| Common Name: | STANADYNE WINTER 1000 |
| Manufacturer: | CLARCOR |
| SDS Revision Date: | 8/10/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 48NT94, 48NT95, 48NT96 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CLARCOR
SAFETY DATA SHEET
MATERIAL NAME: STANADYNE WINTER 1000(R*)
| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NUMBERS:
38574 (16OZ./473ML); 45697 (64OZ./1.9L); 38575 (5GAL./19L); 38576
(55GAL./208L); 4153/24153/89153 (32OZ./946ML)
CHEMICAL NAME: MIXTURE
PRODUCT USE: DIESEL FUEL ADDITIVE
COMPANY INFORMATION:
CLARCOR INC.
840 CRESCENT CENTRE DRIVE
SUITE 600
FRANKLIN, TN 37067
U.S.A.
PHONE: 1-800-842-2496
EMERGENCY #:
CHEMTREC: 1-800-424-9300
CHEMTREC (OUTSIDE US & CANADA): 1-703-527-3887
| SECTION 2 - HAZARDS IDENTIFICATION | |
A. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE LIQUID: CATEGORY 3
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
CARCINOGENICITY: CATEGORY 2
ASPIRATION: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, SINGE EXPOSURE:
CATEGORY 3, CENTRAL NERVOUS SYSTEM, RESPIRATORY SYSTEM
OSHA DEFINED HAZARDS: NONE
B. LABEL ELEMENTS:
1. OSHA:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
DANGER:
FLAMMABLE LIQUID AND VAPOR. CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE
IRRITATION. SUSPECTED OF CAUSING CANCER. MAY BE FATAL IF SWALLOWED AND
ENTERS AIRWAYS. MAY CAUSE DROWSINESS OR DIZZINESS. MAY CAUSE RESPIRATORY
IRRITATION.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN
FLAMES/HOT SURFACES. - NO SMOKING. KEEP CONTAINER TIGHTLY CLOSED. GROUND
/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF ELECTRICAL/
VENTILATING/LIGHTING EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. WEAR PROTECTIVE GLOVES
/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION. WASH CAREFULLY AFTER
HANDLING. AVOID BREATHING MIST/VAPOR/SPRAY. USE ONLY OUTDOORS OR IN A
WELL-VENTILATED AREA.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING; WASH BEFORE REUSE. WASH
SKIN WITH PLENTY OF WATER.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE. STORE IN A WELL-VENTILATED PLACE. KEEP COOL. STORE
LOCKED UP. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL
/NATIONAL REGULATIONS.
OTHER HAZARDS: NONE IDENTIFIED.
2. CONSUMER PRODUCTS:
FRONT:
DANGER:
HARMFUL OR FATAL IF SWALLOWED. COMBUSTIBLE. VAPOR HARMFUL. CAUSES EYE AND
SKIN IRRITATION. KEEP OUT OF REACH OF CHILDREN. SEE BACK PANEL.
BACK:
HAZARDS:
CONTAINS PETROLEUM DISTILLATES, ETHYLENE GLYCOL MONOBUTYL ETHER
AND NAPHTHALENE. HARMFUL OR FATAL IF SWALLOWED. CAUSES SKIN AND
EYE IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. CONTAINS A SMALL
AMOUNT OF NAPHTHALENE WHICH IS SUSPECTED OF CAUSING CANCER.
PRECAUTION:
KEEP AWAY FROM HEAT OR FLAME. AVOID SWALLOWING, CONTACT WITH EYES OR SKIN,
OR BREATHING VAPOR. WASH IMMEDIATELY AFTER CONTACT. USE IN WELL-VENTILATED
AREA.
FIRST AID:
IF SWALLOWED, DO NOT INDUCE VOMITING - CALL PHYSICIAN IMMEDIATELY. IN
CASE OF CONTACT, FLUSH EYES WITH WATER AND WASH SKIN WITH SOAP AND WATER.
