| Common Name: | STANADYNE GASOLINE ADDITIVE |
| Manufacturer: | CLARCOR |
| SDS Revision Date: | 8/25/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 48NT75 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CLARCOR
SAFETY DATA SHEET
MATERIAL NAME: STANADYNE GASOLINE ADDITIVE
| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NUMBERS:
38557 (8OZ./237ML); 45696 (12OZ./355ML); 38558 (55GAL./208L)
CHEMICAL NAME: MIXTURE
PRODUCT USE: GASOLINE FUEL ADDITIVE
COMPANY INFORMATION:
CLARCOR INC.
840 CRESCENT CENTRE DRIVE
SUITE 600
FRANKLIN, TN 37067
U.S.A.
PHONE: 1-800-842-2496
EMERGENCY #:
CHEMTREC: 1-800-424-9300
CHEMTREC (OUTSIDE US & CANADA): 1-703-527-3887
| SECTION 2 - HAZARDS IDENTIFICATION | |
A. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE LIQUID 4:
H227: COMBUSTIBLE LIQUID.
SKIN IRRITATION 2:
H315: CAUSES SKIN IRRITATION.
SKIN SENSITIZATION 1:
H317: MAY CAUSE AN ALLERGIC REACTION.
CARCINOGENICITY 2:
H351: SUSPECTED OF CAUSING CANCER.
STOT-SE 3:
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
ASPIRATION HAZARD 1:
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
OSHA DEFINED HAZARDS: NONE
B. LABEL ELEMENTS:
1. OSHA:
EXCLAMATION MARK
HEALTH HAZARD
DANGER:
COMBUSTIBLE LIQUID. CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN
REACTION. SUSPECTED OF CAUSING CANCER. MAY CAUSE DROWSINESS OR DIZZINESS.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
OBTAIN SPECIAL INSTRUCTION BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM FLAMES AND HOT
SURFACES. NO SMOKING. WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE
PROTECTION. WASH THOROUGHLY AFTER HANDLING. AVOID BREATHING MIST/VAPORS/
SPRAY. CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE
WORKPLACE. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR. DO NOT INDUCE VOMITING.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR IF YOU FEEL UNWELL.
IF ON SKIN:
WASH WITH PLENTY OF WATER. IF SKIN IRRITATION OCCURS: GET MEDICAL
ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. KEEP COOL. KEEP
CONTAINER TIGHTLY CLOSED. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE
WITH LOCAL/REGIONAL/NATIONAL REGULATIONS.
OTHER HAZARDS: NONE IDENTIFIED.
2. CONSUMER PRODUCTS:
FRONT:
DANGER:
HARMFUL OR FATAL IF SWALLOWED. VAPOR HARMFUL. CAUSES SKIN IRRITATION.
KEEP OUT OF REACH OF CHILDREN. SEE BACK PANEL FOR ADDITIONAL HAZARDS
AND PRECAUTIONS.
BACK:
HAZARDS:
CONTAINS PETROLEUM DISTILLATES, BUTYLATED PHENOL, 2-ETHYLHEXANOL,
ETHOXYLATED AMINE AND NAPHTHALENE. HARMFUL OR FATAL IF SWALLOWED. CAUSES
SKIN IRRITATION. MAY CAUSE AN ALLERGIC REACTION. MAY CAUSE DROWSINESS OR
DIZZINESS. CONTAINS SMALL AMOUNT OF NAPHTHALENE WHICH IS SUSPECTED OF
CAUSING CANCER.
PRECAUTION:
KEEP AWAY FROM HEAT OR FLAME. AVOID SWALLOWING, CONTACT WITH EYES OR
SKIN, OR BREATHING VAPOR. WASH IMMEDIATELY AFTER CONTACT. USE IN A WELL
VENTILATED AREA.
FIRST AID:
IF SWALLOWED, DO NOT INDUCE VOMITING - CALL PHYSICIAN IMMEDIATELY. IN CASE
OF CONTACT, FLUSH EYES WITH WATER AND WASH SKIN WITH SOAP AND WATER. IF
EYE DISCOMFORT PERSISTS, CONTACT A PHYSICIAN. IF AFFECTED BY VAPOR, GET
FRESH AIR - CALL PHYSICIAN IF SYMPTOMS PERSIST.
| SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS | |
CAS # CHEMICAL NAME PERCENT INGREDIENT CLASSIFICATION
(W/W)
64742-47-8 DISTILLATES, 60-80 FLAM. LIQ. 4 - H227; SKIN
PETROLEUM, IRRIT. 2 - H315; STOT-SE
HYDROTREATED LIGHT 3 - H304; ASP. 1 - H304;
AQUATIC CHRON. 2 - H411
64741-86-2 DISTILLATES, 7-13 FLAM. LIQ. 3 - H226;
PETROLEUM, ACUTE TOX. 4 - H332; SKIN
SWEETENED MIDDLE IRRIT. 2 - H315; ASP.
