| Common Name: | STANADYNE PERFORMANCE FORMULA - WARM WEATHER BLEND |
| Manufacturer: | CLARCOR |
| SDS Revision Date: | 8/25/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 48NT89, 48NT90, 48NT91, 48NT92, 48NT93 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
CLARCOR
SAFETY DATA SHEET
MATERIAL NAME: STANADYNE PERFORMANCE FORMULA(R*) - WARM WEATHER BLEND
| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NUMBERS:
43568 (8OZ./237ML); 43570 (16OZ./473ML); 43572 (64OZ./1.9L);
43574 (5GAL./19L); 43573 (55 GAL./208L)
CHEMICAL NAME: MIXTURE
PRODUCT USE: DIESEL FUEL ADDITIVE
COMPANY INFORMATION:
CLARCOR INC.
840 CRESCENT CENTRE DRIVE
SUITE 600
FRANKLIN, TN 37067
U.S.A.
PHONE: 1-800-842-2496
EMERGENCY #:
CHEMTREC: 1-800-424-9300
CHEMTREC (OUTSIDE US & CANADA): 1-703-527-3887
| SECTION 2 - HAZARDS IDENTIFICATION | |
A. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE LIQUID 4 - H227: COMBUSTIBLE LIQUID.
SKIN IRRITATION 2 - H315: CAUSES SKIN IRRITATION.
CARCINOGENICITY 2 - H351: SUSPECTED OF CAUSING CANCER.
STOT-SE 3 - H336: MAY CAUSE DROWSINESS OR DIZZINESS.
ASPIRATION HAZARD 1 - H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
OSHA DEFINED HAZARDS: NONE
B. LABEL ELEMENTS:
1. OSHA:
EXCLAMATION MARK
HEALTH HAZARD
DANGER:
COMBUSTIBLE LIQUID. CAUSES SKIN IRRITATION. SUSPECTED OF CAUSING CANCER.
MAY CAUSE DROWSINESS OR DIZZINESS. MAY BE FATAL IF SWALLOWED AND ENTERS
AIRWAYS.
OBTAIN SPECIAL INSTRUCTION BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM FLAMES AND HOT
SURFACES. - NO SMOKING. WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE
PROTECTION. WASH THOROUGHLY AFTER HANDLING. AVOID BREATHING
MIST/VAPORS/SPRAY. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR. DO NOT INDUCE VOMITING.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR IF YOU FEEL UNWELL.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE
REUSE. STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER
TIGHTLY CLOSED. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL REGULATIONS.
OTHER HAZARDS: NONE IDENTIFIED.
2. CONSUMER PRODUCTS:
FRONT:
DANGER:
HARMFUL OR FATAL IF SWALLOWED. COMBUSTIBLE. VAPOR HARMFUL. CAUSES SKIN
IRRITATION. KEEP OUT OF REACH OF CHILDREN. SEE BACK PANEL FOR ADDITIONAL
HAZARDS AND PRECAUTIONS.
BACK:
HAZARDS:
CONTAINS PETROLEUM DISTILLATES, 2-ETHYLHEXYL NITRATE, AND NAPHTHALENE.
HARMFUL OR FATAL IF SWALLOWED. CAUSES SKIN IRRITATION. MAY CAUSE DROWSINESS
OR DIZZINESS. CONTAINS A SMALL AMOUNT OF NAPHTHALENE WHICH IS SUSPECTED OF
CAUSING CANCER.
PRECAUTION:
KEEP AWAY FROM HEAT OR FLAME. AVOID SWALLOWING, CONTACT WITH EYES OR SKIN,
OR BREATHING VAPOR. WASH IMMEDIATELY AFTER CONTACT. USE IN WELL VENTILATED
AREA.
FIRST AID:
IF SWALLOWED, DO NOT INDUCE VOMITING - CALL PHYSICIAN IMMEDIATELY. IN CASE
OF CONTACT, FLUSH EYES WITH WATER AND WASH SKIN WITH SOAP AND WATER. IF EYE
DISCOMFORT PERSISTS, CONTACT A PHYSICIAN. IF AFFECTED BY VAPOR, GET FRESH
AIR - CALL PHYSICIAN IF SYMPTOMS PERSIST.
| SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS | |
CAS # CHEMICAL NAME PERCENT INGREDIENT CLASSIFICATION*
(W/W)
64742-47-8 DISTILLATES, PETROLEUM, 60-80 FLAM. LIQ. 4 - H227
HYDROTREATED LIGHT SKIN IRRIT. 2 - H315
STOT SE 3 - H336
ASP. 1 - H304
AQUATIC CHRON. 2 - H411
27247-96-7 2-ETHYLHEXYL NITRATE 10-24 ACUTE TOX. 4 - H302-312-332
AQUATIC CHRON. 2 - H411
64742-94-5 NAPHTHA (PETROLEUM), 1-3 FLAM. LIQ. 4 - H227
HEAVY AROMATIC SKIN IRRIT. 2 - H315
STOT 3 - H336 (CNS)
ASP. 1 - H304
AQUATIC CHRON. 2 - H411
104-76-7 2-ETHYLHEXANOL 1-3 ACUTE TOX. 4 - H332
SKIN IRRIT. 2 - H315
EYE IRRIT. 2 - H319
STOT-SE 3 - H335
95-63-6 1,2,4-TRIMETHYLBENZENE 0.1-0.9 FLAM. LIQ. 3 - H226
ACUTE TOX. 4 - H332
SKIN IRRIT. 2 - H315
EYE IRRIT. 2 - H319
ASPIRATION TOX. 1 - H304
STOT-SE 3 - H335
AQUATIC CHRON. 2 - H411
91-20-3 NAPHTHALENE 0.1-0.5 ACUTE TOX. 4 - H302
CARC. 2 - H351
AQUATIC ACUTE 1 - H400
AQUATIC CHRON. 1 - H410
108-67-8 1,3,5-TRIMETHYLBENZENE 0.1-0.5 FLAM. LIQ. 3 - H226
SKIN IRRIT. 2 - H315
EYE IRRIT. 2 - H319
ASPIRATION TOX. 1 - H304
STOT-SE 3 - H335
AQUATIC CHRON. 2 - H411
526-73-8 1,2,3-TRIMETHYLEBENZENE 0.1-0.5 FLAM. LIQ. 3 - H226
ACUTE TOX. 4 - H332
SKIN IRRIT. 2 - H315
EYE IRRIT. 2 - H319
ASPIRATION TOX. 1 - H304
STOT-SE 3 - H335
AQUATIC CHRON. 2 - H411
COMPONENT RELATED REGULATORY INFORMATION:
THIS PRODUCT IS CONSIDERED HAZARDOUS UNDER 29 CFR 1910.1200 (HAZARD
COMMUNICATION). THIS PRODUCT CONTAINS GLYCOL ETHERS. THE EXACT
CONCENTRATIONS OF ONE OR MORE OF THE ABOVE LISTED COMPONENTS ARE BEING
WITHHELD AS A TRADE SECRET.
| SECTION 4 - FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
EYES:
QUICKLY AND GENTLY BLOT AWAY EXCESS CHEMICAL. IMMEDIATELY FLUSH THE
CONTAMINATED EYE(S) WITH LUKEWARM, GENTLY FLOWING WATER FOR 15 MINUTES OR
UNTIL THE CHEMICAL IS REMOVED, WHILE HOLDING THE EYELID(S) OPEN. TAKE CARE
NOT TO RINSE CONTAMINATED WATER INTO THE UNAFFECTED EYE OR ONTO THE FACE.
SEEK IMMEDIATE MEDICAL ATTENTION.
SKIN:
REMOVE CONTAMINATED CLOTHING. QUICKLY AND GENTLY BLOT AWAY EXCESS CHEMICAL.
WASH GENTLY AND THOROUGHLY WITH WARM WATER AND NON-ABRASIVE SOAP FOR 15
MINUTES OR UNTIL THE CHEMICAL IS REMOVED. GET MEDICAL ATTENTION IF SKIN
DISORDER DEVELOPS.
INGESTION:
NEVER GIVE ANYTHING BY MOUTH IF VICTIM IS RAPIDLY LOSING CONSCIOUSNESS, OR
IS UNCONSCIOUS OR CONVULSING. HAVE VICTIM RINSE MOUTH THOROUGHLY WITH
WATER. DO NOT INDUCE VOMITING. HAVE VICTIM DRINK 8 TO 10 OZ. OF WATER TO
DILUTE MATERIAL IN STOMACH. IF VOMITING OCCURS NATURALLY, HAVE VICTIM LEAN
FORWARD TO REDUCE RISK OF ASPIRATION. REPEAT ADMINISTRATION OF WATER. SEEK
IMMEDIATE MEDICAL ATTENTION OR ADVICE.
