| Common Name: | CARBON DISULFIDE, 180173 |
| Manufacturer: | SIGMA-ALDRICH |
| SDS Revision Date: | 8/10/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 46AA26 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SIGMA-ALDRICH
SIGMA-ALDRICH.COM
SAFETY DATA SHEET
VERSION: 5.8
REVISION DATE: 08/10/2016
PRINT DATE: 05/19/2017
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
1.1 PRODUCT IDENTIFIERS:
PRODUCT NAME: CARBON DISULFIDE
PRODUCT NUMBER: 180173
BRAND: SIGMA-ALDRICH
INDEX-NO.: 006-003-00-3
CAS-NO.: 75-15-0
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
IDENTIFIED USES: LABORATORY CHEMICALS, SYNTHESIS OF SUBSTANCES
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY:
SIGMA-ALDRICH
3050 SPRUCE STREET
SAINT LOUIS MO 63103
USA
TELEPHONE: +1 800-325-5832
FAX: +1 800-325-5052
1.4 EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE #: +1-703-527-3887 (CHEMTREC)
| 2. HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910 (OSHA HCS):
FLAMMABLE LIQUIDS (CATEGORY 2), H225
ACUTE TOXICITY, INHALATION (CATEGORY 4), H332
SKIN IRRITATION (CATEGORY 2), H315
EYE IRRITATION (CATEGORY 2A), H319
REPRODUCTIVE TOXICITY (CATEGORY 2), H361
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, INHALATION
(CATEGORY 1), H372
ACUTE AQUATIC TOXICITY (CATEGORY 2), H401
FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.
2.2 GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
PICTOGRAM:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT(S):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
H372:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE IF INHALED.
H401: TOXIC TO AQUATIC LIFE.
PRECAUTIONARY STATEMENT(S):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P264: WASH SKIN THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P303 + P361 + P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304 + P340 + P312:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P308 + P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P332 + P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
P370 + P378:
IN CASE OF FIRE:
USE DRY SAND, DRY CHEMICAL OR ALCOHOL-RESISTANT FOAM TO EXTINGUISH.
P403 + P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
P501: DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
2.3 HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) OR NOT COVERED BY GHS: NONE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1 SUBSTANCES:
FORMULA: CS2
MOLECULAR WEIGHT: 76.14 G/MOL
CAS-NO.: 75-15-0
EC-NO.: 200-843-6
INDEX-NO.: 006-003-00-3
HAZARDOUS COMPONENTS:
COMPONENT CLASSIFICATION CONCENTRATION
CARBON DISULPHIDE FLAM. LIQ. 2; ACUTE TOX. 4; <=100%
SKIN IRRIT. 2; EYE IRRIT. 2A; REPR.
2; STOT RE 1; AQUATIC ACUTE
2; H225, H315, H319, H332,
H361, H372, H401
FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.
| 4. FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
CONSULT A PHYSICIAN. SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN
ATTENDANCE. MOVE OUT OF DANGEROUS AREA.
IF INHALED:
IF BREATHED IN, MOVE PERSON INTO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. CONSULT A PHYSICIAN.
IN CASE OF SKIN CONTACT:
WASH OFF WITH SOAP AND PLENTY OF WATER. TAKE VICTIM IMMEDIATELY TO
HOSPITAL. CONSULT A PHYSICIAN.
IN CASE OF EYE CONTACT:
RINSE THOROUGHLY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND CONSULT A
PHYSICIAN.
IF SWALLOWED:
DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. RINSE MOUTH WITH WATER. CONSULT A PHYSICIAN.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
THE MOST IMPORTANT KNOWN SYMPTOMS AND EFFECTS ARE DESCRIBED IN THE
LABELING (SEE SECTION 2.2) AND/OR IN SECTION 11
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO DATA AVAILABLE
| 5. FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE WATER SPRAY, ALCOHOL-RESISTANT FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FLASH BACK POSSIBLE OVER CONSIDERABLE DISTANCE., CONTAINER EXPLOSION MAY
OCCUR UNDER FIRE CONDITIONS., VAPOURS MAY FORM EXPLOSIVE MIXTURE WITH AIR.,
MAY EXPLODE WHEN HEATED.
5.3 ADVICE FOR FIREFIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS FOR FIREFIGHTING IF NECESSARY.
5.4 FURTHER INFORMATION: USE WATER SPRAY TO COOL UNOPENED CONTAINERS.
| 6. ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT. AVOID BREATHING VAPOURS, MIST OR GAS.
