| Common Name: | CELLULOSE, 435236 |
| Manufacturer: | SIGMA-ALDRICH |
| SDS Revision Date: | 3/5/2018 |
| SDS Format: | No Format Specified |
| Item Number(s): | 45ZZ43 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SIGMA-ALDRICH
SIGMA-ALDRICH.COM
SAFETY DATA SHEET
VERSION: 4.6
REVISION DATE: 03/05/2018
PRINT DATE: 06/17/2018
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
1.1 PRODUCT IDENTIFIERS:
PRODUCT NAME: CELLULOSE
PRODUCT NUMBER: 435236
BRAND: ALDRICH
CAS-NO.: 9004-34-6
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
IDENTIFIED USES: LABORATORY CHEMICALS, SYNTHESIS OF SUBSTANCES
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY:
SIGMA-ALDRICH
3050 SPRUCE STREET
SAINT LOUIS, MO 63103
USA
TELEPHONE: +1 800-325-5832
FAX: +1 800-325-5052
1.4 EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE #: +1-703-527-3887 (CHEMTREC)
| 2. HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910 (OSHA HCS):
COMBUSTIBLE DUST,
FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.
2.2 GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
PICTOGRAM: NONE
SIGNAL WORD: WARNING
HAZARD STATEMENT(S): MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR.
PRECAUTIONARY STATEMENT(S): NONE
2.3 HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) OR NOT COVERED BY GHS:
COMBUSTIBLE DUST
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1 SUBSTANCES:
SYNONYMS:
COTTON LINTERS
CELLULOSE POWDER
CAS-NO.: 9004-34-6
EC-NO.: 232-674-9
HAZARDOUS COMPONENTS:
COMPONENT CLASSIFICATION CONCENTRATION
CELLULOSE 90 - 100 %
FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.
| 4. FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
CONSULT A PHYSICIAN. SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN
ATTENDANCE.
IF INHALED:
IF BREATHED IN, MOVE PERSON INTO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. CONSULT A PHYSICIAN.
IN CASE OF SKIN CONTACT:
WASH OFF WITH SOAP AND PLENTY OF WATER. CONSULT A PHYSICIAN.
IN CASE OF EYE CONTACT: FLUSH EYES WITH WATER AS A PRECAUTION.
IF SWALLOWED:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. RINSE MOUTH WITH
WATER. CONSULT A PHYSICIAN.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
THE MOST IMPORTANT KNOWN SYMPTOMS AND EFFECTS ARE DESCRIBED IN THE
LABELING (SEE SECTION 2.2) AND/OR IN SECTION 11
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO DATA AVAILABLE
| 5. FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE WATER SPRAY, ALCOHOL-RESISTANT FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NO DATA AVAILABLE
5.3 ADVICE FOR FIREFIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS FOR FIREFIGHTING IF NECESSARY.
5.4 FURTHER INFORMATION: NO DATA AVAILABLE
| 6. ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT. AVOID DUST FORMATION. AVOID BREATHING
VAPORS, MIST OR GAS. AVOID BREATHING DUST.
FOR PERSONAL PROTECTION SEE SECTION 8.
6.2 ENVIRONMENTAL PRECAUTIONS: DO NOT LET PRODUCT ENTER DRAINS.
6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
PICK UP AND ARRANGE DISPOSAL WITHOUT CREATING DUST. SWEEP UP AND SHOVEL.
KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
6.4 REFERENCE TO OTHER SECTIONS: FOR DISPOSAL SEE SECTION 13.
| 7. HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
FURTHER PROCESSING OF SOLID MATERIALS MAY RESULT IN THE FORMATION OF
COMBUSTIBLE DUSTS. THE POTENTIAL FOR COMBUSTIBLE DUST FORMATION SHOULD BE
TAKEN INTO CONSIDERATION BEFORE ADDITIONAL PROCESSING OCCURS.
PROVIDE APPROPRIATE EXHAUST VENTILATION AT PLACES WHERE DUST IS FORMED.
FOR PRECAUTIONS SEE SECTION 2.2.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
KEEP IN A DRY PLACE.
