| Common Name: | 1-BUTANOL, 537993 |
| Manufacturer: | SIGMA-ALDRICH |
| SDS Revision Date: | 1/15/2020 |
| SDS Format: | No Format Specified |
| Item Number(s): | 45ZZ86 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SIGMA-ALDRICH(R*)
WWW.SIGMAALDRICH.COM
SAFETY DATA SHEET
VERSION: 6.3
REVISION DATE: 01/15/2020
PRINT DATE: 02/20/2020
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIERS:
PRODUCT NAME: 1-BUTANOL
PRODUCT NUMBER: 537993
BRAND: SIGALD
INDEX-NO.: 603-004-00-6
CAS-NO.: 71-36-3
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
IDENTIFIED USES: LABORATORY CHEMICALS, SYNTHESIS OF SUBSTANCES
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY:
SIGMA-ALDRICH INC.
3050 SPRUCE STREET
ST. LOUIS, MO 63103
UNITED STATES
TELEPHONE: +1 314 771-5765
FAX: +1 800 325-5052
1.4 EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE #: +1-703-527-3887
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910 (OSHA HCS):
FLAMMABLE LIQUIDS (CATEGORY 3), H226
ACUTE TOXICITY, ORAL (CATEGORY 4), H302
SKIN IRRITATION (CATEGORY 2), H315
SERIOUS EYE DAMAGE (CATEGORY 1), H318
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE (CATEGORY 3), RESPIRATORY
SYSTEM, CENTRAL NERVOUS SYSTEM, H335, H336
FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.
2.2 GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
PICTOGRAM:
FLAME
CORROSION
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT(S):
H226: FLAMMABLE LIQUID AND VAPOUR.
H302: HARMFUL IF SWALLOWED.
H315: CAUSES SKIN IRRITATION.
H318: CAUSES SERIOUS EYE DAMAGE.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
PRECAUTIONARY STATEMENT(S):
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P261: AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
P264: WASH SKIN THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280: WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION.
P301 + P312 + P330:
IF SWALLOWED: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL. RINSE MOUTH.
P303 + P361 + P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304 + P340 + P312:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
P305 + P351 + P338 + P310:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER/DOCTOR.
P332 + P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
P370 + P378:
IN CASE OF FIRE:
USE DRY SAND, DRY CHEMICAL OR ALCOHOL-RESISTANT FOAM TO EXTINGUISH.
P403 + P233:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P403 + P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
P501: DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
2.3 HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) OR NOT COVERED BY GHS: NONE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1 SUBSTANCES:
SYNONYMS:
BUTYL ALCOHOL
N-BUTANOL
FORMULA: C4H10O
MOLECULAR WEIGHT: 74.12 G/MOL
CAS-NO.: 71-36-3
EC-NO.: 200-751-6
INDEX-NO.: 603-004-00-6
COMPONENT CLASSIFICATION CONCENTRATION
N-BUTANOL FLAM. LIQ. 3; ACUTE TOX. 4; <=100%
SKIN IRRIT. 2; EYE DAM. 1;
STOT SE 3; H226, H302,
H315, H318, H335, H336
CONCENTRATION LIMITS:
>=20%: STOT SE 3,
H335; >=20%: STOT SE
3, H336;
FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.
| SECTION 4: FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
CONSULT A PHYSICIAN. SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN
ATTENDANCE. MOVE OUT OF DANGEROUS AREA.
IF INHALED:
IF BREATHED IN, MOVE PERSON INTO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. CONSULT A PHYSICIAN.
IN CASE OF SKIN CONTACT:
WASH OFF WITH SOAP AND PLENTY OF WATER. CONSULT A PHYSICIAN.
IN CASE OF EYE CONTACT:
RINSE THOROUGHLY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND CONSULT A
PHYSICIAN.
IF SWALLOWED:
DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. RINSE MOUTH WITH WATER. CONSULT A PHYSICIAN.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
THE MOST IMPORTANT KNOWN SYMPTOMS AND EFFECTS ARE DESCRIBED IN THE
LABELING (SEE SECTION 2.2) AND/OR IN SECTION 11
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO DATA AVAILABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA: DRY POWDER DRY SAND
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER JET.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CARBON OXIDES
FLASH BACK POSSIBLE OVER CONSIDERABLE DISTANCE.
