Grainger SDS Lookup

AND OF THE COMPANY/UNDERTAKING

1.1 PRODUCT IDENTIFIERS:

PRODUCT NAME: ACETONE

PRODUCT NUMBER: 179124

BRAND: SIGALD

INDEX-NO.: 606-001-00-8

CAS-NO.: 67-64-1

1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:

IDENTIFIED USES: LABORATORY CHEMICALS, SYNTHESIS OF SUBSTANCES

1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:

COMPANY:
SIGMA-ALDRICH INC.
3050 SPRUCE ST
ST. LOUIS MO 63103
UNITED STATES

TELEPHONE: +1 314 771-5765

FAX: +1 800 325-5052

1.4 EMERGENCY TELEPHONE:

EMERGENCY PHONE #:
800-424-9300 CHEMTREC (USA)
+1-703-527-3887 CHEMTREC (INTERNATIONAL) 24 HOURS/DAY; 7 DAYS/WEEK

SECTION 2: HAZARDS IDENTIFICATION

2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:

GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910 (OSHA HCS):
FLAMMABLE LIQUIDS (CATEGORY 2), H225

EYE IRRITATION (CATEGORY 2A), H319

SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE (CATEGORY 3), CENTRAL
NERVOUS SYSTEM, H336

FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION,
SEE SECTION 16.

2.2 GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:

PICTOGRAM:
FLAME
EXCLAMATION MARK

SIGNAL WORD: DANGER

HAZARD STATEMENT(S):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.

PRECAUTIONARY STATEMENT(S):
P210: KEEP AWAY FROM HEAT/ SPARKS/ OPEN FLAMES/ HOT SURFACES. NO SMOKING.

P233: KEEP CONTAINER TIGHTLY CLOSED.

P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.

P241: USE EXPLOSION-PROOF ELECTRICAL/ VENTILATING/ LIGHTING/ EQUIPMENT.

P242: USE ONLY NON-SPARKING TOOLS.

P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.

P261: AVOID BREATHING DUST/ FUME/ GAS/ MIST/ VAPORS/ SPRAY.

P264: WASH SKIN THOROUGHLY AFTER HANDLING.

P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.

P280: WEAR PROTECTIVE GLOVES/ EYE PROTECTION/ FACE PROTECTION.

P303 + P361 + P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/ SHOWER.

P304 + P340 + P312:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/ DOCTOR IF YOU FEEL UNWELL.

P305 + P351 + P338:
IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.

P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ ATTENTION.

P370 + P378:
IN CASE OF FIRE:
USE DRY SAND, DRY CHEMICAL OR ALCOHOL-RESISTANT FOAM TO EXTINGUISH.

P403 + P233:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.

P403 + P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.

P405: STORE LOCKED UP.

P501: DISPOSE OF CONTENTS/ CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.

2.3 HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) OR NOT COVERED BY GHS:
REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1 SUBSTANCES:

FORMULA: C3H6O

MOLECULAR WEIGHT: 58.08 G/MOL

CAS-NO.: 67-64-1

EC-NO.: 200-662-2

INDEX-NO.: 606-001-00-8

COMPONENT              CLASSIFICATION                        CONCENTRATION

ACETONE                FLAM. LIQ. 2; EYE IRRIT. 2A;          <=100 %
                       STOT SE 3; H225, H319, H336
                       CONCENTRATION LIMITS:
                       >=20 %: STOT SE 3, H336;

FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.

SECTION 4: FIRST AID MEASURES

4.1 DESCRIPTION OF FIRST-AID MEASURES:

GENERAL ADVICE:
SHOW THIS MATERIAL SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.

IF INHALED:
AFTER INHALATION: FRESH AIR. CALL IN PHYSICIAN.

IN CASE OF SKIN CONTACT:

IN CASE OF SKIN CONTACT:
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/ SHOWER.

IN CASE OF EYE CONTACT:

AFTER EYE CONTACT:
RINSE OUT WITH PLENTY OF WATER. CALL IN OPHTHALMOLOGIST. REMOVE CONTACT
LENSES.

IF SWALLOWED:

AFTER SWALLOWING:
IMMEDIATELY MAKE VICTIM DRINK WATER (TWO GLASSES AT MOST). CONSULT A
PHYSICIAN.

