| Common Name: | SPECTRACIDE WEED & GRASS KILLER WITH EXTENDED CONTROL CONCENTRATE |
| Manufacturer: | CHEMSICO |
| SDS Revision Date: | 4/10/2018 |
| SDS Format: | No Format Specified |
| Item Number(s): | 48LY78, 799UW6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
SPECTRACIDE WEED & GRASS KILLER WITH EXTENDED CONTROL CONCENTRATE
REVISION DATE: 4/10/2018
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIERS:
PRODUCT NAME:
SPECTRACIDE WEED & GRASS KILLER WITH EXTENDED CONTROL CONCENTRATE
EPA REGISTRATION NUMBER: 9688-259-8845
PRODUCT USE: HERBICIDE CONCENTRATE - NON-SELECTIVE
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
CHEMSICO
DIVISION OF UNITED INDUSTRIES CORP.
P.O. BOX 142642
ST. LOUIS, MO 63114-0642
FOR PRODUCT INFORMATION: 1-800-917-5438
FOR MEDICAL EMERGENCIES: 1-800-633-2873
| SECTION 2 - HAZARDS IDENTIFICATION | |
CONFORMS TO HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200.
GHS CLASSIFICATION OF SUBSTANCE OR MIXTURE:
PHYSICAL HAZARDS GHS CLASSIFICATION: NOT CLASSIFIED AS A PHYSICAL HAZARD
HEALTH HAZARD GHS CLASSIFICATION:
PRIMARY SKIN IRRITANT - CATEGORY 2
PRIMARY EYE IRRITANT - CATEGORY 2
GHS LABEL ELEMENTS:
HAZARD PICTOGRAM(S): EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
CAUSES SKIN IRRITATION
CAUSES EYE IRRITATION
PRECAUTIONARY STATEMENTS:
WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING. WEAR PROTECTIVE GLOVES.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION/ADVICE.
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION/ADVICE.
| SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS# WEIGHT PERCENT
DIQUAT DIBROMIDE 85-00-7 2.30%
FLUAZIFOP-P-BUTYL 79241-46-6 1.15%
DICAMBA, DIMETHYLAMINE SALT 2300-66-5 0.77%
OXYFLUORFEN 42874-03-3 1.92%
ETHYL 3-ETHOXYPROPIONATE 763-69-9 10.00%
NOTE:
INGREDIENTS NOT IDENTIFIED ARE PROPRIETARY OR NON-HAZARDOUS. VALUES ARE NOT
PRODUCT SPECIFICATIONS.
| SECTION 4 - FIRST AID MEASURES | |
EYE CONTACT:
HOLD EYE OPEN AND RINSE SLOWLY AND GENTLY WITH WATER FOR 15-20 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST 5 MINUTES, THEN CONTINUE
RINSING. CALL A POISON CONTROL CENTER OR DOCTOR FOR TREATMENT ADVICE.
SKIN CONTACT:
TAKE OFF CONTAMINATED CLOTHING. RINSE SKIN IMMEDIATELY WITH PLENTY OF WATER
FOR 15-20 MINUTES. CALL A POISON CONTROL CENTER OR DOCTOR FOR TREATMENT
ADVICE.
INHALATION: NO SPECIAL REQUIREMENTS
INGESTION: NO SPECIAL REQUIREMENTS
NOTES TO PHYSICIAN:
PROBABLE MUCOSAL DAMAGE MAY CONTRAINDICATE THE USE OF GASTRIC LAVAGE.
GENERAL ADVICE:
IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. KEEP OUT OF REACH OF CHILDREN.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLAMMABLE PROPERTIES: NOT FLAMMABLE BY OSHA CRITERIA.
SUITABLE EXTINGUISHING MEDIA: WATER FOG, FOAM, CO2, DRY CHEMICAL
UNSUITABLE EXTINGUISHING MEDIA: NOT AVAILABLE
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTAINER MAY MELT AND LEAK IN HEAT OF FIRE. DO NOT ALLOW RUN-OFF FROM
FIREFIGHTING TO ENTER DRAINS OR WATER COURSES.
PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE CLOTHING INCLUDING SELF-CONTAINED
BREATHING APPARATUS.
HAZARDOUS COMBUSTION PRODUCTS: NONE KNOWN
SENSITIVITY TO MECHANICAL IMPACT: NONE KNOWN
EXPLOSION DATA: NOT AVAILABLE
SENSITIVITY TO STATIC DISCHARGE: NOT AVAILABLE
PERSONAL PRECAUTIONS:
KEEP UNNECESSARY PERSONNEL AWAY. DO NOT TOUCH OR WALK THROUGH SPILLED
MATERIAL. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. KEEP PEOPLE AWAY FROM AND
UPWIND OF SPILL/LEAK.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
REMOVE ALL SOURCES OF IGNITION. WEAR PERSONAL PROTECTIVE EQUIPMENT. WASH
THOROUGHLY AFTER HANDLING.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS.
METHODS FOR CONTAINMENT AND CLEANING UP:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. BEFORE
ATTEMPTING CLEAN UP, REFER TO HAZARD DATA GIVEN ABOVE. SMALL SPILLS MAY BE
ABSORBED WITH EARTH, SAND OR ABSORBENT MATERIAL SWEPT UP AND PLACED IN
SUITABLE, COVERED, AND LABELED CONTAINERS. PREVENT LARGE SPILLS FROM
ENTERING SEWERS OR WATERWAYS. CONTACT EMERGENCY SERVICES AND SUPPLIER FOR
ADVICE. NEVER RETURN SPILLS IN ORIGINAL CONTAINERS FOR RE-USE.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT
USE NEAR HEAT, OPEN FLAME OR ANY OTHER IGNITION SOURCE. TAKE MEASURES TO
PREVENT THE BUILDUP OF ELECTROSTATIC CHARGE. AVOID CONTACT WITH SKIN, EYES
AND CLOTHING. USE AN APPROPRIATE RESPIRATOR WHEN ADEQUATE VENTILATION IS
NOT AVAILABLE. AVOID BREATHING VAPORS OR SPRAY MISTS OF THE PRODUCT.
STORAGE:
STORE PRODUCT IN A COOL, DRY PLACE, OUT OF REACH OF CHILDREN. KEEP
CONTAINER CLOSED WHEN NOT IN USE. KEEP AWAY FROM FOOD, DRINK AND ANIMAL
FEEDINGSTUFFS. KEEP TIGHTLY CLOSED. NON-REFILLABLE CONTAINER. DO NOT REUSE
OR REFILL THIS CONTAINER. PLACE IN TRASH OR OFFER FOR RECYCLING IF
AVAILABLE.
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
COMPONENTS WITH OCCUPATIONAL EXPOSURE LIMITS:
CHEMICAL NAME EXPOSURE LIMITS
OSHA PEL ACGIH TLV SUPPLIER OEL
PPM MG/M3 PPM MG/M3 PPM MG/M3
DIQUAT DIBROMIDE TWA NOT LISTED NOT LISTED NOT LISTED
FLUAZIFOP-P-BUTYL TWA NOT ESTABLISHED NOT ESTABLISHED 0.5
DICAMBA, DIMETHYL- TWA NOT ESTABLISHED 0.5 0.5
AMINE SALT
OXYFLUORFEN TWA 1.6 0.2 NOT LISTED
ETHYL 3-ETHOXY- TWA NOT LISTED NOT LISTED 50
PROPIONATE
ENGINEERING CONTROLS: GENERAL VENTILATION NORMALLY ADEQUATE.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
DURING APPLICATION, PREVENT ENTRY INTO EYES. WEAR SAFETY GLASSES WITH SIDE
SHIELDS IF USING IN LARGE APPLICATIONS. USE PROTECTIVE GLOVES WHEN USING
PRODUCT.