STORAGE CLASS (TRGS 510): 13: NON COMBUSTIBLE SOLIDS
7.3 SPECIFIC END USE(S):
APART FROM THE USES MENTIONED IN SECTION 1.2 NO OTHER SPECIFIC USES ARE
STIPULATED
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENT CAS-NO. VALUE CONTROL BASIS
PARAMETERS
CELLULOSE 9004-34-6 TWA 10 MG/M3 USA. ACGIH THRESHOLD
LIMIT VALUES (TLV)
REMARKS UPPER RESPIRATORY
TRACT IRRITATION
NOT APPLICABLE
TWA 15 MG/M3 USA. OSHA - TABLE Z-1 LIMITS FOR
AIR CONTAMINANTS - 1910.1000
TWA 5 MG/M3 USA. OSHA - TABLE Z-1 LIMITS FOR
AIR CONTAMINANTS - 1910.1000
TWA 5 MG/M3 USA. NIOSH RECOMMENDED EXPOSURE
LIMITS
TWA 10 MG/M3 USA. NIOSH RECOMMENDED EXPOSURE
LIMITS
TWA 15 MG/M3 USA. OCCUPATIONAL EXPOSURE LIMITS
(OSHA) - TABLE Z-1 LIMITS FOR AIR
CONTAMINANTS
TWA 5 MG/M3 USA. OCCUPATIONAL EXPOSURE LIMITS
(OSHA) - TABLE Z-1 LIMITS FOR AIR
CONTAMINANTS
PEL 10 MG/M3 CALIFORNIA PERMISSIBLE EXPOSURE
LIMITS FOR CHEMICAL CONTAMINANTS
(TITLE 8, ARTICLE 107)
PEL 5 MG/M3 CALIFORNIA PERMISSIBLE EXPOSURE
LIMITS FOR CHEMICAL CONTAMINANTS
(TITLE 8, ARTICLE 107)
8.2 EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE. WASH
HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
USE EQUIPMENT FOR EYE PROTECTION TESTED AND APPROVED UNDER APPROPRIATE
GOVERNMENT STANDARDS SUCH AS NIOSH (US) OR EN 166(EU).
SKIN PROTECTION:
HANDLE WITH GLOVES. GLOVES MUST BE INSPECTED PRIOR TO USE. USE PROPER GLOVE
REMOVAL TECHNIQUE (WITHOUT TOUCHING GLOVE'S OUTER SURFACE) TO AVOID SKIN
CONTACT WITH THIS PRODUCT. DISPOSE OF CONTAMINATED GLOVES AFTER USE IN
ACCORDANCE WITH APPLICABLE LAWS AND GOOD LABORATORY PRACTICES. WASH AND DRY
HANDS.
FULL CONTACT:
MATERIAL: NITRILE RUBBER
MINIMUM LAYER THICKNESS: 0.11 MM
BREAK THROUGH TIME: 480 MIN
MATERIAL TESTED: DERMATRIL(R*) (KCL 740 / ALDRICH Z677272, SIZE M)
SPLASH CONTACT:
MATERIAL: NITRILE RUBBER
MINIMUM LAYER THICKNESS: 0.11 MM
BREAK THROUGH TIME: 480 MIN
MATERIAL TESTED: DERMATRIL(R*) (KCL 740 / ALDRICH Z677272, SIZE M)
DATA SOURCE:
KCL GMBH
D-36124 EICHENZELL
PHONE: +49 (0)6659 87300
E-MAIL: SALES@KCL.DE
TEST METHOD: EN374
IF USED IN SOLUTION, OR MIXED WITH OTHER SUBSTANCES, AND UNDER CONDITIONS
WHICH DIFFER FROM EN 374, CONTACT THE SUPPLIER OF THE CE APPROVED GLOVES.
THIS RECOMMENDATION IS ADVISORY ONLY AND MUST BE EVALUATED BY AN INDUSTRIAL
HYGIENIST AND SAFETY OFFICER FAMILIAR WITH THE SPECIFIC SITUATION OF
ANTICIPATED USE BY OUR CUSTOMERS. IT SHOULD NOT BE CONSTRUED AS OFFERING AN
APPROVAL FOR ANY SPECIFIC USE SCENARIO.
BODY PROTECTION:
CHOOSE BODY PROTECTION IN RELATION TO ITS TYPE, TO THE CONCENTRATION AND
AMOUNT OF DANGEROUS SUBSTANCES, AND TO THE SPECIFIC WORK-PLACE., THE TYPE
OF PROTECTIVE EQUIPMENT MUST BE SELECTED ACCORDING TO THE CONCENTRATION AND
AMOUNT OF THE DANGEROUS SUBSTANCE AT THE SPECIFIC WORKPLACE.
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION IS NOT REQUIRED. WHERE PROTECTION FROM NUISANCE
LEVELS OF DUSTS ARE DESIRED, USE TYPE N95 (US) OR TYPE P1 (EN 143) DUST
MASKS. USE RESPIRATORS AND COMPONENTS TESTED AND APPROVED UNDER APPROPRIATE
GOVERNMENT STANDARDS SUCH AS NIOSH (US) OR CEN (EU).
CONTROL OF ENVIRONMENTAL EXPOSURE: DO NOT LET PRODUCT ENTER DRAINS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
A) APPEARANCE:
FORM: CRYSTALLINE, POWDER
COLOR: WHITE
B) ODOR: NO DATA AVAILABLE
C) ODOR THRESHOLD: NO DATA AVAILABLE
D) PH: NO DATA AVAILABLE
E) MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
F) INITIAL BOILING POINT AND BOILING RANGE: NO DATA AVAILABLE
G) FLASH POINT: NO DATA AVAILABLE
H) EVAPORATION RATE: NO DATA AVAILABLE
I) FLAMMABILITY (SOLID, GAS):
MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR.
J) UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NO DATA AVAILABLE
K) VAPOR PRESSURE: NO DATA AVAILABLE
L) VAPOR DENSITY: NO DATA AVAILABLE
M) RELATIVE DENSITY: 0.600 G/CM3
N) WATER SOLUBILITY: NO DATA AVAILABLE
O) PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
P) AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
Q) DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
R) VISCOSITY: NO DATA AVAILABLE
S) EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
T) OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2 OTHER SAFETY INFORMATION: NO DATA AVAILABLE
| 10. STABILITY AND REACTIVITY | |
10.1 REACTIVITY: NO DATA AVAILABLE
10.2 CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS: NO DATA AVAILABLE
10.4 CONDITIONS TO AVOID: NO DATA AVAILABLE
10.5 INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS DECOMPOSITION PRODUCTS FORMED UNDER FIRE CONDITIONS. - NATURE OF
DECOMPOSITION PRODUCTS NOT KNOWN.
OTHER DECOMPOSITION PRODUCTS: NO DATA AVAILABLE
IN THE EVENT OF FIRE: SEE SECTION 5
| 11. TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD50 ORAL - RAT: >5,000 MG/KG
INHALATION: NO DATA AVAILABLE
LD50 DERMAL - RABBIT: > 2,000 MG/KG
NO DATA AVAILABLE
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/EYE IRRITATION: NO DATA AVAILABLE
RESPIRATORY OR SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS ON OSHA'S LIST OF REGULATED CARCINOGENS.
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
ADDITIONAL INFORMATION:
RTECS: FJ5691460
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL
PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
| 12. ECOLOGICAL INFORMATION | |
12.1 TOXICITY: NO DATA AVAILABLE
12.2 PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
12.3 BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
12.4 MOBILITY IN SOIL: NO DATA AVAILABLE
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT/VPVB ASSESSMENT NOT AVAILABLE AS CHEMICAL SAFETY ASSESSMENT NOT
REQUIRED/NOT CONDUCTED
12.6 OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
PRODUCT:
OFFER SURPLUS AND NON-RECYCLABLE SOLUTIONS TO A LICENSED DISPOSAL COMPANY.
CONTAMINATED PACKAGING: DISPOSE OF AS UNUSED PRODUCT.
| 14. TRANSPORT INFORMATION | |
DOT (US): NOT DANGEROUS GOODS
IMDG: NOT DANGEROUS GOODS
IATA: NOT DANGEROUS GOODS
| 15. REGULATORY INFORMATION | |
SARA 302 COMPONENTS:
NO CHEMICALS IN THIS MATERIAL ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SARA TITLE III, SECTION 302.
SARA 313 COMPONENTS:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS ESTABLISHED
BY SARA TITLE III, SECTION 313.
SARA 311/312 HAZARDS: NO SARA HAZARDS
MASSACHUSETTS RIGHT TO KNOW COMPONENTS:
CAS-NO. REVISION DATE
CELLULOSE 9004-34-6 1994-04-01
PENNSYLVANIA RIGHT TO KNOW COMPONENTS:
CAS-NO. REVISION DATE
CELLULOSE 9004-34-6 1994-04-01
CAS-NO. REVISION DATE
CELLULOSE 9004-34-6 1994-04-01
NEW JERSEY RIGHT TO KNOW COMPONENTS:
CAS-NO. REVISION DATE
CELLULOSE 9004-34-6 1994-04-01
CALIFORNIA PROP. 65 COMPONENTS:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO STATE OF CALIFORNIA TO
CAUSE CANCER, BIRTH DEFECTS, OR ANY OTHER REPRODUCTIVE HARM.
| 16. OTHER INFORMATION | |
FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3.
MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR.
HMIS RATING:
HEALTH HAZARD 0
CHRONIC HEALTH HAZARD
FLAMMABILITY 0
PHYSICAL HAZARD 0
NFPA RATING:
HEALTH HAZARD 0
FIRE HAZARD 0
REACTIVITY HAZARD 0
FURTHER INFORMATION:
COPYRIGHT 2016 SIGMA-ALDRICH CO. LLC. LICENSE GRANTED TO MAKE UNLIMITED
PAPER COPIES FOR INTERNAL USE ONLY. THE ABOVE INFORMATION IS BELIEVED TO
BE CORRECT BUT DOES NOT PURPORT TO BE ALL INCLUSIVE AND SHALL BE USED ONLY
AS A GUIDE. THE INFORMATION IN THIS DOCUMENT IS BASED ON THE PRESENT STATE
OF OUR KNOWLEDGE AND IS APPLICABLE TO THE PRODUCT WITH REGARD TO
APPROPRIATE SAFETY PRECAUTIONS. IT DOES NOT REPRESENT ANY GUARANTEE OF THE
PROPERTIES OF THE PRODUCT. SIGMA-ALDRICH CORPORATION AND ITS AFFILIATES
SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM
CONTACT WITH THE ABOVE PRODUCT. SEE WWW.SIGMA-ALDRICH.COM AND/OR THE
REVERSE SIDE OF INVOICE OR PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS
OF SALE.
PREPARATION INFORMATION:
SIGMA-ALDRICH CORPORATION
PRODUCT SAFETY - AMERICAS REGION
1-800-521-8956
VERSION: 4.6
REVISION DATE: 03/05/2018
PRINT DATE: 06/17/2018
ALDRICH - 435236