| Common Name: | SUPEROL KPO GLYCERIN, USP/FCC/EP (FOR EXCIPIENT USE ONLY) |
| Manufacturer: | PROCTER & GAMBLE |
| SDS Revision Date: | 5/16/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 45YP82 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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P&G CHEMICALS
DELIVERING SOLUTIONS, CREATING VALUE
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER:
SUPEROL KPO GLYCERIN, USP/FCC/EP (FOR EXCIPIENT USE ONLY)
SDS NUMBER: GLYC301
PRODUCT CODE: 99318844, 96462112
VERSION #: 06
ISSUE DATE: 12-19-2013
REVISION DATE: 05-16-2014
SUPERSEDES DATE: 12-19-2013
PRODUCT USE:
EMULSIFIER, EMOLLIENT, PLASTICIZER, HUMECTANT, SWEETENER, ANTI-FREEZE, IN
SURFACE COATINGS AND PAINTS, COSMETICS, DRUG EXCIPIENT AND FOOD PRODUCTS.
INTERMEDIATE FOR MAKING GLYCEROL DERIVATIVES.
RECOMMENDED RESTRICTIONS: NOT AVAILABLE.
SYNONYM(S): GLYCEROL
MANUFACTURER:
THE PROCTER & GAMBLE COMPANY
PROCTER & GAMBLE CHEMICALS
SHARON WOODS INNOVATION CENTER
11530 REED HARTMAN HIGHWAY
CINCINNATI, OH 45241
UNITED STATES
FOR QUALITY SERVICE OR PRODUCT RELATED QUESTIONS CALL: 1-800-477-8899
PGCHEMMSDS.IM@PG.COM
FOR EMERGENCY CONTACT CHEMTREC: 1-800-424-9300 U.S. AND CANADA
FOR CALLS ORIGINATING ELSEWHERE CHEMTREC: 1-703-527-3887
| 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
PHYSICAL HAZARDS: NOT CLASSIFIED.
HEALTH HAZARDS: NOT CLASSIFIED.
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
GHS LABEL ELEMENTS:
SIGNAL WORDS: NONE.
SYMBOLS: NONE.
HAZARD STATEMENT: NONE.
PRECAUTIONARY STATEMENT:
PREVENTION: NONE.
RESPONSE: NONE.
STORAGE: NONE.
DISPOSAL: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS CAS # PERCENT
1,2,3-PROPANETRIOL 56-81-5 99.7 - 100
| 4. FIRST AID MEASURES | |
FIRST AID PROCEDURES:
EYE:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR
PERSISTS.
SKIN: WASH SKIN THOROUGHLY WITH SOAP AND WATER.
INHALATION:
IF BREATHING IS DIFFICULT, REMOVE TO FRESH AIR AND KEEP AT REST IN A
POSITION COMFORTABLE FOR BREATHING. GET MEDICAL ATTENTION, IF NEEDED.
INGESTION:
SEEK MEDICAL ATTENTION. DO NOT INDUCE VOMITING WITHOUT ADVICE FROM POISON
CONTROL CENTER OR DOCTOR.
NOTES TO PHYSICIAN: NOT APPLICABLE.
| 5. FIRE-FIGHTING MEASURES | |
FLAMMABLE PROPERTIES:
THIS PRODUCT MAY REACT EXPLOSIVELY WHEN MIXED WITH OXIDIZING AGENTS.
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. WATER SPRAY. FOAM. DRY POWDER. CARBON DIOXIDE (CO2). ALCOHOL
RESISTANT FOAM.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
PROTECTION OF FIREFIGHTERS:
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: COMBUSTION CAUSES TOXIC FUMES.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED POSITIVE
PRESSURE OR PRESSURE DEMAND BREATHING APPARATUS, PROTECTIVE CLOTHING AND
FACE MASK.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS: EVACUATE AREA.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
KEEP UNNECESSARY PERSONNEL AWAY. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
CLOTHING DURING CLEAN-UP.
ENVIRONMENTAL PRECAUTIONS:
PREVENT RUNOFF FROM ENTERING DRAINS, SEWERS, OR STREAMS. AVOID DISCHARGE
ONTO THE GROUND.
METHODS FOR CONTAINMENT: DIKE THE SPILLED MATERIAL, WHERE THIS IS POSSIBLE.
