| Common Name: | REPEL INSECT REPELLENT SPORTSMEN MAX FORMULA PUMP SPRAY 40% DEET |
| Manufacturer: | CHEMSICO |
| SDS Revision Date: | 6/22/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 36WG48, 48WK01 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
REPEL INSECT REPELLENT SPORTSMEN MAX FORMULA SPRAY PUMP 40% DEET
REVISION DATE: 6/22/2016
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIERS:
PRODUCT NAME:
REPEL INSECT REPELLENT SPORTSMEN MAX FORMULA PUMP SPRAY 40% DEET
EPA REGISTRATION NUMBER: 121-88-305
PRODUCT USE: INSECT REPELLENT PUMP SPRAY
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
CHEMSICO
DIVISION OF UNITED INDUSTRIES CORP.
P.O. BOX 142642
ST. LOUIS, MO 63114-0642
FOR PRODUCT INFORMATION: 1-800-880-1181
FOR MEDICAL EMERGENCIES: 1-800-880-1181
| SECTION 2 - HAZARDS IDENTIFICATION | |
CONFORMS TO HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200.
GHS CLASSIFICATION OF SUBSTANCE OR MIXTURE:
ETHANOL SOLUTION
FLAMMABLE LIQUID - CATEGORY 3
GHS LABEL ELEMENTS:
HAZARD PICTOGRAM(S):
FLAME
EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
FLAMMABLE LIQUID - DO NOT USE OR STORE NEAR HEAT OR OPEN FLAME
CAUSES SERIOUS EYE IRRITATION
HARMFUL IF SWALLOWED
MAY CAUSE AN ALLERGIC SKIN REACTION
PRECAUTIONARY STATEMENTS:
KEEP AWAY FROM SPARKS AND OPEN FLAMES. NO SMOKING. KEEP CONTAINER TIGHTLY
CLOSED. USE EXPLOSION-PROOF EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. WEAR EYE PROTECTION/FACE
PROTECTION.
WASH HANDS THOROUGHLY WITH SOAP AND WATER AFTER HANDLING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
IF SWALLOWED:
CALL A POISON CONTROL CENTER OR DOCTOR FOR TREATMENT ADVICE IF YOU FEEL
UNWELL. RINSE MOUTH.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ATTENTION/ADVICE. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE REUSE.
| SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS# WEIGHT PERCENT
DEET (N,N-DIETHYL-M-TOLUAMIDE) 134-62-3 40.0%
ETHANOL 64-17-5 32.0%
NOTE:
INGREDIENTS NOT IDENTIFIED ARE PROPRIETARY OR NON-HAZARDOUS. VALUES ARE
NOT PRODUCT SPECIFICATIONS.
| SECTION 4 - FIRST AID MEASURES | |
EYE CONTACT:
HOLD EYE OPEN AND RINSE SLOWLY AND GENTLY WITH WATER FOR 15-20 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST 5 MINUTES, THEN CONTINUE
RINSING. CALL A POISON CONTROL CENTER OR DOCTOR FOR TREATMENT ADVICE.
SKIN CONTACT:
AFTER RETURNING INDOORS, WASH TREATED SKIN WITH SOAP AND WATER. DISCONTINUE
PRODUCT USE IF IRRITATION OR RASH OCCURS.
INHALATION: NO SPECIAL REQUIREMENTS
INGESTION:
CALL A POISON CONTROL CENTER OR DOCTOR IMMEDIATELY FOR TREATMENT ADVICE.
HAVE PERSON SIP A GLASS OF WATER IF ABLE TO SWALLOW. DO NOT INDUCE VOMITING
UNLESS TOLD TO DO SO BY A POISON CONTROL CENTER OR DOCTOR. DO NOT GIVE
ANYTHING TO AN UNCONSCIOUS PERSON
NOTES TO PHYSICIAN: NONE
GENERAL ADVICE:
IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. KEEP OUT OF REACH OF CHILDREN.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLAMMABLE PROPERTIES: FLAMMABLE LIQUID - CATEGORY 3. FLASHPOINT 85 F.
SUITABLE EXTINGUISHING MEDIA:
WATER FOG, ALCOHOL RESISTANT FOAM, CO2, DRY CHEMICAL
UNSUITABLE EXTINGUISHING MEDIA: NOT AVAILABLE
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FLAMMABLE LIQUID. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL TO A SOURCE OF
IGNITION AND FLASH BACK. LIQUID RUN-OFF TO SEWERS MAY CREATE FIRE/EXPLOSION
HAZARD. CONTAINER MAY MELT AND LEAK IN HEAT OF FIRE. DO NOT ALLOW RUN-OFF
FROM FIREFIGHTING TO ENTER DRAINS OR WATER COURSES.
PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE CLOTHING INCLUDING SELF-CONTAINED
BREATHING APPARATUS.
