DIOXIDE (CO2)
DRY CHEMICAL
ALCOHOL-RESISTANT FOAM
UNSUITABLE EXTINGUISHING MEDIA:
HIGH VOLUME WATER JET
SPECIFIC HAZARDS DURING FIRE-FIGHTING:
DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
HAZARDOUS COMBUSTION PRODUCTS: CARBON OXIDES
SPECIFIC EXTINGUISHING METHODS:
PRODUCT IS COMPATIBLE WITH STANDARD FIRE-FIGHTING AGENTS.
FURTHER INFORMATION:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
FIRE RESIDUES AND CONTAMINATED FIRE EXTINGUISHING WATER MUST BE DISPOSED OF
IN ACCORDANCE WITH LOCAL REGULATIONS.
USE A WATER SPRAY TO COOL FULLY CLOSED CONTAINERS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT.
REMOVE ALL SOURCES OF IGNITION.
ENSURE ADEQUATE VENTILATION.
AVOID BREATHING DUST.
BEWARE OF VAPOURS ACCUMULATING TO FORM EXPLOSIVE CONCENTRATIONS. VAPOURS
CAN ACCUMULATE IN LOW AREAS.
EVACUATE PERSONNEL TO SAFE AREAS.
PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF
SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
PREVENT PRODUCT FROM ENTERING DRAINS.
DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM.
IF THE PRODUCT CONTAMINATES RIVERS AND LAKES OR DRAINS INFORM RESPECTIVE
AUTHORITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILLAGE, AND THEN COLLECT WITH NON-COMBUSTIBLE ABSORBENT MATERIAL,
(E.G. SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND PLACE IN CONTAINER
FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL REGULATIONS (SEE SECTION 13).
| SECTION 7. HANDLING AND STORAGE | |
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
TAKE NECESSARY ACTION TO AVOID STATIC ELECTRICITY DISCHARGE (WHICH MIGHT
CAUSE IGNITION OF ORGANIC VAPOURS).
ELECTRICALLY BOND AND GROUND ALL CONTAINERS, PERSONNEL AND EQUIPMENT BEFORE
TRANSFER OR USE OF MATERIAL. SPECIAL PRECAUTIONS MAY BE NECESSARY TO
DISSIPATE STATIC ELECTRICITY FOR NON-CONDUCTIVE CONTAINERS. USE PROPER
BONDING AND GROUNDING DURING PRODUCT TRANSFER AS DESCRIBED IN NATIONAL FIRE
PROTECTION ASSOCIATION DOCUMENT NFPA 77.
KEEP AWAY FROM OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION.
USE ONLY EXPLOSION-PROOF EQUIPMENT.
DO NOT SPRAY ON A NAKED FLAME OR ANY INCANDESCENT MATERIAL.
ADVICE ON SAFE HANDLING:
OPEN DRUM CAREFULLY AS CONTENT MAY BE UNDER PRESSURE.
AVOID FORMATION OF AEROSOL.
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS.
DO NOT BREATHE VAPOURS/DUST.
DO NOT SMOKE.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES.
AVOID CONTACT WITH SKIN AND EYES.
DISPOSE OF RINSE WATER IN ACCORDANCE WITH LOCAL AND NATIONAL REGULATIONS.
CONTAINER HAZARDOUS WHEN EMPTY.
SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA.
FOR PERSONAL PROTECTION SEE SECTION 8.
CONDITIONS FOR SAFE STORAGE:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
CONTAINERS WHICH ARE OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO
PREVENT LEAKAGE.
OBSERVE LABEL PRECAUTIONS.
NO SMOKING.
PREVENT UNAUTHORIZED ACCESS.
FURTHER INFORMATION ON STORAGE STABILITY:
NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENTS CAS-NO. VALUE TYPE CONTROL BASIS
(FORM OF PARAMETERS /
EXPOSURE) PERMISSIBLE
CONCENTRATION
ACETONE 67-64-1 TWA 250 PPM ACGIH
STEL 500 PPM ACGIH
TWA 250 PPM NIOSH REL
590 MG/M3
TWA 1,000 PPM OSHA Z-1
2,400 MG/M3
TWA 750 PPM OSHA P0
1,800 MG/M3
STEL 1,000 PPM OSHA P0
2,400 MG/M3
METHANOL 67-56-1 TWA 200 PPM ACGIH
STEL 250 PPM ACGIH
TWA 200 PPM NIOSH REL
260 MG/M3
ST 250 PPM NIOSH REL
325 MG/M3
TWA 200 PPM OSHA Z-1
260 MG/M3
STEL 250 PPM OSHA P0
325 MG/M3
TWA 200 PPM OSHA P0
260 MG/M3
ETHYLBENZENE 100-41-4 TWA 20 PPM ACGIH
TWA 100 PPM NIOSH REL
435 MG/M3
ST 125 PPM NIOSH REL
545 MG/M3
TWA 100 PPM OSHA Z-1
435 MG/M3
TWA 100 PPM OSHA P0
435 MG/M3
STEL 125 PPM OSHA P0
545 MG/M3
HAZARDOUS COMPONENTS WITHOUT WORKPLACE CONTROL PARAMETERS:
COMPONENTS CAS-NO.