ENSURE ADEQUATE VENTILATION. REMOVE ALL SOURCES OF IGNITION. EVACUATE
PERSONNEL TO SAFE AREAS. BEWARE OF VAPOURS ACCUMULATING TO FORM EXPLOSIVE
CONCENTRATIONS. VAPOURS CAN ACCUMULATE IN LOW AREAS.
FOR PERSONAL PROTECTION SEE SECTION 8.
6.2 ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT LET PRODUCT
ENTER DRAINS. DISCHARGE INTO THE ENVIRONMENT MUST BE AVOIDED.
6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILLAGE, AND THEN COLLECT WITH AN ELECTRICALLY PROTECTED VACUUM
CLEANER OR BY WET-BRUSHING AND PLACE IN CONTAINER FOR DISPOSAL ACCORDING
TO LOCAL REGULATIONS (SEE SECTION 13).
6.4 REFERENCE TO OTHER SECTIONS: FOR DISPOSAL SEE SECTION 13.
| 7. HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH SKIN AND EYES. AVOID INHALATION OF VAPOUR OR MIST.
USE EXPLOSION-PROOF EQUIPMENT. KEEP AWAY FROM SOURCES OF IGNITION - NO
SMOKING. TAKE MEASURES TO PREVENT THE BUILD UP OF ELECTROSTATIC CHARGE.
FOR PRECAUTIONS SEE SECTION 2.2.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
CONTAINERS WHICH ARE OPENED MUST BE CAREFULLY RESEALED AND KEPT
UPRIGHT TO PREVENT LEAKAGE.
REFRIGERATE BEFORE OPENING.
7.3 SPECIFIC END USE(S):
APART FROM THE USES MENTIONED IN SECTION 1.2 NO OTHER SPECIFIC USES ARE
STIPULATED
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENT CAS-NO. VALUE CONTROL BASIS
PARAMETERS
CARBON DISULPHIDE 75-15-0 TWA 1 PPM USA. ACGIH THRESHOLD
LIMIT VALUES (TLV)
REMARKS PERIPHERAL NERVOUS SYSTEM IMPAIRMENT
SUBSTANCES FOR WHICH THERE IS A BIOLOGICAL
EXPOSURE INDEX OR INDICES (SEE BEI(R*) SECTION)
NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
DANGER OF CUTANEOUS ABSORPTION
TWA 1.000000 PPM USA. ACGIH THRESHOLD
LIMIT VALUES (TLV)
PERIPHERAL NERVOUS SYSTEM IMPAIRMENT
SUBSTANCES FOR WHICH THERE IS A BIOLOGICAL
EXPOSURE INDEX OR INDICES (SEE BEI(R*) SECTION)
NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
DANGER OF CUTANEOUS ABSORPTION
TWA 20.000000 PPM USA. OCCUPATIONAL
EXPOSURE LIMITS (OSHA) -
TABLE Z-2
Z37.3-1968
CEIL 30.000000 PPM USA. OCCUPATIONAL
EXPOSURE LIMITS (OSHA) -
TABLE Z-2
Z37.3-1968
PEAK 100.000000 USA. OCCUPATIONAL
PPM EXPOSURE LIMITS
(OSHA) - TABLE Z-2
Z37.3-1968
TWA 1.000000 PPM USA. NIOSH RECOMMENDED
3.000000 EXPOSURE LIMITS
MG/M3
POTENTIAL FOR DERMAL ABSORPTION
ST 10.000000 PPM USA. NIOSH RECOMMENDED
30.000000 EXPOSURE LIMITS
MG/M3
POTENTIAL FOR DERMAL ABSORPTION
SEE TABLE Z-2
TWA 20 PPM USA. OCCUPATIONAL
EXPOSURE LIMITS (OSHA) -
TABLE Z-2
Z37.3-1968
CEIL 30 PPM USA. OCCUPATIONAL
EXPOSURE LIMITS (OSHA) -
TABLE Z-2
Z37.3-1968
PEAK 100 PPM USA. OCCUPATIONAL
EXPOSURE LIMITS (OSHA) -
TABLE Z-2
Z37.3-1968
PEL 1 PPM CALIFORNIA PERMISSIBLE
3 MG/M3 EXPOSURE LIMITS FOR
CHEMICAL CONTAMINANTS
(TITLE 8, ARTICLE 107)
SKIN
STEL 12 PPM CALIFORNIA PERMISSIBLE
36 MG/M3 EXPOSURE LIMITS FOR
CHEMICAL CONTAMINANTS
(TITLE 8, ARTICLE 107)
SKIN
C 30 PPM CALIFORNIA PERMISSIBLE
EXPOSURE LIMITS FOR
CHEMICAL CONTAMINANTS
(TITLE 8, ARTICLE 107)
SKIN
BIOLOGICAL OCCUPATIONAL EXPOSURE LIMITS:
COMPONENT CAS-NO. PARAMETERS VALUE BIOLOGICAL BASIS
SPECIMEN
CARBON DISULPHIDE 75-15-0 2- 0.5000 URINE ACGIH -
THIOTHIAZOLIDI MG/G BIOLOGICAL
NE-4- EXPOSURE
CARBOXYLIX INDICES
ACID (TTCA) (BEI)
REMARKS END OF SHIFT (AS SOON AS POSSIBLE AFTER
EXPOSURE CEASES)
8.2 EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
FACE SHIELD AND SAFETY GLASSES USE EQUIPMENT FOR EYE PROTECTION TESTED AND
APPROVED UNDER APPROPRIATE GOVERNMENT STANDARDS SUCH AS NIOSH (US) OR EN
166(EU).