TOX. 1 - H304, AQUATIC
CHRON. 2-H411
64742-94-5 NAPHTHA (PETROLEUM), 5-7 FLAM. LIQ. 4 - H227; ASP.
HEAVY AROMATIC TOX. 1 - H304; SKIN
IRRIT. 2 - H315; STOT-SE
3 - H335-336; AQUATIC
CHRON. 2 - H411
128-39-2 2,6-DI-TERT 1-2 SKIN IRRIT. 2 - H315;
BUTYLPHENOL AQUATIC; AQUATIC CHRON.
1 - H410
104-76-7 2-ETHYLHEXANOL 1-2 ACUTE TOX. 4 - H332;
SKIN IRRIT. 2 - H315;
EYE IRRIT. 2 - H319;
STOT-SE 3 - H335
PROPRIETARY ETHOXYLATED AMINE 1-2 ACUTE TOX. 4 - H302; EYE
DAM. 1 - H318; MET. CORR.
- H290; SKIN CORR. 1C -
H314; SKIN SENS. 1 -
H317; AQUATIC ACUTE
1 - H400
91-20-3 NAPHTHALENE 0.1-0.5 ACUTE TOX. 4 - H302;
CARC. 2 - H351; AQUATIC
ACUTE 1 - H400; AQUATIC
CHRON. 1 - H410
COMPONENT RELATED REGULATORY INFORMATION:
THIS PRODUCT IS CONSIDERED HAZARDOUS UNDER 29 CFR 1910.1200 (HAZARD
COMMUNICATION). THE SPECIFIC CHEMICAL IDENTITY AND THE EXACT
CONCENTRATIONS OF ONE OR MORE OF THE ABOVE LISTED COMPONENTS IS
BEING WITHHELD AS A TRADE SECRET.
| SECTION 4 - FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
EYES:
QUICKLY AND GENTLY BLOT AWAY EXCESS CHEMICAL. IMMEDIATELY FLUSH THE
CONTAMINATED EYE(S) WITH LUKEWARM, GENTLY FLOWING WATER FOR 15 MINUTES OR
UNTIL THE CHEMICAL IS REMOVED, WHILE HOLDING THE EYELID(S) OPEN. TAKE CARE
NOT TO RINSE CONTAMINATED WATER INTO THE UNAFFECTED EYE OR ONTO THE FACE.
SEEK IMMEDIATE MEDICAL ATTENTION.
SKIN:
REMOVE CONTAMINATED CLOTHING. QUICKLY AND GENTLY BLOT AWAY EXCESS
CHEMICAL. WASH GENTLY AND THOROUGHLY WITH WARM WATER AND NON-ABRASIVE SOAP
FOR 15 MINUTES OR UNTIL THE CHEMICAL IS REMOVED. GET MEDICAL ATTENTION IF
SKIN DISORDER DEVELOPS.
INGESTION:
NEVER GIVE ANYTHING BY MOUTH IF VICTIM IS RAPIDLY LOSING CONSCIOUSNESS,
OR IS UNCONSCIOUS OR CONVULSING. HAVE VICTIM RINSE MOUTH THOROUGHLY WITH
WATER. DO NOT INDUCE VOMITING. HAVE VICTIM DRINK 8 TO 10 OZ. OF WATER TO
DILUTE MATERIAL IN STOMACH. IF VOMITING OCCURS NATURALLY, HAVE VICTIM LEAN
FORWARD TO REDUCE RISK OF ASPIRATION. REPEAT ADMINISTRATION OF WATER. SEEK
IMMEDIATE MEDICAL ATTENTION OR ADVICE.