IF EYE DISCOMFORT PERSISTS, CONTACT A PHYSICIAN. IF AFFECTED BY VAPOR, GET
FRESH AIR - CALL PHYSICIAN IF SYMPTOMS PERSIST.
| SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS | |
CAS # CHEMICAL NAME PERCENT (W/W) INGREDIENT CLASSIFICATION*
64742-47-8 DISTILLATES, 40-60 FLAM. LIQ. 4 - H227; SKIN
PETROLEUM, IRRIT. 2 - H315; STOT-SE 3
HYDROTREATED - H335; ASP. 1 - H304;
LIGHT AQUATIC CHRON. 2 - H411
64742-94-5 NAPHTHA 20-30 FLAM. LIQ. 4 - H227; SKIN
(PETROLEUM), IRRIT. 2 - H315; STOT 3 -
HEAVY AROMATIC H336 (CNS); ASP. 1 - H304;
AQUATIC CHRON. 2 - H411
111-76-2 ETHYLENE GLYCOL 5-10 ACUTE TOX. 4 - H302, H312
MONOBUTYL ETHER & H332; SKIN IRRIT. 2 -
H315; EYE IRRIT. 2 - H319
91-20-3 NAPHTHALENE 1-5 ACUTE TOX. 4 - H302; CARC.
2 - H351; AQUATIC ACUTE 1
- H400; AQUATIC CHRON. 1 -
H410
95-63-6 1,2,4- 1-5 FLAM. LIQ. 3 - H226; ACUTE
TRIMETHYLBENZENE TOX. 4 - H332; SKIN IRRIT.
2 - H315; EYE IRRIT. 2 -
H319; ASPIRATION TOX. 1 -
H304; STOT-SE 3 - H335;
AQUATIC CHRON. 2 - H411
108-67-8 1,3,5- 1-3 FLAM. LIQ. 3 - H226; SKIN
TRIMETHYLBENZENE IRRIT. 2 - H315; EYE IRRIT.
2 - H319; ASPIRATION TOX.
1 - H304; STOT-SE 3 - H335;
AQUATIC CHRON. 2 - H411
526-73-8 1,2,3- 1-3 FLAM. LIQ. 3 - H226; ACUTE
TRIMETHYLEBENZENE TOX. 4 - H332; SKIN IRRIT.
2 - H315; EYE IRRIT. 2 -
H319; ASPIRATION TOX. 1 -
H304; STOT-SE 3 - H335;
AQUATIC CHRON. 2 - H411
COMPONENT RELATED REGULATORY INFORMATION:
THIS PRODUCT IS CONSIDERED HAZARDOUS UNDER 29 CFR 1910.1200
(HAZARD COMMUNICATION). THIS PRODUCT CONTAINS GLYCOL ETHERS.
THE EXACT CONCENTRATIONS OF ONE OR MORE OF THE ABOVE LISTED
COMPONENTS ARE BEING WITHHELD AS A TRADE SECRET.
| SECTION 4 - FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
EYES:
QUICKLY AND GENTLY BLOT AWAY EXCESS CHEMICAL. IMMEDIATELY FLUSH THE
CONTAMINATED EYE(S) WITH LUKEWARM, GENTLY FLOWING WATER FOR 15 MINUTES
OR UNTIL THE CHEMICAL IS REMOVED, WHILE HOLDING THE EYELID(S) OPEN. TAKE
CARE NOT TO RINSE CONTAMINATED WATER INTO THE UNAFFECTED EYE OR ONTO THE
FACE. SEEK IMMEDIATE MEDICAL ATTENTION.
SKIN:
REMOVE CONTAMINATED CLOTHING. QUICKLY AND GENTLY BLOT AWAY EXCESS
CHEMICAL. WASH GENTLY AND THOROUGHLY WITH WARM WATER AND NON-ABRASIVE
SOAP FOR 15 MINUTES OR UNTIL THE CHEMICAL IS REMOVED. GET MEDICAL
ATTENTION IF SKIN DISORDER DEVELOPS.
INGESTION:
NEVER GIVE ANYTHING BY MOUTH IF VICTIM IS RAPIDLY LOSING CONSCIOUSNESS,
OR IS UNCONSCIOUS OR CONVULSING. HAVE VICTIM RINSE MOUTH THOROUGHLY WITH
WATER. DO NOT INDUCE VOMITING. HAVE VICTIM DRINK 8 TO 10 OZ. OF WATER TO
DILUTE PRODUCT IN STOMACH. IF VOMITING OCCURS NATURALLY, HAVE VICTIM LEAN
FORWARD TO REDUCE RISK OF ASPIRATION. REPEAT ADMINISTRATION OF WATER. SEEK
IMMEDIATE MEDICAL ATTENTION OR ADVICE.
