| Common Name: | GREAT STUFF BIG GAP FILLER INSULATING FOAM SEALANT 12OZ HC ES 12CT |
| Manufacturer: | DOW CHEMICAL |
| SDS Revision Date: | 1/19/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 48WK16 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DOW(R*)
SAFETY DATA SHEET
THE DOW CHEMICAL COMPANY
PRODUCT NAME:
GREAT STUFF(TM) BIG GAP FILLER INSULATING FOAM SEALANT 12OZ HC ES 12CT
ISSUE DATE: 01/19/2016
PRINT DATE: 02/24/2016
THE DOW CHEMICAL COMPANY ENCOURAGES AND EXPECTS YOU TO READ AND
UNDERSTAND THE ENTIRE (M)SDS, AS THERE IS IMPORTANT INFORMATION
THROUGHOUT THE DOCUMENT. WE EXPECT YOU TO FOLLOW THE PRECAUTIONS
IDENTIFIED IN THIS DOCUMENT UNLESS YOUR USE CONDITIONS WOULD
NECESSITATE OTHER APPROPRIATE METHODS OR ACTIONS.
| 1. IDENTIFICATION |  |
PRODUCT NAME:
GREAT STUFF(TM) BIG GAP FILLER INSULATING FOAM SEALANT 12OZ HC ES 12CT
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
IDENTIFIED USES: POLYURETHANE FOAM.
COMPANY IDENTIFICATION:
THE DOW CHEMICAL COMPANY
2030 WILLARD H DOW CENTER
MIDLAND MI 48674-0000
UNITED STATES
CUSTOMER INFORMATION NUMBER: 800-258-2436
SDSQUESTION@DOW.COM
EMERGENCY TELEPHONE NUMBER:
24-HOUR EMERGENCY CONTACT:
CHEMTREC: +1 703-527-3887
LOCAL EMERGENCY CONTACT: 800-424-9300
| 2. HAZARDS IDENTIFICATION | |
HAZARD CLASSIFICATION:
THIS MATERIAL IS HAZARDOUS UNDER THE CRITERIA OF THE FEDERAL OSHA HAZARD
COMMUNICATION STANDARD 29CFR 1910.1200.
FLAMMABLE AEROSOLS: CATEGORY 2
GASES UNDER PRESSURE: LIQUEFIED GAS
SKIN IRRITATION: CATEGORY 2
EYE IRRITATION: CATEGORY 2B
RESPIRATORY SENSITISATION: CATEGORY 1
SKIN SENSITISATION: CATEGORY 1
EFFECTS ON OR VIA LACTATION
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: CATEGORY 2 - INHALATION
LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER!
HAZARDS:
FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SKIN AND EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE HARM TO BREAST-FED CHILDREN.
MAY CAUSE DAMAGE TO ORGANS (RESPIRATORY TRACT) THROUGH PROLONGED OR
REPEATED EXPOSURE IF INHALED.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
DO NOT BREATHE DUST/ FUME/ GAS/ MIST/ VAPOURS/ SPRAY.
AVOID CONTACT DURING PREGNANCY/ WHILE NURSING.
WASH SKIN THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
WEAR PROTECTIVE GLOVES.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR/ PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ ATTENTION.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ADVICE/ ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/ 122 DEG. F.
DISPOSAL:
DISPOSE OF CONTENTS/ CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NO DATA AVAILABLE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NATURE: POLYURETHANE PREPOLYMER
THIS PRODUCT IS A MIXTURE.
COMPONENT CASRN CONCENTRATION
DIPHENYLMETHANE DIISOCYANATE, 9016-87-9 >=10.0 - <=30.0 %
ISOMERS AND HOMOLOGUES
POLYMETHYLENEPOLYPHENYLISOCYANATE, 57029-46-6 >=30.0 - <=60.0 %
PROPOXYLATED GLYCERIN POLYMER
POLYMETHYLENEPOLYPHENYL 53862-89-8 >=10.0 - <=30.0 %
POLYISOCYANATE, POLYPROPYLENEGLYCOL
COPOLYMER
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE 13674-84-5 >=5.0 - <=10.0 %
PARAFFIN WAXES AND HYDROCARBON 63449-39-8 >=5.0 - <=10.0 %
WAXES, CHLORINATED
ISOBUTANE 75-28-5 >=5.0 - <=10.0 %
METHYL ETHER 115-10-6 >=1.0 - <=5.0 %
PROPANE 74-98-6 >=1.0 - <=5.0 %
4,4' -METHYLENEDIPHENYL DIISOCYANATE 101-68-8 >=5.0 - <=10.0 %
NOTE:
NOTE: CAS 101-68-8 IS AN MDI ISOMER THAT IS PART OF CAS 9016-87-9.
| 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
FIRST AID RESPONDERS SHOULD PAY ATTENTION TO SELF-PROTECTION AND USE
THE RECOMMENDED PROTECTIVE CLOTHING (CHEMICAL RESISTANT GLOVES, SPLASH
PROTECTION). IF POTENTIAL FOR EXPOSURE EXISTS REFER TO SECTION 8 FOR
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT.
INHALATION:
MOVE PERSON TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION;
IF BY MOUTH TO MOUTH USE RESCUER PROTECTION (POCKET MASK, ETC). IF
BREATHING IS DIFFICULT, OXYGEN SHOULD BE ADMINISTERED BY QUALIFIED
PERSONNEL. CALL A PHYSICIAN OR TRANSPORT TO A MEDICAL FACILITY.
SKIN CONTACT:
REMOVE MATERIAL FROM SKIN IMMEDIATELY BY WASHING WITH SOAP AND PLENTY OF
WATER. REMOVE CONTAMINATED CLOTHING AND SHOES WHILE WASHING. SEEK MEDICAL
ATTENTION IF IRRITATION PERSISTS. WASH CLOTHING BEFORE REUSE. AN MDI SKIN
DECONTAMINATION STUDY DEMONSTRATED THAT CLEANING VERY SOON AFTER EXPOSURE
IS IMPORTANT, AND THAT A POLYGLYCOL-BASED SKIN CLEANSER OR CORN OIL MAY BE
MORE EFFECTIVE THAN SOAP AND WATER. DISCARD ITEMS WHICH CANNOT BE
DECONTAMINATED, INCLUDING LEATHER ARTICLES SUCH AS SHOES, BELTS AND
WATCHBANDS. SUITABLE EMERGENCY SAFETY SHOWER FACILITY SHOULD BE AVAILABLE
IN WORK AREA.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH WATER; REMOVE CONTACT LENSES, IF PRESENT,
AFTER THE FIRST 5 MINUTES, THEN CONTINUE FLUSHING EYES FOR AT LEAST 15
MINUTES. OBTAIN MEDICAL ATTENTION WITHOUT DELAY, PREFERABLY FROM AN
OPHTHALMOLOGIST. SUITABLE EMERGENCY EYE WASH FACILITY SHOULD BE IMMEDIATELY
AVAILABLE.
