| Common Name: | SODIUM METHOXIDE SOLUTION, 156256 |
| Manufacturer: | SIGMA-ALDRICH |
| SDS Revision Date: | 1/15/2020 |
| SDS Format: | GHS-US |
| Item Number(s): | 45ZX42 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SIGMA-ALDRICH(R*)
WWW.SIGMAALDRICH.COM
SAFETY DATA SHEET
VERSION: 6.3
REVISION DATE: 01/15/2020
PRINT DATE: 08/29/2020
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIERS:
PRODUCT NAME: SODIUM METHOXIDE SOLUTION
PRODUCT NUMBER: 156256
BRAND: SIGMA-ALDRICH
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES
ADVISED AGAINST:
IDENTIFIED USES: LABORATORY CHEMICALS, SYNTHESIS OF SUBSTANCES
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY:
SIGMA-ALDRICH INC.
3050 SPRUCE STREET
ST. LOUIS MO 63103
UNITED STATES
TELEPHONE: +1 314 771-5765
FAX: +1 800 325-5052
1.4 EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE #: 800-424-9300
CHEMTREC (USA): +1-703-527-3887
CHEMTREC (INTERNATIONAL): 24 HOURS/DAY; 7 DAYS/WEEK
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910 (OSHA HCS):
FLAMMABLE LIQUIDS (CATEGORY 2): H225
SELF-HEATING CHEMICALS (CATEGORY 1): H251
CORROSIVE TO METALS (CATEGORY 1): H290
ACUTE TOXICITY, ORAL (CATEGORY 3): H301
ACUTE TOXICITY, INHALATION (CATEGORY 3): H331
ACUTE TOXICITY, DERMAL (CATEGORY 3): H311
SKIN CORROSION (CATEGORY 1A): H314
SERIOUS EYE DAMAGE (CATEGORY 1): H318
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE (CATEGORY 1), EYES: H370
FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.
2.2 GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
PICTOGRAM:
FLAME
SKULLS AND CROSSBONES
HEALTH HAZARD
CORROSION
SIGNAL WORD: DANGER
HAZARD STATEMENT(S):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
H251:
SELF-HEATING: MAY CATCH FIRE.
H290: MAY BE CORROSIVE TO METALS.
H301/H311/H331: TOXIC IF SWALLOWED, IN CONTACT WITH SKIN OR IF INHALED.
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H370: CAUSES DAMAGE TO ORGANS (EYES).
PRECAUTIONARY STATEMENT(S):
P210:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P234: KEEP ONLY IN ORIGINAL CONTAINER.
P235/P410: KEEP COOL. PROTECT FROM SUNLIGHT.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/ VENTILATING/ LIGHTING EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P260: DO NOT BREATHE DUST/ FUME/ GAS/ MIST/ VAPOURS/ SPRAY.
P264: WASH SKIN THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280:
WEAR PROTECTIVE GLOVES/ PROTECTIVE CLOTHING/ EYE PROTECTION/ FACE
PROTECTION.
P301/P310/P330:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER/DOCTOR. RINSE MOUTH.
P301/P330/P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P303/P361/P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304/P340/P310:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IMMEDIATELY CALL A POISON CENTER/DOCTOR.
P305/P351/P338/P310:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT
LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY
CALL A POISON CENTER/DOCTOR.
P307/P311:
IF EXPOSED: CALL A POISON CENTER OR DOCTOR/ PHYSICIAN.
P362: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
P370/P378:
IN CASE OF FIRE:
USE DRY SAND, DRY CHEMICAL OR ALCOHOL-RESISTANT FOAM TO EXTINGUISH.
P390: ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE.
P403/P233:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P403/P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
P406:
STORE IN CORROSIVE RESISTANT CONTAINER WITH A RESISTANT INNER LINER.
P407: MAINTAIN AIR GAP BETWEEN STACKS/ PALLETS.
P420: STORE AWAY FROM OTHER MATERIALS.