SKIN AND BODY PROTECTION: WEAR PROTECTIVE GLOVES. WASH HANDS HANDLING.
RESPIRATORY PROTECTION:
WHERE EXPOSURE GUIDELINE LEVELS MAY BE EXCEEDED, USE AN APPROVED NIOSH
RESPIRATOR.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE. WHEN
USING, DO NOT EAT OR DRINK. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER
HANDLING THE PRODUCT.
| SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR
COLOR: DARK AMBER
PHYSICAL STATE: LIQUID
ODOR: SOLVENT
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 5.0 - 7.0
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: >200 DEG. F
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY LIMITS IN AIR, LOWER, % BY VOLUME: NO DATA AVAILABLE
FLAMMABILITY LIMITS IN AIR, UPPER, % BY VOLUME: NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY @ 20 DEG. C: 1.03
OCTANOL/WATER COEFFICIENT: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
SOLUBILITY: SOLUBLE IN WATER
% VOLATILE ORGANIC COMPOUNDS: .01%
| SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION | |
REACTIVITY:
CONDITIONS TO AVOID: DO NOT MIX WITH OTHER CHEMICALS.
INCOMPATIBLE MATERIALS: AVOID STRONG OXIDIZERS.
CHEMICAL STABILITY:
PRODUCT STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
OTHER:
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
PRIMARY EYE IRRITATION:
CAUSES MODERATE EYE IRRITATION (EPA TOX. CATEGORY III)
PRIMARY SKIN IRRITATION: CAUSES SKIN IRRITATION (EPA TOX. CATEGORY II)
ACUTE DERMAL: LD50 >5000 MG/KG (EPA TOX. CATEGORY IV)
ACUTE INHALATION: LC50 >2 MG/L (EPA TOX. CATEGORY IV)
ACUTE ORAL: LD50 >5000 MG/KG (EPA TOX. CATEGORY IV)
SENSITIZATION: NOT A SKIN SENSITIZER.
CHRONIC EFFECTS: NO DATA AVAILABLE
CARCINOGENICITY: NO DATA AVAILABLE
MUTAGENICITY: NO DATA AVAILABLE
REPRODUCTIVE EFFECTS: NO DATA AVAILABLE
TERATOGENICITY: NO DATA AVAILABLE
ECOTOXICITY: NO DATA AVAILABLE
| SECTION 12 - ECOLOGICAL INFORMATION | |
ENVIRONMENTAL EFFECTS: NO DATA AVAILABLE
AQUATIC TOXICITY: TOXIC TO AQUATIC ORGANISMS.
PERSISTENCE / DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATION / ACCUMULATION: NO DATA AVAILABLE
PARTITION COEFFICIENT: NO DATA AVAILABLE
MOBILITY IN ENVIRONMENTAL MEDIA: NO DATA AVAILABLE
CHEMICAL FATE INFORMATION: NO DATA AVAILABLE
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE CODES: NOT AVAILABLE
DISPOSAL INSTRUCTIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
WASTE FROM RESIDUES/UNUSED PRODUCTS: NOT AVAILABLE
CONTAMINATED PACKAGING: NOT AVAILABLE
| SECTION 14 - TRANSPORTATION INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION (DOT): NOT REGULATED
IATA:
FOR QUANTITIES <5KG/5L SHIP AS: NOT REGULATED
FOR QUANTITIES >/=5KG/5L SHIP AS:
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.,
(FLUAZIFOP-P-BUTYL), LIMITED QUANTITY, 9, III
IMDG:
FOR QUANTITIES <5KG/5L SHIP AS: NOT REGULATED
FOR QUANTITIES >/=5KG/5L SHIP AS:
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.,
(FLUAZIFOP-P-BUTYL), LIMITED QUANTITY, 9, III
| SECTION 15 - REGULATORY INFORMATION | |