INGESTION:
IF SWALLOWED, SEEK MEDICAL ATTENTION. DO NOT INDUCE VOMITING UNLESS
DIRECTED TO DO SO BY MEDICAL PERSONNEL.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ASIDE FROM THE INFORMATION FOUND UNDER DESCRIPTION OF FIRST AID
MEASURES (ABOVE) AND INDICATION OF IMMEDIATE MEDICAL ATTENTION AND
SPECIAL TREATMENT NEEDED (BELOW), ANY ADDITIONAL IMPORTANT SYMPTOMS
AND EFFECTS ARE DESCRIBED IN SECTION 11: TOXICOLOGY INFORMATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN:
EXCESSIVE EXPOSURE MAY AGGRAVATE PREEXISTING ASTHMA AND OTHER RESPIRATORY
DISORDERS (E.G. EMPHYSEMA, BRONCHITIS, REACTIVE AIRWAYS DYSFUNCTION
SYNDROME). REPEATED EXCESSIVE EXPOSURE MAY AGGRAVATE PREEXISTING LUNG
DISEASE. MAINTAIN ADEQUATE VENTILATION AND OXYGENATION OF THE PATIENT.
MAY CAUSE RESPIRATORY SENSITIZATION OR ASTHMA-LIKE SYMPTOMS.
BRONCHODILATORS, EXPECTORANTS AND ANTITUSSIVES MAY BE OF HELP.
TREAT BRONCHOSPASM WITH INHALED BETA2 AGONIST AND ORAL OR PARENTERAL
CORTICOSTEROIDS. RESPIRATORY SYMPTOMS, INCLUDING PULMONARY EDEMA, MAY BE
DELAYED. PERSONS RECEIVING SIGNIFICANT EXPOSURE SHOULD BE OBSERVED 24-48
HOURS FOR SIGNS OF RESPIRATORY DISTRESS. EXPOSURE MAY INCREASE "MYOCARDIAL
IRRITABILITY". DO NOT ADMINISTER SYMPATHOMIMETIC DRUGS SUCH AS EPINEPHRINE
UNLESS ABSOLUTELY NECESSARY. IF YOU ARE SENSITIZED TO DIISOCYANATES,
CONSULT YOUR PHYSICIAN REGARDING WORKING WITH OTHER RESPIRATORY IRRITANTS
OR SENSITIZERS. ALTHOUGH CHOLINESTERASE DEPRESSION HAS BEEN REPORTED WITH
THIS MATERIAL, IT IS NOT OF BENEFIT IN DETERMINING EXPOSURE AND NEED NOT
BE CONSIDERED IN THE TREATMENT OF PERSONS EXPOSED TO THE MATERIAL.
TREATMENT OF EXPOSURE SHOULD BE DIRECTED AT THE CONTROL OF SYMPTOMS AND
THE CLINICAL CONDITION OF THE PATIENT.
| 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG OR FINE SPRAY. DRY CHEMICAL FIRE EXTINGUISHERS. CARBON
DIOXIDE FIRE EXTINGUISHERS. FOAM. ALCOHOL RESISTANT FOAMS (ATC TYPE)
ARE PREFERRED. GENERAL PURPOSE SYNTHETIC FOAMS (INCLUDING AFFF) OR
PROTEIN FOAMS MAY FUNCTION, BUT WILL BE LESS EFFECTIVE.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE DIRECT WATER STREAM. STRAIGHT OR DIRECT WATER STREAMS MAY NOT
BE EFFECTIVE TO EXTINGUISH FIRE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HAZARDOUS COMBUSTION PRODUCTS:
DURING A FIRE, SMOKE MAY CONTAIN THE ORIGINAL MATERIAL IN ADDITION TO
COMBUSTION PRODUCTS OF VARYING COMPOSITION WHICH MAY BE TOXIC AND/OR
IRRITATING. COMBUSTION PRODUCTS MAY INCLUDE AND ARE NOT LIMITED TO:
NITROGEN OXIDES. ISOCYANATES. HYDROGEN CHLORIDE. CARBON MONOXIDE. CARBON
DIOXIDE. HYDROGEN CYANIDE.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTAINS FLAMMABLE PROPELLANT. AEROSOL CANS EXPOSED TO FIRE CAN RUPTURE
AND BECOME FLAMING PROJECTILES. PROPELLANT RELEASE MAY RESULT IN A
FIREBALL. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A LONG DISTANCE AND
ACCUMULATE IN LOW LYING AREAS. IGNITION AND/OR FLASH BACK MAY OCCUR. DENSE
SMOKE IS PRODUCED WHEN PRODUCT BURNS.
ADVICE FOR FIREFIGHTERS:
FIRE FIGHTING PROCEDURES:
KEEP PEOPLE AWAY. ISOLATE FIRE AND DENY UNNECESSARY ENTRY. STAY UPWIND.
KEEP OUT OF LOW AREAS WHERE GASES (FUMES) CAN ACCUMULATE. WATER MAY NOT
BE EFFECTIVE IN EXTINGUISHING FIRE. DO NOT USE DIRECT WATER STREAM. MAY
SPREAD FIRE. FIGHT FIRE FROM PROTECTED LOCATION OR SAFE DISTANCE.
CONSIDER THE USE OF UNMANNED HOSE HOLDERS OR MONITOR NOZZLES. ELIMINATE
IGNITION SOURCES. MOVE CONTAINER FROM FIRE AREA IF THIS IS POSSIBLE
WITHOUT HAZARD. USE WATER SPRAY TO COOL FIREEXPOSED CONTAINERS AND
FIRE-AFFECTED ZONE UNTIL FIRE IS OUT.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
WEAR POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND
PROTECTIVE FIRE FIGHTING CLOTHING (INCLUDES FIRE FIGHTING HELMET, COAT,
TROUSERS, BOOTS, AND GLOVES). AVOID CONTACT WITH THIS MATERIAL DURING
FIRE FIGHTING OPERATIONS. IF CONTACT IS LIKELY, CHANGE TO FULL CHEMICAL
RESISTANT FIRE FIGHTING CLOTHING WITH SELF-CONTAINED BREATHING APPARATUS.
IF THIS IS NOT AVAILABLE, WEAR FULL CHEMICAL RESISTANT CLOTHING WITH
SELF-CONTAINED BREATHING APPARATUS AND FIGHT FIRE FROM A REMOTE LOCATION.