SKIN PROTECTION:
HANDLE WITH GLOVES. GLOVES MUST BE INSPECTED PRIOR TO USE. USE PROPER GLOVE
REMOVAL TECHNIQUE (WITHOUT TOUCHING GLOVE'S OUTER SURFACE) TO AVOID SKIN
CONTACT WITH THIS PRODUCT. DISPOSE OF CONTAMINATED GLOVES AFTER USE IN
ACCORDANCE WITH APPLICABLE LAWS AND GOOD LABORATORY PRACTICES. WASH AND
DRY HANDS.
FULL CONTACT:
MATERIAL: FLUORINATED RUBBER
MINIMUM LAYER THICKNESS: 0.7 MM
BREAK THROUGH TIME: 480 MIN
MATERIAL TESTED: VITOJECT(R*) (KCL 890 / ALDRICH Z677698, SIZE M)
SPLASH CONTACT:
MATERIAL: FLUORINATED RUBBER
MINIMUM LAYER THICKNESS: 0.7 MM
BREAK THROUGH TIME: 480 MIN
MATERIAL TESTED: VITOJECT(R*) (KCL 890 / ALDRICH Z677698, SIZE M)
DATA SOURCE:
KCL GMBH, D-36124 EICHENZELL, PHONE +49 (0)6659 87300, E-MAIL SALES@KCL.DE,
TEST METHOD: EN374
IF USED IN SOLUTION, OR MIXED WITH OTHER SUBSTANCES, AND UNDER CONDITIONS
WHICH DIFFER FROM EN 374, CONTACT THE SUPPLIER OF THE CE APPROVED GLOVES.
THIS RECOMMENDATION IS ADVISORY ONLY AND MUST BE EVALUATED BY AN INDUSTRIAL
HYGIENIST AND SAFETY OFFICER FAMILIAR WITH THE SPECIFIC SITUATION OF
ANTICIPATED USE BY OUR CUSTOMERS. IT SHOULD NOT BE CONSTRUED AS OFFERING AN
APPROVAL FOR ANY SPECIFIC USE SCENARIO.
BODY PROTECTION:
COMPLETE SUIT PROTECTING AGAINST CHEMICALS, FLAME RETARDANT ANTISTATIC
PROTECTIVE CLOTHING., THE TYPE OF PROTECTIVE EQUIPMENT MUST BE SELECTED
ACCORDING TO THE CONCENTRATION AND AMOUNT OF THE DANGEROUS SUBSTANCE AT
THE SPECIFIC WORKPLACE.
RESPIRATORY PROTECTION:
WHERE RISK ASSESSMENT SHOWS AIR-PURIFYING RESPIRATORS ARE APPROPRIATE USE
A FULL-FACE RESPIRATOR WITH MULTIPURPOSE COMBINATION (US) OR TYPE AXBEK
(EN 14387) RESPIRATOR CARTRIDGES AS A BACKUP TO ENGINEERING CONTROLS. IF
THE RESPIRATOR IS THE SOLE MEANS OF PROTECTION, USE A FULL-FACE SUPPLIED
AIR RESPIRATOR. USE RESPIRATORS AND COMPONENTS TESTED AND APPROVED UNDER
APPROPRIATE GOVERNMENT STANDARDS SUCH AS NIOSH (US) OR CEN (EU).
CONTROL OF ENVIRONMENTAL EXPOSURE:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT LET PRODUCT
ENTER DRAINS. DISCHARGE INTO THE ENVIRONMENT MUST BE AVOIDED.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
A) APPEARANCE:
FORM: LIQUID
COLOUR: COLOURLESS
B) ODOUR: STENCH.