METHODS FOR CLEANING UP:
USE A NON-COMBUSTIBLE MATERIAL LIKE VERMICULITE, SAND OR EARTH TO SOAK UP
THE PRODUCT AND PLACE INTO A CONTAINER FOR LATER DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
STORAGE: STORE IN A COOL, DRY PLACE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
CONTROL PARAMETERS:
U.S. - OSHA:
MATERIAL TYPE VALUE FORM
1,2,3-PROPANETRIOL PEL 5 MG/M3 RESPIRABLE FRACTION.
(56-81-5) 15 MG/M3 TOTAL DUST.
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE FORM
1,2,3-PROPANETRIOL PEL 5 MG/M3 RESPIRABLE FRACTION.
(56-81-5) 15 MG/M3 TOTAL DUST.
ENGINEERING CONTROLS:
ADEQUATE VENTILATION SHOULD BE PROVIDED SO THAT EXPOSURE LIMITS ARE NOT
EXCEEDED.
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
EYE/FACE PROTECTION: SAFETY GLASSES.
SKIN PROTECTION:
WEAR SUITABLE PROTECTIVE CLOTHING. USE PROTECTIVE GLOVES MADE OF: NEOPRENE,
NITRILE, POLYETHYLENE OR PVC.
RESPIRATORY PROTECTION:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED. IN CASE OF
INADEQUATE VENTILATION OR RISK OF INHALATION OF VAPORS, USE SUITABLE
RESPIRATORY EQUIPMENT WITH COMBINATION FILTER (TYPE A2/P2).
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE. KEEP
AWAY FROM FOOD AND DRINK. WASH HANDS AFTER HANDLING AND BEFORE EATING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: WATER. WHITE.
FORM: LIQUID.
ODOR: MILD.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: 64.4 DEG. F (18 DEG. C)
BOILING POINT: 554 DEG. F (290 DEG. C)
FLASH POINT: 390.20 DEG. F (199.00 DEG. C) PENSKY-MARTENS CLOSED CUP
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
FLAMMABILITY LIMITS IN AIR, LOWER, % BY VOLUME: NOT AVAILABLE.
FLAMMABILITY LIMITS IN AIR, UPPER, % BY VOLUME: NOT AVAILABLE.
VAPOR PRESSURE: <0.2 MM Hg AT 100 DEG. C
RELATIVE DENSITY: 1.261 G/ML AT 20 DEG. C
SOLUBILITY (H2O): MISCIBLE AT 25 DEG. C
PARTITION COEFFICIENT (N-OCTANOL/WATER): -1.8
AUTO-IGNITION TEMPERATURE: 698 DEG. F (370 DEG. C)
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.261326133
OTHER DATA:
DYNAMIC VISCOSITY: 1412 MPA.S @ 20 DEG. C
SURFACE TENSION: >60 MN/M
| 10. STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID:
AVOID TEMPERATURES EXCEEDING THE DECOMPOSITION TEMPERATURE.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
WILL DECOMPOSE AT TEMPERATURES EXCEEDING 200 DEG. C. DECOMPOSITION MAY
YIELD ACROLEIN.
| 11. TOXICOLOGICAL INFORMATION | |
TOXICOLOGICAL DATA:
COMPONENTS SPECIES TEST RESULTS
1,2,3-PROPANETRIOL (56-81-5)
ACUTE:
DERMAL:
LD50 GUINEA PIG 45 ML/KG, BW. OECD GHS
INHALATION:
RAT 4655, 7 HOURS, MG/MIN/L; L(CT)50. OECD GHS
ORAL:
LD50 MOUSE 23000 MG/KG, BW. CA. OECD GHS
GENERAL INFORMATION: NOT AVAILABLE.
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION: NOT CLASSIFIED.
INHALATION: NOT CLASSIFIED.
SKIN CONTACT: NOT CLASSIFIED.
EYE CONTACT: NOT CLASSIFIED.
SENSITIZATION: NOT CLASSIFIED.
CARCINOGENICITY: NOT CLASSIFIED.
THIS PRODUCT IS NOT CONSIDERED TO BE A CARCINOGEN BY IARC, ACGIH, NTP, OR
OSHA.
1,2,3-PROPANETRIOL IN VIVO ORAL
RESULT: NO EFFECTS
SPECIES: RAT
TEST DURATION: 2 YEARS
MUTAGENICITY: NOT CLASSIFIED.