FOR PROTECTIVE EQUIPMENT IN POST-FIRE OR NON-FIRE CLEAN-UP SITUATIONS,
REFER TO THE RELEVANT SECTIONS.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. ONLY TRAINED AND PROPERLY PROTECTED PERSONNEL MUST BE
INVOLVED IN CLEAN-UP OPERATIONS. KEEP PERSONNEL OUT OF LOW AREAS. KEEP
PERSONNEL OUT OF CONFINED OR POORLY VENTILATED AREAS. KEEP UPWIND OF
SPILL. VENTILATE AREA OF LEAK OR SPILL. NO SMOKING IN AREA. FOR LARGE
SPILLS, WARN PUBLIC OF DOWNWIND EXPLOSION HAZARD. CHECK AREA WITH
COMBUSTIBLE GAS DETECTOR BEFORE REENTERING AREA. GROUND AND BOND ALL
CONTAINERS AND HANDLING EQUIPMENT. ELIMINATE ALL SOURCES OF IGNITION
IN VICINITY OF SPILL OR RELEASED VAPOR TO AVOID FIRE OR EXPLOSION.
VAPOR EXPLOSION HAZARD. KEEP OUT OF SEWERS. SEE SECTION 10 FOR MORE
SPECIFIC INFORMATION. USE APPROPRIATE SAFETY EQUIPMENT. FOR ADDITIONAL
INFORMATION, REFER TO SECTION 8, EXPOSURE CONTROLS AND PERSONAL
PROTECTION. CONFINED SPACE ENTRY PROCEDURES MUST BE FOLLOWED BEFORE
ENTERING THE AREA. REFER TO SECTION 7, HANDLING, FOR ADDITIONAL
PRECAUTIONARY MEASURES.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FROM ENTERING INTO SOIL, DITCHES, SEWERS, WATERWAYS AND/OR
GROUNDWATER. SEE SECTION 12, ECOLOGICAL INFORMATION. SPILLS OR
DISCHARGE TO NATURAL WATERWAYS IS LIKELY TO KILL AQUATIC ORGANISMS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILLED MATERIAL IF POSSIBLE. GROUND AND BOND ALL CONTAINERS AND
HANDLING EQUIPMENT. ISOLATE AREA UNTIL GAS HAS DISPERSED. USE NON-SPARKING
TOOLS IN CLEANUP OPERATIONS. ELIMINATE ALL SOURCES OF IGNITION IN VICINITY
OF SPILL OR RELEASED VAPOR TO AVOID FIRE OR EXPLOSION. CHECK AREA WITH
COMBUSTIBLE GAS DETECTOR BEFORE REENTERING AREA. GROUND AND BOND ALL
CONTAINERS AND HANDLING EQUIPMENT. COLLECT IN SUITABLE AND PROPERLY
LABELED CONTAINERS. ABSORB WITH MATERIALS SUCH AS:
CLAY. DIRT. MILSORB(R*). SAND. SAWDUST. VERMICULITE. SEE SECTION 10 FOR
MORE SPECIFIC INFORMATION. SEE SECTION 13, DISPOSAL CONSIDERATIONS, FOR
ADDITIONAL INFORMATION.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM HEAT, SPARKS AND FLAME. AVOID BREATHING VAPOR. AVOID
CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID PROLONGED OR REPEATED CONTACT
WITH SKIN. WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER CLOSED. USE ONLY
WITH ADEQUATE VENTILATION. NO SMOKING, OPEN FLAMES OR SOURCES OF IGNITION
IN HANDLING AND STORAGE AREA. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL
A LONG DISTANCE AND ACCUMULATE IN LOW LYING AREAS. IGNITION AND/OR FLASH
BACK MAY OCCUR. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE OR INCINERATE
CONTAINER. CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, CAN CONTAIN
VAPORS. DO NOT CUT, DRILL, GRIND, WELD, OR PERFORM SIMILAR OPERATIONS
ON OR NEAR EMPTY CONTAINERS. DO NOT ENTER CONFINED SPACES UNLESS
ADEQUATELY VENTILATED. NEVER USE AIR PRESSURE FOR TRANSFERRING PRODUCT.
USE OF NON-SPARKING OR EXPLOSION-PROOF EQUIPMENT MAY BE NECESSARY,
DEPENDING UPON THE TYPE OF OPERATION. SEE SECTION 8, EXPOSURE CONTROLS
AND PERSONAL PROTECTION.
CONDITIONS FOR SAFE STORAGE:
MINIMIZE SOURCES OF IGNITION, SUCH AS STATIC BUILD-UP, HEAT, SPARK
OR FLAME. STORE IN A DRY PLACE. SEE SECTION 10 FOR MORE SPECIFIC
INFORMATION.
STORAGE STABILITY:
STORAGE TEMPERATURE: 25 DEG. C (77 DEG. F)
STORAGE PERIOD: 12 MONTH
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS: EXPOSURE LIMITS ARE LISTED BELOW, IF THEY EXIST.
COMPONENT REGULATION TYPE OF LISTING VALUE/NOTATION
ISOBUTANE ACGIH STEL 1,000 PPM
METHYL ETHER US WEEL TWA 1,000 PPM
PROPANE ACGIH ASPHYXIANT
OSHA Z-1 TWA 1,800 MG/M3
1,000 PPM
4,4' -METHYLENEDIPHENYL DOW IHG TWA 0.005 PPM
DIISOCYANATE
DOW IHG STEL 0.02 PPM
ACGIH TWA 0.005 PPM
OSHA Z-1 C 0.2 MG/M3
0.02 PPM
NIOSH REL TWA 0.05 MG/M3
0.005 PPM
NIOSH REL C 0.2 MG/M3
0.02 PPM
EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. LOCAL EXHAUST VENTILATION MAY BE
NECESSARY FOR SOME OPERATIONS. PROVIDE GENERAL AND/OR LOCAL EXHAUST
VENTILATION TO CONTROL AIRBORNE LEVELS BELOW THE EXPOSURE GUIDELINES.
EXHAUST SYSTEMS SHOULD BE DESIGNED TO MOVE THE AIR AWAY FROM THE SOURCE
OF VAPOR/AEROSOL GENERATION AND PEOPLE WORKING AT THIS POINT. THE ODOR
AND IRRITANCY OF THIS MATERIAL ARE INADEQUATE TO WARN OF EXCESSIVE
EXPOSURE. LETHAL CONCENTRATIONS MAY EXIST IN AREAS WITH POOR VENTILATION.
INDIVIDUAL PROTECTION MEASURES:
EYE/FACE PROTECTION: USE SAFETY GLASSES (WITH SIDE SHIELDS).
SKIN PROTECTION:
HAND PROTECTION: USE GLOVES CHEMICALLY RESISTANT TO THIS MATERIAL.
EXAMPLES OF PREFERRED GLOVE BARRIER MATERIALS INCLUDE:
BUTYL RUBBER. CHLORINATED POLYETHYLENE. POLYETHYLENE. ETHYL VINYL ALCOHOL
LAMINATE ("EVAL").
