| Common Name: | MS HEAVY DUTY ACID CLEANER GAL 4PK, HDAC4GAL |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 10/28/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 48RE96, 48RE97 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DATE PRINTED: 10/28/2019
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: MS HEAVY DUTY ACID CLEANER GAL 4PK
PRODUCT IDENTIFIER: HDAC4GAL
RECOMMENDED USE: CLEANER
REVISION DATE: 10/28/2019
SUPERCEDES DATE: NEW SDS
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
| 2. HAZARD IDENTIFICATION | |
CLASSIFICATION:
SYMBOL(S) OF PRODUCT:
CORROSION
SKULLS AND CROSSBONES
SIGNAL WORD: DANGER
GHS HAZARD STATEMENTS:
ACUTE TOXICITY, INHALATION, CATEGORY 3:
H331: TOXIC IF INHALED.
ACUTE TOXICITY, ORAL, CATEGORY 4:
H302: HARMFUL IF SWALLOWED.
STOT, SINGLE EXPOSURE, CATEGORY 3, RTI:
H335: MAY CAUSE RESPIRATORY IRRITATION.
SKIN CORROSION, CATEGORY 1A:
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
GHS LABEL PRECAUTIONARY STATEMENTS:
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P301+P312:
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P310: IF EXPOSED IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P311: CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P321: FOR SPECIFIC TREATMENT SEE LABEL
P403+P233:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL AND
NATIONAL REGULATIONS.
GHS SDS PRECAUTIONARY STATEMENTS:
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
RANGE
HYDROCHLORIC ACID 7647-01-0 50-75 GHS04-GHS05 H280-301-314-331
-GHS06 -335
POLYOXYETHYLENE 9002-92-0 25-50 GHS07 H302
LAURYL ETHER
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES
HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF
EYES OR KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS. IMMEDIATELY FLUSH SKIN WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CLOTHING. GET
MEDICAL ATTENTION IMMEDIATELY. WASH CLOTHING SEPARATELY BEFORE REUSE.
DESTROY CONTAMINATED SHOES.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION:
IF SWALLOWED, RINSE MOUTH WITH WATER. IF FEELING UNWELL, GET MEDICAL
ATTENTION. SWALLOWING LESS THAN AN OUNCE WILL NOT CAUSE SIGNIFICANT HARM.
FOR LARGER AMOUNTS, DO NOT INDUCE VOMITING, BUT GIVE ONE OR TWO GLASSES OF
WATER TO DRINK AND GET MEDICAL ATTENTION. IF SWALLOWED, DO NOT INDUCE
VOMITING. IF VICTIM IS CONSCIOUS AND ALERT, GIVE 2 TO 4 CUPFULS OF WATER
OR MILK. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. TREAT SYMPTOMATICALLY AND
SUPPORTIVELY. DO NOT INDUCE VOMITING UNLESS ADVISED BY A PHYSICIAN. CALL
NEAREST POISON CONTROL CENTER OR PHYSICIAN IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA: NONE KNOWN
UNUSUAL FIRE AND EXPLOSION HAZARDS:
KEEP CONTAINERS TIGHTLY CLOSED. FLASH POINT IS TESTED TO BE GREATER THAN
200 DEGREES F. NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
SPECIAL FIREFIGHTING PROCEDURES:
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT BUILDUP OF STEAM.
IF WATER IS USED, FOG NOZZLES ARE PREFERRED. CONTAINERS CAN RUPTURE AND
RELEASE HIGHLY TOXIC MATERIAL IF EXPOSED TO HEAT. SUBSTANCE IS
NONCOMBUSTIBLE BUT REACTS WITH MANY METALS TO FORM EXPLOSIVE HYDROGEN GAS.
USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. CONTAINERS MAY
EXPLODE WHEN HEATED.
SPECIAL FIRE AND EXPLOSION HAZARD (COMBUSTIBLE DUST): NO INFORMATION
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
IF SPILLED, CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT.
DISPOSE OF CONTAMINATED ABSORBENT, CONTAINER, AND UNUSED CONTENTS IN
ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO NOT INCINERATE
CLOSED CONTAINERSAVOID RUNOFF INTO SEWERS AND WATERWAYS. PROVIDE
VENTILATION AND APPROACH SPILL FROM UPWIND USING PROPER PERSONAL
PROTECTIVE EQUIPMENT AS INDICATED IN SECTION 8. CAREFULLY NEUTRALIZE SPILL
WITH SODIUM BICARBONATE (NAHCO3). CONTAIN SPILLED LIQUID WITH SAND OR
EARTH. DO NOT USE COMBUSTIBLE MATERIALS SUCH AS SAWDUST. DISPOSE OF
ACCORDING TO LOCAL, STATE (PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT
INCINERATE CLOSED CONTAINERS.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. USE ONLY WITH ADEQUATE
VENTILATION. FOLLOW ALL SDS AND LABEL PRECAUTIONS EVEN AFTER CONTAINER IS
EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE:
STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN
NOT IN USE.
ADVICE ON SAFE HANDLING OF COMBUSTIBLE DUST: NO INFORMATION
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % ACGIH ACGIH OSHA OSHA
LESS THAN TLV-TWA TLV-STEL PEL-TWA PEL-
CEILING
HYDROCHLORIC 7647-01-0 55.0 N.E. N.E. N.E. 5 PPM
ACID
POLYOXYETHYLENE 9002-92-0 50.0 N.E. N.E. N.E. N.E.