XYLENE 1330-20-7
BIOLOGICAL OCCUPATIONAL EXPOSURE LIMITS:
COMPONENTS CAS-NO. CONTROL BIOLOGICAL SAMPLING PERMISSIBLE BASIS
PARA- SPECIMEN TIME CONCENTR-
METERS ATION
ACETONE 67-64-1 ACETONE URINE END OF 25 MG/L ACGIH
SHIFT (AS BEI
SOON AS
POSSIBLE
AFTER
EXPOSURE
CEASES)
METHANOL 67-56-1 METHANOL URINE END OF 15 MG/L ACGIH
SHIFT (AS BEI
SOON AS
POSSIBLE
AFTER
EXPOSURE
CEASES)
ETHYLBENZENE 100-41-4 SUM OF URINE END OF 0.15 G/G ACGIH
MANDELIC SHIFT (AS CREATININE BEI
ACID AND SOON AS
PHENYL POSSIBLE
GLYOXYLIC AFTER
ACID EXPOSURE
CEASES)
ENGINEERING MEASURES:
PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO
MAINTAIN EXPOSURE BELOW EXPOSURE GUIDELINES (IF APPLICABLE) OR BELOW LEVELS
THAT CAUSE KNOWN, SUSPECTED OR APPARENT ADVERSE EFFECTS.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
IN THE CASE OF VAPOUR FORMATION USE A RESPIRATOR WITH AN APPROVED FILTER.
HAND PROTECTION:
REMARKS:
WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER). THE
SUITABILITY FOR A SPECIFIC WORKPLACE SHOULD BE DISCUSSED WITH THE PRODUCERS
OF THE PROTECTIVE GLOVES. DISCARD GLOVES THAT SHOW TEARS, PINHOLES, OR
SIGNS OF WEAR.
EYE PROTECTION:
WEAR CHEMICAL SPLASH GOGGLES WHEN THERE IS THE POTENTIAL FOR EXPOSURE OF
THE EYES TO LIQUID, VAPOR OR MIST.
SKIN AND BODY PROTECTION:
CHOOSE BODY PROTECTION ACCORDING TO THE AMOUNT AND CONCENTRATION OF THE
DANGEROUS SUBSTANCE AT THE WORK PLACE.
WEAR AS APPROPRIATE:
IMPERVIOUS CLOTHING
FLAME-RESISTANT CLOTHING
SAFETY SHOES
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
AVOID CONTACT WITH SKIN, EYES AND CLOTHING.
WHEN USING DO NOT SMOKE.
WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER HANDLING THE PRODUCT.
WHEN USING DO NOT EAT OR DRINK.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
ODOUR: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
BOILING POINT/BOILING RANGE:
56.05 DEG. C (1,013 HPA) THE VALUE IS CALCULATED
FLASH POINT: -20 DEG. C THE VALUE IS CALCULATED
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
FLAMMABILITY (LIQUIDS): STATIC-ACCUMULATING FLAMMABLE LIQUID.
SELF-IGNITION: NO DATA AVAILABLE
UPPER EXPLOSION LIMIT / UPPER FLAMMABILITY LIMIT:
36%(V) THE VALUE IS CALCULATED
LOWER EXPLOSION LIMIT / LOWER FLAMMABILITY LIMIT:
1%(V) THE VALUE IS CALCULATED
VAPOUR PRESSURE: 307.9692 HPA (25 DEG. C) THE VALUE IS CALCULATED
DENSITY: NO DATA AVAILABLE
SOLUBILITY(IES):
WATER SOLUBILITY: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
CHEMICAL STABILITY: NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
VAPOURS MAY FORM EXPLOSIVE MIXTURE WITH AIR.
CONDITIONS TO AVOID: HEAT, FLAMES AND SPARKS.