INHALATION:
IF AFFECTED, REMOVE SOURCE OF CONTAMINATION OR MOVE INDIVIDUAL TO FRESH
AIR. IF THE AFFECTED PERSON IS NOT BREATHING, TRAINED PERSONNEL SHOULD
BEGIN ARTIFICIAL RESPIRATION IMMEDIATELY. SEEK MEDICAL ATTENTION IF
SYMPTOMS PERSIST. IF OVERCOME BY VAPOR FROM HOT PRODUCT, IMMEDIATELY
REMOVE TO FRESH AIR AND CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
POTENTIAL HEALTH EFFECTS:
EYES:
THIS PRODUCT MAY BE IRRITATING TO THE EYES. EFFECTS MAY INCLUDE A BURNING
SENSATION, REDNESS, SWELLING AND/OR BLURRED VISION.
POTENTIAL HEALTH EFFECTS:
SKIN:
THIS PRODUCT IS IRRITATING TO THE SKIN. PROLONGED OR REPEATED CONTACT WITH
THIS PRODUCT MAY DRY AND/OR DEFAT THE SKIN. SYMPTOMS MAY INCLUDE REDNESS,
EDEMA, DRYING OR CRACKING OF SKIN. CONTACT MAY CAUSE AN ALLERGIC SKIN
REACTION IN SENSITIVE INDIVIDUALS. SEE SECTION 11 FOR ADDITIONAL
INFORMATION.
POTENTIAL HEALTH EFFECTS:
INGESTION:
THIS PRODUCT MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE
MOUTH. INGESTION OF THIS PRODUCT MAY CAUSE HEADACHE, DIZZINESS,
UNCOORDINATION, AND GENERAL WEAKNESS. SMALL AMOUNTS OF THIS PRODUCT,
IF ASPIRATED INTO THE LUNGS, MAY CAUSE MILD TO SEVERE PULMONARY INJURY,
POSSIBLY DEATH. SEE SECTION 11 FOR ADDITIONAL INFORMATION.
POTENTIAL HEALTH EFFECTS:
INHALATION:
HARMFUL IF INHALED. INHALATION OF OIL MISTS OR FUMES CAN CAUSE IRRITATION
OF THE MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. EXCESSIVE INHALATION
OF THIS MATERIAL CAUSES HEADACHE, DIZZINESS, NAUSEA, STUPOR, AND OTHER
CENTRAL NERVOUS SYSTEM EFFECTS LEADING TO VISUAL IMPAIRMENT, DIFFICULTY
BREATHING, MEMORY LOSS, CONVULSIONS AND UNCOORDINATION. BREATHING OF VAPOR
OR MIST MAY AGGRAVATE ASTHMA AND INFLAMMATORY OR FIBROTIC PULMONARY
DISEASE. SEE SECTION 11 FOR ADDITIONAL INFORMATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
PULMONARY ASPIRATION HAZARD IF SWALLOWED; TREAT SYMPTOMATICALLY.
| SECTION 5 - FIRE FIGHTING MEASURES | |
GENERAL FIRE HAZARDS:
FIRE AND EXPLOSION HAZARDS ARE MODERATE WHEN THIS PRODUCT IS EXPOSED TO
HEAT OR FLAME. LIQUID CAN BURN UPON HEATING TO TEMPERATURES AT OR ABOVE
THE FLASH POINT. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG THE
GROUND TO SOME DISTANT SOURCE OF IGNITION AND FLASH BACK.
EXTINGUISHING MEDIA:
DRY CHEMICAL, FOAM, CARBON DIOXIDE, WATER FOG. USE WATER TO COOL FIRE-
EXPOSED CONTAINERS AND TO PROTECT PERSONNEL. DIRECT WATER SPRAY OR FOAM
MAY CAUSE FROTHING AND SPATTERING. IF A LEAK OR SPILL HAS NOT IGNITED,
USE WATER SPRAY TO DISPERSE VAPORS AND TO FLUSH SPILLS AWAY FROM EXPOSURE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
IRRITATING AND TOXIC GASES OR FUMES MAY BE RELEASED DURING A FIRE. UPON
COMBUSTION, THIS PRODUCT MAY YIELD OXIDES OF NITROGEN CARBON MONOXIDE,
CARBON DIOXIDE, AND/OR OTHER LOW MOLECULAR WEIGHT HYDROCARBONS.
ADVICE FOR FIREFIGHTERS:
FIREFIGHTERS SHOULD WEAR FULL-FACE, SELF-CONTAINED BREATHING APPARATUS
AND IMPERVIOUS PROTECTIVE CLOTHING. FIREFIGHTERS SHOULD AVOID INHALING
ANY COMBUSTION PRODUCTS.