INHALATION:
IF AFFECTED, REMOVE SOURCE OF CONTAMINATION OR MOVE INDIVIDUAL TO FRESH
AIR. IF THE AFFECTED PERSON IS NOT BREATHING, TRAINED PERSONNEL SHOULD
BEGIN ARTIFICIAL RESPIRATION IMMEDIATELY. SEEK MEDICAL ATTENTION IF
SYMPTOMS PERSIST. IF OVERCOME BY VAPOR FROM HOT PRODUCT, IMMEDIATELY
REMOVE TO FRESH AIR AND CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
POTENTIAL HEALTH EFFECTS:
EYES:
THIS PRODUCT IS IRRITATING TO THE EYES. EFFECTS MAY INCLUDE A BURNING
SENSATION, REDNESS, SWELLING AND/OR BLURRED VISION.
POTENTIAL HEALTH EFFECTS:
SKIN:
THIS PRODUCT IS IRRITATING TO THE SKIN. PROLONGED OR REPEATED CONTACT
WITH THIS PRODUCT MAY DRY AND/OR DEFAT SKIN. SYMPTOMS MAY INCLUDE REDNESS,
EDEMA, DRYING OR CRACKING OF SKIN.
POTENTIAL HEALTH EFFECTS:
INGESTION:
MAY CAUSE IRRITATION OF THE MOUTH, GASTROINTESTINAL LINING, NAUSEA,
VOMITING, DIARRHEA, AND ABDOMINAL PAIN. SMALL AMOUNTS OF THIS PRODUCT,
IF ASPIRATED INTO THE LUNGS, MAY CAUSE MILD TO SEVERE PULMONARY INJURY,
POSSIBLY DEATH.
POTENTIAL HEALTH EFFECTS:
INHALATION:
INHALATION OF OIL MISTS OR FUMES CAN CAUSE IRRITATION OF THE MUCOUS
MEMBRANES AND UPPER RESPIRATORY TRACT. EXCESSIVE INHALATION OF THIS
PRODUCT CAUSES HEADACHE, DIZZINESS, NAUSEA, STUPOR, AND OTHER CENTRAL
NERVOUS SYSTEM EFFECTS LEADING TO VISUAL IMPAIRMENT, DIFFICULTY BREATHING,
MEMORY LOSS, CONVULSIONS AND INCOORDINATION. REPEATED AND PROLONGED
OVEREXPOSURE TO OIL MISTS MAY RESULT IN DROPLET DEPOSITION, OIL GRANULOMA
FORMATION, INFLAMMATION AND INCREASED INCIDENCE OF INFECTION. BREATHING OF
VAPOR OR MIST MAY AGGRAVATE ASTHMA AND INFLAMMATORY OR FIBROTIC PULMONARY
DISEASE.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PULMONARY ASPIRATION HAZARD IF SWALLOWED; TREAT SYMPTOMATICALLY.
| SECTION 5 - FIRE FIGHTING MEASURES | |
GENERAL FIRE HAZARDS:
FIRE AND EXPLOSION HAZARDS ARE MODERATE WHEN THIS PRODUCT IS EXPOSED TO
HEAT OR FLAME. LIQUID CAN BURN UPON HEATING TO TEMPERATURES AT OR ABOVE
THE FLASH POINT. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG THE
GROUND TO SOME DISTANT SOURCE OF IGNITION AND FLASH BACK.
EXTINGUISHING MEDIA:
DRY CHEMICAL, FOAM, CARBON DIOXIDE, WATER FOG. USE WATER TO COOL
FIRE-EXPOSED CONTAINERS AND TO PROTECT PERSONNEL. DIRECT WATER SPRAY
OR FOAM MAY CAUSE FROTHING AND SPATTERING. IF A LEAK OR SPILL HAS NOT
IGNITED, USE WATER SPRAY TO DISPERSE VAPORS AND TO FLUSH SPILLS AWAY
FROM EXPOSURE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
IRRITATING AND TOXIC GASES OR FUMES MAY BE RELEASED DURING A FIRE. UPON
COMBUSTION, THIS PRODUCT MAY YIELD CARBON MONOXIDE, CARBON DIOXIDE, AND/OR
OTHER LOW MOLECULAR WEIGHT HYDROCARBONS.
ADVICE FOR FIREFIGHTERS:
FIREFIGHTERS SHOULD WEAR FULL-FACE, SELF-CONTAINED BREATHING APPARATUS
AND IMPERVIOUS PROTECTIVE CLOTHING. FIREFIGHTERS SHOULD AVOID INHALING
ANY COMBUSTION PRODUCTS.
