| Common Name: | LOCTITE AA H3151 50ML H, 2025105_343602, LOCTITE AA H3151 50ML R, 2025105_201092 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 8/5/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 48VG66 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 005.0
ISSUE DATE: 08/05/2014
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE AA H3151 50ML H
IDH NUMBER: 2024929
PRODUCT TYPE: ACRYLICS
ITEM NUMBER: 2025105_343602
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE LIQUID 2
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S):
FLAME
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES - NO SMOKING. KEEP
CONTAINER TIGHTLY CLOSED. NO RELEASE INTO WATER. USE EXPLOSION-PROOF
EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST
STATIC DISCHARGE. AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH THOROUGHLY
AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
WEAR PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN (OR HAIR): TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING. CALL A POISON CONTROL CENTER
OR PHYSICIAN IF YOU FEEL UNWELL.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
IN CASE OF FIRE: USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A
WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
METHYL METHACRYLATE 80-62-6 60 - 100
METHACRYLATE MONOMER PROPRIETARY 5 - 10
ALDEHYDE-AMINE CONDENSATE PROPRIETARY 1 - 5
ZINC CHLORIDE 7646-85-7 1 - 5
ZEOLITES 1318-02-1 0.1 - 1
*EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED
TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES
BEFORE REUSE.
EYE CONTACT:
FLUSH WITH COPIOUS AMOUNTS OF WATER, PREFERABLY, LUKEWARM WATER FOR AT
LEAST 15 MINUTES, HOLDING EYELIDS OPEN ALL THE TIME. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS, TRAVEL CONSIDERABLE
DISTANCE TO SOURCE OF IGNITION, AND FLASH BACK. CLOSED CONTAINERS MAY
RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. OXIDES OF ZINC. CYANIDES. HYDROGEN
CHLORIDE. TOXIC FUMES. IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. ENSURE ADEQUATE VENTILATION. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. REFER TO SECTION 8 "EXPOSURE
CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP. SOAK UP WITH INERT
ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER,
SAWDUST). SCRAPE UP SPILLED MATERIAL AND PLACE IN A CLOSED CONTAINER FOR
DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER CLOSED.
DURING USE AND UNTIL ALL VAPORS ARE GONE:
KEEP AREA VENTILATED - DO NOT SMOKE; EXTINGUISH ALL FLAMES, PILOT LIGHTS,
AND HEATERS; TURN OFF STOVES, ELECTRICAL TOOLS AND APPLIANCES, AND ANY
OTHER SOURCES OF IGNITION. MAKE SURE CONTAINERS ARE PROPERLY GROUNDED
BEFORE USE OR TRANSFER OF MATERIAL.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN 0 DEG. C (32 DEG. F) AND 32 DEG. C
(89.6 DEG. F) KEEP CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED
PLACE AWAY FROM INCOMPATIBLE MATERIALS. KEEP AWAY FROM HEAT, SPARK AND
FLAME. PROTECT FROM DIRECT SUNLIGHT. MAINTAIN HEAD SPACE IN STORAGE
CONTAINERS TO SUPPORT OXYGEN REQUIREMENTS OF THE INHIBITOR(S).
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
METHYL METHACRYLATE 50 PPM TWA 100 PPM NONE 50 PPM
100 PPM STEL (410 MG/M3)
(SENSITIZER.) PEL
METHACRYLATE MONOMER NONE NONE NONE NONE
ALDEHYDE-AMINE NONE NONE NONE NONE
CONDENSATE
ZINC CHLORIDE 2 MG/M3 STEL 1 MG/M3 PEL NONE NONE
FUME. FUME.
1 MG/M3 TWA
FUME.
ZEOLITES 1 MG/M3 TWA NONE NONE NONE
RESPIRABLE
FRACTION.
10 MG/M3 TWA
INHALABLE
DUST.
3 MG/M3 TWA
RESPIRABLE
FRACTION.
ENGINEERING CONTROLS:
USE LOCAL VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO MAINTAIN
VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID, PASTE
COLOR: YELLOW
ODOR: STRONG
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: >212 DEG. F (>100 DEG. C) NONE
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 0.96
VAPOR DENSITY: >1
FLASH POINT: 14 DEG. C (57.2 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: (ETHER = 1), FASTER THAN ETHER.
