| Common Name: | AMMONIUM CITRATE DIBASIC, 247561 |
| Manufacturer: | SIGMA-ALDRICH |
| SDS Revision Date: | 3/27/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 45ZR87 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SIGMA-ALDRICH
SIGMA-ALDRICH.COM
SAFETY DATA SHEET
VERSION: 5.4
REVISION DATE: 03/27/2017
PRINT DATE: 05/16/2017
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
1.1 PRODUCT IDENTIFIERS:
PRODUCT NAME: AMMONIUM CITRATE DIBASIC
PRODUCT NUMBER: 247561
BRAND: SIGMA-ALDRICH
CAS-NO.: 3012-65-5
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
IDENTIFIED USES: LABORATORY CHEMICALS, SYNTHESIS OF SUBSTANCES
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY:
SIGMA-ALDRICH
3050 SPRUCE STREET
SAINT LOUIS MO 63103
USA
TELEPHONE: +1 800-325-5832
FAX: +1 800-325-5052
1.4 EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE #: +1-703-527-3887 (CHEMTREC)
| 2. HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910 (OSHA HCS):
EYE IRRITATION (CATEGORY 2A), H319
FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.
2.2 GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
PICTOGRAM: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENT(S):
H319: CAUSES SERIOUS EYE IRRITATION.
PRECAUTIONARY STATEMENT(S):
P264: WASH SKIN THOROUGHLY AFTER HANDLING.
P280: WEAR EYE PROTECTION/FACE PROTECTION.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
2.3 HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) OR NOT COVERED BY GHS: NONE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1 SUBSTANCES:
SYNONYMS:
AMMONIUM HYDROGENCITRATE
AMMONIUM CITRATE DIBASIC
CITRIC ACID AMMONIUM SALT
DIAMMONIUM HYDROGEN CITRATE
FORMULA: C6H14N2O7
MOLECULAR WEIGHT: 226.18 G/MOL
CAS-NO.: 3012-65-5
EC-NO.: 221-146-3
HAZARDOUS COMPONENTS:
COMPONENT CLASSIFICATION CONCENTRATION
DIAMMONIUM HYDROGEN 2-HYDROXYPROPANE- EYE IRRIT. 2A; H319 90 - 100%
1,2,3-TRICARBOXYLATE
FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.
| 4. FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
CONSULT A PHYSICIAN. SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN
ATTENDANCE. MOVE OUT OF DANGEROUS AREA.
IF INHALED:
IF BREATHED IN, MOVE PERSON INTO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. CONSULT A PHYSICIAN.
IN CASE OF SKIN CONTACT:
WASH OFF WITH SOAP AND PLENTY OF WATER. CONSULT A PHYSICIAN.
IN CASE OF EYE CONTACT:
RINSE THOROUGHLY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND CONSULT A
PHYSICIAN.
IF SWALLOWED:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. RINSE MOUTH WITH
WATER. CONSULT A PHYSICIAN.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
THE MOST IMPORTANT KNOWN SYMPTOMS AND EFFECTS ARE DESCRIBED IN THE LABELING
(SEE SECTION 2.2) AND/OR IN SECTION 11
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO DATA AVAILABLE
| 5. FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE WATER SPRAY, ALCOHOL-RESISTANT FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NO DATA AVAILABLE
5.3 ADVICE FOR FIREFIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS FOR FIREFIGHTING IF NECESSARY.
5.4 FURTHER INFORMATION: NO DATA AVAILABLE
| 6. ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT. AVOID DUST FORMATION. AVOID BREATHING
VAPOURS, MIST OR GAS. ENSURE ADEQUATE VENTILATION. AVOID BREATHING DUST.
FOR PERSONAL PROTECTION SEE SECTION 8.
6.2 ENVIRONMENTAL PRECAUTIONS: DO NOT LET PRODUCT ENTER DRAINS.
6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
PICK UP AND ARRANGE DISPOSAL WITHOUT CREATING DUST. SWEEP UP AND SHOVEL.
KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
6.4 REFERENCE TO OTHER SECTIONS: FOR DISPOSAL SEE SECTION 13.
| 7. HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
FURTHER PROCESSING OF SOLID MATERIALS MAY RESULT IN THE FORMATION OF
COMBUSTIBLE DUSTS. THE POTENTIAL FOR COMBUSTIBLE DUST FORMATION SHOULD BE
TAKEN INTO CONSIDERATION BEFORE ADDITIONAL PROCESSING OCCURS. AVOID CONTACT
WITH SKIN AND EYES. AVOID FORMATION OF DUST AND AEROSOLS.
PROVIDE APPROPRIATE EXHAUST VENTILATION AT PLACES WHERE DUST IS FORMED.
FOR PRECAUTIONS SEE SECTION 2.2.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
7.3 SPECIFIC END USE(S):
APART FROM THE USES MENTIONED IN SECTION 1.2 NO OTHER SPECIFIC USES ARE
STIPULATED
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
CONTAINS NO SUBSTANCES WITH OCCUPATIONAL EXPOSURE LIMIT VALUES.
HAZARDOUS COMPONENTS WITHOUT WORKPLACE CONTROL PARAMETERS
8.2 EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE. WASH
HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
SAFETY GLASSES WITH SIDE-SHIELDS CONFORMING TO EN166 USE EQUIPMENT FOR EYE
PROTECTION TESTED AND APPROVED UNDER APPROPRIATE GOVERNMENT STANDARDS SUCH
AS NIOSH (US) OR EN 166(EU).
SKIN PROTECTION:
HANDLE WITH GLOVES. GLOVES MUST BE INSPECTED PRIOR TO USE. USE PROPER GLOVE
REMOVAL TECHNIQUE (WITHOUT TOUCHING GLOVE'S OUTER SURFACE) TO AVOID SKIN
CONTACT WITH THIS PRODUCT. DISPOSE OF CONTAMINATED GLOVES AFTER USE IN
ACCORDANCE WITH APPLICABLE LAWS AND GOOD LABORATORY PRACTICES. WASH AND DRY
HANDS.
FULL CONTACT:
MATERIAL: NITRILE RUBBER
MINIMUM LAYER THICKNESS: 0.11 MM
BREAK THROUGH TIME: 480 MIN
MATERIAL TESTED: DERMATRIL(R*) (KCL 740 / ALDRICH Z677272, SIZE M)
SPLASH CONTACT:
MATERIAL: NITRILE RUBBER
MINIMUM LAYER THICKNESS: 0.11 MM
BREAK THROUGH TIME: 480 MIN
MATERIAL TESTED: DERMATRIL(R*) (KCL 740 / ALDRICH Z677272, SIZE M)
DATA SOURCE:
KCL GMBH, D-36124 EICHENZELL, PHONE +49 (0)6659 87300, E-MAIL SALES@KCL.DE,
TEST METHOD: EN374
IF USED IN SOLUTION, OR MIXED WITH OTHER SUBSTANCES, AND UNDER CONDITIONS
WHICH DIFFER FROM EN 374, CONTACT THE SUPPLIER OF THE CE APPROVED GLOVES.
THIS RECOMMENDATION IS ADVISORY ONLY AND MUST BE EVALUATED BY AN INDUSTRIAL
HYGIENIST AND SAFETY OFFICER FAMILIAR WITH THE SPECIFIC SITUATION OF
ANTICIPATED USE BY OUR CUSTOMERS. IT SHOULD NOT BE CONSTRUED AS OFFERING AN
APPROVAL FOR ANY SPECIFIC USE SCENARIO.
BODY PROTECTION:
IMPERVIOUS CLOTHING, THE TYPE OF PROTECTIVE EQUIPMENT MUST BE SELECTED
ACCORDING TO THE CONCENTRATION AND AMOUNT OF THE DANGEROUS SUBSTANCE AT THE
SPECIFIC WORKPLACE.