EXAMPLES OF ACCEPTABLE GLOVE BARRIER MATERIALS INCLUDE:
NEOPRENE. NITRILE/BUTADIENE RUBBER ("NITRILE" OR "NBR"). VITON. POLYVINYL
CHLORIDE ("PVC" OR "VINYL").
NOTICE:
THE SELECTION OF A SPECIFIC GLOVE FOR A PARTICULAR APPLICATION AND
DURATION OF USE IN A WORKPLACE SHOULD ALSO TAKE INTO ACCOUNT ALL RELEVANT
WORKPLACE FACTORS SUCH AS, BUT NOT LIMITED TO:
OTHER CHEMICALS WHICH MAY BE HANDLED, PHYSICAL REQUIREMENTS (CUT/PUNCTURE
PROTECTION, DEXTERITY, THERMAL PROTECTION), POTENTIAL BODY REACTIONS TO
GLOVE MATERIALS, AS WELL AS THE INSTRUCTIONS/SPECIFICATIONS PROVIDED BY
THE GLOVE SUPPLIER.
OTHER PROTECTION:
USE PROTECTIVE CLOTHING CHEMICALLY RESISTANT TO THIS MATERIAL. SELECTION
OF SPECIFIC ITEMS SUCH AS FACE SHIELD, BOOTS, APRON, OR FULL BODY SUIT
WILL DEPEND ON THE TASK.
RESPIRATORY PROTECTION:
ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE EXPOSURE GUIDELINE.
WHEN ATMOSPHERIC LEVELS MAY EXCEED THE EXPOSURE GUIDELINE, USE AN APPROVED
AIRPURIFYING RESPIRATOR EQUIPPED WITH AN ORGANIC VAPOR SORBENT AND A
PARTICLE FILTER. FOR SITUATIONS WHERE THE ATMOSPHERIC LEVELS MAY EXCEED
THE LEVEL FOR WHICH AN AIR-PURIFYING RESPIRATOR IS EFFECTIVE, USE A
POSITIVE-PRESSURE AIR-SUPPLYING RESPIRATOR (AIR LINE OR SELF-CONTAINED
BREATHING APPARATUS). FOR EMERGENCY RESPONSE OR FOR SITUATIONS WHERE THE
ATMOSPHERIC LEVEL IS UNKNOWN, USE AN APPROVED POSITIVE-PRESSURE
SELF-CONTAINED BREATHING APPARATUS OR POSITIVEPRESSURE AIR LINE WITH
AUXILIARY SELF-CONTAINED AIR SUPPLY. IN CONFINED OR POORLY VENTILATED
AREAS, USE AN APPROVED SELF-CONTAINED BREATHING APPARATUS OR POSITIVE
PRESSURE AIR LINE WITH AUXILIARY SELF-CONTAINED AIR SUPPLY.
THE FOLLOWING SHOULD BE EFFECTIVE TYPES OF AIR-PURIFYING RESPIRATORS:
ORGANIC VAPOR CARTRIDGE WITH A PARTICULATE PRE-FILTER.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: FOAM
COLOR: YELLOW
ODOR: MILD
ODOR THRESHOLD: NO TEST DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT/RANGE: NO TEST DATA AVAILABLE
FREEZING POINT: NO TEST DATA AVAILABLE
BOILING POINT (760 MMHg): NOT APPLICABLE
FLASH POINT:
CLOSED CUP: -104 DEG. C ( -155 DEG. F) ESTIMATED.
EVAPORATION RATE (BUTYL ACETATE = 1): NO TEST DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO TEST DATA AVAILABLE
UPPER EXPLOSION LIMIT: NO TEST DATA AVAILABLE
VAPOR PRESSURE: 1,151 KPA AT 55 DEG. C (131 DEG. F) CALCULATED.
RELATIVE VAPOR DENSITY (AIR = 1): NO TEST DATA AVAILABLE
RELATIVE DENSITY (WATER = 1): 1.06 ESTIMATED.
WATER SOLUBILITY: INSOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO TEST DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO TEST DATA AVAILABLE
KINEMATIC VISCOSITY: NOT APPLICABLE
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
OXIDIZING PROPERTIES: NO
MOLECULAR WEIGHT: NO DATA AVAILABLE
NOTE:
THE PHYSICAL DATA PRESENTED ABOVE ARE TYPICAL VALUES AND SHOULD NOT BE
CONSTRUED AS A SPECIFICATION.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE
CHEMICAL STABILITY:
STABLE UNDER RECOMMENDED STORAGE CONDITIONS. SEE STORAGE, SECTION 7.
UNSTABLE AT ELEVATED TEMPERATURES.
POSSIBILITY OF HAZARDOUS REACTIONS:
CAN OCCUR. EXPOSURE TO ELEVATED TEMPERATURES CAN CAUSE PRODUCT TO
DECOMPOSE AND GENERATE GAS. THIS CAN CAUSE PRESSURE BUILD-UP AND/OR
RUPTURING OF CLOSED CONTAINERS. ACIDS.
CONDITIONS TO AVOID:
AVOID TEMPERATURES ABOVE 50 DEG. C
ELEVATED TEMPERATURES CAN CAUSE CONTAINER TO VENT AND/OR RUPTURE.
EXPOSURE TO ELEVATED TEMPERATURES CAN CAUSE PRODUCT TO DECOMPOSE.
INCOMPATIBLE MATERIALS:
AVOID CONTACT WITH:
ACIDS. ALCOHOLS. AMINES. AMMONIA. BASES. METAL COMPOUNDS. STRONG
OXIDIZERS. PRODUCTS BASED ON DIISOCYANATES LIKE TDI AND MDI REACT
WITH MANY MATERIALS TO RELEASE HEAT. THE REACTION RATE INCREASES
WITH TEMPERATURE AS WELL AS WITH INCREASED CONTACT; THESE REACTIONS
CAN BECOME VIOLENT. CONTACT IS INCREASED BY STIRRING OR IF THE OTHER
MATERIAL ACTS AS A SOLVENT. PRODUCTS BASED ON DIISOCYANATES SUCH AS
TDI AND MDI ARE NOT SOLUBLE IN WATER AND WILL SINK TO THE BOTTOM, BUT
REACT SLOWLY AT THE INTERFACE. THE REACTION FORMS CARBON DIOXIDE GAS
AND A LAYER OF SOLID POLYUREA. REACTION WITH WATER WILL GENERATE CARBON
DIOXIDE AND HEAT.
HAZARDOUS DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS DEPEND UPON TEMPERATURE, AIR SUPPLY AND
THE PRESENCE OF OTHER MATERIALS. TOXIC GASES ARE RELEASED DURING
DECOMPOSITION.
| 11. TOXICOLOGICAL INFORMATION | |
TOXICOLOGICAL INFORMATION APPEARS IN THIS SECTION WHEN SUCH DATA IS
AVAILABLE.