HAZARDOUS COMBUSTION PRODUCTS: NONE KNOWN
SENSITIVITY TO MECHANICAL IMPACT: NONE KNOWN
EXPLOSION DATA: NOT AVAILABLE
SENSITIVITY TO STATIC DISCHARGE: NOT AVAILABLE
PERSONAL PRECAUTIONS:
KEEP UNNECESSARY PERSONNEL AWAY. DO NOT TOUCH OR WALK THROUGH SPILLED
MATERIAL. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. KEEP PEOPLE AWAY FROM AND UPWIND
OF SPILL/LEAK.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
REMOVE ALL SOURCES OF IGNITION. BEWARE OF VAPORS ACCUMULATING TO FORM
EXPLOSIVE CONCENTRATIONS. VAPORS CAN ACCUMULATE IN LOW AREAS. WEAR PERSONAL
PROTECTIVE EQUIPMENT. WASH THOROUGHLY AFTER HANDLING.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS.
METHODS FOR CONTAINMENT AND CLEANING UP:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. BEFORE
ATTEMPTING CLEAN UP, REFER TO HAZARD DATA GIVEN ABOVE. SMALL SPILLS MAY BE
ABSORBED WITH EARTH, SAND OR ABSORBENT MATERIAL SWEPT UP AND PLACED IN
SUITABLE, COVERED, AND LABELED CONTAINERS. PREVENT LARGE SPILLS FROM
ENTERING SEWERS OR WATERWAYS. CONTACT EMERGENCY SERVICES AND SUPPLIER FOR
ADVICE. NEVER RETURN SPILLS IN ORIGINAL CONTAINERS FOR RE-USE.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. FLAMMABLE LIQUID - KEEP
AWAY FROM SOURCES OF IGNITION. TAKE MEASURES TO PREVENT THE BUILDUP OF
ELECTROSTATIC CHARGE.
STORAGE:
STORE PRODUCT IN A COOL, DRY PLACE, OUT OF REACH OF CHILDREN. KEEP
CONTAINER CLOSED WHEN NOT IN USE. KEEP AWAY FROM FOOD, DRINK AND ANIMAL
FEEDINGSTUFFS. KEEP TIGHTLY CLOSED. NON-REFILLABLE CONTAINER. DO NOT REUSE
OR REFILL THIS CONTAINER. PLACE IN TRASH OR OFFER FOR RECYCLING IF
AVAILABLE.
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
COMPONENTS WITH OCCUPATIONAL EXPOSURE LIMITS:
CHEMICAL NAME EXPOSURE LIMITS
OSHA PEL ACGIH TLV SUPPLIER OEL
PPM MG/M3 PPM MG/M3 PPM MG/M3
DEET (N,N-DIETHYL- TWA NONE NONE NONE
M-TOLUAMIDE)
ETHANOL TWA 1000 1900 1000 1000 1900
ENGINEERING CONTROLS: GENERAL VENTILATION NORMALLY ADEQUATE.
PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
DURING APPLICATION, PREVENT ENTRY INTO EYES. WEAR SAFETY GLASSES WITH SIDE
SHIELDS IF USING IN LARGE APPLICATIONS.
SKIN AND BODY PROTECTION:
AFTER RETURNING INDOORS, WASH TREATED SKIN WITH SOAP AND WATER.
RESPIRATORY PROTECTION:
WHERE EXPOSURE GUIDELINE LEVELS MAY BE EXCEEDED, USE AN APPROVED NIOSH
RESPIRATOR.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE. WHEN
USING, DO NOT EAT OR DRINK. WASH HANDS BEFORE BREAKS AND IMMEDIATELY AFTER
HANDLING THE PRODUCT.
| SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR
COLOR: LIGHT YELLOW TO WATER-WHITE
PHYSICAL STATE: LIQUID
ODOR: ALCOHOL
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 7.5
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: 85 DEG. F
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY LIMITS IN AIR, LOWER, % BY VOLUME: NO DATA AVAILABLE
FLAMMABILITY LIMITS IN AIR, UPPER, % BY VOLUME: NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY @ 20 DEG. C: 0.940
OCTANOL/WATER COEFFICIENT: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
SOLUBILITY: MISCIBLE IN WATER
% VOLATILE ORGANIC COMPOUNDS: 32
| SECTION 10 - CHEMICAL STABILITY & REACTIVITY INFORMATION | |
REACTIVITY:
CONDITIONS TO AVOID: DO NOT MIX WITH OTHER CHEMICALS.
INCOMPATIBLE MATERIALS: OXIDIZERS
CHEMICAL STABILITY:
PRODUCT STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
OTHER:
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
PRIMARY EYE IRRITATION:
CAUSES SUBSTANTIAL BUT TEMPORARY EYE INJURY (EPA TOX. CATEGORY II)
PRIMARY SKIN IRRITATION: NON-IRRITATING (EPA TOX. CATEGORY IV)
ACUTE DERMAL:
LD50: >5000 MG/KG (EPA CATEGORY IV)
ACUTE INHALATION:
LC50: >2 MG/L (EPA TOX. CATEGORY IV)
ACUTE ORAL:
LD50: >3000 MG/KG (EPA TOX. CATEGORY III)
SENSITIZATION: MAY CAUSE ALLERGIC REACTION AFTER REPEATED CONTACT.