P501:
DISPOSE OF CONTENTS/ CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
2.3 HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) OR NOT COVERED BY GHS:
REACTS VIOLENTLY WITH WATER.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2 MIXTURES:
SYNONYMS: SODIUM METHYLATE
FORMULA: CH3NaO
MOLECULAR WEIGHT: 54.02 G/MOL
COMPONENT CLASSIFICATION CONCENTRATION
METHANOL:
CAS-NO.: FLAM. LIQ. 2; >=70 - <90%
67-56-1 ACUTE TOX. 3;
STOT SE 1; H225,
H301, H331, H311,
H370
EC-NO.:
200-659-6
INDEX-NO.:
603-001-00-X
REGISTRATION NUMBER:
01-2119433307-44-XXXX
SODIUM METHYLATE:
CAS-NO.: FLAM. SOL. 1; SELF-HEAT. 1; >=20 - <30%
124-41-4 MET. CORR. 1; ACUTE TOX. 4;
SKIN CORR. 1A; EYE DAM.
1; H228, H251, H290,
H302, H314, H318
EC-NO.:
204-699-5
INDEX-NO.:
603-040-00-2
REGISTRATION NUMBER:
01-2119519241-51-XXXX
FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION,
SEE SECTION 16.
| SECTION 4: FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
CONSULT A PHYSICIAN. SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN
ATTENDANCE.MOVE OUT OF DANGEROUS AREA.
IF INHALED:
IF BREATHED IN, MOVE PERSON INTO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. CONSULT A PHYSICIAN.
IN CASE OF SKIN CONTACT:
TAKE OFF CONTAMINATED CLOTHING AND SHOES IMMEDIATELY. WASH OFF WITH
SOAP AND PLENTY OF WATER. TAKE VICTIM IMMEDIATELY TO HOSPITAL. CONSULT
A PHYSICIAN.
IN CASE OF EYE CONTACT:
RINSE THOROUGHLY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND CONSULT
A PHYSICIAN.CONTINUE RINSING EYES DURING TRANSPORT TO HOSPITAL.
IF SWALLOWED:
DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. RINSE MOUTH WITH WATER. CONSULT A PHYSICIAN.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
THE MOST IMPORTANT KNOWN SYMPTOMS AND EFFECTS ARE DESCRIBED IN THE
LABELLING (SEE SECTION 2.2) AND/OR IN SECTION 11
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NO DATA AVAILABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA: DRY POWDER DRY SAND
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER JET.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CARBON OXIDES, SODIUM OXIDES
5.3 ADVICE FOR FIREFIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS FOR FIREFIGHTING IF NECESSARY.
5.4 FURTHER INFORMATION: NO DATA AVAILABLE
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR RESPIRATORY PROTECTION. AVOID BREATHING VAPOURS, MIST OR GAS. ENSURE
ADEQUATE VENTILATION. REMOVE ALL SOURCES OF IGNITION. EVACUATE PERSONNEL
TO SAFE AREAS. BEWARE OF VAPOURS ACCUMULATING TO FORM EXPLOSIVE
CONCENTRATIONS. VAPOURS CAN ACCUMULATE IN LOW AREAS.
FOR PERSONAL PROTECTION SEE SECTION 8.
6.2 ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT LET PRODUCT
ENTER DRAINS.
6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILLAGE, AND THEN COLLECT WITH NON-COMBUSTIBLE ABSORBENT
MATERIAL, (E.G. SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND
PLACE IN CONTAINER FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL
REGULATIONS (SEE SECTION 13). DO NOT FLUSH WITH WATER.
6.4 REFERENCE TO OTHER SECTIONS: FOR DISPOSAL SEE SECTION 13.
| SECTION 7: HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH SKIN AND EYES. AVOID INHALATION OF VAPOUR OR MIST.
USE EXPLOSION-PROOF EQUIPMENT.KEEP AWAY FROM SOURCES OF IGNITION - NO
SMOKING.TAKE MEASURES TO PREVENT THE BUILD UP OF ELECTROSTATIC CHARGE.
FOR PRECAUTIONS SEE SECTION 2.2.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
CONTAINERS WHICH ARE OPENED MUST BE CAREFULLY RESEALED AND KEPT
UPRIGHT TO PREVENT LEAKAGE. NEVER ALLOW PRODUCT TO GET IN CONTACT
WITH WATER DURING STORAGE.