ACUTE TOXICITY:
ACUTE ORAL TOXICITY:
LOW TOXICITY IF SWALLOWED. SMALL AMOUNTS SWALLOWED INCIDENTALLY AS A
RESULT OF NORMAL HANDLING OPERATIONS ARE NOT LIKELY TO CAUSE INJURY;
HOWEVER, SWALLOWING LARGER AMOUNTS MAY CAUSE INJURY.
OBSERVATIONS IN ANIMALS INCLUDE: GASTROINTESTINAL IRRITATION.
AS PRODUCT: SINGLE DOSE ORAL LD50 HAS NOT BEEN DETERMINED.
LD50, RAT, >2,000 MG/KG ESTIMATED.
ACUTE DERMAL TOXICITY:
PROLONGED SKIN CONTACT IS UNLIKELY TO RESULT IN ABSORPTION OF HARMFUL
AMOUNTS.
AS PRODUCT: THE DERMAL LD50 HAS NOT BEEN DETERMINED.
LD50, RABBIT, >2,000 MG/KG ESTIMATED.
ACUTE INHALATION TOXICITY:
IN CONFINED OR POORLY VENTILATED AREAS, VAPOR CAN EASILY ACCUMULATE
AND CAN CAUSE UNCONSCIOUSNESS AND DEATH DUE TO DISPLACEMENT OF OXYGEN.
EXCESSIVE EXPOSURE MAY CAUSE IRRITATION TO UPPER RESPIRATORY TRACT (NOSE
AND THROAT) AND LUNGS. MAY CAUSE PULMONARY EDEMA (FLUID IN THE LUNGS.)
EFFECTS MAY BE DELAYED. MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.
SYMPTOMS OF EXCESSIVE EXPOSURE MAY BE ANESTHETIC OR NARCOTIC EFFECTS;
DIZZINESS AND DROWSINESS MAY BE OBSERVED. EXCESSIVE EXPOSURE MAY INCREASE
SENSITIVITY TO EPINEPHRINE AND INCREASE MYOCARDIAL IRRITABILITY (IRREGULAR
HEARTBEATS). DECREASED LUNG FUNCTION HAS BEEN ASSOCIATED WITH OVEREXPOSURE
TO ISOCYANATES.
THE LC50 HAS NOT BEEN DETERMINED.
SKIN CORROSION/IRRITATION:
PROLONGED CONTACT MAY CAUSE MODERATE SKIN IRRITATION WITH LOCAL REDNESS.
MATERIAL MAY STICK TO SKIN CAUSING IRRITATION UPON REMOVAL.
MAY STAIN SKIN.
SERIOUS EYE DAMAGE/EYE IRRITATION:
MAY CAUSE EYE IRRITATION.
MAY CAUSE SLIGHT TEMPORARY CORNEAL INJURY.
SENSITIZATION:
SKIN CONTACT MAY CAUSE AN ALLERGIC SKIN REACTION.
ANIMAL STUDIES HAVE SHOWN THAT SKIN CONTACT WITH ISOCYANATES MAY PLAY A
ROLE IN RESPIRATORY SENSITIZATION.
MAY CAUSE ALLERGIC RESPIRATORY REACTION.
MDI CONCENTRATIONS BELOW THE EXPOSURE GUIDELINES MAY CAUSE ALLERGIC
RESPIRATORY REACTIONS IN INDIVIDUALS ALREADY SENSITIZED.
ASTHMA-LIKE SYMPTOMS MAY INCLUDE COUGHING, DIFFICULT BREATHING AND A
FEELING OF TIGHTNESS IN THE CHEST.
OCCASIONALLY, BREATHING DIFFICULTIES MAY BE LIFE THREATENING.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE):
MAY CAUSE RESPIRATORY IRRITATION.
ROUTE OF EXPOSURE: INHALATION
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE):
TISSUE INJURY IN THE UPPER RESPIRATORY TRACT AND LUNGS HAS BEEN OBSERVED
IN LABORATORY ANIMALS AFTER REPEATED EXCESSIVE EXPOSURES TO MDI/POLYMERIC
MDI AEROSOLS.
CONTAINS COMPONENT(S) WHICH HAVE BEEN REPORTED TO CAUSE EFFECTS ON THE
FOLLOWING ORGANS IN ANIMALS:
KIDNEY
LIVER.
CARCINOGENICITY:
LUNG TUMORS HAVE BEEN OBSERVED IN LABORATORY ANIMALS EXPOSED TO RESPIRABLE
AEROSOL DROPLETS OF MDI/POLYMERIC MDI (6 MG/M3) FOR THEIR LIFETIME. TUMORS
OCCURRED CONCURRENTLY WITH RESPIRATORY IRRITATION AND LUNG INJURY. CURRENT
EXPOSURE GUIDELINES ARE EXPECTED TO PROTECT AGAINST THESE EFFECTS REPORTED
FOR MDI.
TERATOGENICITY:
IN LABORATORY ANIMALS, MDI/POLYMERIC MDI DID NOT CAUSE BIRTH DEFECTS;
OTHER FETAL EFFECTS OCCURRED ONLY AT HIGH DOSES WHICH WERE TOXIC TO THE
MOTHER.
REPRODUCTIVE TOXICITY:
BASED ON INFORMATION FOR COMPONENT(S): MAY CAUSE HARM TO BREASTFED BABIES.
MUTAGENICITY:
IN VITRO GENETIC TOXICITY STUDIES WERE NEGATIVE FOR COMPONENT(S) TESTED.
GENETIC TOXICITY DATA ON MDI ARE INCONCLUSIVE. MDI WAS WEAKLY POSITIVE
IN SOME IN VITRO STUDIES; OTHER IN VITRO STUDIES WERE NEGATIVE. ANIMAL
MUTAGENICITY STUDIES WERE PREDOMINANTLY NEGATIVE.
ASPIRATION HAZARD:
BASED ON PHYSICAL PROPERTIES, NOT LIKELY TO BE AN ASPIRATION HAZARD.
CARCINOGENICITY:
COMPONENT LIST CLASSIFICATION
PARAFFIN WAXES AND IARC GROUP 2B: POSSIBLY CARCINOGENIC TO HUMANS
HYDROCARBON WAXES,
CHLORINATED US NTP REASONABLY ANTICIPATED TO BE A HUMAN
CARCINOGEN
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION APPEARS IN THIS SECTION WHEN SUCH DATA IS
AVAILABLE.
TOXICITY:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
ACUTE TOXICITY TO FISH:
THE MEASURED ECOTOXICITY IS THAT OF THE HYDROLYZED PRODUCT, GENERALLY
UNDER CONDITIONS MAXIMIZING PRODUCTION OF SOLUBLE SPECIES.