NFPA RATINGS:
HEALTH 2
FIRE 2
REACTIVITY 0
OTHER
HAZARD SCALE:
0 = MINIMAL
1 = SLIGHT
2 = MODERATE
3 = SERIOUS
4 = SEVERE
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ELIMINATE ALL SOURCES OF IGNITION OR FLAMMABLES THAT MAY COME INTO CONTACT
WITH A SPILL OF THIS PRODUCT. SURFACES MAY BECOME SLIPPERY AFTER SPILLAGE.
WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING DURING CLEANUP. DO NOT
ALLOW THE SPILLED PRODUCT TO ENTER PUBLIC DRAINAGE SYSTEMS OR OPEN
WATERCOURSES. IF PRODUCT IS SPILLED, NOTIFY APPROPRIATE AUTHORITIES AT
THE LOCAL, STATE, FEDERAL, AND PROVINCIAL LEVELS. PERSONS NOT WEARING
PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEANUP
HAS BEEN COMPLETED. STOP THE FLOW OF PRODUCT, IF THIS CAN BE DONE WITHOUT
RISK.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEAN-UP PROCEDURES:
ABSORB WITH NON-FLAMMABLE SUITABLE ABSORBENT SUCH AS SAND OR EARTH.
SCOOP UP USED ABSORBENT INTO DRUMS OR OTHER APPROPRIATE CONTAINER.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
AVOID PROLONGED OR REPEATED SKIN CONTACT WITH THIS PRODUCT. AVOID GETTING
THIS PRODUCT INTO CONTACT WITH YOUR EYES. AVOID THE GENERATION OF MISTS.
WASH THOROUGHLY AFTER HANDLING. USE THIS PRODUCT WITH ADEQUATE VENTILATION.
DISCARD ANY SHOES OR CLOTHING ITEMS THAT CANNOT BE DECONTAMINATED.
CONDITIONS FOR SAFE STORAGE (INCLUDING ANY INCOMPATIBILITIES):
DO NOT STORE NEAR HEAT, SPARKS, OPEN FLAME OR STRONG OXIDIZING AGENTS. DO
NOT STORE THIS PRODUCT IN OPEN OR UNLABELED CONTAINERS. STORE DRUMS IN A
COVERED AREA WITH SECONDARY CONTAINMENT. "EMPTY" CONTAINERS RETAIN PRODUCT
RESIDUE (LIQUID AND/OR VAPOR) AND CAN BE DANGEROUS. DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT,
FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY
EXPLODE. FOLLOW APPROPRIATE GROUNDING PROCEDURES.
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
A:
GENERAL PRODUCT INFORMATION:
FOLLOW ALL APPLICABLE EXPOSURE LIMITS. UNDER CONDITIONS WHICH MAY GENERATE
MISTS, THE COMPONENT SUPPLIER RECOMMENDS THE OSHA PEL OF 5 MG/M3 AND THE
ACGIH STEL OF 10 MG/M3 FOR OIL MISTS. INCLUDED BELOW ARE THE OSHA VACATED
PERMISSIBLE EXPOSURE LIMITS (PELS).
B:
COMPONENT EXPOSURE LIMITS:
COMPOUND ACGIH NIOSH OSHA OTHER
TWA STEL TWA STEL TWA STEL TWA
PETROLEUM N/E N/E 350 1800 500 PPM N/E N/E
DISTILLATES MG/M3 (C) MG/M3
2000
MG/M3
ETHYLENE GLYCOL 25 N/E 5 PPM (S) N/E 50 PPM (S) N/E IDLH
MONOBUTYL ETHE PPM (S) = 700
PPM
1,2,4- N/E N/E 25 PPM N/E N/E N/E N/E
TRIMETHYLBENZENE
1,3,5- N/E N/E 25 PPM N/E N/E N/E N/E
TRIMETHYLBENZENE
NAPHTHALENE 10 PPM 15 10 PPM 15 10 PPM N/E N/E
PPM PPM
(S) - SKIN EXPOSURE
(C) - CEILING EXPOSURE
N/E - NONE ESTABLISHED
ENGINEERING CONTROLS:
USE GENERAL VENTILATION AND USE LOCAL EXHAUST, WHERE POSSIBLE, IN CONFINED
OR ENCLOSED SPACES.