GERM CELL MUTAGENICITY: AMES TEST
1,2,3-PROPANETRIOL IN VITRO, OECD 471
RESULT: NEGATIVE
SPECIES: SALMONELLA TYPHIMIRIUM (SALMONELLA ENTERICA)
GERM CELL MUTAGENICITY: CHROMOSOME ABBERATION
1,2,3-PROPANETRIOL IN VITRO - CHINESE HAMSTER OVARY, OECD 473
RESULT: NO EFFECTS
REPRODUCTIVE EFFECTS: NOT CLASSIFIED.
FERTILITY EFFECTS - MALES AND FEMALES:
1,2,3-PROPANETRIOL 2000 MG/KG BW/DAY IN VIVO ORAL, 2 GENERATION STUDY
RESULT: NO EFFECTS
SPECIES: RAT
TERATOGENICITY: NOT CLASSIFIED.
DEVELOPMENTAL EFFECTS:
1,2,3-PROPANETRIOL 1310 MG/KG BW/DAY IN VIVO ORAL, NOAEL. STUDY FOLLOWED
INTENT OF OECD 414
RESULT: NO EFFECTS
SPECIES: RAT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED.
IRRITATION CORROSION - SKIN:
1,2,3-PROPANETRIOL 0.5 ML IN VIVO
RESULT: NO EFFECTS
SPECIES: RABBIT
TEST DURATION: 24 HOURS
SERIOUS EYE DAMAGE/EYE IRRITATION: NOT CLASSIFIED.
IRRITATION CORROSION - EYE:
1,2,3-PROPANETRIOL 0.1 ML IN VIVO
RESULT: NO EFFECTS
SPECIES: RABBIT
TEST DURATION: 7 DAYS
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
1,2,3-PROPANETRIOL 167 MG/M3 INHALATION, NOAEL. STUDY FOLLOWED INTENT OF
OECD 413
RESULT: NO EFFECTS.
SPECIES: RAT
TEST DURATION: 13 WEEKS
5040 MG/KG BW/DAY DERMAL, NOEL
RESULT: NO EFFECTS.
SPECIES: RABBIT
TEST DURATION: 45 WEEKS
8000 - 10000 MG/KG BW/DAY ORAL, NOAEL. STUDY FOLLOWED
INTENT OF OECD 452
RESULT: NO EFFECTS.
SPECIES: RAT
TEST DURATION: 2 YEARS
OTHER INFORMATION: NOT AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL DATA:
COMPONENTS SPECIES TEST RESULTS
1,2,3-PROPANETRIOL (56-81-5)
EC3 (TT) PSEUDOMONAS PUTIDA >10000 MG/L, 16
HOURS
AQUATIC:
ALGAE EC3 (TT) GREEN ALGAE (SCENEDESMUS >10000 MG/L, 8 DAYS
QUADRICAUDA)
CRUSTACEA LC50 WATER FLEA (DAPHNIA MAGNA) >10000 MG/L, 24
HOURS
FISH LC50 RAINBOW TROUT, DONALDSON TROUT 54000 MG/L, 96 HOURS
(ONCORHYNCHUS MYKISS)
ECOTOXICITY: NOT CLASSIFIED AS AN ENVIRONMENTAL HAZARD.
PERSISTENCE AND DEGRADABILITY:
EVEN THOUGH THIS PRODUCT IS READILY BIODEGRADABLE, IT MUST NOT BE
INDISCRIMINATELY DISCARDED INTO THE ENVIRONMENT.
BIODEGRADABILITY:
PERCENT DEGRADATION (AEROBIC BIODEGRADATION-READY):
1,2,3-PROPANETRIOL RESULT: READILY BIODEGRADABLE
SPECIES: ACTIVATED SLUDGE, INDUSTRIAL
TEST DURATION: 24 HOURS
BIOACCUMULATIVE POTENTIAL: THE PRODUCT IS NOT BIOACCUMULATING.
OCTANOL/WATER PARTITION COEFFICIENT LOG KOW:
1,2,3-PROPANETRIOL -1.75
MOBILITY IN SOIL: NOT AVAILABLE.