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
LC50, DANIO RERIO (ZEBRA FISH), STATIC TEST, 96 HOUR, >1,000 MG/L, OECD
TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 24 HOUR, >1,000 MG/L, OECD
TEST GUIDELINE 202 OR EQUIVALENT
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
NOEC, DESMODESMUS SUBSPICATUS (GREEN ALGAE), STATIC TEST, 72 HOUR, GROWTH
RATE INHIBITION, 1,640 MG/L, OECD TEST GUIDELINE 201 OR EQUIVALENT
TOXICITY TO BACTERIA:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, ACTIVATED SLUDGE, STATIC TEST, 3 HOUR, RESPIRATION RATES., >100 MG/L
TOXICITY TO SOIL-DWELLING ORGANISMS:
EC50, EISENIA FETIDA (EARTHWORMS), BASED ON INFORMATION FOR A SIMILAR
MATERIAL:, 14 D, >1,000 MG/KG
TOXICITY TO TERRESTRIAL PLANTS:
EC50, AVENA SATIVA (OATS), GROWTH INHIBITION, 1,000 MG/L
EC50, LACTUCA SATIVA (LETTUCE), GROWTH INHIBITION, 1,000 MG/L
POLYMETHYLENEPOLYPHENYLISOCYANATE, PROPOXYLATED GLYCERIN POLYMER:
ACUTE TOXICITY TO FISH:
FOR THIS FAMILY OF MATERIALS:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
POLYMETHYLENEPOLYPHENYL POLYISOCYANATE, POLYPROPYLENEGLYCOL COPOLYMER:
ACUTE TOXICITY TO FISH:
NOT EXPECTED TO BE ACUTELY TOXIC TO AQUATIC ORGANISMS.
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
ACUTE TOXICITY TO FISH:
MATERIAL IS SLIGHTLY TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50 BETWEEN 10 AND 100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, LEPOMIS MACROCHIRUS (BLUEGILL SUNFISH), STATIC TEST, 96 HOUR,
84 MG/L, OECD TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
EC50, DAPHNIA MAGNA (WATER FLEA), 48 HOUR, 131 MG/L
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
ERC50, PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE), STATIC TEST,
96 HOUR, GROWTH RATE INHIBITION, 82 MG/L, OECD TEST GUIDELINE 201
OR EQUIVALENT
TOXICITY TO BACTERIA:
EC50, ACTIVATED SLUDGE, RESPIRATION INHIBITION, 3 HOUR, 784 MG/L, OECD
209 TEST
CHRONIC TOXICITY TO AQUATIC INVERTEBRATES:
NOEC, DAPHNIA MAGNA (WATER FLEA), SEMI-STATIC TEST, 21 D, NUMBER OF
OFFSPRING, 32 MG/L
LOEC, DAPHNIA MAGNA (WATER FLEA), SEMI-STATIC TEST, 21 D, NUMBER OF
OFFSPRING, >32 MG/L
PARAFFIN WAXES AND HYDROCARBON WAXES, CHLORINATED:
ACUTE TOXICITY TO FISH:
MATERIAL IS HIGHLY TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS (LC50/EC50
BETWEEN 0.1 AND 1 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, ONCORHYNCHUS MYKISS (RAINBOW TROUT), 96 HOUR, >0.1 MG/L
ISOBUTANE:
ACUTE TOXICITY TO FISH: NO RELEVANT DATA FOUND.
METHYL ETHER:
ACUTE TOXICITY TO FISH:
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, POECILIA RETICULATA (GUPPY), SEMI-STATIC TEST, 96 HOUR, >4,000 MG/L
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
LC50, DAPHNIA MAGNA (WATER FLEA), 48 HOUR, >4,000 MG/L, OECD TEST
GUIDELINE 202 OR EQUIVALENT
PROPANE:
ACUTE TOXICITY TO FISH: NO RELEVANT DATA FOUND.
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
ACUTE TOXICITY TO FISH:
THE MEASURED ECOTOXICITY IS THAT OF THE HYDROLYZED PRODUCT, GENERALLY
UNDER CONDITIONS MAXIMIZING PRODUCTION OF SOLUBLE SPECIES.
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
LC50, DANIO RERIO (ZEBRA FISH), STATIC TEST, 96 HOUR, >1,000 MG/L, OECD
TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 24 HOUR, >1,000 MG/L, OECD
TEST GUIDELINE 202 OR EQUIVALENT
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
NOEC, DESMODESMUS SUBSPICATUS (GREEN ALGAE), STATIC TEST, 72 HOUR, GROWTH
RATE INHIBITION, 1,640 MG/L, OECD TEST GUIDELINE 201 OR EQUIVALENT
TOXICITY TO BACTERIA:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, ACTIVATED SLUDGE, STATIC TEST, 3 HOUR, RESPIRATION RATES., >100 MG/L
TOXICITY TO SOIL-DWELLING ORGANISMS:
EC50, EISENIA FETIDA (EARTHWORMS), BASED ON INFORMATION FOR A SIMILAR
MATERIAL:, 14 D, >1,000 MG/KG
TOXICITY TO TERRESTRIAL PLANTS:
EC50, AVENA SATIVA (OATS), GROWTH INHIBITION, 1,000 MG/L
EC50, LACTUCA SATIVA (LETTUCE), GROWTH INHIBITION, 1,000 MG/L
PERSISTENCE AND DEGRADABILITY:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
BIODEGRADABILITY:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MATERIAL REACTS WITH WATER
FORMING PREDOMINANTLY INSOLUBLE POLYUREAS WHICH APPEAR TO BE STABLE.
IN THE ATMOSPHERIC ENVIRONMENT, MATERIAL IS EXPECTED TO HAVE A SHORT
TROPOSPHERIC HALF-LIFE, BASED ON CALCULATIONS AND BY ANALOGY WITH
RELATED DIISOCYANATES.
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: 0 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 302C OR EQUIVALENT
POLYMETHYLENEPOLYPHENYLISOCYANATE, PROPOXYLATED GLYCERIN POLYMER:
BIODEGRADABILITY:
FOR THIS FAMILY OF MATERIALS: MATERIAL IS READILY BIODEGRADABLE. PASSES
OECD TEST(S) FOR READY BIODEGRADABILITY.
POLYMETHYLENEPOLYPHENYL POLYISOCYANATE, POLYPROPYLENEGLYCOL COPOLYMER:
BIODEGRADABILITY: EXPECTED TO DEGRADE SLOWLY IN THE ENVIRONMENT.
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
BIODEGRADABILITY:
MATERIAL IS EXPECTED TO BIODEGRADE VERY SLOWLY (IN THE ENVIRONMENT). FAILS
TO PASS OECD/EEC TESTS FOR READY BIODEGRADABILITY.