5.3 ADVICE FOR FIREFIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS FOR FIREFIGHTING IF NECESSARY.
5.4 FURTHER INFORMATION:
IN CASE OF FIRE:
EVACUATE AREA. FIGHT FIRE REMOTELY DUE TO THE RISK OF EXPLOSION. USE WATER
SPRAY TO COOL UNOPENED CONTAINERS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT. AVOID BREATHING VAPORS, MIST OR GAS.
ENSURE ADEQUATE VENTILATION. REMOVE ALL SOURCES OF IGNITION. EVACUATE
PERSONNEL TO SAFE AREAS. BEWARE OF VAPORS ACCUMULATING TO FORM EXPLOSIVE
CONCENTRATIONS. VAPORS CAN ACCUMULATE IN LOW AREAS.
FOR PERSONAL PROTECTION SEE SECTION 8.
6.2 ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT LET PRODUCT
ENTER DRAINS.
6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILLAGE, AND THEN COLLECT WITH NON-COMBUSTIBLE ABSORBENT MATERIAL,
(E.G. SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND PLACE IN CONTAINER
FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL REGULATIONS (SEE SECTION 13).
6.4 REFERENCE TO OTHER SECTIONS: FOR DISPOSAL SEE SECTION 13.
| SECTION 7: HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH SKIN AND EYES. AVOID INHALATION OF VAPOUR OR MIST.
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING. TAKE MEASURES TO PREVENT
THE BUILD UP OF ELECTROSTATIC CHARGE.
FOR PRECAUTIONS SEE SECTION 2.2.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
CONTAINERS WHICH ARE OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO
PREVENT LEAKAGE.
HANDLE AND STORE UNDER INERT GAS. HYGROSCOPIC
STORAGE CLASS (TRGS 510): 3: FLAMMABLE LIQUIDS
7.3 SPECIFIC END USE(S):
APART FROM THE USES MENTIONED IN SECTION 1.2 NO OTHER SPECIFIC USES ARE
STIPULATED
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENT CAS-NO. VALUE CONTROL BASIS
PARAMETERS
N-BUTANOL 71-36-3 TWA 20 PPM USA. ACGIH THRESHOLD LIMIT
VALUES (TLV)
REMARKS UPPER RESPIRATORY TRACT IRRITATION
EYE IRRITATION
C 50 PPM USA. NIOSH RECOMMENDED
150 MG/M3 EXPOSURE LIMITS
POTENTIAL FOR DERMAL ABSORPTION
TWA 100 PPM USA. OCCUPATIONAL EXPOSURE
300 MG/M3 LIMITS (OSHA) - TABLE Z-1
LIMITS FOR AIR CONTAMINANTS
THE VALUE IN MG/M3 IS APPROXIMATE.
C 50 PPM CALIFORNIA PERMISSIBLE EXPOSURE
150 MG/M3 LIMITS FOR CHEMICAL CONTAMINANTS
(TITLE 8, ARTICLE 107)
SKIN
8.2 EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE. WASH
HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
TIGHTLY FITTING SAFETY GOGGLES. FACESHIELD (8-INCH MINIMUM). USE EQUIPMENT
FOR EYE PROTECTION TESTED AND APPROVED UNDER APPROPRIATE GOVERNMENT
STANDARDS SUCH AS NIOSH (US) OR EN 166(EU).
SKIN PROTECTION:
HANDLE WITH GLOVES. GLOVES MUST BE INSPECTED PRIOR TO USE. USE PROPER GLOVE
REMOVAL TECHNIQUE (WITHOUT TOUCHING GLOVE'S OUTER SURFACE) TO AVOID SKIN
CONTACT WITH THIS PRODUCT. DISPOSE OF CONTAMINATED GLOVES AFTER USE IN
ACCORDANCE WITH APPLICABLE LAWS AND GOOD LABORATORY PRACTICES. WASH AND DRY
HANDS.