INCOMPATIBLE MATERIALS:
ACIDS
BASES
ALUMINIUM
AMINES
AMMONIA
HALOGENS
LEAD
PEROXIDES
REDUCING AGENTS
STRONG BASES
STRONG OXIDIZING AGENTS
ZINC
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION
EYE CONTACT
SKIN CONTACT
INGESTION
ACUTE TOXICITY:
HARMFUL IF SWALLOWED OR IN CONTACT WITH SKIN.
TOXIC IF INHALED.
PRODUCT:
ACUTE ORAL TOXICITY:
ACUTE TOXICITY ESTIMATE: 407.85 MG/KG
METHOD: CALCULATION METHOD
ACUTE INHALATION TOXICITY:
ACUTE TOXICITY ESTIMATE: 9.66 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOUR
METHOD: CALCULATION METHOD
ACUTE DERMAL TOXICITY:
ACUTE TOXICITY ESTIMATE: 1,101 MG/KG
METHOD: CALCULATION METHOD
COMPONENTS:
ACETONE:
ACUTE ORAL TOXICITY:
LD50 (RAT, FEMALE): 5,800 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT, FEMALE): 76 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOUR
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >7,426 MG/KG
METHANOL:
ACUTE ORAL TOXICITY:
LDLO (HUMANS): 300 MG/KG
ASSESSMENT: THE COMPONENT/MIXTURE IS TOXIC AFTER SINGLE INGESTION.
ACUTE INHALATION TOXICITY:
TEST ATMOSPHERE: DUST/MIST
ASSESSMENT: THE COMPONENT/MIXTURE IS TOXIC AFTER SHORT TERM INHALATION.
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): 12,800 MG/KG
ASSESSMENT: THE COMPONENT/MIXTURE IS TOXIC AFTER SINGLE CONTACT WITH SKIN.
XYLENE:
ACUTE ORAL TOXICITY:
LD50 (RAT): 3,523 - 8,600 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): 6700 PPM
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOUR
ASSESSMENT:
THE COMPONENT/MIXTURE IS MODERATELY TOXIC AFTER SHORT TERM INHALATION.
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): 1,700 MG/KG
ETHYLBENZENE:
ACUTE ORAL TOXICITY:
LD50 (RAT): CA. 3,500 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): 4000 PPM
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOUR
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): 17,800 MG/KG
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
PRODUCT:
REMARKS: MAY CAUSE SKIN IRRITATION AND/OR DERMATITIS.
COMPONENTS:
ACETONE:
RESULT: POSSIBLY IRRITATING TO SKIN
RESULT: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
METHANOL:
SPECIES: RABBIT
RESULT: NO SKIN IRRITATION
XYLENE:
ASSESSMENT: IRRITATING TO SKIN.
RESULT: IRRITATING TO SKIN.
ETHYLBENZENE:
RESULT: IRRITATING TO SKIN.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
PRODUCT:
REMARKS:
VAPOURS MAY CAUSE IRRITATION TO THE EYES, RESPIRATORY SYSTEM AND THE SKIN.
COMPONENTS:
ACETONE:
RESULT: IRRITATING TO EYES.
ASSESSMENT: IRRITATING TO EYES.
METHANOL:
SPECIES: RABBIT
RESULT: POSSIBLY IRRITATING TO EYES
XYLENE:
RESULT: IRRITATING TO EYES.
ETHYLBENZENE:
RESULT: IRRITATING TO EYES.
RESPIRATORY OR SKIN SENSITIZATION:
SKIN SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
RESPIRATORY SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
METHANOL:
TEST TYPE: MAXIMIZATION TEST
SPECIES: GUINEA PIG
ASSESSMENT: DOES NOT CAUSE SKIN SENSITIZATION.
METHOD: OECD TEST GUIDELINE 406
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
ETHYLBENZENE:
CARCINOGENICITY - ASSESSMENT: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
IARC:
GROUP 2B: POSSIBLY CARCINOGENIC TO HUMANS
ETHYLBENZENE 100-41-4
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS ON OSHA'S LIST OF REGULATED CARCINOGENS.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
REPRODUCTIVE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT - SINGLE EXPOSURE:
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
CAUSES DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM, EYES).
COMPONENTS:
ACETONE:
EXPOSURE ROUTES: INHALATION
TARGET ORGANS: NERVOUS SYSTEM
ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS.
METHANOL:
TARGET ORGANS: CENTRAL NERVOUS SYSTEM, EYES
ASSESSMENT:
THE SUBSTANCE OR MIXTURE IS CLASSIFIED AS SPECIFIC TARGET ORGAN TOXICANT,
SINGLE EXPOSURE, CATEGORY 1.