C) ODOUR THRESHOLD: NO DATA AVAILABLE
D) PH: NO DATA AVAILABLE
E) MELTING POINT/FREEZING POINT:
MELTING POINT/RANGE: -112 DEG. C (-170 DEG. F) - LIT.
F) INITIAL BOILING POINT AND BOILING RANGE: 46 DEG. C (115 DEG. F) - LIT.
G) FLASH POINT: -30 DEG. C (-22 DEG. F) - CLOSED CUP
H) EVAPORATION RATE: NO DATA AVAILABLE
I) FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
J) UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
UPPER EXPLOSION LIMIT: 50%(V)
LOWER EXPLOSION LIMIT: 1.3%(V)
K) VAPOUR PRESSURE:
394.956 HPA (296.241 MMHg) AT 20 DEG. C (68 DEG. F)
1,342.711 HPA (1,007.116 MMHg) AT 55 DEG. C (131 DEG. F)
L) VAPOUR DENSITY: 2.63 - (AIR = 1.0)
M) RELATIVE DENSITY: 1.266 G/ML AT 25 DEG. C (77 DEG. F)
N) WATER SOLUBILITY:
2.9 G/L AT 20 DEG. C (68 DEG. F) - OECD TEST GUIDELINE 105
O) PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 2.7 AT 25 DEG. C (77 DEG. F)
P) AUTO-IGNITION TEMPERATURE: 97 - 107 DEG. C (207 - 225 DEG. F)
Q) DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
R) VISCOSITY: NO DATA AVAILABLE
S) EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
T) OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2 OTHER SAFETY INFORMATION:
SURFACE TENSION: 71.9 MN/M AT 19.5 DEG. C (67.1 DEG. F)
RELATIVE VAPOUR DENSITY: 2.63 - (AIR = 1.0)
| 10. STABILITY AND REACTIVITY | |
10.1 REACTIVITY: NO DATA AVAILABLE
10.2 CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
VAPOURS MAY FORM EXPLOSIVE MIXTURE WITH AIR.
10.4 CONDITIONS TO AVOID: HEAT, FLAMES AND SPARKS.
10.5 INCOMPATIBLE MATERIALS:
ALKALI METALS, ZINC, AMINES, AZIDES, OXIDIZING AGENTS
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS DECOMPOSITION PRODUCTS FORMED UNDER FIRE CONDITIONS. - CARBON
OXIDES, SULPHUR OXIDES
OTHER DECOMPOSITION PRODUCTS - NO DATA AVAILABLE
IN THE EVENT OF FIRE: SEE SECTION 5
| 11. TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD50 ORAL - RAT - FEMALE: >2,000 MG/KG (OECD TEST GUIDELINE 423)
LC50 INHALATION - RAT - MALE AND FEMALE - 4 H - 10.35 MG/L
(OECD TEST GUIDELINE 403)
DERMAL: NO DATA AVAILABLE
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/EYE IRRITATION: NO DATA AVAILABLE
RESPIRATORY OR SKIN SENSITIZATION:
MOUSE
RESULT:
DOES NOT CAUSE SKIN SENSITIZATION.
(OECD TEST GUIDELINE 429)
GERM CELL MUTAGENICITY:
LABORATORY EXPERIMENTS HAVE SHOWN MUTAGENIC EFFECTS.
AMES TEST
SALMONELLA TYPHIMURIUM
RESULT: NEGATIVE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN
BY IARC.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL
TO 0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL
TO 0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
REPRODUCTIVE TOXICITY:
SUSPECTED HUMAN REPRODUCTIVE TOXICANT
MAY CAUSE REPRODUCTIVE DISORDERS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
ADDITIONAL INFORMATION:
RTECS: FF6650000
MAY CAUSE CONVULSIONS.