PERSONAL PROTECTIVE EQUIPMENT:
EYES/FACE:
WEAR SAFETY GLASSES. WEAR CHEMICAL GOGGLES OR FACESHIELD IF MIST IS LIKELY
TO OCCUR.
SKIN:
USE IMPERVIOUS GLOVES. WEAR OIL-IMPERVIOUS GARMENTS IF CONTACT IS
UNAVOIDABLE.
RESPIRATORY:
IN THE EVENT OF EXCESSIVE EXPOSURE TO VAPORS/MISTS/FUMES, USE NIOSH/OSHA
APPROVED RESPIRATORY EQUIPMENT. RESPIRATOR SHOULD BE SELECTED ON THE BASIS
OF FORM AND CONCENTRATION OF CONTAMINANT.
GENERAL:
USE GOOD HYGIENE WHEN HANDLING PETROLEUM PRODUCT. LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. EXCESSIVE MISTING MAY CAUSE SLIPPERY FLOORS - WEAR
APPROPRIATE FOOTWEAR. EYE WASH FOUNTAINS ARE RECOMMENDED.
| SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES | |
APPEARANCE: AMBER COLORED
ODOR: OIL / SOLVENT
PHYSICAL STATE: LIQUID
ODOR THRESHOLD: NOT APPLICABLE
PH: NOT APPLICABLE
MELTING/FREEZING POINT: NOT DETERMINED
INITIAL BOILING POINT & RANGE: NOT DETERMINED
FLASH POINT: 132 DEG. F (55.6 DEG. C)
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NOT DETERMINED
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
AUTO-IGNITION TEMPERATURE: NOT DETERMINED
DECOMPOSITION TEMPERATURE: NOT DETERMINED
VAPOR DENSITY: NOT DETERMINED
VAPOR PRESSURE: NOT DETERMINED
SOLUBILITIES: NEGLIGIBLE
PARTITION COEFFICIENT: NOT DETERMINED
EVAPORATION RATE: NOT DETERMINED
VISCOSITY: NOT DETERMINED
RELATIVE DENSITY: 0.83
DENSITY: NOT DETERMINED
| SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION | |
REACTIVITY: NOT REACTIVE
CHEMICAL STABILITY: STABLE
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
CONDITIONS TO AVOID: HEAT, IGNITION SOURCES AND SPARKS.
INCOMPATIBILITY:
THIS PRODUCT MAY REACT WITH STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION:
DECOMPOSITION OF THIS PRODUCT MAY YIELD CARBON MONOXIDE, CARBON DIOXIDE
AND/OR LOW MOLECULAR WEIGHT HYDROCARBONS.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
DESCRIPTION OF THE VARIOUS TOXICOLOGICAL EFFECTS:
LIKELY ROUTES OF EXPOSURE: INHALATION
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS (INCLUDING IMMEDIATE AND DELAYED EFFECTS AND
CHRONIC EFFECTS FOR SHORT- AND LONG-TERM EXPOSURE):
THIS PRODUCT IS IRRITATING TO THE EYES, RESPIRATORY SYSTEM AND SKIN.
EXCESSIVE INHALATION OF THIS PRODUCT CAUSES HEADACHE, DIZZINESS AND
INCOORDINATION. THIS PRODUCT MAY CAUSE NERVOUS SYSTEM EFFECTS INCLUDING
PERIPHERAL NEUROPATHY. THIS PRODUCT CONTAINS A CHEMICAL(S) WHICH HAS BEEN
SHOWN TO CAUSE CANCER IN LABORATORY ANIMALS. A COMPONENT OF THIS PRODUCT
HAS BEEN REPORTED TO CAUSE BIRTH DEFECTS AND/OR OTHER REPRODUCTIVE HARM.
COMPONENTS OF THIS PRODUCT MAY HAVE ADVERSE EFFECTS ON THE BLOOD-FORMING
SYSTEM. IRRITATING AND TOXIC VAPORS MAY BE RELEASED UPON COMBUSTION OF
PRODUCT.
POTENTIAL HEALTH EFFECTS:
EYES:
EFFECTS MAY INCLUDE A BURNING SENSATION, REDNESS, SWELLING AND/OR BLURRED
VISION.
POTENTIAL HEALTH EFFECTS:
SKIN:
PROLONGED OR REPEATED CONTACT WITH THIS PRODUCT MAY DRY AND/OR DEFAT SKIN.
SYMPTOMS MAY INCLUDE REDNESS, EDEMA, DRYING OR CRACKING OF SKIN.