4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
THE MOST IMPORTANT KNOWN SYMPTOMS AND EFFECTS ARE DESCRIBED IN THE
LABELLING (SEE SECTION 2.2) AND/OR IN SECTION 11

4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO DATA AVAILABLE

SECTION 5: FIREFIGHTING MEASURES

5.1 EXTINGUISHING MEDIA:

SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE (CO2) FOAM DRY POWDER

UNSUITABLE EXTINGUISHING MEDIA:
FOR THIS SUBSTANCE/MIXTURE NO LIMITATIONS OF EXTINGUISHING AGENTS ARE
GIVEN.

5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CARBON OXIDES

COMBUSTIBLE.

PAY ATTENTION TO FLASHBACK.

VAPORS ARE HEAVIER THAN AIR AND MAY SPREAD ALONG FLOORS.

DEVELOPMENT OF HAZARDOUS COMBUSTION GASES OR VAPOURS POSSIBLE IN THE EVENT
OF FIRE.

FORMS EXPLOSIVE MIXTURES WITH AIR AT AMBIENT TEMPERATURES.

5.3 ADVICE FOR FIREFIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.

5.4 FURTHER INFORMATION:
REMOVE CONTAINER FROM DANGER ZONE AND COOL WITH WATER. PREVENT FIRE
EXTINGUISHING WATER FROM CONTAMINATING SURFACE WATER OR THE GROUND
WATER SYSTEM.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:

ADVICE FOR NON-EMERGENCY PERSONNEL:
DO NOT BREATHE VAPORS, AEROSOLS. AVOID SUBSTANCE CONTACT. ENSURE ADEQUATE
VENTILATION. KEEP AWAY FROM HEAT AND SOURCES OF IGNITION.

EVACUATE THE DANGER AREA, OBSERVE EMERGENCY PROCEDURES, CONSULT AN EXPERT.

FOR PERSONAL PROTECTION SEE SECTION 8.

6.2 ENVIRONMENTAL PRECAUTIONS:
DO NOT LET PRODUCT ENTER DRAINS. RISK OF EXPLOSION.

6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
COVER DRAINS. COLLECT, BIND, AND PUMP OFF SPILLS. OBSERVE POSSIBLE
MATERIAL RESTRICTIONS (SEE SECTIONS 7 AND 10). TAKE UP WITH
LIQUID-ABSORBENT MATERIAL (E.G. CHEMIZORB(R*)). DISPOSE OF PROPERLY.
CLEAN UP AFFECTED AREA.

6.4 REFERENCE TO OTHER SECTIONS: FOR DISPOSAL SEE SECTION 13.

SECTION 7: HANDLING AND STORAGE

7.1 PRECAUTIONS FOR SAFE HANDLING:

ADVICE ON SAFE HANDLING: AVOID GENERATION OF VAPOURS/AEROSOLS.

ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
KEEP AWAY FROM OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION.TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.

HYGIENE MEASURES:
CHANGE CONTAMINATED CLOTHING. PREVENTIVE SKIN PROTECTION RECOMMENDED. WASH
HANDS AFTER WORKING WITH SUBSTANCE.

FOR PRECAUTIONS SEE SECTION 2.2.

7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:

STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. KEEP
AWAY FROM HEAT AND SOURCES OF IGNITION.

STORAGE CLASS (TRGS 510):
3: FLAMMABLE LIQUIDS

7.3 SPECIFIC END USE(S):
APART FROM THE USES MENTIONED IN SECTION 1.2 NO OTHER SPECIFIC USES ARE
STIPULATED

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 CONTROL PARAMETERS:

INGREDIENTS WITH WORKPLACE CONTROL PARAMETERS:

COMPONENT   CAS-NO.    VALUE    CONTROL PARAMETERS   BASIS

ACETONE     67-64-1    TWA      250 PPM              USA. ACGIH THRESHOLD
                                                     LIMIT VALUES (TLV)

REMARKS: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN

                       STEL     500 PPM              USA. ACGIH THRESHOLD
                                                     LIMIT VALUES (TLV)

NOT CLASSIFIABLE AS A HUMAN CARCINOGEN

                       TWA      250 PPM              USA. NIOSH RECOMMENDED
                                590 MG/M3            EXPOSURE LIMITS

                       TWA      1,000 PPM            USA. OCCUPATIONAL
                                2,400 MG/M3          EXPOSURE LIMITS (OSHA)
                                                     - TABLE Z-1 LIMITS FOR
                                                     AIR CONTAMINANTS