INHALATION:
IF AFFECTED, REMOVE SOURCE OF CONTAMINATION OR MOVE INDIVIDUAL TO FRESH
AIR. IF THE AFFECTED PERSON IS NOT BREATHING, TRAINED PERSONNEL SHOULD
BEGIN ARTIFICIAL RESPIRATION IMMEDIATELY. SEEK MEDICAL ATTENTION IF
SYMPTOMS PERSIST. IF OVERCOME BY VAPOR FROM HOT PRODUCT, IMMEDIATELY
REMOVE TO FRESH AIR AND CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
POTENTIAL HEALTH EFFECTS:
EYES:
THIS PRODUCT MAY BE IRRITATING TO THE EYES. EFFECTS MAY INCLUDE A BURNING
SENSATION, REDNESS, SWELLING AND/OR BLURRED VISION.
POTENTIAL HEALTH EFFECTS:
SKIN:
THIS PRODUCT IS IRRITATING TO THE SKIN. PROLONGED OR REPEATED CONTACT WITH
THIS PRODUCT MAY DRY AND/OR DEFAT THE SKIN. SYMPTOMS MAY INCLUDE REDNESS,
EDEMA, DRYING OR CRACKING OF SKIN. SEE SECTION 11 FOR ADDITIONAL
INFORMATION.
POTENTIAL HEALTH EFFECTS:
INGESTION:
THIS PRODUCT MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE
MOUTH. INGESTION OF THIS PRODUCT MAY CAUSE HEADACHE, DIZZINESS,
UNCOORDINATION, AND GENERAL WEAKNESS. SMALL AMOUNTS OF THIS PRODUCT, IF
ASPIRATED INTO THE LUNGS, MAY CAUSE MILD TO SEVERE PULMONARY INJURY,
POSSIBLY DEATH. SEE SECTION 11 FOR ADDITIONAL INFORMATION.
POTENTIAL HEALTH EFFECTS:
INHALATION:
HARMFUL IF INHALED. INHALATION OF OIL MISTS OR FUMES CAN CAUSE IRRITATION
OF THE MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. EXCESSIVE INHALATION
OF THIS MATERIAL CAUSES HEADACHE, DIZZINESS, NAUSEA, STUPOR, AND OTHER
CENTRAL NERVOUS SYSTEM EFFECTS LEADING TO VISUAL IMPAIRMENT, DIFFICULTY
BREATHING, MEMORY LOSS, CONVULSIONS AND UNCOORDINATION. BREATHING OF VAPOR
OR MIST MAY AGGRAVATE ASTHMA AND INFLAMMATORY OR FIBROTIC PULMONARY
DISEASE. SEE SECTION 11 FOR ADDITIONAL INFORMATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PULMONARY ASPIRATION HAZARD IF SWALLOWED; TREAT SYMPTOMATICALLY.
| SECTION 5 - FIRE FIGHTING MEASURES | |
GENERAL FIRE HAZARDS:
FIRE AND EXPLOSION HAZARDS ARE MODERATE WHEN THIS PRODUCT IS EXPOSED TO
HEAT OR FLAME. LIQUID CAN BURN UPON HEATING TO TEMPERATURES AT OR ABOVE THE
FLASH POINT. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG THE GROUND TO
SOME DISTANT SOURCE OF IGNITION AND FLASH BACK.
EXTINGUISHING MEDIA:
DRY CHEMICAL, FOAM, CARBON DIOXIDE, WATER FOG. USE WATER TO COOL
FIRE-EXPOSED CONTAINERS AND TO PROTECT PERSONNEL. DIRECT WATER SPRAY OR
FOAM MAY CAUSE FROTHING AND SPATTERING. IF A LEAK OR SPILL HAS NOT IGNITED,
USE WATER SPRAY TO DISPERSE VAPORS AND TO FLUSH SPILLS AWAY FROM EXPOSURE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
IRRITATING AND TOXIC GASES OR FUMES MAY BE RELEASED DURING A FIRE. UPON
COMBUSTION, THIS PRODUCT MAY YIELD OXIDES OF NITROGEN CARBON MONOXIDE,
CARBON DIOXIDE, AND/OR OTHER LOW MOLECULAR WEIGHT HYDROCARBONS.