STORAGE CLASS (TRGS 510):
4.2: PYROPHORIC AND SELF-HEATING HAZARDOUS MATERIALS
7.3 SPECIFIC END USE(S):
APART FROM THE USES MENTIONED IN SECTION 1.2 NO OTHER SPECIFIC USES
ARE STIPULATED:
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENT CAS-NO. VALUE CONTROL BASIS
PARAMETERS
METHANOL 67-56-1 TWA 200 PPM USA. ACGIH
THRESHOLD
LIMIT
VALUES (TLV)
REMARKS HEADACHE
NAUSEA
DIZZINESS
EYE DAMAGE
SUBSTANCES
FOR WHICH
THERE IS A
BIOLOGICAL
EXPOSURE INDEX
OR INDICES
(SEE BEI(R*)
SECTION)
DANGER OF
CUTANEOUS
ABSORPTION
STEL 250 PPM USA. ACGIH THRESHOLD
LIMIT VALUES (TLV)
HEADACHE
NAUSEA
DIZZINESS
EYE DAMAGE
SUBSTANCES
FOR WHICH
THERE IS A
BIOLOGICAL
EXPOSURE INDEX
OR INDICES
(SEE BEI(R*)
SECTION)
DANGER OF
CUTANEOUS
ABSORPTION
TWA 200 PPM USA. NIOSH RECOMMENDED
260 MG/M3 EXPOSURE LIMITS
POTENTIAL
FOR DERMAL
ABSORPTION
ST 250 PPM USA. NIOSH RECOMMENDED
325 MG/M3 EXPOSURE LIMITS
POTENTIAL
FOR DERMAL
ABSORPTION
TWA 200 PPM USA. OCCUPATIONAL
260 MG/M3 EXPOSURE LIMITS (OSHA)
- TABLE Z-1
LIMITS FOR AIR
CONTAMINANTS
THE VALUE IN
MG/M3 IS
APPROXIMATE.
C 1,000 PPM CALIFORNIA PERMISSIBLE
EXPOSURE LIMITS FOR
CHEMICAL CONTAMINANTS
(TITLE 8, ARTICLE 107)
SKIN
PEL 200 PPM CALIFORNIA PERMISSIBLE
260 MG/M3 EXPOSURE LIMITS FOR
CHEMICAL ONTAMINANTS
(TITLE 8, ARTICLE 107)
SKIN
STEL 250 PPM CALIFORNIA PERMISSIBLE
325 MG/M3 EXPOSURE LIMITS FOR
CHEMICAL ONTAMINANTS
(TITLE 8, ARTICLE 107)
SKIN
BIOLOGICAL OCCUPATIONAL EXPOSURE LIMITS:
COMPONENT CAS-NO. PARAMETERS VALUE BIOLOGICAL BASIS
SPECIMEN
METHANOL 67-56-1 METHANOL 15 MG/L URINE ACGIH -
BIOLOGICAL
EXPOSURE
INDICES (BEI)
REMARKS END OF SHIFT
(AS SOON
AS POSSIBLE
AFTER
EXPOSURE
CEASES)
8.2 EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. WASH HANDS BEFORE BREAKS
AND IMMEDIATELY AFTER HANDLING THE PRODUCT.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
TIGHTLY FITTING SAFETY GOGGLES. FACESHIELD (8-INCH MINIMUM).
USE EQUIPMENT FOR EYE PROTECTION TESTED AND APPROVED UNDER
APPROPRIATE GOVERNMENT STANDARDS SUCH AS NIOSH (US) OR EN 166(EU).
SKIN PROTECTION:
HANDLE WITH GLOVES. GLOVES MUST BE INSPECTED PRIOR TO USE. USE
PROPER GLOVE REMOVAL TECHNIQUE (WITHOUT TOUCHING GLOVE'S OUTER
SURFACE) TO AVOID SKIN CONTACT WITH THIS PRODUCT. DISPOSE OF
CONTAMINATED GLOVES AFTER USE IN ACCORDANCE WITH APPLICABLE
LAWS AND GOOD LABORATORY PRACTICES. WASH AND DRY HANDS.
FULL CONTACT:
MATERIAL: BUTYL-RUBBER
MINIMUM LAYER THICKNESS: 0.3 MM
BREAK THROUGH TIME: 480 MIN
MATERIAL TESTED: BUTOJECT(R*) (KCL 897 / ALDRICH Z677647, SIZE M)
SPLASH CONTACT:
MATERIAL: NITRILE RUBBER
MINIMUM LAYER THICKNESS: 0.4 MM
BREAK THROUGH TIME: 30 MIN
MATERIAL TESTED:CAMATRIL(R*) (KCL 730 / ALDRICH Z677442, SIZE M)
DATA SOURCE: KCL GMBH, D-36124 EICHENZELL
PHONE: +49 (0)6659 87300
E-MAIL: SALES@KCL.DE, TEST
METHOD: EN374
IF USED IN SOLUTION, OR MIXED WITH OTHER SUBSTANCES, AND UNDER
CONDITIONS WHICH DIFFER FROM EN 374, CONTACT THE SUPPLIER OF THE
CE APPROVED GLOVES. THIS RECOMMENDATION IS ADVISORY ONLY AND MUST
BE EVALUATED BY AN INDUSTRIAL HYGIENIST AND SAFETY OFFICER FAMILIAR
WITH THE SPECIFIC SITUATION OF ANTICIPATED USE BY OUR CUSTOMERS.