FULL CONTACT:
MATERIAL: NITRILE RUBBER
MINIMUM LAYER THICKNESS: 0.4 MM
BREAK THROUGH TIME: 480 MIN
MATERIAL TESTED: CAMATRIL(R*) (KCL 730 / ALDRICH Z677442, SIZE M)
SPLASH CONTACT:
MATERIAL: NITRILE RUBBER
MINIMUM LAYER THICKNESS: 0.2 MM
BREAK THROUGH TIME: 58 MIN
MATERIAL TESTED: DERMATRIL(R*) P (KCL 743 / ALDRICH Z677388, SIZE M)
DATA SOURCE:
KCL GMBH
D-36124 EICHENZELL
PHONE: +49 (0)6659 87300
E-MAIL: SALES@KCL.DE
TEST METHOD: EN374
IF USED IN SOLUTION, OR MIXED WITH OTHER SUBSTANCES, AND UNDER CONDITIONS
WHICH DIFFER FROM EN 374, CONTACT THE SUPPLIER OF THE CE APPROVED GLOVES.
THIS RECOMMENDATION IS ADVISORY ONLY AND MUST BE EVALUATED BY AN INDUSTRIAL
HYGIENIST AND SAFETY OFFICER FAMILIAR WITH THE SPECIFIC SITUATION OF
ANTICIPATED USE BY OUR CUSTOMERS. IT SHOULD NOT BE CONSTRUED AS OFFERING AN
APPROVAL FOR ANY SPECIFIC USE SCENARIO.
BODY PROTECTION:
COMPLETE SUIT PROTECTING AGAINST CHEMICALS, FLAME RETARDANT ANTISTATIC
PROTECTIVE CLOTHING., THE TYPE OF PROTECTIVE EQUIPMENT MUST BE SELECTED
ACCORDING TO THE CONCENTRATION AND AMOUNT OF THE DANGEROUS SUBSTANCE AT THE
SPECIFIC WORKPLACE.
RESPIRATORY PROTECTION:
WHERE RISK ASSESSMENT SHOWS AIR-PURIFYING RESPIRATORS ARE APPROPRIATE USE A
FULL-FACE RESPIRATOR WITH MULTI-PURPOSE COMBINATION (US) OR TYPE ABEK (EN
14387) RESPIRATOR CARTRIDGES AS A BACKUP TO ENGINEERING CONTROLS. IF THE
RESPIRATOR IS THE SOLE MEANS OF PROTECTION, USE A FULL-FACE SUPPLIED AIR
RESPIRATOR. USE RESPIRATORS AND COMPONENTS TESTED AND APPROVED UNDER
APPROPRIATE GOVERNMENT STANDARDS SUCH AS NIOSH (US) OR CEN (EU).
CONTROL OF ENVIRONMENTAL EXPOSURE:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT LET PRODUCT
ENTER DRAINS.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
A) APPEARANCE:
FORM: LIQUID, CLEAR
COLOR: COLORLESS
B) ODOR: ETHANOLIC
C) ODOR THRESHOLD: NO DATA AVAILABLE
D) PH: 7 AT 70 G/L AT 20 DEG. C (68 DEG. F)
E) MELTING POINT/FREEZING POINT:
MELTING POINT/RANGE: -90 DEG. C (-130 DEG. F)
F) INITIAL BOILING POINT AND BOILING RANGE:
116 - 118 DEG. C 241 - 244 DEG. F
G) FLASH POINT:
35 DEG. C (95 DEG. F) - PENSKY-MARTENS CLOSED CUP - ISO 2719
H) EVAPORATION RATE: NO DATA AVAILABLE
I) FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
J) UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
UPPER EXPLOSION LIMIT: 11.2%(V)
LOWER EXPLOSION LIMIT: 1.4%(V)
K) VAPOUR PRESSURE: <10 HPA AT 20 DEG. C (68 DEG. F)
L) VAPOUR DENSITY: 2.56 AT 20 DEG. C(68 DEG. F) - (AIR = 1.0)
M) RELATIVE DENSITY: 0.81 G/ML AT 25 DEG. C (77 DEG. F)
N) WATER SOLUBILITY:
66 G/L AT 20 DEG. C (68 DEG. F) - OECD TEST GUIDELINE 105
O) PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 1 AT 25 DEG. C (77 DEG. F) - BIOACCUMULATION IS NOT EXPECTED.
P) AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
Q) DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
R) VISCOSITY: NO DATA AVAILABLE
S) EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
T) OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2 OTHER SAFETY INFORMATION:
SURFACE TENSION:
69.9 MN/M AT 1G/L AT 20 DEG. C (68 DEG. F) - OECD TEST GUIDELINE 115
RELATIVE VAPOUR DENSITY: 2.56 AT 20 DEG. C (68 DEG. F) - (AIR = 1.0)
| SECTION 10: STABILITY AND REACTIVITY | |
10.1 REACTIVITY: NO DATA AVAILABLE
10.2 CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
VAPORS MAY FORM EXPLOSIVE MIXTURE WITH AIR.
10.4 CONDITIONS TO AVOID:
EXPOSURE TO MOISTURE
HEAT, FLAMES AND SPARKS.
10.5 INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS, ALKALI METALS, BASES, STRONG ACIDS, HALOGENS
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
OTHER DECOMPOSITION PRODUCTS - NO DATA AVAILABLE
HAZARDOUS DECOMPOSITION PRODUCTS FORMED UNDER FIRE CONDITIONS. - CARBON
OXIDES
IN THE EVENT OF FIRE: SEE SECTION 5
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD50 ORAL - RAT: 790 MG/KG
REMARKS:
LIVER: FATTY LIVER DEGENERATION. KIDNEY, URETER
BLADDER: OTHER CHANGES.
BLOOD: OTHER CHANGES. (RTECS)
INHALATION: NO DATA AVAILABLE
LD50 DERMAL - RABBIT - MALE - 3,430 MG/KG
(OECD TEST GUIDELINE 402)
NO DATA AVAILABLE
SKIN CORROSION/IRRITATION:
SKIN - RABBIT
RESULT: SKIN IRRITATION - 2 H
REMARKS: (ECHA)
(REGULATION (EC) NO 1272/2008, ANNEX VI)
SERIOUS EYE DAMAGE/EYE IRRITATION:
EYES - RABBIT
RESULT: IRREVERSIBLE EFFECTS ON THE EYE
(OECD TEST GUIDELINE 405)
(REGULATION (EC) NO 1272/2008, ANNEX VI)
RESPIRATORY OR SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY:
MUTAGENICITY (MAMMAL CELL TEST): MICRONUCLEUS.
CHINESE HAMSTER LUNG CELLS
RESULT: NEGATIVE
(ECHA)
IN VITRO MAMMALIAN CELL GENE MUTATION TEST
CHINESE HAMSTER LUNG CELLS
RESULT: NEGATIVE
OECD TEST GUIDELINE 474
MOUSE - MALE AND FEMALE
RESULT: NEGATIVE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS ON OSHA'S LIST OF REGULATED CARCINOGENS.
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
ADDITIONAL INFORMATION:
RTECS: EO1400000
DRYING, CRACKING OF THE SKIN, SKIN IRRITATION
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL
PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
STOMACH - IRREGULARITIES - BASED ON HUMAN EVIDENCE
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
TOXICITY TO FISH STATIC TEST LC50 - PIMEPHALES PROMELAS (FATHEAD MINNOW):
1,376 MG/L - 96 H (OECD TEST GUIDELINE 203)
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
STATIC TEST EC50 - DAPHNIA MAGNA (WATER FLEA):
1,328 MG/L - 48 H (OECD TEST GUIDELINE 202)
TOXICITY TO ALGAE:
STATIC TEST ERC50 - PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE): 225 MG/L
- 96 H (OECD TEST GUIDELINE 201)
TOXICITY TO BACTERIA:
STATIC TEST EC50 - PSEUDOMONAS PUTIDA: 4,390 MG/L - 17 H (DIN 38421 TEIL 8)
12.2 PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY:
AEROBIC - EXPOSURE TIME 20 D
RESULT: 92% - READILY BIODEGRADABLE.