RESPIRATORY PROTECTION:
FOR NUISANCE EXPOSURES USE TYPE P95 (US) OR TYPE P1 (EU EN 143) PARTICLE
RESPIRATOR. FOR HIGHER LEVEL PROTECTION USE TYPE OV/AG/P99 (US) OR TYPE
ABEK-P2 (EU EN 143) RESPIRATOR CARTRIDGES. USE RESPIRATORS AND COMPONENTS
TESTED AND APPROVED UNDER APPROPRIATE GOVERNMENT STANDARDS SUCH AS NIOSH
(US) OR CEN (EU).
CONTROL OF ENVIRONMENTAL EXPOSURE: DO NOT LET PRODUCT ENTER DRAINS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
A) APPEARANCE:
FORM: SOLID
B) ODOUR: NO DATA AVAILABLE
C) ODOUR THRESHOLD: NO DATA AVAILABLE
D) PH: 5.2 AT 50 G/L AT 20 DEG. C (68 DEG. F)
E) MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
F) INITIAL BOILING POINT AND BOILING RANGE: NO DATA AVAILABLE
G) FLASH POINT: NO DATA AVAILABLE
H) EVAPORATION RATE: NO DATA AVAILABLE
I) FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
J) UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NO DATA AVAILABLE
K) VAPOUR PRESSURE: NO DATA AVAILABLE
L) VAPOUR DENSITY: NO DATA AVAILABLE
M) RELATIVE DENSITY: NO DATA AVAILABLE
N) WATER SOLUBILITY: NO DATA AVAILABLE
O) PARTITION COEFFICIENT N-OCTANOL/WATER: LOG POW: -2.84
P) AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
Q) DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
R) VISCOSITY: NO DATA AVAILABLE
S) EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
T) OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2 OTHER SAFETY INFORMATION:
BULK DENSITY: 0.4 - 0.6 G/L
| 10. STABILITY AND REACTIVITY | |
10.1 REACTIVITY: NO DATA AVAILABLE
10.2 CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS: NO DATA AVAILABLE
10.4 CONDITIONS TO AVOID: NO DATA AVAILABLE
10.5 INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS, STRONG BASES, STRONG ACIDS
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS DECOMPOSITION PRODUCTS FORMED UNDER FIRE CONDITIONS. - CARBON
OXIDES, NITROGEN OXIDES (NOX)
OTHER DECOMPOSITION PRODUCTS: NO DATA AVAILABLE
IN THE EVENT OF FIRE: SEE SECTION 5
| 11. TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NO DATA AVAILABLE
INHALATION: NO DATA AVAILABLE
DERMAL: NO DATA AVAILABLE
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/EYE IRRITATION:
EYE IRRITATION INFORMATION GIVEN IS BASED ON DATA OBTAINED FROM SIMILAR
SUBSTANCES.
RESPIRATORY OR SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
ADDITIONAL INFORMATION:
RTECS: GE7545000
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL
PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
| 12. ECOLOGICAL INFORMATION | |
12.1 TOXICITY: NO DATA AVAILABLE
12.2 PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
12.3 BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
12.4 MOBILITY IN SOIL: NO DATA AVAILABLE
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT/VPVB ASSESSMENT NOT AVAILABLE AS CHEMICAL SAFETY ASSESSMENT NOT
REQUIRED/NOT CONDUCTED
12.6 OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
PRODUCT:
OFFER SURPLUS AND NON-RECYCLABLE SOLUTIONS TO A LICENSED DISPOSAL COMPANY.
CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL SERVICE TO DISPOSE OF THIS
MATERIAL.