IT SHOULD NOT BE CONSTRUED AS OFFERING AN APPROVAL FOR ANY SPECIFIC
USE SCENARIO.
BODY PROTECTION:
COMPLETE SUIT PROTECTING AGAINST CHEMICALS, FLAME RETARDANT ANTISTATIC
PROTECTIVE CLOTHING., THE TYPE OF PROTECTIVE EQUIPMENT MUST BE SELECTED
ACCORDING TO THE CONCENTRATION AND AMOUNT OF THE DANGEROUS SUBSTANCE AT
THE SPECIFIC WORKPLACE.
RESPIRATORY PROTECTION:
WHERE RISK ASSESSMENT SHOWS AIR-PURIFYING RESPIRATORS ARE APPROPRIATE
USE A FULLFACE RESPIRATOR WITH MULTI-PURPOSE COMBINATION (US) OR TYPE
ABEK (EN 14387) RESPIRATOR CARTRIDGES AS A BACKUP TO ENGINEERING
CONTROLS. IF THE RESPIRATOR IS THE SOLE MEANS OF PROTECTION, USE A
FULL-FACE SUPPLIED AIR RESPIRATOR. USE RESPIRATORS AND COMPONENTS
TESTED AND APPROVED UNDER APPROPRIATE GOVERNMENT STANDARDS SUCH AS
NIOSH (US) OR CEN (EU).
CONTROL OF ENVIRONMENTAL EXPOSURE:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT LET PRODUCT
ENTER DRAINS.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
A) APPEARANCE FORM: LIQUID
B) ODOUR: NO DATA AVAILABLE
C) ODOUR THRESHOLD: NO DATA AVAILABLE
D) PH: NO DATA AVAILABLE
E) MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
F) INITIAL BOILING POINT AND BOILING RANGE: 87 DEG. C 189 DEG. F
G) FLASH POINT: 11 DEG. C (52 DEG. F) - CLOSED CUP - SOLVENT
H) EVAPORATION RATE: NO DATA AVAILABLE
I) FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
J) UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NO DATA AVAILABLE
K) VAPOUR PRESSURE: 128 HPA AT 25 DEG. C (77 DEG. F)
L) VAPOUR DENSITY: NO DATA AVAILABLE
M) RELATIVE DENSITY: 0.945 G/ML AT 25 DEG. C (77 DEG. F)
N) WATER SOLUBILITY: NO DATA AVAILABLE
O) PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
P) AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
Q) DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
R) VISCOSITY: NO DATA AVAILABLE
S) EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
T) OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2 OTHER SAFETY INFORMATION: NO DATA AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1 REACTIVITY: NO DATA AVAILABLE
10.2 CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
VAPOURS MAY FORM EXPLOSIVE MIXTURE WITH AIR.REACTS VIOLENTLY WITH WATER.
10.4 CONDITIONS TO AVOID:
HEAT, FLAMES AND SPARKS. EXPOSURE TO MOISTURE
10.5 INCOMPATIBLE MATERIALS: NO DATA AVAILABLE
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS DECOMPOSITION PRODUCTS FORMED UNDER FIRE CONDITIONS.:
CARBON OXIDES, SODIUM OXIDES
OTHER DECOMPOSITION PRODUCTS: NO DATA AVAILABLE
IN THE EVENT OF FIRE: SEE SECTION 5
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NO DATA AVAILABLE
INHALATION: NO DATA AVAILABLE
DERMAL: NO DATA AVAILABLE
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/EYE IRRITATION: NO DATA AVAILABLE
RESPIRATORY OR SKIN SENSITISATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL
TO 0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN
BY IARC.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL
TO 0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL
TO 0.1% IS ON OSHA'S LIST OF REGULATED CARCINOGENS.