10-DAY WINDOW: FAIL
BIODEGRADATION: 14 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301E OR EQUIVALENT
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: 95 %
EXPOSURE TIME: 64 D
METHOD: OECD TEST GUIDELINE 302A OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 1.17 MG/MG
PHOTODEGRADATION:
TEST TYPE: HALF-LIFE (INDIRECT PHOTOLYSIS)
SENSITIZER: OH RADICALS
ATMOSPHERIC HALF-LIFE: 0.24 D
METHOD: ESTIMATED.
PARAFFIN WAXES AND HYDROCARBON WAXES, CHLORINATED:
BIODEGRADABILITY: EXPECTED TO DEGRADE SLOWLY IN THE ENVIRONMENT.
THEORETICAL OXYGEN DEMAND: 2.89 MG/MG
ISOBUTANE:
BIODEGRADABILITY:
BIODEGRADATION MAY OCCUR UNDER AEROBIC CONDITIONS (IN THE PRESENCE
OF OXYGEN).
THEORETICAL OXYGEN DEMAND: 3.58 MG/MG
PHOTODEGRADATION:
TEST TYPE: HALF-LIFE (INDIRECT PHOTOLYSIS)
SENSITIZER: OH RADICALS
ATMOSPHERIC HALF-LIFE: 4.4 D
METHOD: ESTIMATED.
METHYL ETHER:
BIODEGRADABILITY:
MATERIAL IS EXPECTED TO BIODEGRADE VERY SLOWLY (IN THE ENVIRONMENT). FAILS
TO PASS OECD/EEC TESTS FOR READY BIODEGRADABILITY.
10-DAY WINDOW: FAIL
BIODEGRADATION: 5 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301A OR EQUIVALENT
THEORETICAL OXYGEN DEMAND: 2.08 MG/MG
PHOTODEGRADATION:
TEST TYPE: HALF-LIFE (INDIRECT PHOTOLYSIS)
SENSITIZER: OH RADICALS
ATMOSPHERIC HALF-LIFE: 6.4 D
METHOD: ESTIMATED.
PROPANE:
BIODEGRADABILITY: NO RELEVANT DATA FOUND.
THEORETICAL OXYGEN DEMAND: 3.64 MG/MG
PHOTODEGRADATION:
TEST TYPE: HALF-LIFE (INDIRECT PHOTOLYSIS)
SENSITIZER: OH RADICALS
ATMOSPHERIC HALF-LIFE: 8.4 D
METHOD: ESTIMATED.
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
BIODEGRADABILITY:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MATERIAL REACTS WITH WATER
FORMING PREDOMINANTLY INSOLUBLE POLYUREAS WHICH APPEAR TO BE STABLE.
IN THE ATMOSPHERIC ENVIRONMENT, MATERIAL IS EXPECTED TO HAVE A SHORT
TROPOSPHERIC HALF-LIFE, BASED ON CALCULATIONS AND BY ANALOGY WITH
RELATED DIISOCYANATES.
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: 0 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 302C OR EQUIVALENT
BIOACCUMULATIVE POTENTIAL:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3). REACTS
WITH WATER. IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS
EXPECTED TO BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY
INSOLUBLE POLYUREAS.
BIOCONCENTRATION FACTOR (BCF): 92 CYPRINUS CARPIO (CARP) 28 D
POLYMETHYLENEPOLYPHENYLISOCYANATE, PROPOXYLATED GLYCERIN POLYMER:
BIOACCUMULATION: NO RELEVANT DATA FOUND.
POLYMETHYLENEPOLYPHENYL POLYISOCYANATE, POLYPROPYLENEGLYCOL COPOLYMER:
BIOACCUMULATION:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED TO
BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3).
PARTITION COEFFICIENT N-OCTANOL/WATER(LOG POW): 2.59 MEASURED
BIOCONCENTRATION FACTOR (BCF):
0.8 - 4.6 CYPRINUS CARPIO (CARP) 42 D MEASURED
PARAFFIN WAXES AND HYDROCARBON WAXES, CHLORINATED:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF LESS THAN 100 OR LOG POW GREATER
THAN 7).
PARTITION COEFFICIENT N-OCTANOL/WATER(LOG POW): 7.4 ESTIMATED.
ISOBUTANE:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3).
PARTITION COEFFICIENT N-OCTANOL/WATER(LOG POW): 2.76 MEASURED
METHYL ETHER:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3).
PARTITION COEFFICIENT N-OCTANOL/WATER(LOG POW): 0.10 MEASURED
PROPANE:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3).
PARTITION COEFFICIENT N-OCTANOL/WATER(LOG POW): 2.36 MEASURED
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3). REACTS WITH
WATER. IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED
TO BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
BIOCONCENTRATION FACTOR (BCF): 92 CYPRINUS CARPIO (CARP) 28 D
MOBILITY IN SOIL:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED TO
BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
POLYMETHYLENEPOLYPHENYLISOCYANATE, PROPOXYLATED GLYCERIN POLYMER:
NO RELEVANT DATA FOUND.
POLYMETHYLENEPOLYPHENYL POLYISOCYANATE, POLYPROPYLENEGLYCOL COPOLYMER:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED TO
BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
TRIS(1-CHLORO-2-PROPYL) PHOSPHATE:
POTENTIAL FOR MOBILITY IN SOIL IS SLIGHT (KOC BETWEEN 2000 AND 5000).
PARTITION COEFFICIENT(KOC): 1300 ESTIMATED.
PARAFFIN WAXES AND HYDROCARBON WAXES, CHLORINATED:
GIVEN ITS VERY LOW HENRY'S CONSTANT, VOLATILIZATION FROM NATURAL BODIES
OF WATER OR MOIST SOIL IS NOT EXPECTED TO BE AN IMPORTANT FATE PROCESS.
EXPECTED TO BE RELATIVELY IMMOBILE IN SOIL (KOC >5000).
PARTITION COEFFICIENT(KOC): >5000 ESTIMATED.
ISOBUTANE:
POTENTIAL FOR MOBILITY IN SOIL IS VERY HIGH (KOC BETWEEN 0 AND 50).
PARTITION COEFFICIENT(KOC): 35 ESTIMATED.
METHYL ETHER:
POTENTIAL FOR MOBILITY IN SOIL IS VERY HIGH (KOC BETWEEN 0 AND 50).
PARTITION COEFFICIENT(KOC): 1.29 - 14 ESTIMATED.
PROPANE:
POTENTIAL FOR MOBILITY IN SOIL IS VERY HIGH (KOC BETWEEN 0 AND 50).
PARTITION COEFFICIENT(KOC): 24 - 460 ESTIMATED.