LIVER - IRREGULARITIES - BASED ON HUMAN EVIDENCE
| 12. ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
TOXICITY TO FISH:
LC50 - POECILIA RETICULATA (GUPPY) - 4 MG/L - 96 H
(OECD TEST GUIDELINE 203)
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
IMMOBILIZATION EC50 - DAPHNIA MAGNA (WATER FLEA) - 2.1 MG/L - 48 H
(OECD TEST GUIDELINE 202)
TOXICITY TO ALGAE:
GROWTH INHIBITION EC50 - CHLORELLA PYRENOIDOSA - 21 MG/L - 96 H
(OECD TEST GUIDELINE 201)
12.2 PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY:
AEROBIC - EXPOSURE TIME 28 D
RESULT: >80% - READILY BIODEGRADABLE
(OECD TEST GUIDELINE 301D)
12.3 BIOACCUMULATIVE POTENTIAL:
12.4 MOBILITY IN SOIL: NO DATA AVAILABLE
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
PBT/VPVB ASSESSMENT NOT AVAILABLE AS CHEMICAL SAFETY ASSESSMENT NOT
REQUIRED/NOT CONDUCTED
12.6 OTHER ADVERSE EFFECTS:
AN ENVIRONMENTAL HAZARD CANNOT BE EXCLUDED IN THE EVENT OF UNPROFESSIONAL
HANDLING OR DISPOSAL. TOXIC TO AQUATIC LIFE.
NO DATA AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
PRODUCT:
BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER
BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY FLAMMABLE.
OFFER SURPLUS AND NON-RECYCLABLE SOLUTIONS TO A LICENSED DISPOSAL COMPANY.
CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL SERVICE TO DISPOSE OF THIS
MATERIAL.
CONTAMINATED PACKAGING: DISPOSE OF AS UNUSED PRODUCT.
| 14. TRANSPORT INFORMATION | |
DOT (US):
UN NUMBER: 1131
CLASS: 3 (6.1)
PACKING GROUP: I
PROPER SHIPPING NAME: CARBON DISULFIDE
REPORTABLE QUANTITY (RQ): 100 LBS
POISON INHALATION HAZARD: NO
IMDG:
UN NUMBER: 1131
CLASS: 3 (6.1)
PACKING GROUP: I
EMS-NO: F-E, S-D
PROPER SHIPPING NAME: CARBON DISULPHIDE
IATA:
UN NUMBER: 1131
CLASS: 3 (6.1)
PROPER SHIPPING NAME: CARBON DISULPHIDE
IATA PASSENGER: NOT PERMITTED FOR TRANSPORT
IATA CARGO: NOT PERMITTED FOR TRANSPORT
| 15. REGULATORY INFORMATION | |
SARA 302 COMPONENTS:
THE FOLLOWING COMPONENTS ARE SUBJECT TO REPORTING LEVELS ESTABLISHED BY
SARA TITLE III, SECTION 302:
CAS-NO. REVISION DATE
CARBON DISULPHIDE 75-15-0 2007-07-01
SARA 313 COMPONENTS:
THE FOLLOWING COMPONENTS ARE SUBJECT TO REPORTING LEVELS ESTABLISHED BY
SARA TITLE III, SECTION 313:
CAS-NO. REVISION DATE
CARBON DISULPHIDE 75-15-0 2007-07-01
SARA 311/312 HAZARDS:
FIRE HAZARD, ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
MASSACHUSETTS RIGHT TO KNOW COMPONENTS:
CAS-NO. REVISION DATE
CARBON DISULPHIDE 75-15-0 2007-07-01
PENNSYLVANIA RIGHT TO KNOW COMPONENTS:
CAS-NO. REVISION DATE
CARBON DISULPHIDE 75-15-0 2007-07-01
NEW JERSEY RIGHT TO KNOW COMPONENTS:
CAS-NO. REVISION DATE
CARBON DISULPHIDE 75-15-0 2007-07-01
CALIFORNIA PROP. 65 COMPONENTS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CAS-NO. REVISION DATE
CARBON DISULPHIDE 75-15-0 2008-06-17
| 16. OTHER INFORMATION | |
FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3.
ACUTE TOX.: ACUTE TOXICITY
AQUATIC ACUTE: ACUTE AQUATIC TOXICITY
EYE IRRIT.: EYE IRRITATION
FLAM. LIQ.: FLAMMABLE LIQUIDS
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
H372:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE IF INHALED.
H401: TOXIC TO AQUATIC LIFE.
REPR.: REPRODUCTIVE TOXICITY
HMIS RATING:
HEALTH HAZARD 2
CHRONIC HEALTH HAZARD *
FLAMMABILITY 3
PHYSICAL HAZARD 0
NFPA RATING:
HEALTH HAZARD 2
FIRE HAZARD 3
REACTIVITY HAZARD 0
FURTHER INFORMATION:
COPYRIGHT 2016 SIGMA-ALDRICH CO. LLC.
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PREPARATION INFORMATION:
SIGMA-ALDRICH CORPORATION
PRODUCT SAFETY - AMERICAS REGION
1-800-521-8956
VERSION: 5.8
REVISION DATE: 08/10/2016
PRINT DATE: 05/19/2017
SIGMA-ALDRICH - 180173