CONTAMINATED PACKAGING: DISPOSE OF AS UNUSED PRODUCT.
| 14. TRANSPORT INFORMATION | |
DOT (US):
UN NUMBER: 3077
CLASS: 9
PACKING GROUP: III
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. (DIAMMONIUM HYDROGEN
2-HYDROXYPROPANE-1,2,3-TRICARBOXYLATE)
REPORTABLE QUANTITY (RQ): 5000 LBS
POISON INHALATION HAZARD: NO
IMDG: NOT DANGEROUS GOODS
IATA: NOT DANGEROUS GOODS
| 15. REGULATORY INFORMATION | |
SARA 302 COMPONENTS:
NO CHEMICALS IN THIS MATERIAL ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SARA TITLE III, SECTION 302.
SARA 313 COMPONENTS:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS ESTABLISHED
BY SARA TITLE III, SECTION 313.
SARA 311/312 HAZARDS: ACUTE HEALTH HAZARD
MASSACHUSETTS RIGHT TO KNOW COMPONENTS:
CAS-NO. REVISION DATE
DIAMMONIUM HYDROGEN 2-HYDROXYPROPANE- 3012-65-5 1993-04-24
1,2,3-TRICARBOXYLATE
PENNSYLVANIA RIGHT TO KNOW COMPONENTS:
CAS-NO. REVISION DATE
DIAMMONIUM HYDROGEN 2-HYDROXYPROPANE- 3012-65-5 1993-04-24
1,2,3-TRICARBOXYLATE
CAS-NO. REVISION DATE
DIAMMONIUM HYDROGEN 2-HYDROXYPROPANE- 3012-65-5 1993-04-24
1,2,3-TRICARBOXYLATE
NEW JERSEY RIGHT TO KNOW COMPONENTS:
CAS-NO. REVISION DATE
DIAMMONIUM HYDROGEN 2-HYDROXYPROPANE- 3012-65-5 1993-04-24
1,2,3-TRICARBOXYLATE
CALIFORNIA PROP. 65 COMPONENTS:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO STATE OF CALIFORNIA TO
CAUSE CANCER, BIRTH DEFECTS, OR ANY OTHER REPRODUCTIVE HARM.
| 16. OTHER INFORMATION | |
FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3.:
EYE IRRIT.: EYE IRRITATION
H319: CAUSES SERIOUS EYE IRRITATION.
HMIS RATING:
HEALTH HAZARD 2
CHRONIC HEALTH HAZARD
FLAMMABILITY 0
PHYSICAL HAZARD 0
NFPA RATING
HEALTH HAZARD 0
FIRE HAZARD 0
REACTIVITY HAZARD 0
FURTHER INFORMATION:
COPYRIGHT 2017 SIGMA-ALDRICH CO. LLC. LICENSE GRANTED TO MAKE UNLIMITED
PAPER COPIES FOR INTERNAL USE ONLY. THE ABOVE INFORMATION IS BELIEVED TO BE
CORRECT BUT DOES NOT PURPORT TO BE ALL INCLUSIVE AND SHALL BE USED ONLY AS
A GUIDE. THE INFORMATION IN THIS DOCUMENT IS BASED ON THE PRESENT STATE OF
OUR KNOWLEDGE AND IS APPLICABLE TO THE PRODUCT WITH REGARD TO APPROPRIATE
SAFETY PRECAUTIONS. IT DOES NOT REPRESENT ANY GUARANTEE OF THE PROPERTIES
OF THE PRODUCT. SIGMA-ALDRICH CORPORATION AND ITS AFFILIATES SHALL NOT BE
HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WITH THE
ABOVE PRODUCT. SEE WWW.SIGMA-ALDRICH.COM AND/OR THE REVERSE SIDE OF INVOICE
OR PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
PREPARATION INFORMATION:
SIGMA-ALDRICH CORPORATION
PRODUCT SAFETY - AMERICAS REGION
1-800-521-8956
VERSION: 5.4
REVISION DATE: 03/27/2017
PRINT DATE: 05/16/2017