POTENTIAL HEALTH EFFECTS:
INGESTION:
THIS PRODUCT MAY CAUSE IRRITATION OF THE MOUTH, GASTROINTESTINAL LINING,
NAUSEA, VOMITING, DIARRHEA, AND ABDOMINAL PAIN. INGESTION OF THIS PRODUCT
MAY CAUSE HEADACHE, DIZZINESS, INCOORDINATION, AND GENERAL WEAKNESS. SMALL
AMOUNTS OF THIS PRODUCT, IF ASPIRATED INTO THE LUNGS, MAY CAUSE MILD TO
SEVERE PULMONARY INJURY, POSSIBLY DEATH. INGESTION OF THIS PRODUCT MAY
CAUSE RED BLOOD CELL HEMOLYSIS AND POSSIBLE LIVER AND KIDNEY INJURY.
POTENTIAL HEALTH EFFECTS:
INHALATION:
INHALATION OF OIL MISTS OR FUMES CAN CAUSE IRRITATION OF THE MUCOUS
MEMBRANES AND UPPER RESPIRATORY TRACT. EXCESSIVE INHALATION OF THIS
PRODUCT CAUSES HEADACHE, DIZZINESS, NAUSEA, STUPOR, AND OTHER CENTRAL
NERVOUS SYSTEM EFFECTS LEADING TO VISUAL IMPAIRMENT, DIFFICULTY BREATHING,
MEMORY LOSS, CONVULSIONS AND INCOORDINATION. REPEATED AND PROLONGED
OVEREXPOSURE TO OIL MISTS MAY RESULT IN DROPLET DEPOSITION, OIL GRANULOMA
FORMATION, INFLAMMATION AND INCREASED INCIDENCE OF INFECTION. BREATHING OF
VAPOR OR MIST MAY AGGRAVATE ASTHMA AND INFLAMMATORY OR FIBROTIC PULMONARY
DISEASE. REPEATED OVEREXPOSURE TO NAPHTHALENE MAY CAUSE DESTRUCTION OF
RED BLOOD CELLS WITH ANEMIA, FEVER, JAUNDICE AND KIDNEY AND LIVER DAMAGE.
DATA AND/OR ACUTE TOXICITY ESTIMATES:
NO DATA AVAILABLE ON PRODUCT AS A WHOLE.
CAS # COMPONENT PERCENT LD50 - LD50 - LC50 -
ORAL DERMAL INHALATION
(RAT) (RABBIT) (RAT)
111-76-2 ETHYLENE GLYCOL 5-10 470 MG/ KG 220 MG/KG 450 PPM
MONOBUTYL ETHER (4H)
91-20-3 NAPHTHALENE 1-5 490 MG/KG >20 G/KG >340 MG/M3
(1H)
95-63-6 1,2,4- 1-5 5 G/KG NOT 18 G/M3
TRIMETHYLBENZENE AVAILABLE (4H)
108-67-8 1,3,5- 1-5 NOT NOT 24 G/M3
TRIMETHYLBENZENE AVAILABLE AVAILABLE (4H)
ONE OR MORE COMPONENTS HAVE PRODUCED DAMAGE AFTER PROLONGED EXPOSURE
IN LABORATORY ANIMALS TO ONE OR MORE OF THE FOLLOWING: KIDNEYS, LIVER,
SPLEEN, BLOOD AND/OR CIRCULATORY SYSTEM. NAPHTHALENE HAS BEEN SHOWN TO
CAUSE CANCER IN LABORATORY ANIMALS AND IS CLASSIFIED GROUP 2B BY IARC.
ETHYLENE GLYCOL MONOBUTYL ETHER HAS BEEN CLASSIFIED GROUP 3 BY IARC.
ETHYLENE GLYCOL MONOBUTYL ETHER HAS BEEN LINKED WITH OR REPORTED TO
CAUSE EITHER BIRTH DEFECTS AND/OR OTHER REPRODUCTIVE HARM.
CATEGORY CLASSIFICATION BASED ON AVAILABLE DATA
ACUTE TOXICITY CONCLUSIVE BUT NOT SUFFICIENT FOR CLASSIFICATION
SKIN/EYE IRRITATION SKIN IRRITATION 2 (COMPONENT ADDITIVITY); EYE
IRRITATION 2 (COMPONENT ADDITIVITY)
CORROSIVITY CONCLUSIVE BUT NOT SUFFICIENT FOR CLASSIFICATION
RESPIRATORY OR CONCLUSIVE BUT NOT SUFFICIENT FOR CLASSIFICATION
SKIN SENSITIZATION
GERM CELL MUTAGENICITY DATA LACKING
CARCINOGENICITY CONTAINS NAPHTHALENE WHICH IS SUSPECTED OF
CAUSING CANCER BASED ON ANIMAL STUDIES.