ADVICE FOR FIREFIGHTERS:
FIREFIGHTERS SHOULD WEAR FULL-FACE, SELF-CONTAINED BREATHING APPARATUS AND
IMPERVIOUS PROTECTIVE CLOTHING. FIREFIGHTERS SHOULD AVOID INHALING ANY
COMBUSTION PRODUCTS.
NFPA RATINGS:
HEALTH 2
FIRE 2
REACTIVITY 0
OTHER
HAZARD SCALE:
0 = MINIMAL
1 = SLIGHT
2 = MODERATE
3 = SERIOUS
4 = SEVERE
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ELIMINATE ALL SOURCES OF IGNITION OR FLAMMABLES THAT MAY COME INTO CONTACT
WITH A SPILL OF THIS PRODUCT. SURFACES MAY BECOME SLIPPERY AFTER SPILLAGE.
WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING DURING CLEANUP. DO NOT
ALLOW THE SPILLED PRODUCT TO ENTER PUBLIC DRAINAGE SYSTEMS OR OPEN
WATERCOURSES. IF PRODUCT IS SPILLED, NOTIFY APPROPRIATE AUTHORITIES AT THE
LOCAL, STATE, FEDERAL, AND PROVINCIAL LEVELS. PERSONS NOT WEARING
PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEANUP
HAS BEEN COMPLETED. STOP THE FLOW OF PRODUCT, IF THIS CAN BE DONE WITHOUT
RISK.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEAN-UP PROCEDURES:
ABSORB WITH NON-FLAMMABLE SUITABLE ABSORBENT SUCH AS SAND OR EARTH. SCOOP
UP USED ABSORBENT INTO DRUMS OR OTHER APPROPRIATE CONTAINER.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
AVOID PROLONGED OR REPEATED SKIN CONTACT WITH THIS PRODUCT. AVOID GETTING
THIS PRODUCT INTO CONTACT WITH YOUR EYES. AVOID THE GENERATION OF MISTS.
WASH THOROUGHLY AFTER HANDLING. USE THIS PRODUCT WITH ADEQUATE VENTILATION.
DISCARD ANY SHOES OR CLOTHING ITEMS THAT CANNOT BE DECONTAMINATED.
CONDITIONS FOR SAFE STORAGE (INCLUDING ANY INCOMPATIBILITIES):
DO NOT STORE NEAR HEAT, SPARKS, OPEN FLAME OR STRONG OXIDIZING AGENTS. DO
NOT STORE THIS PRODUCT IN OPEN OR UNLABELED CONTAINERS. STORE DRUMS IN A
COVERED AREA WITH SECONDARY CONTAINMENT. "EMPTY" CONTAINERS RETAIN PRODUCT
RESIDUE (LIQUID AND/OR VAPOR) AND CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT,
WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT,
FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY
EXPLODE. FOLLOW APPROPRIATE GROUNDING PROCEDURES.
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
A:
GENERAL PRODUCT INFORMATION:
FOLLOW ALL APPLICABLE EXPOSURE LIMITS. UNDER CONDITIONS WHICH MAY GENERATE
MISTS, THE COMPONENT SUPPLIER RECOMMENDS THE OSHA PEL OF 5 MG/M3 AND THE
ACGIH STEL OF 10 MG/M3 FOR OIL MISTS. INCLUDED BELOW ARE THE OSHA VACATED
PERMISSIBLE EXPOSURE LIMITS (PELS).
B:
COMPONENT EXPOSURE LIMITS:
COMPOUND ACGIH NIOSH OSHA OTHER
TWA STEL TWA STEL TWA STEL TWA
PETROLEUM N/E N/E 350 MG/M3 1800 500 PPM N/E N/E
DISTILLATES (C) MG/M3 2000 MG/M3
1,2,4- N/E N/E 25 PPM N/E N/E N/E N/E
TRIMETHYL-
BENZENE
1,3,5- N/E N/E 25 PPM N/E N/E N/E N/E
TRIMETHYL-
BENZENE
NAPHTHALENE 10 PPM 15 PPM 10 PPM 15 PPM 10 PPM N/E N/E
(S) - SKIN EXPOSURE
(C) - CEILING EXPOSURE
N/E - NONE ESTABLISHED
ENGINEERING CONTROLS:
USE GENERAL VENTILATION AND USE LOCAL EXHAUST, WHERE POSSIBLE, IN CONFINED
OR ENCLOSED SPACES.
PERSONAL PROTECTIVE EQUIPMENT:
EYES/FACE:
WEAR SAFETY GLASSES. WEAR CHEMICAL GOGGLES OR FACESHIELD IF MIST IS LIKELY
TO OCCUR.