                       TWA      750 PPM              USA. OSHA - TABLE Z-1
                                1,800 MG/M3          LIMITS FOR AIR
                                                     CONTAMINANTS -
                                                     1910.1000

                       STEL     1,000 PPM            USA. OSHA - TABLE Z-1
                                2,400 MG/M3          LIMITS FOR AIR
                                                     CONTAMINANTS -
                                                     1910.1000

                       STEL     750 PPM              CALIFORNIA PERMISSIBLE
                                1,780 MG/M3          EXPOSURE LIMITS FOR
                                                     CHEMICAL CONTAMINANTS
                                                     (TITLE 8, ARTICLE 107)

                       C        3,000 PPM            CALIFORNIA PERMISSIBLE
                                                     EXPOSURE LIMITS FOR
                                                     CHEMICAL CONTAMINANTS
                                                     (TITLE 8, ARTICLE 107)

                       PEL      500 PPM              CALIFORNIA PERMISSIBLE
                                1,200 MG/M3          EXPOSURE LIMITS FOR
                                                     CHEMICAL CONTAMINANTS
                                                     (TITLE 8, ARTICLE 107)

BIOLOGICAL OCCUPATIONAL EXPOSURE LIMITS:

COMPONENT  CAS-NO.   PARAMETERS   VALUE     BIOLOGICAL  BASIS
                                            SPECIMEN

ACETONE    67-64-1   ACETONE      25 MG/L   URINE       ACGIH - BIOLOGICAL
                                                        EXPOSURE INDICES
                                                        (BEI)

REMARKS: END OF SHIFT (AS SOON AS POSSIBLE AFTER EXPOSURE CEASES)

PREDICTED NO EFFECT CONCENTRATION (PNEC):

COMPARTMENT                               VALUE

SOIL                                      33.3 MG/KG

SEA WATER                                 1.06 MG/L

FRESH WATER                               10.6 MG/L

SEA SEDIMENT                              3.04 MG/KG

FRESH WATER SEDIMENT                      30.4 MG/KG

ONSITE SEWAGE TREATMENT PLANT             100 MG/L

8.2 EXPOSURE CONTROLS:

APPROPRIATE ENGINEERING CONTROLS:
CHANGE CONTAMINATED CLOTHING. PREVENTIVE SKIN PROTECTION RECOMMENDED. WASH
HANDS AFTER WORKING WITH SUBSTANCE.

PERSONAL PROTECTIVE EQUIPMENT:

EYE/FACE PROTECTION:
USE EQUIPMENT FOR EYE PROTECTION TESTED AND APPROVED UNDER APPROPRIATE
GOVERNMENT STANDARDS SUCH AS NIOSH (US) OR EN 166(EU). SAFETY GLASSES

SKIN PROTECTION:
THIS RECOMMENDATION APPLIES ONLY TO THE PRODUCT STATED IN THE SAFETY DATA
SHEET, SUPPLIED BY US AND FOR THE DESIGNATED USE. WHEN DISSOLVING IN OR
MIXING WITH OTHER SUBSTANCES AND UNDER CONDITIONS DEVIATING FROM THOSE
STATED IN EN374 PLEASE CONTACT THE SUPPLIER OF CE-APPROVED GLOVES
(E.G. KCL GMBH, D-36124 EICHENZELL, INTERNET: WWW.KCL.DE).

FULL CONTACT

MATERIAL: BUTYL-RUBBER

MINIMUM LAYER THICKNESS: 0.7 MM

BREAK THROUGH TIME: 480 MIN

MATERIAL TESTED: BUTOJECT(R*) (KCL 898)

THIS RECOMMENDATION APPLIES ONLY TO THE PRODUCT STATED IN THE SAFETY DATA
SHEET, SUPPLIED BY US AND FOR THE DESIGNATED USE. WHEN DISSOLVING IN OR
MIXING WITH OTHER SUBSTANCES AND UNDER CONDITIONS DEVIATING FROM THOSE
STATED IN EN374 PLEASE CONTACT THE SUPPLIER OF CE-APPROVED GLOVES
(E.G. KCL GMBH, D-36124 EICHENZELL, INTERNET: WWW.KCL.DE).

SPLASH CONTACT

MATERIAL: LATEX GLOVES

MINIMUM LAYER THICKNESS: 0.6 MM

BREAK THROUGH TIME: 10 MIN

MATERIAL TESTED: LAPREN(R*) (KCL 706 / ALDRICH Z677558, SIZE M)

BODY PROTECTION:
FLAME RETARDANT ANTISTATIC PROTECTIVE CLOTHING.