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
ADDITIONAL INFORMATION:
RTECS: NOT AVAILABLE
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL
PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
STOMACH - IRREGULARITIES - BASED ON HUMAN EVIDENCE
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY: NO DATA AVAILABLE
12.2 PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
12.3 BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
12.4 MOBILITY IN SOIL: NO DATA AVAILABLE
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT/VPVB ASSESSMENT NOT AVAILABLE AS CHEMICAL SAFETY ASSESSMENT NOT
REQUIRED/NOT CONDUCTED
12.6 OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
PRODUCT:
BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER
BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY FLAMMABLE.
OFFER SURPLUS AND NON-RECYCLABLE SOLUTIONS TO A LICENSED DISPOSAL COMPANY.
CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL SERVICE TO DISPOSE OF THIS
MATERIAL.
CONTAMINATED PACKAGING: DISPOSE OF AS UNUSED PRODUCT.
| SECTION 14: TRANSPORT INFORMATION | |
DOT (US):
UN NUMBER: 1289
CLASS: 3 (8)
PACKING GROUP: II
PROPER SHIPPING NAME: SODIUM METHYLATE SOLUTIONS
REPORTABLE QUANTITY (RQ): 4000 LBS
POISON INHALATION HAZARD: NO
IMDG:
UN NUMBER: 1289
CLASS: 3 (8)
PACKING GROUP: II
EMS-NO: F-E, S-C
PROPER SHIPPING NAME: SODIUM METHYLATE SOLUTION
IATA:
UN NUMBER: 1289
CLASS: 3 (8)
PACKING GROUP: II
PROPER SHIPPING NAME: SODIUM METHYLATE SOLUTION
| SECTION 15: REGULATORY INFORMATION | |
SARA 302 COMPONENTS:
NO CHEMICALS IN THIS MATERIAL ARE SUBJECT TO THE REPORTING REQUIREMENTS
OF SARA TITLE III, SECTION 302.
SARA 313 COMPONENTS:
THE FOLLOWING COMPONENTS ARE SUBJECT TO REPORTING LEVELS ESTABLISHED BY
SARA TITLE III, SECTION 313:
CAS-NO. REVISION DATE
METHANOL 67-56-1 2007-07-01
SARA 311/312 HAZARDS:
FIRE HAZARD, ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
MASSACHUSETTS RIGHT TO KNOW COMPONENTS:
NO COMPONENTS ARE SUBJECT TO THE MASSACHUSETTS RIGHT TO KNOW ACT.
PENNSYLVANIA RIGHT TO KNOW COMPONENTS:
CAS-NO. REVISION DATE
METHANOL 67-56-1 2007-07-01
SODIUM METHYLATE 124-41-4 1993-02-16
| SECTION 16: OTHER INFORMATION | |
FURTHER INFORMATION:
COPYRIGHT 2020 SIGMA-ALDRICH CO. LLC.
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT
TO BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. THE INFORMATION
IN THIS DOCUMENT IS BASED ON THE PRESENT STATE OF OUR KNOWLEDGE AND IS
APPLICABLE TO THE PRODUCT WITH REGARD TO APPROPRIATE SAFETY PRECAUTIONS.
IT DOES NOT REPRESENT ANY GUARANTEE OF THE PROPERTIES OF THE PRODUCT.
SIGMA-ALDRICH CORPORATION AND ITS AFFILIATES SHALL NOT BE HELD LIABLE
FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WITH THE ABOVE
PRODUCT. SEE WWW.SIGMA-ALDRICH.COM AND/OR THE REVERSE SIDE OF INVOICE
OR PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
THE BRANDING ON THE HEADER AND/OR FOOTER OF THIS DOCUMENT MAY TEMPORARILY
NOT VISUALLY MATCH THE PRODUCT PURCHASED AS WE TRANSITION OUR BRANDING.
HOWEVER, ALL OF THE INFORMATION IN THE DOCUMENT REGARDING THE PRODUCT
REMAINS UNCHANGED AND MATCHES THE PRODUCT ORDERED. FOR FURTHER INFORMATION
PLEASE CONTACT MLSBRANDING@SIAL.COM.
VERSION: 6.3
REVISION DATE: 01/15/2020
PRINT DATE: 08/29/2020
SIGMA-ALDRICH - 156256
THE LIFE SCIENCE BUSINESS OF MERCK KGAA, DARMSTADT, GERMANY OPERATES
AS MILLIPORESIGMA IN THE US AND CANADA
MILLIPORE SIGMA