SKIN:
USE IMPERVIOUS GLOVES. WEAR OIL-IMPERVIOUS GARMENTS IF CONTACT IS
UNAVOIDABLE.
RESPIRATORY:
IN THE EVENT OF EXCESSIVE EXPOSURE TO VAPORS/MISTS/FUMES, USE NIOSH/OSHA
APPROVED RESPIRATORY EQUIPMENT. RESPIRATOR SHOULD BE SELECTED ON THE BASIS
OF FORM AND CONCENTRATION OF CONTAMINANT.
GENERAL:
USE GOOD HYGIENE WHEN HANDLING PETROLEUM PRODUCT. LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. EXCESSIVE MISTING MAY CAUSE SLIPPERY FLOORS - WEAR
APPROPRIATE FOOTWEAR. EYE WASH FOUNTAINS ARE RECOMMENDED.
| SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES | |
APPEARANCE: AMBER COLORED
ODOR: OIL / SOLVENT
PHYSICAL STATE: LIQUID
ODOR THRESHOLD: NOT APPLICABLE
PH: NOT APPLICABLE
MELTING/FREEZING POINT: NOT DETERMINED
INITIAL BOILING POINT & RANGE: NOT DETERMINED
FLASH POINT: 145 DEG. F (62.8 DEG. C)
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NOT DETERMINED
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
AUTO-IGNITION TEMPERATURE: NOT DETERMINED
DECOMPOSITION TEMPERATURE: NOT DETERMINED
VAPOR DENSITY: NOT DETERMINED
VAPOR PRESSURE: NOT DETERMINED
SOLUBILITIES: NEGLIGIBLE
PARTITION COEFFICIENT: NOT DETERMINED
EVAPORATION RATE: NOT DETERMINED
VISCOSITY: NOT DETERMINED
RELATIVE DENSITY: 0.86
DENSITY: NOT DETERMINED
| SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION | |
REACTIVITY: NOT REACTIVE
CHEMICAL STABILITY: STABLE
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
CONDITIONS TO AVOID: HEAT, IGNITION SOURCES AND SPARKS.
INCOMPATIBILITY: THIS PRODUCT MAY REACT WITH STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION:
DECOMPOSITION OF THIS PRODUCT MAY YIELD CARBON MONOXIDE, CARBON DIOXIDE
AND/OR LOW MOLECULAR WEIGHT HYDROCARBONS.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
DESCRIPTION OF THE VARIOUS TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION, SKIN
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS (INCLUDING IMMEDIATE AND DELAYED EFFECTS AND
CHRONIC EFFECTS FOR SHORT- AND LONG-TERM EXPOSURE):
THIS PRODUCT IS IRRITATING TO THE SKIN. EXCESSIVE INHALATION OF THIS
PRODUCT CAUSES HEADACHE, DIZZINESS AND INCOORDINATION. THIS PRODUCT MAY
CAUSE NERVOUS SYSTEM EFFECTS INCLUDING PERIPHERAL NEUROPATHY. THIS PRODUCT
CONTAINS A CHEMICAL(S) WHICH HAS BEEN SHOWN TO CAUSE CANCER IN LABORATORY
ANIMALS. A COMPONENT OF THIS PRODUCT HAS BEEN REPORTED TO CAUSE BIRTH
DEFECTS AND/OR OTHER REPRODUCTIVE HARM. COMPONENTS OF THIS PRODUCT MAY HAVE
ADVERSE EFFECTS ON THE BLOOD-FORMING SYSTEM. IRRITATING AND TOXIC VAPORS
MAY BE RELEASED UPON COMBUSTION OF PRODUCT.
POTENTIAL HEALTH EFFECTS:
EYES:
EFFECTS IN SENSITIVE INDIVIDUALS MAY INCLUDE A BURNING SENSATION, REDNESS,
SWELLING AND/OR BLURRED VISION.
POTENTIAL HEALTH EFFECTS:
SKIN:
THIS PRODUCT IS IRRITATING TO THE SKIN. PROLONGED OR REPEATED CONTACT WITH
THIS PRODUCT MAY DRY AND/OR DEFAT THE SKIN. SYMPTOMS MAY INCLUDE REDNESS,
EDEMA, DRYING OR CRACKING OF SKIN. PRODUCT CONTAINS COMPONENT(S) THAT CAN
BE HARMFUL IF ABSORBED THROUGH THE SKIN. ABSORPTION OF 2-ETHYLHEXYL NITRATE
MAY CAUSE VASODILATION RESULTING IN REDUCED BLOOD PRESSURE AND OTHER
CARDIOVASCULAR EFFECTS. SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, NAUSEA,
FATIGUE, HEART PALPITATIONS, CONFUSION AND POSSIBLE LOSS OF CONSCIOUSNESS.