29 CFR 1910.1200 HAZARDOUS CHEMICAL OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION (OSHA): NO
CERCLA (SUPERFUND) REPORTABLE QUANTITY: NOT AVAILABLE
HAZARD CATEGORIES:
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
IMMEDIATE HAZARD: NO
DELAYED HAZARD: NO
FIRE HAZARD: NO
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SECTION 311 HAZARDOUS CHEMICAL: NO
CLEAN AIR ACT (CAA): NOT AVAILABLE
CLEAN WATER ACT (CWA): NOT AVAILABLE
STATE REGULATIONS: NONE
FIFRA LABELING:
THIS CHEMICAL IS A PESTICIDE PRODUCT REGISTERED BY THE ENVIRONMENTAL
PROTECTION AGENCY AND IS SUBJECT TO CERTAIN LABELING REQUIREMENTS UNDER
FEDERAL PESTICIDE LAW. THESE REQUIREMENTS DIFFER FROM THE CLASSIFICATION
CRITERIA AND HAZARD INFORMATION REQUIRED FOR SAFETY DATA SHEETS, AND FOR
WORKPLACE NON-PESTICIDE CHEMICALS. FOLLOWING IS THE HAZARD INFORMATION AS
REQUIRED ON THE PESTICIDE LABEL:
SIGNAL WORD: WARNING
PRECAUTIONARY STATEMENTS:
CAUSES SKIN IRRITATION. CAUSES MODERATE EYE IRRITATION. DO NOT GET ON SKIN
OR CLOTHING. AVOID CONTACT WITH EYES OR CLOTHING. WASH THOROUGHLY WITH SOAP
AND WATER AFTER HANDLING AND BEFORE EATING, DRINKING, CHEWING GUM OR USING
TOBACCO.
THIS PESTICIDE IS TOXIC TO AQUATIC INVERTEBRATES. TO PROTECT THE
ENVIRONMENT, DO NOT ALLOW PESTICIDE TO ENTER OR RUN OFF INTO STORM DRAINS,
DRAINAGE DITCHES, GUTTERS OR SURFACE WATERS. APPLYING THIS PRODUCT IN CALM
WEATHER WHEN RAIN IS NOT PREDICTED FOR THE NEXT 24 HOURS WILL HELP ENSURE
THAT WIND OR RAIN DOES NOT BLOW OR WASH PESTICIDE OFF THE TREATMENT AREA.
RINSING APPLICATION EQUIPMENT OVER THE TREATED AREA WILL HELP AVOID RUNOFF
TO WATER BODIES OR DRAINAGE SYSTEMS.
NOTIFICATION STATUS:
ALL INGREDIENTS OF THIS PRODUCT ARE LISTED OR ARE EXCLUDED FROM LISTING ON
THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCE INVENTORY.
CALIFORNIA PROP. 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR ANY OTHER REPRODUCTIVE HARM.
DISCLAIMER:
INFORMATION CONTAINED HEREIN WAS OBTAINED FROM SOURCES CONSIDERED
TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY EFFORT HAS BEEN MADE TO
ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME CASES DATA IS NOT
AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL PRODUCT USE ARE
BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF THIS MATERIAL
HAVE BEEN FULLY TRAINED ACCORDING TO THE REQUIREMENTS OF ALL APPLICABLE
LEGISLATION AND REGULATORY INSTRUMENTS. NO WARRANTY, EXPRESSED OR IMPLIED,
IS MADE AND SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES, INJURIES OR
CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR RELIANCE ON ANY
INFORMATION CONTAINED IN THIS DOCUMENT.
| SECTION 16 - OTHER INFORMATION | |
HMIS RATINGS:
HEALTH HAZARD 2
FLAMMABILITY 0
PHYSICAL HAZARD 0
ITEM NUMBER(S): HG-95963; HG-96391; HG-96622; HG-96628
FORMULA NUMBER(S): 21-1141
ISSUE DATE: 3/1/2016
PREPARED BY:
SPECTRUM GROUP
DIVISION OF UNITED INDUSTRIES CORP.
P.O. BOX 142642
ST. LOUIS, MO 63114-0642
(800) 242-1166