| Common Name: | STREPTOMYCIN SULFATE SALT, S9137 |
| Manufacturer: | SIGMA-ALDRICH |
| SDS Revision Date: | 10/26/2017 |
| SDS Format: | No Format Specified |
| Item Number(s): | 45ZZ55 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SIGMA-ALDRICH
SIGMA-ALDRICH.COM
SAFETY DATA SHEET
VERSION: 4.10
REVISION DATE: 10/26/2017
PRINT DATE: 06/10/2018
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
1.1 PRODUCT IDENTIFIERS:
PRODUCT NAME: STREPTOMYCIN SULFATE SALT
PRODUCT NUMBER: S9137
BRAND: SIGMA
CAS-NO.: 3810-74-0
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
IDENTIFIED USES: LABORATORY CHEMICALS, SYNTHESIS OF SUBSTANCES
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY:
SIGMA-ALDRICH
3050 SPRUCE STREET
SAINT LOUIS, MO 63103
USA
TELEPHONE: +1 800-325-5832
FAX: +1 800-325-5052
1.4 EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE #: +1-703-527-3887 (CHEMTREC)
| 2. HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910 (OSHA HCS):
ACUTE TOXICITY, ORAL (CATEGORY 4), H302
REPRODUCTIVE TOXICITY (CATEGORY 2), H361
FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.
2.2 GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
PICTOGRAM:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENT(S):
H302: HARMFUL IF SWALLOWED.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
PRECAUTIONARY STATEMENT(S):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P264: WASH SKIN THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P301 + P312 IF SWALLOWED: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
P308 + P313 IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ ATTENTION.
P330: RINSE MOUTH.
P405: STORE LOCKED UP.
P501: DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
2.3 HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) OR NOT COVERED BY GHS: NONE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1 SUBSTANCES:
FORMULA: C21H39N7O12 . 1.5H2O4S
MOLECULAR WEIGHT: 728.69 G/MOL
CAS-NO.: 3810-74-0
EC-NO.: 223-286-0
HAZARDOUS COMPONENTS:
COMPONENT CLASSIFICATION CONCENTRATION
STREPTOMYCIN SULPHATE ACUTE TOX. 4; REPR. 2; 90 - 100%
H302, H361
FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.
| 4. FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
CONSULT A PHYSICIAN. SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN
ATTENDANCE. MOVE OUT OF DANGEROUS AREA.
IF INHALED:
IF BREATHED IN, MOVE PERSON INTO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. CONSULT A PHYSICIAN.
IN CASE OF SKIN CONTACT:
WASH OFF WITH SOAP AND PLENTY OF WATER. CONSULT A PHYSICIAN.
IN CASE OF EYE CONTACT: FLUSH EYES WITH WATER AS A PRECAUTION.
IF SWALLOWED:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. RINSE MOUTH WITH
WATER. CONSULT A PHYSICIAN.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
THE MOST IMPORTANT KNOWN SYMPTOMS AND EFFECTS ARE DESCRIBED IN THE
LABELING (SEE SECTION 2.2) AND/OR IN SECTION 11
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO DATA AVAILABLE
| 5. FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE WATER SPRAY, ALCOHOL-RESISTANT FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NO DATA AVAILABLE
5.3 ADVICE FOR FIREFIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS FOR FIREFIGHTING IF NECESSARY.
5.4 FURTHER INFORMATION: NO DATA AVAILABLE
| 6. ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT. AVOID DUST FORMATION. AVOID BREATHING
VAPORS, MIST OR GAS. ENSURE ADEQUATE VENTILATION. EVACUATE PERSONNEL TO
SAFE AREAS. AVOID BREATHING DUST.
FOR PERSONAL PROTECTION SEE SECTION 8.
6.2 ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT LET PRODUCT
ENTER DRAINS.
6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
PICK UP AND ARRANGE DISPOSAL WITHOUT CREATING DUST. SWEEP UP AND SHOVEL.
KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
6.4 REFERENCE TO OTHER SECTIONS: FOR DISPOSAL SEE SECTION 13.
| 7. HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH SKIN AND EYES. AVOID FORMATION OF DUST AND AEROSOLS.
PROVIDE APPROPRIATE EXHAUST VENTILATION AT PLACES WHERE DUST IS FORMED.
FOR PRECAUTIONS SEE SECTION 2.2.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
RECOMMENDED STORAGE TEMPERATURE 2 - 8 DEG. C
KEEP IN A DRY PLACE.
STORAGE CLASS (TRGS 510):
13: NON COMBUSTIBLE SOLIDS
7.3 SPECIFIC END USE(S):
APART FROM THE USES MENTIONED IN SECTION 1.2 NO OTHER SPECIFIC USES ARE
STIPULATED
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
CONTAINS NO SUBSTANCES WITH OCCUPATIONAL EXPOSURE LIMIT VALUES.