POTENTIAL HEALTH EFFECTS:
INGESTION:
THIS PRODUCT MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE
MOUTH, GASTROINTESTINAL LINING, NAUSEA, VOMITING, DIARRHEA, AND ABDOMINAL
PAIN. INGESTION OF THIS PRODUCT MAY CAUSE HEADACHE, DIZZINESS,
UNCOORDINATION, AND GENERAL WEAKNESS. INGESTION OF 2-ETHYLHEXYL NITRATE MAY
CAUSE VASODILATION RESULTING IN REDUCED BLOOD PRESSURE AND OTHER
CARDIOVASCULAR EFFECTS. SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, NAUSEA,
FATIGUE, HEART PALPITATIONS, CONFUSION AND POSSIBLE LOSS OF CONSCIOUSNESS.
SMALL AMOUNTS OF THIS PRODUCT, IF ASPIRATED INTO THE LUNGS, MAY CAUSE MILD
TO SEVERE PULMONARY INJURY, POSSIBLY DEATH. INGESTION OF THIS PRODUCT MAY
CAUSE RED BLOOD CELL HEMOLYSIS AND POSSIBLE LIVER AND KIDNEY INJURY.
POTENTIAL HEALTH EFFECTS:
INHALATION:
INHALATION OF OIL MISTS OR FUMES CAN CAUSE IRRITATION OF THE MUCOUS
MEMBRANES AND UPPER RESPIRATORY TRACT. EXCESSIVE INHALATION OF THIS
MATERIAL CAUSES HEADACHE, DIZZINESS, NAUSEA, STUPOR, AND OTHER CENTRAL
NERVOUS SYSTEM EFFECTS LEADING TO VISUAL IMPAIRMENT, DIFFICULTY BREATHING,
MEMORY LOSS, CONVULSIONS AND UNCOORDINATION. OVEREXPOSURE TO ORGANIC
NITRATES BY INHALATION MAY CAUSE HEADACHE, NAUSEA AND DECREASED BLOOD
PRESSURE. REPEATED AND PROLONGED OVEREXPOSURE TO OIL MISTS MAY RESULT IN
DROPLET DEPOSITION, OIL GRANULOMA FORMATION, INFLAMMATION AND INCREASED
INCIDENCE OF INFECTION. BREATHING OF VAPOR OR MIST MAY AGGRAVATE ASTHMA AND
INFLAMMATORY OR FIBROTIC PULMONARY DISEASE. REPEATED OVEREXPOSURE TO
NAPHTHALENE MAY CAUSE DESTRUCTION OF RED BLOOD CELLS WITH ANEMIA, FEVER,
JAUNDICE AND KIDNEY AND LIVER DAMAGE.
DATA AND/OR ACUTE TOXICITY ESTIMATES:
NO DATA AVAILABLE ON PRODUCT AS A WHOLE.
CAS # COMPONENT PERCENT LD50 - ORAL LD50 - DERMAL LC50 -
(RAT) (RABBIT) INHALATION
(RAT)
91-20-3 NAPHTHALENE 1-5 490 MG/KG >20 G/KG >340 MG/M3
(1H)
95-63-6 1,2,4- 1-5 5 G/KG NOT AVAILABLE 18 G/M3 (4H)
TRIMETHYL-
BENZENE
108-67-8 1,3,5- 1-3 NOT AVAILABLE NOT AVAILABLE 24 G/M3 (4H)
TRIMETHYL-
BENZENE
ONE OR MORE COMPONENTS HAVE PRODUCED DAMAGE AFTER PROLONGED EXPOSURE IN
LABORATORY ANIMALS TO ONE OR MORE OF THE FOLLOWING:
KIDNEYS, LIVER, SPLEEN, BLOOD AND/OR CIRCULATORY SYSTEM. NAPHTHALENE HAS
BEEN SHOWN TO CAUSE CANCER IN LABORATORY ANIMALS AND IS CLASSIFIED GROUP
2B BY IARC.