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0.28 %; 2.65 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS:
POLYMERIZATION MAY OCCUR AT ELEVATED TEMPERATURES OR UPON DEPLETION OF
INHIBITOR.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. OXIDES OF ZINC. HYDROGEN CHLORIDE.
CYANIDES. TOXIC FUMES. IRRITATING VAPORS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS. ACIDS. BASES. FREE RADICAL INITIATORS. ALKALI METALS.
SULFIDES.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS. PROTECT
FROM DIRECT SUNLIGHT. LOSS OF POLYMERIZATION INHIBITOR. LOSS OF DISSOLVED
AIR. DO NOT MIX IN BATCHES GREATER THAN 100 GRAMS (0.22 POUNDS) UNLESS YOU
PLAN TO USE IMMEDIATELY.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION. DROWSINESS. DIZZINESS.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
METHYL METHACRYLATE ORAL LD50 (RAT): ALLERGEN, IRRITANT,
7,800 MG/KG KIDNEY, LIVER,
MUTAGEN, NERVOUS
ORAL LD50 (RABBIT): SYSTEM, RESPIRATORY
6,000 MG/KG
ORAL LD50 (RAT):
9,400 MG/KG
INHALATION LC50
(RAT, 8 H): 3750 PPM
METHACRYLATE MONOMER ORAL LD50 (RAT): IRRITANT, ALLERGEN
22,600 MG/KG
ORAL LD50 (RAT):
16.0 G/KG
DERMAL LD50 (RABBIT):
11,300 MG/KG
INHALATION LC50
(RAT, 4 H): 4,910 MG/L
ALDEHYDE-AMINE CONDENSATE NONE NO RECORDS
ZINC CHLORIDE ORAL LD50 (RAT): LUNG, CORROSIVE,
350 MG/KG IRRITANT, CENTRAL
NERVOUS SYSTEM, EYES,
ORAL LD50 (RAT): METABOLIC, PANCREAS,
350 MG/KG KIDNEY, BLOOD, IMMUNE
SYSTEM
ORAL LD50 (RAT):
1,100 MG/KG
INHALATION LC50
(RAT, 10 MIN):
<=1.975 MG/L
ZEOLITES NONE MUTAGEN, RESPIRATORY,
SOME EVIDENCE OF
CARCINOGENICITY
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
METHYL METHACRYLATE NO NO NO
METHACRYLATE MONOMER NO NO NO
ALDEHYDE-AMINE CONDENSATE NO NO NO
ZINC CHLORIDE NO NO NO
ZEOLITES NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER:
D001: IGNITABLE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: ADHESIVES
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1133
PACKING GROUP: II
DOT HAZARDOUS SUBSTANCE(S): METHYL METHACRYLATE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: ADHESIVES
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1133
PACKING GROUP: II
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: ADHESIVES
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1133
PACKING GROUP: II
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: FIRE, IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). METHYL METHACRYLATE
(CAS# 80-62-6). ZINC CHLORIDE (CAS# 7646-85-7).
CERCLA REPORTABLE QUANTITY:
METHYL METHACRYLATE (CAS# 80-62-6): 1,000 LBS. (454 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: RENA PETRIDES, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 08/05/2014
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 002.0
ISSUE DATE: 03/23/2015
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: LOCTITE AA H3151 50ML R
PRODUCT TYPE: ACRYLIC ADHESIVE
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 2024930
ITEM NUMBER: 2025105_2010926
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE DAMAGE.
MAY CAUSE RESPIRATORY IRRITATION.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE LIQUID 2
SKIN IRRITATION 2
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S):
FLAME
CORROSION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES - NO SMOKING. KEEP
CONTAINER TIGHTLY CLOSED. NO RELEASE INTO WATER. USE EXPLOSION-PROOF
EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST
STATIC DISCHARGE. AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH THOROUGHLY
AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
WEAR PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN (OR HAIR): TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CONTROL CENTER OR PHYSICIAN.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
IN CASE OF FIRE: USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE IN
A WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
METHYL METHACRYLATE 80-62-6 30 - 60
2-HYDROXYETHYL METHACRYLATE 868-77-9 10 - 30
METHACRYLIC ACID 79-41-4 1 - 5
METHACRYLATE ESTER PROPRIETARY 1 - 5
TERT-BUTYL PERBENZOATE 614-45-9 0.1 - 1
GLASS, OXIDE, CHEMICALS 65997-17-3 0.1 - 1
TALC 14807-96-6 0.1 - 1
1,1,2-TRICHLOROETHANE 79-00-5 0.1 - 1
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED
TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. IMMEDIATELY FLUSH SKIN WITH
PLENTY OF WATER (USING SOAP, IF AVAILABLE). GET MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE.