NFPA RATINGS:
HEALTH 2
FIRE 2
REACTIVITY 0
OTHER
HAZARD SCALE:
0 = MINIMAL
1 = SLIGHT
2 = MODERATE
3 = SERIOUS
4 = SEVERE
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ELIMINATE ALL SOURCES OF IGNITION OR FLAMMABLES THAT MAY COME INTO CONTACT
WITH A SPILL OF THIS PRODUCT. SURFACES MAY BECOME SLIPPERY AFTER SPILLAGE.
WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING DURING CLEANUP. DO NOT
ALLOW THE SPILLED PRODUCT TO ENTER PUBLIC DRAINAGE SYSTEMS OR OPEN
WATERCOURSES. IF PRODUCT IS SPILLED, NOTIFY APPROPRIATE AUTHORITIES AT
THE LOCAL, STATE, FEDERAL, AND PROVINCIAL LEVELS. PERSONS NOT WEARING
PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEANUP
HAS BEEN COMPLETED. STOP THE FLOW OF PRODUCT, IF THIS CAN BE DONE WITHOUT
RISK.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEAN-UP PROCEDURES:
ABSORB WITH NON-FLAMMABLE SUITABLE ABSORBENT SUCH AS SAND OR EARTH.
SCOOP UP USED ABSORBENT INTO DRUMS OR OTHER APPROPRIATE CONTAINER.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
AVOID PROLONGED OR REPEATED SKIN CONTACT WITH THIS PRODUCT. AVOID GETTING
THIS PRODUCT INTO CONTACT WITH YOUR EYES. AVOID THE GENERATION OF MISTS.
WASH THOROUGHLY AFTER HANDLING. USE THIS PRODUCT WITH ADEQUATE
VENTILATION. DISCARD ANY SHOES OR CLOTHING ITEMS THAT CANNOT BE
DECONTAMINATED.
CONDITIONS FOR SAFE STORAGE (INCLUDING ANY INCOMPATIBILITIES):
DO NOT STORE NEAR HEAT, SPARKS, OPEN FLAME OR STRONG OXIDIZING AGENTS. DO
NOT STORE THIS PRODUCT IN OPEN OR UNLABELED CONTAINERS. STORE DRUMS IN A
COVERED AREA WITH SECONDARY CONTAINMENT. "EMPTY" CONTAINERS RETAIN PRODUCT
RESIDUE (LIQUID AND/OR VAPOR) AND CAN BE DANGEROUS. DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT,
FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY
EXPLODE. FOLLOW APPROPRIATE GROUNDING PROCEDURES.
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
A:
GENERAL PRODUCT INFORMATION:
FOLLOW ALL APPLICABLE EXPOSURE LIMITS. UNDER CONDITIONS WHICH MAY GENERATE
MISTS, THE COMPONENT SUPPLIER RECOMMENDS THE OSHA PEL OF 5 MG/M3 AND THE
ACGIH STEL OF 10 MG/M3 FOR OIL MISTS. INCLUDED BELOW ARE THE OSHA VACATED
PERMISSIBLE EXPOSURE LIMITS (PELS).
B:
COMPONENT EXPOSURE LIMITS:
COMPOUND ACGIH NIOSH OSHA OTHER
TWA STEL TWA STEL TWA STEL TWA
PETROLEUM N/E N/E 350 MG/M3 1800 500 PPM N/E N/E
DISTILLATES (C) MG/M3 2000
MG/M3
TRIMETHYLBENZENE N/E N/E 25 PPM N/E N/E N/E N/E
NAPHTHALENE 10 15 10 PPM 15 PPM 10 PPM N/E N/E
PPM PPM
(S) - SKIN EXPOSURE
(C) - CEILING EXPOSURE
N/E - NONE ESTABLISHED
ENGINEERING CONTROLS:
USE GENERAL VENTILATION AND USE LOCAL EXHAUST, WHERE POSSIBLE, IN CONFINED
OR ENCLOSED SPACES.
PERSONAL PROTECTIVE EQUIPMENT:
EYES/FACE:
WEAR SAFETY GLASSES. WEAR CHEMICAL GOGGLES OR FACESHIELD IF MIST IS LIKELY
TO OCCUR.
SKIN:
USE IMPERVIOUS GLOVES. WEAR OIL-IMPERVIOUS GARMENTS IF CONTACT IS
UNAVOIDABLE.