LAURYL ETHER
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
PROVIDE GENERAL DILUTION OF LOCAL EXHAUST VENTILATION IN VOLUME AND
PATTERN TO KEEP TLV OF HAZARDOUS INGREDIENTS BELOW ACCEPTABLE LIMITS.
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSSVENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE.
SKIN PROTECTION:
USE GLOVES TO PREVENT PROLONGED SKIN CONTACT. USE IMPERVIOUS GLOVES TO
PREVENT SKIN CONTACT AND ABSORPTION OF THIS MATERIAL THROUGH THE SKIN.
NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE
REGARDING TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
ENGINEERING MEASURES FOR COMBUSTIBLE DUST: NO INFORMATION
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
PHYSICAL STATE: LIQUID
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
SPECIFIC GRAVITY: 1.117
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT, N-OCTANOL/WATER: N.D.
DECOMPOSTION TEMP., DEG. C: N.D.
BOILING RANGE, DEG. C: -18 - 100
EXPLOSIVE LIMITS, VOL%: N.A. - N.A.
FLAMMABILITY: DOES NOT SUPPORT COMBUSTION
FLASH POINT, DEG. C: 537
EVAPORATION RATE: SLOWER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: N.D.
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID: AVOID CONTACT WITH METALS.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES. PRODUCT SLOWLY CORRODES COPPER, ALUMINUM, ZINC, AND GALVANIZED
SURFACES.
HAZARDOUS DECOMPOSITION:
WHEN HEATED TO DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
DECOMPOSITION PRODUCES HYDROGEN CHLORIDE, CHLORINE AND HYDROGEN GASES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT:
IRRITATING, AND MAY INJURE EYE TISSUE IF NOT REMOVED PROMPTLY. SUBSTANCE
CAUSES SEVERE EYE IRRITATION. INJURY MAY BE PERMANENT.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
SEVERELY IRRITATING; MAY CAUSE PERMANENT SKIN DAMAGE. LOW HAZARD FOR USUAL
INDUSTRIAL HANDLING OR COMMERCIAL HANDLING BY TRAINED PERSONNEL.
EFFECTS OF OVEREXPOSURE - INHALATION:
HARMFUL IF INHALED. HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE
HARMFUL IF INHALED. AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST. HIGH
VAPOR CONCENTRATIONS ARE IRRITATING TO THE EYES, NOSE, THROAT AND LUNGS.
EFFECTS OF OVEREXPOSURE - INGESTION:
CORROSIVE AND MAY CAUSE SEVERE AND PERMANENT DAMAGE TO MOUTH, THROAT AND
STOMACH. SUBSTANCE MAY BE HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
REPEATED EXPOSURE TO LOW CONCENTRATIONS OF HCl VAPOR OR MIST MAY CAUSE
BLEEDING OF NOSE AND GUMS.
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
7647-01-0 HYDROCHLORIC 238 - 277 MG/KG >5010 MG/KG N.E.
ACID RAT RABBIT
9002-92-0 POLYOXYETHYLENE 1000 MG/KG RAT N.E. 2000 G/L
LAURYL ETHER
N.E. - NOT ESTABLISHED
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. RCRA HAZARDOUS WASTE:
THIS MATERIAL, WHEN DISCARDED OR DISPOSED OF, COULD BE A HAZARDOUS WASTE
ACCORDING TO FEDERAL REGULATIONS (40 CFR 261) DUE TO THE CHARACTERISTIC OF
CORROSIVITY (D002). CHECK STATE AND LOCAL REGULATIONS FOR DISPOSAL
REQUIREMENTS. CHEMICAL ADDITIONS, PROCESSING OR OTHERWISE ALTERING THIS
MATERIAL MAY MAKE THE WASTE MANAGEMENT INFORMATION PRESENTED IN THIS SDS
INCOMPLETE, INACCURATE, OR OTHERWISE INAPPROPRIATE.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER NA1760 UN1760 UN1760 N.A.
PROPER SHIPPING COMPOUNDS, CORROSIVE CORROSIVE NOT
NAME: CLEANING LIQUID, LIQUID, REGULATED
LIQUID, N.O.S. N.O.S.
(HYDROCHLORIC (HYDROCHLORIC (HYDROCHLORIC
ACID) ACID) ACID)
HAZARD CLASS 8 8 8 N.A.
PACKING GROUP III III III N.A.
LIMITED NO NO NO NO
QUANTITY
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
ACUTE TOXICITY (ANY ROUTE OF EXPOSURE), SKIN CORROSION OR IRRITATION,
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
HYDROCHLORIC ACID 7647-01-0
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
U.S. STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
WARNING: NO PROP. 65 WARNING IS REQUIRED.
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA RATINGS:
HEALTH 3
FLAMMABILITY 0
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS: 0.00%
SDS REVISION DATE: 10/28/2019
REASON FOR REVISION:
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
THE MANUFACTURER BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION AND
BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS OF
THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS OF
HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL, WE
ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. THE MANUFACTURER MAKES NO
WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY OF
THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE
USER TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO
COMPLY WITH ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL
LAWS AND REGULATIONS.