RESPIRATORY PROTECTION:
REQUIRED WHEN VAPOURS/AEROSOLS ARE GENERATED.

OUR RECOMMENDATIONS ON FILTERING RESPIRATORY PROTECTION ARE BASED ON THE
FOLLOWING STANDARDS:
DIN EN 143, DIN 14387 AND OTHER ACCOMPANYING STANDARDS RELATING TO THE
USED RESPIRATORY PROTECTION SYSTEM.

CONTROL OF ENVIRONMENTAL EXPOSURE:
DO NOT LET PRODUCT ENTER DRAINS. RISK OF EXPLOSION.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:

A) APPEARANCE:
FORM: CLEAR, LIQUID
COLOR: COLORLESS

B) ODOR: PUNGENT, WEAKLY AROMATIC

C) ODOR THRESHOLD: 0.1 PPM

D) PH: 5 - 6 AT 395 G/L AT 20 DEG. C (68 DEG. F)

E) MELTING POINT/FREEZING POINT:
MELTING POINT/RANGE: -94 DEG. C (-137 DEG. F) - LIT.

F) INITIAL BOILING POINT AND BOILING RANGE:
56 DEG. C 133 DEG. F AT 1,013 HPA - LIT.

G) FLASH POINT: -17.0 DEG. C (1.4 DEG. F) - CLOSED CUP

H) EVAPORATION RATE: NO DATA AVAILABLE

I) FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE

J) UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
UPPER EXPLOSION LIMIT: 13 %(V)
LOWER EXPLOSION LIMIT: 2 %(V)

K) VAPOR PRESSURE: 245.3 HPA AT 20.0 DEG. C (68.0 DEG. F)

L) VAPOR DENSITY: NO DATA AVAILABLE

M) RELATIVE DENSITY: NO DATA AVAILABLE

N) WATER SOLUBILITY: SOLUBLE, IN ALL PROPORTIONS

O) PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE

P) AUTOIGNITION TEMPERATURE: 465.0 DEG. C (869.0 DEG. F)

Q) DECOMPOSITION TEMPERATURE:
DISTILLABLE IN AN UNDECOMPOSED STATE AT NORMAL PRESSURE.

R) VISCOSITY: NO DATA AVAILABLE

S) EXPLOSIVE PROPERTIES: NO DATA AVAILABLE

T) OXIDIZING PROPERTIES: NO DATA AVAILABLE

9.2 OTHER SAFETY INFORMATION:
CONDUCTIVITY: 0.01 (MICRO)S/CM AT 20 DEG. C (68 DEG. F)
SURFACE TENSION 23.2 MN/M AT 20.0 DEG. C (68.0 DEG. F)

SECTION 10: STABILITY AND REACTIVITY

10.1 REACTIVITY:
VAPORS MAY FORM EXPLOSIVE MIXTURE WITH AIR.

10.2 CHEMICAL STABILITY:
THE PRODUCT IS CHEMICALLY STABLE UNDER STANDARD AMBIENT CONDITIONS
(ROOM TEMPERATURE) .

10.3 POSSIBILITY OF HAZARDOUS REACTIONS:

RISK OF IGNITION OR FORMATION OF INFLAMMABLE GASES OR VAPOURS WITH:
CHROMOSULFURIC ACID
CHROMYL CHLORIDE
ETHANOLAMINE
FLUORINE
STRONG OXIDIZING AGENTS
STRONG REDUCING AGENTS
NITRIC ACID
CHROMIUM(VI) OXIDE

RISK OF EXPLOSION WITH:
NONMETALLIC OXYHALIDES
HALOGEN-HALOGEN COMPOUNDS
CHLOROFORM
NITRATING ACID
NITROSYL COMPOUNDS
HYDROGEN PEROXIDE
HALOGEN OXIDES
ORGANIC NITRO COMPOUNDS
PEROXI COMPOUNDS

EXOTHERMIC REACTION WITH:
BROMINE
ALKALI METALS
ALKALI HYDROXIDES
HALOGENATED HYDROCARBON
SULFUR DICHLORIDE
PHOSPHOROUS OXICHLORIDE

10.4 CONDITIONS TO AVOID: WARMING.

10.5 INCOMPATIBLE MATERIALS: RUBBER, VARIOUS PLASTICS

10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
IN THE EVENT OF FIRE: SEE SECTION 5