RESPIRATORY:
IN THE EVENT OF EXCESSIVE EXPOSURE TO VAPORS/MISTS/FUMES, USE NIOSH/OSHA
APPROVED RESPIRATORY EQUIPMENT. RESPIRATOR SHOULD BE SELECTED ON THE BASIS
OF FORM AND CONCENTRATION OF CONTAMINANT.
GENERAL:
USE GOOD HYGIENE WHEN HANDLING PETROLEUM PRODUCT. LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. EXCESSIVE MISTING MAY CAUSE SLIPPERY FLOORS - WEAR
APPROPRIATE FOOTWEAR. EYE WASH FOUNTAINS ARE RECOMMENDED.
| SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES | |
APPEARANCE: AMBER COLORED
ODOR: OIL / SOLVENT
PHYSICAL STATE: LIQUID
ODOR THRESHOLD: NOT APPLICABLE
PH: NOT APPLICABLE
MELTING/FREEZING POINT: NOT DETERMINED
INITIAL BOILING POINT & RANGE: NOT DETERMINED
FLASH POINT: 158 DEG. F (70.0 DEG. C)
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NOT DETERMINED
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
AUTO-IGNITION TEMPERATURE: NOT DETERMINED
DECOMPOSITION TEMPERATURE: NOT DETERMINED
VAPOR DENSITY: NOT DETERMINED
VAPOR PRESSURE: NOT DETERMINED
SOLUBILITIES: NEGLIGIBLE
PARTITION COEFFICIENT: NOT DETERMINED
EVAPORATION RATE: NOT DETERMINED
VISCOSITY: NOT DETERMINED
RELATIVE DENSITY: 0.803
DENSITY: NOT DETERMINED
| SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION | |
REACTIVITY: NOT REACTIVE
CHEMICAL STABILITY: STABLE
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
CONDITIONS TO AVOID: HEAT, IGNITION SOURCES AND SPARKS.
INCOMPATIBILITY:
THIS PRODUCT MAY REACT WITH STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION:
DECOMPOSITION OF THIS PRODUCT MAY YIELD CARBON MONOXIDE, CARBON DIOXIDE
AND/OR LOW MOLECULAR WEIGHT HYDROCARBONS.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
DESCRIPTION OF THE VARIOUS TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION, SKIN
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS (INCLUDING IMMEDIATE AND DELAYED EFFECTS AND
CHRONIC EFFECTS FOR SHORT- AND LONG-TERM EXPOSURE):
THIS PRODUCT IS IRRITATING TO THE SKIN. EXCESSIVE INHALATION OF THIS
PRODUCT CAUSES HEADACHE, DIZZINESS AND INCOORDINATION. THIS PRODUCT MAY
CAUSE NERVOUS SYSTEM EFFECTS INCLUDING PERIPHERAL NEUROPATHY. THIS PRODUCT
CONTAINS A CHEMICAL(S) WHICH HAS BEEN SHOWN TO CAUSE CANCER IN LABORATORY
ANIMALS. A COMPONENT OF THIS PRODUCT HAS BEEN REPORTED TO CAUSE BIRTH
DEFECTS AND/OR OTHER REPRODUCTIVE HARM. COMPONENTS OF THIS PRODUCT MAY
HAVE ADVERSE EFFECTS ON THE BLOODFORMING SYSTEM. IRRITATING AND TOXIC
VAPORS MAY BE RELEASED UPON COMBUSTION OF PRODUCT.
POTENTIAL HEALTH EFFECTS:
EYES:
EFFECTS IN SENSITIVE INDIVIDUALS MAY INCLUDE A BURNING SENSATION, REDNESS,
SWELLING AND/OR BLURRED VISION.
POTENTIAL HEALTH EFFECTS:
SKIN:
THIS PRODUCT IS IRRITATING TO THE SKIN. PROLONGED OR REPEATED CONTACT WITH
THIS PRODUCT MAY DRY AND/OR DEFAT THE SKIN. SYMPTOMS MAY INCLUDE REDNESS,
EDEMA, DRYING OR CRACKING OF SKIN. PRODUCT CONTAINS COMPONENT(S) THAT CAN
BE HARMFUL IF ABSORBED THROUGH THE SKIN. PRODUCT CONTAINS COMPONENT(S)
THAT MAY CAUSE AN ALLERGIC SKIN REACTION IN SUSCEPTIBLE INDIVIDUALS.