VOLATILITY:
HENRY'S LAW:
1,2,3-PROPANETRIOL CALCULATION
RESULT: 0.000000006 ATM M3/MOL@25 DEG. C
OTHER ADVERSE EFFECTS: NONE KNOWN.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
DO NOT ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES. DISPOSE OF
CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL
REGULATIONS.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
CONTAMINATED PACKAGING:
OFFER RINSED PACKAGING MATERIAL TO LOCAL RECYCLING FACILITIES.
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED AS DANGEROUS GOODS.
IATA: NOT REGULATED AS DANGEROUS GOODS.
IMDG: NOT REGULATED AS DANGEROUS GOODS.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS NOT KNOWN TO BE A "HAZARDOUS CHEMICAL" AS DEFINED BY THE
OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200.
ALL COMPONENTS ARE ON THE U.S. EPA TSCA INVENTORY LIST.
CERCLA/SARA HAZARDOUS SUBSTANCES: NOT APPLICABLE.
CERCLA (SUPERFUND) REPORTABLE QUANTITY: NONE
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: NO
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SECTION 311 HAZARDOUS CHEMICAL: NO
INVENTORY STATUS:
COUNTRY(S) OR INVENTORY NAME ON INVENTORY
REGION
(YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES YES
(AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES YES
IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING COMMERCIAL YES
CHEMICAL SUBSTANCES (EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW CHEMICAL YES
SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS AND YES
CHEMICAL SUBSTANCES (PICCS)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
STATE REGULATIONS:
THIS PRODUCT DOES NOT CONTAIN A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
US - MINNESOTA HAZ SUBS: HAZARDOUS SUBSTANCE
1,2,3-PROPANETRIOL (CAS 56-81-5) HAZARDOUS SUBSTANCE.
US - NEW JERSEY RTK - SUBSTANCES: LISTED SUBSTANCE
1,2,3-PROPANETRIOL (CAS 56-81-5) LISTED.
US - PENNSYLVANIA RTK - HAZARDOUS SUBSTANCES: LISTED SUBSTANCE
1,2,3-PROPANETRIOL (CAS 56-81-5) LISTED.
| 16. OTHER INFORMATION | |
FURTHER INFORMATION:
HMIS(R*) IS A REGISTERED TRADE AND SERVICE MARK OF THE NPCA.
MEETS THE CRITERIA OF PARAGRAPH 9 OF ANNEX V OF THE REACH EC REGULATION NO.
987/2008 AND IS THEREFORE EXEMPTED FROM THE OBLIGATION TO REGISTER UNDER
REACH.
HMIS(R*) RATINGS:
HEALTH 0
FLAMMABILITY 1
PHYSICAL HAZARD 0
NFPA RATINGS:
HEALTH 0
FLAMMABILITY 1
INSTABILITY 0
DISCLAIMER:
THE SUBMISSION OF THE SDS MAY BE REQUIRED BY LAW, BUT THIS IS NOT AN
ASSERTION THAT THE SUBSTANCE IS HAZARDOUS WHEN USED IN ACCORDANCE WITH
PROPER SAFETY PRACTICES AND NORMAL HANDLING PROCEDURES. DATA SUPPLIED ARE
FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH.
THE INFORMATION CONTAINED HEREIN HAS BEEN COMPILED FROM SOURCES CONSIDERED
BY PROCTER & GAMBLE TO BE DEPENDABLE AND IS ACCURATE TO THE BEST OF THE
COMPANY'S KNOWLEDGE. THE INFORMATION RELATES TO THE SPECIFIC PRODUCT
DESIGNATED HEREIN, AND DOES NOT RELATE TO USE IN COMBINATION WITH ANY OTHER
MATERIAL OF ANY OTHER PROCESS. PROCTER & GAMBLE ASSUMES NO RESPONSIBILITY
FOR INJURY TO THE RECIPIENT OR THIRD PERSONS, OR FOR ANY DAMAGE TO ANY
PROPERTY RESULTING FROM MISUSE OF THE CONTROLLED PRODUCT.
THIS DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN SECTION(S):
THIS DOCUMENT HAS UNDERGONE SIGNIFICANT CHANGES AND SHOULD BE REVIEWED IN
ITS ENTIRETY.
MATERIAL NAME: SUPEROL KPO GLYCERIN, USP/FCC/EP (FOR EXCIPIENT USE ONLY)
SDS NO.: 99318844, 96462112
MSDS US GHS