CHRONIC EFFECTS: NO DATA AVAILABLE
CARCINOGENICITY: NO DATA AVAILABLE
MUTAGENICITY: NO DATA AVAILABLE
REPRODUCTIVE EFFECTS: NO DATA AVAILABLE
TERATOGENICITY: NO DATA AVAILABLE
ECOTOXICITY: NO DATA AVAILABLE
| SECTION 12 - ECOLOGICAL INFORMATION | |
ENVIRONMENTAL EFFECTS: NO DATA AVAILABLE
AQUATIC TOXICITY: NONE
PERSISTENCE / DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATION / ACCUMULATION: NO DATA AVAILABLE
PARTITION COEFFICIENT: NO DATA AVAILABLE
MOBILITY IN ENVIRONMENTAL MEDIA: NO DATA AVAILABLE
CHEMICAL FATE INFORMATION: NO DATA AVAILABLE
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE CODES: NOT AVAILABLE
DISPOSAL INSTRUCTIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
WASTE FROM RESIDUES/UNUSED PRODUCTS: NOT AVAILABLE
CONTAMINATED PACKAGING: NOT AVAILABLE
| SECTION 14 - TRANSPORTATION INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION:
(DOT): ETHANOL SOLUTION, 3, UN-1170, PG-III
IATA: ETHANOL SOLUTION, 3, UN-1170, PG-III
IMDG: ETHANOL SOLUTION, 3, UN-1170, PG-III
| SECTION 15 - REGULATORY INFORMATION | |
29 CFR 1910.1200 HAZARDOUS CHEMICAL OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION (OSHA): NO
CERCLA (SUPERFUND) REPORTABLE QUANTITY: NOT AVAILABLE
HAZARD CATEGORIES:
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
IMMEDIATE HAZARD: NO
DELAYED HAZARD: NO
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SECTION 311 HAZARDOUS CHEMICAL: NO
CLEAN AIR ACT (CAA): NOT AVAILABLE
CLEAN WATER ACT (CWA): NOT AVAILABLE
STATE REGULATIONS: NONE
FIFRA LABELING:
THIS CHEMICAL IS A PESTICIDE PRODUCT REGISTERED BY THE ENVIRONMENTAL
PROTECTION AGENCY AND IS SUBJECT TO CERTAIN LABELING REQUIREMENTS UNDER
FEDERAL PESTICIDE LAW. THESE REQUIREMENTS DIFFER FROM THE CLASSIFICATION
CRITERIA AND HAZARD INFORMATION REQUIRED FOR SAFETY DATA SHEETS, AND FOR
WORKPLACE NON-PESTICIDE CHEMICALS. FOLLOWING IS THE HAZARD INFORMATION AS
REQUIRED ON THE PESTICIDE LABEL:
SIGNAL WORD: WARNING
PRECAUTIONARY STATEMENTS:
CAUSES SUBSTANTIAL BUT TEMPORARY EYE INJURY. HARMFUL IF SWALLOWED. DO NOT
GET IN EYES. USE OF THIS PRODUCT MAY CAUSE SKIN REACTIONS IN RARE CASES.
WASH TREATED CLOTHING BEFORE WEARING IT AGAIN. WASH HANDS BEFORE EATING,
DRINKING, CHEWING GUM, USING TOBACCO OR USING THE TOILET. WASH HANDS
THOROUGHLY WITH SOAP AND WATER AFTER HANDLING AND BEFORE EATING, DRINKING,
CHEWING GUM OR USING TOBACCO.
COMBUSTIBLE. DO NOT USE OR STORE NEAR HEAT OR OPEN FLAME.
NOTIFICATION STATUS:
ALL INGREDIENTS OF THIS PRODUCT ARE LISTED OR ARE EXCLUDED FROM LISTING ON
THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCE INVENTORY.
CALIFORNIA PROP. 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR ANY OTHER REPRODUCTIVE HARM.
DISCLAIMER:
INFORMATION CONTAINED HEREIN WAS OBTAINED FROM SOURCES CONSIDERED
TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY EFFORT HAS BEEN MADE TO
ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME CASES DATA IS NOT
AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL PRODUCT USE ARE
BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF THIS MATERIAL
HAVE BEEN FULLY TRAINED ACCORDING TO THE REQUIREMENTS OF ALL APPLICABLE
LEGISLATION AND REGULATORY INSTRUMENTS. NO WARRANTY, EXPRESSED OR IMPLIED,
IS MADE AND SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES, INJURIES OR
CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR RELIANCE ON ANY
INFORMATION CONTAINED IN THIS DOCUMENT.
| SECTION 16 - OTHER INFORMATION | |
HMIS RATINGS:
HEALTH HAZARD 2
FIRE HAZARD 3
REACTIVITY 0
ITEM NUMBER(S): HG-24101; HG-34101; HG-84101; HG-94095; HG-94101
FORMULA NUMBER(S): 21-0811
ISSUE DATE: 6/22/2016
PREPARED BY:
WPC BRANDS, INC.
P.O. BOX 4406
BRIDGETON, MO 63044-0406
(800) 242-1166