EYE CONTACT:
FLUSH WITH COPIOUS AMOUNTS OF WATER, PREFERABLY, LUKEWARM WATER FOR AT
LEAST 15 MINUTES, HOLDING EYELIDS OPEN ALL THE TIME. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS, TRAVEL CONSIDERABLE
DISTANCE TO SOURCE OF IGNITION, AND FLASH BACK. CLOSED CONTAINERS MAY
RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF PHOSPHORUS. OXIDES OF SULFUR. HYDROGEN
CHLORIDE. ACIDS. ALCOHOLS. ALDEHYDES. TOXIC FUMES. IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. ENSURE ADEQUATE VENTILATION. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. REFER TO SECTION 8 "EXPOSURE
CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP. SOAK UP WITH INERT
ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER,
SAWDUST). SCRAPE UP SPILLED MATERIAL AND PLACE IN A CLOSED CONTAINER FOR
DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING.
DURING USE AND UNTIL ALL VAPORS ARE GONE:
KEEP AREA VENTILATED - DO NOT SMOKE; EXTINGUISH ALL FLAMES, PILOT LIGHTS,
AND HEATERS; TURN OFF STOVES, ELECTRICAL TOOLS AND APPLIANCES, AND ANY
OTHER SOURCES OF IGNITION. KEEP CONTAINER CLOSED.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN 2 DEG. C (35.6 DEG. F) AND 8 DEG. C
(46.4 DEG. F) KEEP CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED
PLACE AWAY FROM INCOMPATIBLE MATERIALS. KEEP AWAY FROM HEAT, SPARK AND
FLAME. PROTECT FROM DIRECT SUNLIGHT. MAINTAIN HEAD SPACE IN STORAGE
CONTAINERS TO SUPPORT OXYGEN REQUIREMENTS OF THE INHIBITOR(S).
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
METHYL METHACRYLATE 50 PPM TWA 100 PPM NONE 50 PPM
(410 MG/M3)
100 PPM STEL PEL
(SENSITIZER.)
2-HYDROXYETHYL NONE NONE NONE 3 PPM
METHACRYLATE CEILING
METHACRYLIC ACID 20 PPM TWA NONE NONE NONE
METHACRYLATE ESTER NONE NONE NONE NONE
TERT-BUTYL PERBENZOATE NONE NONE NONE NONE
GLASS, OXIDE, CHEMICALS 10 MG/M3 TWA 15 MG/M3 TWA NONE NONE
INHALABLE TOTAL DUST.
DUST.
3 MG/M3 TWA 5 MG/M3 TWA
RESPIRABLE RESPIRABLE
FRACTION. FRACTION.
1 FIBERS/CM3
TWA FIBER.
TALC 2 MG/M3 TWA 20 MPPCF TWA NONE 50 PPM
RESPIRABLE
FRACTION. 2.4 MPPCF TWA
RESPIRABLE.
0.1 MG/M3 TWA
RESPIRABLE.
0.3 MG/M3 TWA
TOTAL DUST.