POTENTIAL HEALTH EFFECTS:
INGESTION:
THIS PRODUCT MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE
MOUTH, GASTROINTESTINAL LINING, NAUSEA, VOMITING, DIARRHEA, AND ABDOMINAL
PAIN. INGESTION OF THIS PRODUCT MAY CAUSE HEADACHE, DIZZINESS,
UNCOORDINATION, AND GENERAL WEAKNESS. SMALL AMOUNTS OF THIS PRODUCT, IF
ASPIRATED INTO THE LUNGS, MAY CAUSE MILD TO SEVERE PULMONARY INJURY,
POSSIBLY DEATH. INGESTION OF THIS PRODUCT MAY CAUSE RED BLOOD CELL
HEMOLYSIS AND POSSIBLE LIVER AND KIDNEY INJURY.
POTENTIAL HEALTH EFFECTS:
INHALATION:
INHALATION OF OIL MISTS OR FUMES CAN CAUSE IRRITATION OF THE MUCOUS
MEMBRANES AND UPPER RESPIRATORY TRACT. EXCESSIVE INHALATION OF THIS
MATERIAL CAUSES HEADACHE, DIZZINESS, NAUSEA, STUPOR, AND OTHER CENTRAL
NERVOUS SYSTEM EFFECTS LEADING TO VISUAL IMPAIRMENT, DIFFICULTY BREATHING,
MEMORY LOSS, CONVULSIONS AND UNCOORDINATION. REPEATED AND PROLONGED
OVEREXPOSURE TO OIL MISTS MAY RESULT IN DROPLET DEPOSITION, OIL GRANULOMA
FORMATION, INFLAMMATION AND INCREASED INCIDENCE OF INFECTION. BREATHING OF
VAPOR OR MIST MAY AGGRAVATE ASTHMA AND INFLAMMATORY OR FIBROTIC PULMONARY
DISEASE. REPEATED OVEREXPOSURE TO NAPHTHALENE MAY CAUSE DESTRUCTION OF RED
BLOOD CELLS WITH ANEMIA, FEVER, JAUNDICE AND KIDNEY AND LIVER DAMAGE.
DATA AND/OR ACUTE TOXICITY ESTIMATES:
NO DATA AVAILABLE ON PRODUCT AS A WHOLE.
CAS # CHEMICAL NAME PERCENT LD50 - LD50 - LC50 -
ORAL DERMAL INHALATION
(RAT) (RABBIT) (RAT)
64742-47-8 DISTILLATES, 60-80 LD50 (RAT) LD50 LC50 (RAT)
PETROLEUM, >5000 (RABBIT) >4.3 MG/L
HYDROTREATED MG/KG = 2000 -
LIGHT 4000 MG/KG
64741-86-2 DISTILLATES, 7-13 LD50 (RAT) LD50 LC50 (RAT)
PETROLEUM, >5000 (RABBIT) =4.6 MG/L
SWEETENED MG/KG >2000 (4 HR)
MIDDLE MG/KG
64742-94-5 NAPHTHA 5-7 LD50 (RAT) LD50 LC50 (RAT)
(PETROLEUM), >5000 (RABBIT) >0.17 MG/L
HEAVY AROMATIC MG/KG >3160 (4 HR; NO
MG/KG DEATHS)
128-39-2 2,6-DI-TERT 1-2 LD50 (RAT) NOT NOT
BUTYLPHENOL >5000 CLASSIFIED CLASSIFIED
MG/KG DATA DATA
UNAVAILABLE UNAVAILABLE
104-76-7 2-ETHYLHEXANOL 1-2 LD50 (RAT) LD50 LC50 (RAT)
=3290 (RABBIT) >0.89 MG/L
MG/KG >3000 (4 HR)
MG/KG
PROPRIETARY ETHOXYLATED 1-2 ATE = 500 NOT NOT
AMINE CLASSIFIED CLASSIFIED
DATA DATA
UNAVAILABLE UNAVAILABLE
91-20-3 NAPHTHALENE 0.1-0.5 490 MG/KG >20 G/KG >340 MG/M3
(1H)
ONE OR MORE COMPONENTS HAVE PRODUCED DAMAGE AFTER PROLONGED EXPOSURE IN
LABORATORY ANIMALS TO ONE OR MORE OF THE FOLLOWING:
KIDNEYS, LIVER, SPLEEN, BLOOD AND/OR CIRCULATORY SYSTEM. NAPHTHALENE HAS
BEEN SHOWN TO CAUSE CANCER IN LABORATORY ANIMALS AND IS CLASSIFIED GROUP
2B BY IARC.