REPRODUCTIVE TOXICITY DATA LACKING
STOT-SE STOT 3 (CNS EFFECTS, RESPIRATORY IRRITATION)
STOT-RE DATA LACKING
ASPIRATION HAZARD ASP. 1
| SECTION 12 - ECOLOGICAL INFORMATION | |
NO ECOTOXICITY OR ENVIRONMENTAL FATE DATA AVAILABLE ON PRODUCT AS A WHOLE.
A SUMMARY OF AQUATIC TOXICITY DATA FOR COMPONENTS OF THIS PRODUCT IS
AVAILABLE UPON REQUEST.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
US EPA WASTE NUMBER & DESCRIPTIONS:
USER MUST TEST WASTE USING METHODS DESCRIBED IN 40 CFR PART 261 TO
DETERMINE IF IT MEETS APPLICABLE DEFINITIONS OF HAZARDOUS WASTE. IF
DISPOSED OF AS SHIPPED, THIS PRODUCT MAY BE CONSIDERED A D001 IGNITABLE
WASTE.
DISPOSAL INSTRUCTIONS:
DISPOSE OF WASTE PRODUCT ACCORDING TO LOCAL, STATE, FEDERAL, AND
PROVINCIAL ENVIRONMENTAL REGULATIONS. DO NOT ALLOW THIS PRODUCT
TO DRAIN INTO SEWERS/WATER SUPPLIES. PRODUCT SHOULD BE RECYCLED
IF POSSIBLE.
| SECTION 14 - TRANSPORTATION INFORMATION | |
GENERAL TRANSPORTATION INFORMATION:
NOTE:
INFORMATION IN THIS SECTION (SECTION 14) IS PRESENTED AS A GUIDE ONLY.
REQUIREMENTS MAY VARY DEPENDING UPON PACKAGE SIZE AND EXCEPTIONS USED,
IF ANY. FOLLOW CURRENT, APPLICABLE REQUIREMENTS UNDER DOT, TDG, IMO/IMDG,
AND ICAO/IATA TO ENSURE REGULATORY COMPLIANCE.
U.S. DEPARTMENT OF TRANSPORTATION REGULATIONS GROUND TRANSPORTATION:
NON-BULK. NOT REGULATED BASED ON COMBUSTIBLE LIQUID EXCEPTION
[49CFR 173.150(F)]. REVIEW AND FOLLOW ALL REQUIREMENTS PERTAINING
TO THIS EXCEPTION. SEE ALSO 49 CFR 171.4(C). NAPHTHALENE: RQ 100 LBS.
CANADIAN TDG REGULATIONS GROUND TRANSPORTATION:
NON-BULK. NOT REGULATED BASED ON EXCEPTION, CANADA TDG, PART I, SECTION
1.33. REVIEW AND FOLLOW ALL REQUIREMENTS PERTAINING TO THIS EXCEPTION.
ICAO/IATA:
UN1268, PETROLEUM DISTILLATES, N.O.S., (PETROLEUM NAPHTHAS) 3, PG III
LABEL: FLAMMABLE LIQUID
IMO/IMDG:
UN1268, PETROLEUM DISTILLATES, N.O.S., (PETROLEUM NAPHTHAS) 3, PG III,
(55.6 DEG. C C.C.), MARINE POLLUTANT
EMS: F-E, S-E
LABEL: FLAMMABLE LIQUID
| SECTION 15 - REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
A:
GENERAL PRODUCT INFORMATION:
COMPONENTS LISTED IN SECTION 3 OF THE SDS ARE PRESENT ON THE TSCA
INVENTORY.
THIS PRODUCT IS A REGISTERED FUEL ADDITIVE (40 CFR 79) - REGISTRATION
#1255-0004.
B:
COMPONENT ANALYSIS:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS REQUIRED TO BE IDENTIFIED
UNDER SARA SECTION 313 (40 CFR 372.65).
ETHYLENE GLYCOL MONOBUTYL ETHER (111-76-2) (GLYCOL ETHER CATEGORY):
NAPHTHALENE (91-20-3)
1,2,4-TRIMETHYLBENZENE (95-63-6)
C.