1,1,2-TRICHLOROETHANE 10 PPM TWA 10 PPM NONE NONE
(SKIN) (45 MG/M3)
PEL (SKIN)
ENGINEERING CONTROLS:
USE LOCAL VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO MAINTAIN
VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN
APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE, LIQUID
COLOR: WHITE
ODOR: ACRYLIC
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.026
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: 17 DEG. C (62.6 DEG. F) SETAFLASH CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 1.65% METHOD 40 CFR PART 63 APPENDIX A TO SUBPART PPPP
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS:
POLYMERIZATION MAY OCCUR AT ELEVATED TEMPERATURES OR UPON DEPLETION OF
INHIBITOR.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF PHOSPHORUS. OXIDES OF SULFUR. HYDROGEN
CHLORIDE. ACIDS. ALDEHYDES. ALCOHOLS. TOXIC FUMES. IRRITATING VAPORS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS. REDUCING AGENTS. ACIDS. BASES. PEROXIDES. FREE RADICAL
INITIATORS. METALS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS. PROTECT
FROM DIRECT SUNLIGHT. LOSS OF POLYMERIZATION INHIBITOR. LOSS OF DISSOLVED
AIR. INERT GAS BLANKETING. DO NOT MIX IN BATCHES GREATER THAN 100 GRAMS
(0.22 POUNDS) UNLESS YOU PLAN TO USE IMMEDIATELY.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION. DROWSINESS. DIZZINESS.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
METHYL METHACRYLATE ORAL LD50 (RAT): ALLERGEN, IRRITANT,
7,800 MG/KG KIDNEY, LIVER,
MUTAGEN, NERVOUS
ORAL LD50 (RABBIT): SYSTEM, RESPIRATORY
6,000 MG/KG
ORAL LD50 (RAT):
9,400 MG/KG
INHALATION LC50
(RAT, 8 H): 3750 PPM
2-HYDROXYETHYL ORAL LD50 (RAT): IRRITANT, ALLERGEN
METHACRYLATE 11.2 G/KG
ORAL LD50 (RAT):
5,050 MG/KG
METHACRYLIC ACID ORAL LD50 (RABBIT): CORROSIVE, IRRITANT,
1,200 MG/KG ALLERGEN
ORAL LD50 (RAT):
1,060 MG/KG
ORAL LD50 (RAT):
2,224 MG/KG
DERMAL LD50 (RABBIT):
500 MG/KG
INHALATION LC50
(RAT, 4 H): 7.1 MG/L
METHACRYLATE ESTER NONE IRRITANT, ALLERGEN
TERT-BUTYL PERBENZOATE NONE CENTRAL NERVOUS
SYSTEM, IRRITANT,
MUTAGEN
GLASS, OXIDE, CHEMICALS NONE ALLERGEN, RESPIRATORY
TALC NONE IRRITANT, LUNG, SOME
EVIDENCE OF
CARCINOGENICITY
1,1,2-TRICHLOROETHANE ORAL LD50 (RAT): IRRITANT, CENTRAL
835 MG/KG NERVOUS SYSTEM, LUNG,
LIVER, KIDNEY, IMMUNE
ORAL LD50 (RAT): SYSTEM, SOME EVIDENCE
100 - 200 MG/KG OF CARCINOGENICITY,
MUTAGEN
DERMAL LD50 (RABBIT):
5,377 MG/KG
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
METHYL METHACRYLATE NO NO NO
2-HYDROXYETHYL NO NO NO
METHACRYLATE
METHACRYLIC ACID NO NO NO
METHACRYLATE ESTER NO NO NO
TERT-BUTYL PERBENZOATE NO NO NO
GLASS, OXIDE, CHEMICALS REASONABLY GROUP 2B NO
ANTICIPATED
TO BE A
HUMAN
CARCINOGEN.
TALC NO GROUP 2B NO
1,1,2-TRICHLOROETHANE NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL GOVERNMENTAL REGULATIONS.
HAZARDOUS WASTE NUMBER:
D001: IGNITABLE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: ADHESIVES
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1133
PACKING GROUP: II
DOT HAZARDOUS SUBSTANCE(S): METHYL METHACRYLATE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: ADHESIVES
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1133
PACKING GROUP: II
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: ADHESIVES
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1133
PACKING GROUP: II
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: FIRE, IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). METHYL METHACRYLATE
(CAS# 80-62-6).
CERCLA REPORTABLE QUANTITY:
METHYL METHACRYLATE (CAS# 80-62-6): 1,000 LBS. (454 KG)
TERT-BUTYL PERBENZOATE (CAS# 614-45-9): 100 LBS. (45.4 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NOT AVAILABLE.
PREPARED BY: RENA PETRIDES, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 03/23/2015
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.