CATEGORY CLASSIFICATION BASED ON AVAILABLE DATA
ACUTE TOXICITY CONCLUSIVE BUT NOT SUFFICIENT FOR CLASSIFICATION
SKIN/EYE IRRITATION SKIN IRRITATION 2 (COMPONENT ADDITIVITY)
CORROSIVITY CONCLUSIVE BUT NOT SUFFICIENT FOR CLASSIFICATION
RESPIRATORY OR SKIN RESPIRATORY:
SENSITIZATION CONCLUSIVE BUT NOT SUFFICIENT FOR CLASSIFICATION
SKIN: SENSITIZER
GERM CELL MUTAGENICITY DATA LACKING
CARCINOGENICITY CONTAINS NAPHTHALENE WHICH IS SUSPECTED OF
CAUSING CANCER BASED ON ANIMAL STUDIES.
REPRODUCTIVE TOXICITY DATA LACKING
STOT-SE STOT 3 (CNS EFFECTS, RESPIRATORY IRRITATION)
STOT-RE DATA LACKING
ASPIRATION HAZARD ASP. 1
| SECTION 12 - ECOLOGICAL INFORMATION | |
NO ECOTOXICITY OR ENVIRONMENTAL FATE DATA AVAILABLE ON PRODUCT AS A WHOLE.
A SUMMARY OF AQUATIC TOXICITY DATA FOR COMPONENTS OF THIS PRODUCT IS
AVAILABLE UPON REQUEST.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
US EPA WASTE NUMBER & DESCRIPTIONS:
USER MUST TEST WASTE USING METHODS DESCRIBED IN 40 CFR PART 261 TO
DETERMINE IF IT MEETS APPLICABLE DEFINITIONS OF HAZARDOUS WASTE. IF
DISPOSED OF AS SHIPPED, THIS PRODUCT MAY BE CONSIDERED A D001 IGNITABLE
WASTE.
DISPOSAL INSTRUCTIONS:
DISPOSE OF WASTE PRODUCT ACCORDING TO LOCAL, STATE, FEDERAL, AND
PROVINCIAL ENVIRONMENTAL REGULATIONS. DO NOT ALLOW THIS PRODUCT TO
DRAIN INTO SEWERS/WATER SUPPLIES. PRODUCT SHOULD BE RECYCLED IF POSSIBLE.
| SECTION 14 - TRANSPORTATION INFORMATION | |
GENERAL TRANSPORTATION INFORMATION:
NOTE:
INFORMATION IN THIS SECTION (SECTION 14) IS PRESENTED AS A GUIDE ONLY.
REQUIREMENTS MAY VARY DEPENDING UPON PACKAGE SIZE AND EXCEPTIONS USED,
IF ANY. FOLLOW CURRENT, APPLICABLE REQUIREMENTS UNDER DOT, TDG, IMO/IMDG,
AND ICAO/IATA TO ENSURE REGULATORY COMPLIANCE.
U.S. DEPARTMENT OF TRANSPORTATION REGULATIONS GROUND TRANSPORTATION:
NON-BULK. NOT REGULATED BASED ON COMBUSTIBLE LIQUID EXCEPTION [49CFR
173.150(F)]. REVIEW AND FOLLOW ALL REQUIREMENTS PERTAINING TO THIS
EXCEPTION. SEE ALSO 49 CFR 171.4(C). NAPHTHALENE: RQ 100 LBS.
CANADIAN TDG REGULATIONS GROUND TRANSPORTATION:
NON-BULK. NOT REGULATED BASED ON EXCEPTION, CANADA TDG, PART I, SECTION
1.33. REVIEW AND FOLLOW ALL REQUIREMENTS PERTAINING TO THIS EXCEPTION.
ICAO/IATA:
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PETROLEUM
NAPHTHAS), 9, PG III
IMO/IMDG:
UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(PETROLEUM NAPHTHAS) 9, PG III, (61.1 DEG. C C.C.), MARINE POLLUTANT
EMS: F-A, S-F
| SECTION 15 - REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
A:
GENERAL PRODUCT INFORMATION:
COMPONENTS LISTED IN SECTION 3 OF THE SDS ARE PRESENT ON THE TSCA
INVENTORY. THIS PRODUCT IS A REGISTERED FUEL ADDITIVE (40 CFR 79)
- REGISTRATION #125520004.
B:
COMPONENT ANALYSIS:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS REQUIRED TO BE IDENTIFIED
UNDER SARA SECTION 313 (40 CFR 372.65).