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED TO
BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF
WATER. ALL DISPOSAL PRACTICES MUST BE IN COMPLIANCE WITH ALL FEDERAL,
STATE/PROVINCIAL AND LOCAL LAWS AND REGULATIONS. REGULATIONS MAY VARY
IN DIFFERENT LOCATIONS. WASTE CHARACTERIZATIONS AND COMPLIANCE WITH
APPLICABLE LAWS ARE THE RESPONSIBILITY SOLELY OF THE WASTE GENERATOR.
AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL.
THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED
IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION:
COMPOSITION INFORMATION. FOR UNUSED & UNCONTAMINATED PRODUCT, THE
PREFERRED OPTIONS INCLUDE SENDING TO A LICENSED, PERMITTED: INCINERATOR
OR OTHER THERMAL DESTRUCTION DEVICE.
| 14. TRANSPORT INFORMATION | |
DOT:
PROPER SHIPPING NAME: AEROSOLS
UN NUMBER: UN 1950
CLASS: 2.1
PACKING GROUP:
CLASSIFICATION FOR SEA TRANSPORT (IMO-IMDG):
PROPER SHIPPING NAME: AEROSOLS
UN NUMBER: UN 1950
CLASS: 2.1
PACKING GROUP:
MARINE POLLUTANT: PARAFFIN WAXES AND HYDROCARBON WAXES, CHLORINATED
TRANSPORT IN BULK ACCORDING TO ANNEX I OR II OF MARPOL 73/78 AND THE IBC
OR IGC CODE: CONSULT IMO REGULATIONS BEFORE TRANSPORTING OCEAN BULK
CLASSIFICATION FOR AIR TRANSPORT (IATA/ICAO):
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
UN NUMBER: UN 1950
CLASS: 2.1
PACKING GROUP:
THIS INFORMATION IS NOT INTENDED TO CONVEY ALL SPECIFIC REGULATORY
OR OPERATIONAL REQUIREMENTS/INFORMATION RELATING TO THIS PRODUCT.
TRANSPORTATION CLASSIFICATIONS MAY VARY BY CONTAINER VOLUME AND MAY
BE INFLUENCED BY REGIONAL OR COUNTRY VARIATIONS IN REGULATIONS. ADDITIONAL
TRANSPORTATION SYSTEM INFORMATION CAN BE OBTAINED THROUGH AN AUTHORIZED
SALES OR CUSTOMER SERVICE REPRESENTATIVE. IT IS THE RESPONSIBILITY OF THE
TRANSPORTING ORGANIZATION TO FOLLOW ALL APPLICABLE LAWS, REGULATIONS AND
RULES RELATING TO THE TRANSPORTATION OF THE MATERIAL.
| 15. REGULATORY INFORMATION | |
OSHA HAZARD COMMUNICATION STANDARD:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY
PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986) SECTIONS 311 AND 312:
ACUTE HEALTH HAZARD
CHRONIC HEALTH HAZARD
FIRE HAZARD
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY
PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986) SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES WHICH ARE SUBJECT TO
THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND WHICH ARE LISTED IN
40 CFR 372.
COMPONENTS CASRN
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES 9016-87-9
4,4' -METHYLENEDIPHENYL DIISOCYANATE 101-68-8
PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
THE FOLLOWING CHEMICALS ARE LISTED BECAUSE OF THE ADDITIONAL REQUIREMENTS
OF PENNSYLVANIA LAW:
COMPONENTS CASRN
ISOBUTANE 75-28-5
METHYL ETHER 115-10-6
PROPANE 74-98-6
CALIFORNIA PROPOSITION 65 (SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT
OF 1986):
THIS PRODUCT CONTAINS NO LISTED SUBSTANCES KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE
HARM, AT LEVELS WHICH WOULD REQUIRE A WARNING UNDER THE STATUTE.
UNITED STATES TSCA INVENTORY (TSCA):
ALL COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE INVENTORY
LISTING REQUIREMENTS OF THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA)
CHEMICAL SUBSTANCE INVENTORY.
| 16. OTHER INFORMATION | |
REVISION:
IDENTIFICATION NUMBER: 101194255 / A001
ISSUE DATE: 01/19/2016
VERSION: 8.0
MOST RECENT REVISION(S) ARE NOTED BY THE BOLD, DOUBLE BARS IN LEFT-HAND
MARGIN THROUGHOUT THIS DOCUMENT.
LEGEND:
ACGIH: USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
ASPHYXIANT: ASPHYXIANT
C: CEILING
DOW IHG: DOW INDUSTRIAL HYGIENE GUIDELINE
NIOSH REL: USA. NIOSH RECOMMENDED EXPOSURE LIMITS
OSHA Z-1:
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z-1 LIMITS FOR AIR
CONTAMINANTS
STEL: SHORT TERM EXPOSURE LIMIT
TWA: TIME WEIGHTED AVERAGE
US WEEL: USA. WORKPLACE ENVIRONMENTAL EXPOSURE LEVELS (WEEL)
INFORMATION SOURCE AND REFERENCES:
THIS SDS IS PREPARED BY PRODUCT REGULATORY SERVICES AND HAZARD
COMMUNICATIONS GROUPS FROM INFORMATION SUPPLIED BY INTERNAL REFERENCES
WITHIN OUR COMPANY.
THE DOW CHEMICAL COMPANY URGES EACH CUSTOMER OR RECIPIENT OF THIS (M)SDS
TO STUDY IT CAREFULLY AND CONSULT APPROPRIATE EXPERTISE, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
(M)SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THE INFORMATION HEREIN
IS PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE
DATE SHOWN ABOVE. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN.
REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN
VARIOUS LOCATIONS. IT IS THE BUYER'S/USER'S RESPONSIBILITY TO ENSURE THAT
HIS ACTIVITIES COMPLY WITH ALL FEDERAL, STATE, PROVINCIAL OR LOCAL LAWS.
THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED.
SINCE CONDITIONS FOR USE OF THE PRODUCT ARE NOT UNDER THE CONTROL OF THE
MANUFACTURER, IT IS THE BUYER'S/USER'S DUTY TO DETERMINE THE CONDITIONS
NECESSARY FOR THE SAFE USE OF THIS PRODUCT. DUE TO THE PROLIFERATION OF
SOURCES FOR INFORMATION SUCH AS MANUFACTURERSPECIFIC (M)SDSS, WE ARE NOT
AND CANNOT BE RESPONSIBLE FOR (M)SDSS OBTAINED FROM ANY SOURCE OTHER THAN
OURSELVES. IF YOU HAVE OBTAINED AN (M)SDS FROM ANOTHER SOURCE OR IF YOU
ARE NOT SURE THAT THE (M)SDS YOU HAVE IS CURRENT, PLEASE CONTACT US FOR
THE MOST CURRENT VERSION.
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COMPANY OF DOW