REMARKS: (ECHA)
RATIO BOD/THBOD: 33%
REMARKS: (IUCLID)
12.3 BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATION:
ONCORHYNCHUS MYKISS (RAINBOW TROUT) - 24 H: 921 MG/L(N-BUTANOL)
BIOCONCENTRATION FACTOR (BCF): 0.38
12.4 MOBILITY IN SOIL: NO DATA AVAILABLE
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT/VPVB ASSESSMENT NOT AVAILABLE AS CHEMICAL SAFETY ASSESSMENT NOT
REQUIRED/NOT CONDUCTED
12.6 OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
PRODUCT:
OFFER SURPLUS AND NON-RECYCLABLE SOLUTIONS TO A LICENSED DISPOSAL COMPANY.
BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER
BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY FLAMMABLE.
CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL SERVICE TO DISPOSE OF THIS
MATERIAL.
CONTAMINATED PACKAGING: DISPOSE OF AS UNUSED PRODUCT.
| SECTION 14: TRANSPORT INFORMATION | |
DOT (US):
UN NUMBER: 1120
CLASS: 3
PACKING GROUP: III
PROPER SHIPPING NAME: BUTANOLS
REPORTABLE QUANTITY (RQ): 5000 LBS
REPORTABLE QUANTITY (RQ): 100 LBS
POISON INHALATION HAZARD: NO
IMDG:
UN NUMBER: 1120
CLASS: 3
PACKING GROUP: III
EMS-NO: F-E, S-D
PROPER SHIPPING NAME: BUTANOLS
IATA:
UN NUMBER: 1120
CLASS: 3
PACKING GROUP: III
PROPER SHIPPING NAME: BUTANOLS
| SECTION 15: REGULATORY INFORMATION | |
SARA 302 COMPONENTS:
NO CHEMICALS IN THIS MATERIAL ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SARA TITLE III, SECTION 302.
SARA 313 COMPONENTS:
THE FOLLOWING COMPONENTS ARE SUBJECT TO REPORTING LEVELS ESTABLISHED BY
SARA TITLE III, SECTION 313:
CAS-NO. REVISION DATE
N-BUTANOL 71-36-3 2007-07-01
SARA 311/312 HAZARDS:
FIRE HAZARD, ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
REPORTABLE QUANTITY: F003 LBS
MASSACHUSETTS RIGHT TO KNOW COMPONENTS:
NO COMPONENTS ARE SUBJECT TO THE MASSACHUSETTS RIGHT TO KNOW ACT.
PENNSYLVANIA RIGHT TO KNOW COMPONENTS:
CAS-NO. REVISION DATE
N-BUTANOL 71-36-3 2007-07-01
| SECTION 16: OTHER INFORMATION | |
FURTHER INFORMATION:
COPYRIGHT 2020 SIGMA-ALDRICH CO. LLC. LICENSE GRANTED TO MAKE UNLIMITED
PAPER COPIES FOR INTERNAL USE ONLY.
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE
ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. THE INFORMATION IN THIS
DOCUMENT IS BASED ON THE PRESENT STATE OF OUR KNOWLEDGE AND IS APPLICABLE
TO THE PRODUCT WITH REGARD TO APPROPRIATE SAFETY PRECAUTIONS. IT DOES NOT
REPRESENT ANY GUARANTEE OF THE PROPERTIES OF THE PRODUCT. SIGMA-ALDRICH
CORPORATION AND ITS AFFILIATES SHALL NOT BE HELD LIABLE FOR ANY DAMAGE
RESULTING FROM HANDLING OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE
WWW.SIGMA-ALDRICH.COM AND/OR THE REVERSE SIDE OF INVOICE OR PACKING SLIP
FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
THE BRANDING ON THE HEADER AND/OR FOOTER OF THIS DOCUMENT MAY TEMPORARILY
NOT VISUALLY MATCH THE PRODUCT PURCHASED AS WE TRANSITION OUR BRANDING.
HOWEVER, ALL OF THE INFORMATION IN THE DOCUMENT REGARDING THE PRODUCT
REMAINS UNCHANGED AND MATCHES THE PRODUCT ORDERED. FOR FURTHER INFORMATION
PLEASE CONTACT MLSBRANDING@SIAL.COM.
VERSION: 6.3
REVISION DATE: 01/15/2020
PRINT DATE: 02/20/2020
THE LIFE SCIENCE BUSINESS OF MERCK KGAA, DARMSTADT, GERMANY OPERATES AS
MILLIPORESIGMA IN THE US AND CANADA
MILLIPORE SIGMA