COMPONENT MARINE POLLUTANT:
THIS PRODUCT CONTAINS PETROLEUM NAPHTHAS WHICH ARE REQUIRED BY US DOT
TO BE IDENTIFIED AS A MARINE POLLUTANT.
OTHER REGULATIONS:
COMPONENTS LISTED IN SECTION 3 OF THE SDS ARE PRESENT ON THE DSL AND
EINECS INVENTORIES. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH
THE HAZARD CRITERIA REQUIRED BY THE CANADIAN HAZARDOUS PRODUCT ACT AND
THE SDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CANADIAN HAZARDOUS
PRODUCTS REGULATIONS.
WHMIS CLASSIFICATION:
FLAM. LIQ. 3 - H226; SKIN IRRIT. 2 - H315; EYE IRRIT. 2 - H319; CARC.
2 - H351; STOT-SE 3 - H335 & H336; ASP. 1 - H304.
| SECTION 16 - OTHER INFORMATION | |
OTHER INFORMATION:
HAZARD STATEMENTS FROM SECTION 3:
H226: FLAMMABLE LIQUID AND VAPOR.
H227: COMBUSTIBLE.
H302: HARMFUL IF SWALLOWED.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H312: HARMFUL IN CONTACT WITH SKIN.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H351: SUSPECTED OF CAUSING CANCER.
H400: VERY TOXIC TO AQUATIC LIFE.
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
HMIS RATINGS:
HEALTH 2*
FIRE 2
REACTIVITY 0
PERS. PROT. IMPERVIOUS GLOVES/SAFETY GLASSES (CHEMICAL GOGGLES
IF SPLASHING IS POSSIBLE)
HAZARD SCALE:
0 = MINIMAL
1 = SLIGHT
2 = MODERATE
3 = SERIOUS
4 = SEVERE
* = CHRONIC HAZARD
OTHER INFORMATION:
THE INFORMATION AND RECOMMENDATIONS PRESENTED IN THIS SAFETY DATA SHEET
ARE BASED ON SOURCES BELIEVED TO BE RELIABLE ON THE DATE HEREOF. CLARCOR
INC. MAKES NO REPRESENTATION ON ITS COMPLETENESS OR ACCURACY. THIS PRODUCT
IS SOLD "AS IS" AND IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE
PRODUCT'S SUITABILITY FOR ITS INTENDED USE, THE PRODUCT'S SAFE USE, AND
THE PRODUCT'S PROPER DISPOSAL. THE STATEMENTS AND DESCRIPTIONS PROVIDED
ARE INFORMATIONAL ONLY AND NO REPRESENTATIONS OR WARRANTIES, EITHER
EXPRESSED OR IMPLIED, OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR
PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION
PROVIDED IN THIS SAFETY DATA SHEET OR TO THE PRODUCT TO WHICH SUCH
INFORMATION REFERS. CLARCOR INC. NEITHER ASSUMES NOR AUTHORIZES ANY
OTHER PERSON TO ASSUME FOR IT, ANY OTHER OR ADDITIONAL LIABILITY OR
RESPONSIBILITY RESULTING FROM THE USE OF, OR RELIANCE UPON, THIS
INFORMATION. CLARCOR INC. ASSUMES NO RESPONSIBILITY FOR INJURY TO
RECIPIENT OR TO THIRD PERSONS OR FOR ANY DAMAGE TO ANY PROPERTY AND
RECIPIENT ASSUMES ALL SUCH RISKS.
KEY/LEGEND:
N = NO
Y = YES
PPM - PARTS PER MILLION
MG/M3 = MILLIGRAMS PER CUBIC METER OF AIR
ACGIH = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
OSHA = OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
TLV = THRESHOLD LIMIT VALUE
NIOSH = NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
IDLH = IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONCENTRATIONS
NTP = NATIONAL TOXICOLOGY PROGRAM
IARC = INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
TSCA = TOXIC SUBSTANCE CONTROL ACT
DSL = DANGEROUS SUBSTANCES LIST
EINECS = EUROPEAN INVENTORY OF NEW AND EXISTING CHEMICAL SUBSTANCES
CONTACT:
FOR FURTHER INFORMATION CALL: 1-800-842-2496
ISSUE DATE: 8/10/2015
PRINT DATE: 10/1/2015
REVISION: 14