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:

ACUTE TOXICITY:
LD50 ORAL - RAT - FEMALE: 5,800 MG/KG
REMARKS: (ECHA)

LC50 INHALATION - RAT - 4 H: 76 MG/L
REMARKS: UNCONSCIOUSNESSDROWSINESSDIZZINESS(EXTERNAL MSDS)

LD50 DERMAL - RABBIT: 20,000 MG/KG
REMARKS: (IUCLID)

NO DATA AVAILABLE

SKIN CORROSION/IRRITATION:
SKIN - RABBIT
RESULT: MILD SKIN IRRITATION - 24 H
(DRAIZE TEST)
REMARKS: (RTECS)

SERIOUS EYE DAMAGE/EYE IRRITATION:
EYES - RABBIT
RESULT: EYE IRRITATION - 24 H
(DRAIZE TEST)
REMARKS: (RTECS)

RESPIRATORY OR SKIN SENSITIZATION:
MAXIMIZATION TEST - GUINEA PIG
RESULT: NOT A SKIN SENSITIZER.
REMARKS:
(ECHA)
CHRONIC EXPOSURE MAY CAUSE DERMATITIS.

GERM CELL MUTAGENICITY:

TEST TYPE:
MUTAGENICITY (MAMMAL CELL TEST): CHROMOSOME ABERRATION.

TEST SYSTEM: CHINESE HAMSTER OVARY CELLS

METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION

METHOD: OECD TEST GUIDELINE 473

RESULT: NEGATIVE

TEST TYPE: AMES TEST
TEST SYSTEM: SALMONELLA TYPHIMURIUM
METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION
METHOD: OECD TEST GUIDELINE 471
RESULT: NEGATIVE

TEST TYPE: IN VITRO MAMMALIAN CELL GENE MUTATION TEST
TEST SYSTEM: MOUSE LYMPHOMA TEST
METABOLIC ACTIVATION: WITHOUT METABOLIC ACTIVATION
METHOD: OECD TEST GUIDELINE 476
RESULT: NEGATIVE

CARCINOGENICITY:

IARC:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN
BY IARC.

NTP:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.

OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS ON OSHA'S LIST OF REGULATED CARCINOGENS.

REPRODUCTIVE TOXICITY: NO DATA AVAILABLE

SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
INHALATION - MAY CAUSE DROWSINESS OR DIZZINESS. - NARCOTIC EFFECTS

SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NO DATA AVAILABLE

ASPIRATION HAZARD: NO DATA AVAILABLE

11.2 ADDITIONAL INFORMATION:

RTECS: AL3150000

TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL
PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.

AFTER ABSORPTION:
HEADACHE
SALIVATION
NAUSEA
VOMITING
DIZZINESS
NARCOSIS
COMA

OTHER DANGEROUS PROPERTIES CAN NOT BE EXCLUDED.

HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.

KIDNEY - IRREGULARITIES - BASED ON HUMAN EVIDENCE

SKIN - DERMATITIS - BASED ON HUMAN EVIDENCE

KIDNEY - IRREGULARITIES - BASED ON HUMAN EVIDENCE

SKIN - DERMATITIS - BASED ON HUMAN EVIDENCE

SECTION 12: ECOLOGICAL INFORMATION

12.1 TOXICITY:

TOXICITY TO FISH:
FLOW-THROUGH TEST LC50 - PIMEPHALES PROMELAS (FATHEAD MINNOW) -
6,210 MG/L - 96 H

(OECD TEST GUIDELINE 203)

TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
STATIC TEST LC50 - DAPHNIA PULEX (WATER FLEA) - 8,800 MG/L - 48 H
REMARKS: (ECHA)

TOXICITY TO ALGAE:
STATIC TEST NOEC - M.AERUGINOSA - 530 MG/L - 8 D
(DIN 38412)

REMARKS: (MAXIMUM PERMISSIBLE TOXIC CONCENTRATION)
(IUCLID)

TOXICITY TO BACTERIA:
STATIC TEST EC50 - ACTIVATED SLUDGE - 61.15 MG/L - 30 MIN
(OECD TEST GUIDELINE 209)

12.2 PERSISTENCE AND DEGRADABILITY:

BIODEGRADABILITY:
AEROBIC - EXPOSURE TIME 28 D
RESULT: 91 % - READILY BIODEGRADABLE.
(OECD TEST GUIDELINE 301B)

BIOCHEMICAL OXYGEN: 1,850 MG/G

DEMAND (BOD):
REMARKS: (IUCLID)

CHEMICAL OXYGEN: 2,070 MG/G

DEMAND (COD):
REMARKS: (IUCLID)

THEORETICAL OXYGEN: 2,200 MG/G

DEMAND:
REMARKS: (LIT.)