XYLENE:
ASSESSMENT:
MAY CAUSE DROWSINESS OR DIZZINESS., MAY CAUSE RESPIRATORY IRRITATION.
STOT - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS (AUDITORY SYSTEM) THROUGH PROLONGED OR REPEATED
EXPOSURE.
COMPONENTS:
ETHYLBENZENE:
TARGET ORGANS: AUDITORY SYSTEM
ASSESSMENT:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION TOXICITY: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
COMPONENTS:
ACETONE: MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS.
XYLENE: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
ETHYLBENZENE: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
FURTHER INFORMATION:
PRODUCT:
REMARKS:
SYMPTOMS OF OVEREXPOSURE MAY BE HEADACHE, DIZZINESS, TIREDNESS, NAUSEA AND
VOMITING.
| SECTION 12. ECOLOGICAL INFORMATION | |
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES:
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY REMAINING CONTENTS.
DISPOSE OF AS UNUSED PRODUCT.
DO NOT RE-USE EMPTY CONTAINERS.
DO NOT BURN, OR USE A CUTTING TORCH ON, THE EMPTY DRUM.
| SECTION 14. TRANSPORT INFORMATION | |
DANGEROUS GOODS DESCRIPTIONS (IF INDICATED BELOW) MAY NOT REFLECT QUANTITY,
END-USE, OR REGION-SPECIFIC EXCEPTIONS THAT CAN BE APPLIED. CONSULT
SHIPPING DOCUMENTS FOR DESCRIPTIONS THAT ARE SPECIFIC TO THE SHIPMENT.
INTERNATIONAL REGULATIONS:
IATA-DGR:
UN/ID NO.: UN 1992
PROPER SHIPPING NAME: FLAMMABLE LIQUID, TOXIC, N.O.S. (ACETONE, METHANOL)
CLASS: 3
SUBSIDIARY RISK: 6.1
PACKING GROUP: II
LABELS: 3 (6.1)
PACKING INSTRUCTION (CARGO AIRCRAFT): 364
PACKING INSTRUCTION (PASSENGER AIRCRAFT): 352
IMDG-CODE:
UN NUMBER: UN 1992
PROPER SHIPPING NAME: FLAMMABLE LIQUID, TOXIC, N.O.S. (ACETONE, METHANOL)
CLASS: 3
SUBSIDIARY RISK: 6.1
PACKING GROUP: II
LABELS: 3 (6.1)
EMS CODE: F-E, S-D
MARINE POLLUTANT: NO
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE FOR PRODUCT AS SUPPLIED.
NATIONAL REGULATIONS:
49 CFR:
UN/ID/NA NUMBER: UN 1993
PROPER SHIPPING NAME: FLAMMABLE LIQUIDS, N.O.S. (ACETONE, METHANOL)
CLASS: 3
PACKING GROUP: II
LABELS: 3
ERG CODE: 128
MARINE POLLUTANT: NO
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT:
CERCLA REPORTABLE QUANTITY:
COMPONENTS CAS-NO. COMPONENT RQ (LBS) CALCULATED PRODUCT RQ (LBS)
XYLENE 1330-20-7 100 467
XYLENE 1330-20-7 100 100 (F003)
SARA 304 EXTREMELY HAZARDOUS SUBSTANCES REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 304 EHS RQ.
SARA 302 EXTREMELY HAZARDOUS SUBSTANCES THRESHOLD PLANNING QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 302 EHS TPQ.
SARA 311/312 HAZARDS:
FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
HAZARD NOT OTHERWISE CLASSIFIED (PHYSICAL HAZARDS)
ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
SKIN CORROSION OR IRRITATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
ASPIRATION HAZARD
SARA 313:
THE FOLLOWING COMPONENTS ARE SUBJECT TO REPORTING LEVELS ESTABLISHED BY
SARA TITLE III, SECTION 313:
METHANOL 67-56-1 >/= 20 - <30%
ETHYLBENZENE 100-41-4 >/= 5 - <10%
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO CHEMICALS INCLUDING ETHYLBENZENE, BENZENE,
WHICH IS/ARE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, AND
METHANOL, TOLUENE, BENZENE, WHICH IS/ARE KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. FOR MORE INFORMATION GO
TO WWW.P65WARNINGS.CA.GOV.
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
NFPA:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
SPECIAL HAZARD.
REVISION DATE: 09/06/2018
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.
US / EN