8.2 EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE. WASH
HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
SAFETY GLASSES WITH SIDE-SHIELDS CONFORMING TO EN166 USE EQUIPMENT FOR EYE
PROTECTION TESTED AND APPROVED UNDER APPROPRIATE GOVERNMENT STANDARDS SUCH
AS NIOSH (US) OR EN 166(EU).
SKIN PROTECTION:
HANDLE WITH GLOVES. GLOVES MUST BE INSPECTED PRIOR TO USE. USE PROPER GLOVE
REMOVAL TECHNIQUE (WITHOUT TOUCHING GLOVE'S OUTER SURFACE) TO AVOID SKIN
CONTACT WITH THIS PRODUCT. DISPOSE OF CONTAMINATED GLOVES AFTER USE IN
ACCORDANCE WITH APPLICABLE LAWS AND GOOD LABORATORY PRACTICES. WASH AND DRY
HANDS.
FULL CONTACT:
MATERIAL: NITRILE RUBBER
MINIMUM LAYER THICKNESS: 0.11 MM
BREAK THROUGH TIME: 480 MIN
MATERIAL TESTED: DERMATRIL(R*) (KCL 740 / ALDRICH Z677272, SIZE M)
SPLASH CONTACT:
MATERIAL: NITRILE RUBBER
MINIMUM LAYER THICKNESS: 0.11 MM
BREAK THROUGH TIME: 480 MIN
MATERIAL TESTED: DERMATRIL(R*) (KCL 740 / ALDRICH Z677272, SIZE M)
DATA SOURCE:
KCL GMBH
D-36124 EICHENZELL
PHONE: +49 (0)6659 87300
E-MAIL SALES@KCL.DE
TEST METHOD: EN374
IF USED IN SOLUTION, OR MIXED WITH OTHER SUBSTANCES, AND UNDER CONDITIONS
WHICH DIFFER FROM EN 374, CONTACT THE SUPPLIER OF THE CE APPROVED GLOVES.
THIS RECOMMENDATION IS ADVISORY ONLY AND MUST BE EVALUATED BY AN INDUSTRIAL
HYGIENIST AND SAFETY OFFICER FAMILIAR WITH THE SPECIFIC SITUATION OF
ANTICIPATED USE BY OUR CUSTOMERS. IT SHOULD NOT BE CONSTRUED AS OFFERING AN
APPROVAL FOR ANY SPECIFIC USE SCENARIO.
BODY PROTECTION:
COMPLETE SUIT PROTECTING AGAINST CHEMICALS, THE TYPE OF PROTECTIVE
EQUIPMENT MUST BE SELECTED ACCORDING TO THE CONCENTRATION AND AMOUNT OF THE
DANGEROUS SUBSTANCE AT THE SPECIFIC WORKPLACE.
RESPIRATORY PROTECTION:
WHERE RISK ASSESSMENT SHOWS AIR-PURIFYING RESPIRATORS ARE APPROPRIATE USE A
FULL-FACE PARTICLE RESPIRATOR TYPE N100 (US) OR TYPE P3 (EN 143) RESPIRATOR
CARTRIDGES AS A BACKUP TO ENGINEERING CONTROLS. IF THE RESPIRATOR IS THE
SOLE MEANS OF PROTECTION, USE A FULL-FACE SUPPLIED AIR RESPIRATOR. USE
RESPIRATORS AND COMPONENTS TESTED AND APPROVED UNDER APPROPRIATE GOVERNMENT
STANDARDS SUCH AS NIOSH (US) OR CEN (EU).
CONTROL OF ENVIRONMENTAL EXPOSURE:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT LET PRODUCT
ENTER DRAINS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
A) APPEARANCE:
FORM: POWDER
B) ODOR: NO DATA AVAILABLE
C) ODOR THRESHOLD: NO DATA AVAILABLE
D) PH: NO DATA AVAILABLE
E) MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
F) INITIAL BOILING POINT AND BOILING RANGE: NO DATA AVAILABLE
G) FLASH POINT: NO DATA AVAILABLE
H) EVAPORATION RATE: NO DATA AVAILABLE
I) FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
J) UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NO DATA AVAILABLE
K) VAPOUR PRESSURE: NO DATA AVAILABLE
L) VAPOUR DENSITY: NO DATA AVAILABLE
M) RELATIVE DENSITY: NO DATA AVAILABLE
N) WATER SOLUBILITY: NO DATA AVAILABLE
O) PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
P) AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
Q) DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
R) VISCOSITY: NO DATA AVAILABLE
S) EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
T) OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2 OTHER SAFETY INFORMATION: NO DATA AVAILABLE
| 10. STABILITY AND REACTIVITY | |
10.1 REACTIVITY: NO DATA AVAILABLE
10.2 CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS: NO DATA AVAILABLE
10.4 CONDITIONS TO AVOID: NO DATA AVAILABLE
10.5 INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS DECOMPOSITION PRODUCTS FORMED UNDER FIRE CONDITIONS. - CARBON
OXIDES, NITROGEN OXIDES (NOx), SULPHUR OXIDES
OTHER DECOMPOSITION PRODUCTS - NO DATA AVAILABLE
IN THE EVENT OF FIRE: SEE SECTION 5
| 11. TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD50 ORAL - RAT: 430 MG/KG
INHALATION: NO DATA AVAILABLE
DERMAL: NO DATA AVAILABLE
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/EYE IRRITATION: NO DATA AVAILABLE
RESPIRATORY OR SKIN SENSITIZATION:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE ALLERGIC REACTIONS IN CERTAIN
SENSITIVE INDIVIDUALS.