CATEGORY CLASSIFICATION BASED ON AVAILABLE DATA
ACUTE TOXICITY CONCLUSIVE BUT NOT SUFFICIENT FOR CLASSIFICATION
SKIN/EYE IRRITATION SKIN IRRITATION 2 (COMPONENT ADDITIVITY)
CORROSIVITY CONCLUSIVE BUT NOT SUFFICIENT FOR CLASSIFICATION
RESPIRATORY OR SKIN CONCLUSIVE BUT NOT SUFFICIENT FOR CLASSIFICATION
SENSITIZATION
GERM CELL MUTAGENICITY DATA LACKING
CARCINOGENICITY CONTAINS NAPHTHALENE WHICH IS SUSPECTED OF CAUSING
CANCER BASED ON ANIMAL STUDIES.
REPRODUCTIVE TOXICITY DATA LACKING
STOT-SE STOT 3 (CNS EFFECTS, RESPIRATORY IRRITATION)
STOT-RE DATA LACKING
ASPIRATION HAZARD ASP. 1
| SECTION 12 - ECOLOGICAL INFORMATION | |
NO ECOTOXICITY OR ENVIRONMENTAL FATE DATA AVAILABLE ON PRODUCT AS A WHOLE.
A SUMMARY OF AQUATIC TOXICITY DATA FOR COMPONENTS OF THIS PRODUCT IS
AVAILABLE UPON REQUEST.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
US EPA WASTE NUMBER & DESCRIPTIONS:
USER MUST TEST WASTE USING METHODS DESCRIBED IN 40 CFR PART 261 TO
DETERMINE IF IT MEETS APPLICABLE DEFINITIONS OF HAZARDOUS WASTE. IF
DISPOSED OF AS SHIPPED, THIS PRODUCT MAY BE CONSIDERED A D001 IGNITABLE
WASTE.
DISPOSAL INSTRUCTIONS:
DISPOSE OF WASTE PRODUCT ACCORDING TO LOCAL, STATE, FEDERAL, AND PROVINCIAL
ENVIRONMENTAL REGULATIONS. DO NOT ALLOW THIS PRODUCT TO DRAIN INTO
SEWERS/WATER SUPPLIES. PRODUCT SHOULD BE RECYCLED IF POSSIBLE.
| SECTION 14 - TRANSPORTATION INFORMATION | |
GENERAL TRANSPORTATION INFORMATION:
NOTE:
INFORMATION IN THIS SECTION (SECTION 14) IS PRESENTED AS A GUIDE ONLY.
REQUIREMENTS MAY VARY DEPENDING UPON PACKAGE SIZE AND EXCEPTIONS USED, IF
ANY. FOLLOW CURRENT, APPLICABLE REQUIREMENTS UNDER DOT, TDG, IMO/IMDG, AND
ICAO/IATA TO ENSURE REGULATORY COMPLIANCE.
U.S. DEPARTMENT OF TRANSPORTATION REGULATIONS GROUND TRANSPORTATION:
NON-BULK. NOT REGULATED BASED ON COMBUSTIBLE LIQUID EXCEPTION [49CFR
173.150(F)]. REVIEW AND FOLLOW ALL REQUIREMENTS PERTAINING TO THIS
EXCEPTION. SEE ALSO 49 CFR 171.4(C).
NAPHTHALENE:
RQ: 100 LBS.
CANADIAN TDG REGULATIONS GROUND TRANSPORTATION:
NON-BULK. NOT REGULATED BASED ON EXCEPTION, CANADA TDG, PART I, SECTION
1.33. REVIEW AND FOLLOW ALL REQUIREMENTS PERTAINING TO THIS EXCEPTION.
INTERNATIONAL TRANSPORTATION REGULATIONS:
ICAO/IATA:
UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-ETHYHEXYL
NITRATE; NAPHTHAS), 9, PG III
IMO/IMDG:
UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2-ETHYHEXYL
NITRATE; NAPHTHAS) 9, PG III, (61.1 DEG. C C.C.), MARINE POLLUTANT
EMS: F-A, S-F
| SECTION 15 - REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
A:
GENERAL PRODUCT INFORMATION:
COMPONENTS LISTED IN SECTION 3 OF THE SDS ARE PRESENT ON THE TSCA
INVENTORY.
THIS PRODUCT IS A REGISTERED FUEL ADDITIVE (40 CFR 79) - REGISTRATION
#125520004.