12.3 BIOACCUMULATIVE POTENTIAL: DOES NOT BIOACCUMULATE.

12.4 MOBILITY IN SOIL: NO DATA AVAILABLE

12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT/VPVB ASSESSMENT NOT AVAILABLE AS CHEMICAL SAFETY ASSESSMENT NOT
REQUIRED/NOT CONDUCTED

12.6 OTHER ADVERSE EFFECTS:
ADDITIONAL ECOLOGICAL INFORMATION: NO DATA AVAILABLE

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 WASTE TREATMENT METHODS:

PRODUCT:
WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE WITH THE NATIONAL AND
LOCAL REGULATIONS. LEAVE CHEMICALS IN ORIGINAL CONTAINERS. NO MIXING WITH
OTHER WASTE. HANDLE UNCLEANED CONTAINERS LIKE THE PRODUCT ITSELF. SEE
WWW.RETROLOGISTIK.COM FOR PROCESSES REGARDING THE RETURN OF CHEMICALS AND
CONTAINERS, OR CONTACT US THERE IF YOU HAVE FURTHER QUESTIONS.

SECTION 14: TRANSPORT INFORMATION

DOT (US):
UN NUMBER: 1090
CLASS: 3
PACKING GROUP: II
PROPER SHIPPING NAME: ACETONE
REPORTABLE QUANTITY (RQ): 5000 LBS
POISON INHALATION HAZARD: NO

IMDG:
UN NUMBER: 1090
CLASS: 3
PACKING GROUP: II
EMS-NO: F-E, S-D
PROPER SHIPPING NAME: ACETONE

IATA:
UN NUMBER: 1090
CLASS: 3
PACKING GROUP: II
PROPER SHIPPING NAME: ACETONE

SECTION 15: REGULATORY INFORMATION

SARA 302 COMPONENTS:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 302 EHS TPQ.

SARA 313 COMPONENTS:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN
CAS NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS
ESTABLISHED BY SARA TITLE III, SECTION 313.

SARA 311/312 HAZARDS:
FIRE HAZARD, ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD

MASSACHUSETTS RIGHT TO KNOW COMPONENTS:
NO COMPONENTS ARE SUBJECT TO THE MASSACHUSETTS RIGHT TO KNOW ACT.

SECTION 16: OTHER INFORMATION

FURTHER INFORMATION:
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. THE INFORMATION IN
THIS DOCUMENT IS BASED ON THE PRESENT STATE OF OUR KNOWLEDGE AND IS
APPLICABLE TO THE PRODUCT WITH REGARD TO APPROPRIATE SAFETY PRECAUTIONS.
IT DOES NOT REPRESENT ANY GUARANTEE OF THE PROPERTIES OF THE PRODUCT.
SIGMA-ALDRICH CORPORATION AND ITS AFFILIATES SHALL NOT BE HELD LIABLE
FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WITH THE ABOVE
PRODUCT. SEE WWW.SIGMA-ALDRICH.COM AND/OR THE REVERSE SIDE OF INVOICE
OR PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.

COPYRIGHT 2020 SIGMA-ALDRICH CO. LLC.
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.

THE BRANDING ON THE HEADER AND/OR FOOTER OF THIS DOCUMENT MAY TEMPORARILY
NOT VISUALLY MATCH THE PRODUCT PURCHASED AS WE TRANSITION OUR BRANDING.
HOWEVER, ALL OF THE INFORMATION IN THE DOCUMENT REGARDING THE PRODUCT
REMAINS UNCHANGED AND MATCHES THE PRODUCT ORDERED. FOR FURTHER INFORMATION
PLEASE CONTACT MLSBRANDING@SIAL.COM.

VERSION: 6.5

REVISION DATE: 04/17/2021

PRINT DATE: 09/05/2021

MILLIPORE SIGMA

THE LIFE SCIENCE BUSINESS OF MERCK KGAA, DARMSTADT, GERMANY OPERATES AS
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