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
ACGIH:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY ACGIH.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
REPRODUCTIVE TOXICITY:
SUSPECTED HUMAN REPRODUCTIVE TOXICANT
NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
ADDITIONAL INFORMATION:
RTECS: WK4990000
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL
PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
LIVER - IRREGULARITIES - BASED ON HUMAN EVIDENCE
| 12. ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
TOXICITY TO FISH:
LC50 - ONCORHYNCHUS MYKISS (RAINBOW TROUT): >180 MG/L - 96 H
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 - DAPHNIA MAGNA (WATER FLEA): 650 MG/L - 48 H
12.2 PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
12.3 BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
12.4 MOBILITY IN SOIL: NO DATA AVAILABLE
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT/VPVB ASSESSMENT NOT AVAILABLE AS CHEMICAL SAFETY ASSESSMENT NOT
REQUIRED/NOT CONDUCTED
12.6 OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
PRODUCT:
OFFER SURPLUS AND NON-RECYCLABLE SOLUTIONS TO A LICENSED DISPOSAL COMPANY.
CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL SERVICE TO DISPOSE OF THIS
MATERIAL. DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN
IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
CONTAMINATED PACKAGING: DISPOSE OF AS UNUSED PRODUCT.
| 14. TRANSPORT INFORMATION | |
DOT (US): NOT DANGEROUS GOODS
IMDG: NOT DANGEROUS GOODS
IATA: NOT DANGEROUS GOODS
| 15. REGULATORY INFORMATION | |
SARA 302 COMPONENTS:
NO CHEMICALS IN THIS MATERIAL ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SARA TITLE III, SECTION 302.
SARA 313 COMPONENTS:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS ESTABLISHED
BY SARA TITLE III, SECTION 313.
SARA 311/312 HAZARDS: ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
MASSACHUSETTS RIGHT TO KNOW COMPONENTS:
NO COMPONENTS ARE SUBJECT TO THE MASSACHUSETTS RIGHT TO KNOW ACT.
PENNSYLVANIA RIGHT TO KNOW COMPONENTS:
CAS-NO. REVISION DATE
STREPTOMYCIN SULPHATE 3810-74-0 2009-07-17
NEW JERSEY RIGHT TO KNOW COMPONENTS:
CAS-NO. REVISION DATE
STREPTOMYCIN SULPHATE 3810-74-0 2009-07-17
CALIFORNIA PROP. 65 COMPONENTS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CAS-NO. REVISION DATE
STREPTOMYCIN SULPHATE 3810-74-0 2007-09-28
| 16. OTHER INFORMATION | |
FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3.
ACUTE TOX.: ACUTE TOXICITY
H302: HARMFUL IF SWALLOWED.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
REPR.: REPRODUCTIVE TOXICITY
HMIS RATING:
HEALTH HAZARD 2
CHRONIC HEALTH HAZARD *
FLAMMABILITY 0
PHYSICAL HAZARD 0
NFPA RATING:
HEALTH HAZARD 2
FIRE HAZARD 0
REACTIVITY HAZARD 0
FURTHER INFORMATION:
COPYRIGHT 2016 SIGMA-ALDRICH CO. LLC. LICENSE GRANTED TO MAKE UNLIMITED
PAPER COPIES FOR INTERNAL USE ONLY. THE ABOVE INFORMATION IS BELIEVED TO
BE CORRECT BUT DOES NOT PURPORT TO BE ALL INCLUSIVE AND SHALL BE USED ONLY
AS A GUIDE. THE INFORMATION IN THIS DOCUMENT IS BASED ON THE PRESENT STATE
OF OUR KNOWLEDGE AND IS APPLICABLE TO THE PRODUCT WITH REGARD TO
APPROPRIATE SAFETY PRECAUTIONS. IT DOES NOT REPRESENT ANY GUARANTEE OF THE
PROPERTIES OF THE PRODUCT. SIGMA-ALDRICH CORPORATION AND ITS AFFILIATES
SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM
CONTACT WITH THE ABOVE PRODUCT. SEE WWW.SIGMA-ALDRICH.COM AND/OR THE
REVERSE SIDE OF INVOICE OR PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS
OF SALE.
PREPARATION INFORMATION:
SIGMA-ALDRICH CORPORATION
PRODUCT SAFETY - AMERICAS REGION
1-800-521-8956
VERSION: 4.10
REVISION DATE: 10/26/2017
PRINT DATE: 06/10/2018
SIGMA - S9137