B:
COMPONENT ANALYSIS:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS REQUIRED TO BE IDENTIFIED
UNDER SARA SECTION 313 (40 CFR 372.65).
NAPHTHALENE (91-20-3)
1,2,4-TRIMETHYLBENZENE (95-63-6)
C:
COMPONENT MARINE POLLUTANT:
THIS MATERIAL CONTAINS 2-ETHYLHEXYL NITRATE AND PETROLEUM NAPHTHAS WHICH
ARE REQUIRED BY US DOT TO BE IDENTIFIED AS MARINE POLLUTANTS.
OTHER REGULATIONS:
COMPONENTS LISTED IN SECTION 3 OF THE SDS ARE PRESENT ON THE DSL AND EINECS
INVENTORIES. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD
CRITERIA REQUIRED BY THE CANADIAN HAZARDOUS PRODUCT ACT AND THE SDS
CONTAINS ALL THE INFORMATION REQUIRED BY THE CANADIAN HAZARDOUS PRODUCTS
REGULATIONS.
WHMIS CLASSIFICATION:
FLAM. LIQ. 4 - H227; SKIN IRRIT. 2 - H315; CARC. 2 - H351; STOT-SE 3 -
H336; ASP. 1 - H304.
| SECTION 16 - OTHER INFORMATION | |
OTHER INFORMATION:
HAZARD STATEMENTS FROM SECTION 3:
H226: FLAMMABLE LIQUID AND VAPOR.
H227: COMBUSTIBLE.
H302: HARMFUL IF SWALLOWED.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H312: HARMFUL IN CONTACT WITH SKIN.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H351: SUSPECTED OF CAUSING CANCER.
H400: VERY TOXIC TO AQUATIC LIFE.
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
HMIS RATINGS:
HEALTH 2*
FIRE 2
REACTIVITY 0
PERS. PROT. IMPERVIOUS GLOVES/SAFETY GLASSES (CHEMICAL GOGGLES IF
SPLASHING IS POSSIBLE)
HAZARD SCALE:
0 = MINIMAL
1 = SLIGHT
2 = MODERATE
3 = SERIOUS
4 = SEVERE
* = CHRONIC HAZARD
OTHER INFORMATION:
THE INFORMATION AND RECOMMENDATIONS PRESENTED IN THIS SAFETY DATA SHEET ARE
BASED ON SOURCES BELIEVED TO BE RELIABLE ON THE DATE HEREOF. CLARCOR INC.
MAKES NO REPRESENTATION ON ITS COMPLETENESS OR ACCURACY. THIS PRODUCT IS
SOLD "AS IS" AND IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE PRODUCT'S
SUITABILITY FOR ITS INTENDED USE, THE PRODUCT'S SAFE USE, AND THE PRODUCT'S
PROPER DISPOSAL. THE STATEMENTS AND DESCRIPTIONS PROVIDED ARE INFORMATIONAL
ONLY AND NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE
ARE MADE WITH RESPECT TO THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET
OR TO THE PRODUCT TO WHICH SUCH INFORMATION REFERS. CLARCOR INC. NEITHER
ASSUMES NOR AUTHORIZES ANY OTHER PERSON TO ASSUME FOR IT, ANY OTHER OR
ADDITIONAL LIABILITY OR RESPONSIBILITY RESULTING FROM THE USE OF, OR
RELIANCE UPON, THIS INFORMATION. CLARCOR INC. ASSUMES NO RESPONSIBILITY FOR
INJURY TO RECIPIENT OR TO THIRD PERSONS OR FOR ANY DAMAGE TO ANY PROPERTY
AND RECIPIENT ASSUMES ALL SUCH RISKS.
KEY/LEGEND:
N = NO
Y = YES
PPM - PARTS PER MILLION
MG/M3 = MILLIGRAMS PER CUBIC METER OF AIR
ACGIH = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
OSHA = OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
TLV = THRESHOLD LIMIT VALUE
NIOSH = NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
IDLH = IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONCENTRATIONS
NTP = NATIONAL TOXICOLOGY PROGRAM
IARC = INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
TSCA = TOXIC SUBSTANCE CONTROL ACT
DSL = DANGEROUS SUBSTANCES LIST
EINECS = EUROPEAN INVENTORY OF NEW AND EXISTING CHEMICAL SUBSTANCES
CONTACT:
FOR FURTHER INFORMATION CALL: 1-800-842-2496
ISSUE DATE: 8/25/2015
PRINT DATE: 10/1/2015
REVISION: 4