NAPHTHALENE (91-20-3):
C. COMPONENT MARINE POLLUTANT:
THIS MATERIAL CONTAINS PETROLEUM NAPHTHAS WHICH ARE REQUIRED BY US DOT TO
BE IDENTIFIED AS MARINE POLLUTANTS.
OTHER REGULATIONS:
COMPONENTS LISTED IN SECTION 3 OF THE SDS ARE PRESENT ON THE DSL
INVENTORIES. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE
HAZARD CRITERIA REQUIRED BY THE CANADIAN HAZARDOUS PRODUCT ACT AND THE
SDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CANADIAN HAZARDOUS
PRODUCTS REGULATIONS.
WHMIS CLASSIFICATION:
FLAM. LIQ. 4 - H227; SKIN IRRIT. 2 - H315; SKIN SENS. 1 - H317; CARC. 2 -
H351; STOT-SE 3 - H335 & H336; ASP. 1 - H304.
| SECTION 16 - OTHER INFORMATION | |
OTHER INFORMATION:
HAZARD STATEMENTS FROM SECTION 3:
H226: FLAMMABLE LIQUID AND VAPOR.
H227: COMBUSTIBLE LIQUID.
H290: MAY BE CORROSIVE TO METALS.
H302: HARMFUL IF SWALLOWED.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H318: CAUSES SERIOUS EYE DAMAGE.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H351: SUSPECTED OF CAUSING CANCER.
H400: VERY TOXIC TO AQUATIC LIFE.
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
HMIS RATINGS:
HEALTH 2*
FIRE 2
REACTIVITY 0
PERS. PROT.:
IMPERVIOUS GLOVES/SAFETY GLASSES (CHEMICAL GOGGLES IF SPLASHING IS
POSSIBLE)
HAZARD SCALE:
0 = MINIMAL
1 = SLIGHT
2 = MODERATE
3 = SERIOUS
4 = SEVERE
* = CHRONIC HAZARD
OTHER INFORMATION:
THE INFORMATION AND RECOMMENDATIONS PRESENTED IN THIS SAFETY DATA SHEET
ARE BASED ON SOURCES BELIEVED TO BE RELIABLE ON THE DATE HEREOF. CLARCOR
INC. MAKES NO REPRESENTATION ON ITS COMPLETENESS OR ACCURACY. THIS PRODUCT
IS SOLD "AS IS" AND IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE
PRODUCT'S SUITABILITY FOR ITS INTENDED USE, THE PRODUCT'S SAFE USE, AND
THE PRODUCT'S PROPER DISPOSAL. THE STATEMENTS AND DESCRIPTIONS PROVIDED
ARE INFORMATIONAL ONLY AND NO REPRESENTATIONS OR WARRANTIES, EITHER
EXPRESSED OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR
PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION
PROVIDED IN THIS SAFETY DATA SHEET OR TO THE PRODUCT TO WHICH SUCH
INFORMATION REFERS. CLARCOR INC. NEITHER ASSUMES NOR AUTHORIZES ANY
OTHER PERSON TO ASSUME FOR IT, ANY OTHER OR ADDITIONAL LIABILITY OR
RESPONSIBILITY RESULTING FROM THE USE OF, OR RELIANCE UPON, THIS
INFORMATION. CLARCOR INC. ASSUMES NO RESPONSIBILITY FOR INJURY TO
RECIPIENT OR TO THIRD PERSONS OR FOR ANY DAMAGE TO ANY PROPERTY AND
RECIPIENT ASSUMES ALL SUCH RISKS.
KEY/LEGEND:
N = NO
Y = YES
PPM = PARTS PER MILLION
MG/M3 = MILLIGRAMS PER CUBIC METER OF AIR
ACGIH = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
OSHA = OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
TLV = THRESHOLD LIMIT VALUE
NIOSH = NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
IDLH = IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONCENTRATIONS
NTP = NATIONAL TOXICOLOGY PROGRAM
IARC = INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
TSCA = TOXIC SUBSTANCE CONTROL ACT
DSL = DANGEROUS SUBSTANCES LIST
EINECS = EUROPEAN INVENTORY OF NEW AND EXISTING CHEMICAL SUBSTANCES
CONTACT:
FOR FURTHER INFORMATION CALL: 1-800-842-2496
ISSUE DATE: 8/25/2015
PRINT DATE: 10/1/2015
REVISION: 3