| Common Name: | FROTH-PAK HIGH DENSITY ISO HFO 115BF CYLINDER |
| Manufacturer: | DDP SPECIALTY ELECTRONIC MATERIALS |
| SDS Revision Date: | 2/16/2022 |
| SDS Format: | No Format Specified |
| Item Number(s): | 48WK25 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DUPONT(TM)
SAFETY DATA SHEET
DDP SPECIALTY ELECTRONIC MATERIALS US, LLC
PRODUCT NAME: FROTH-PAK(TM) HIGH DENSITY ISO HFO 115BF CYLINDER
ISSUE DATE: 02/16/2022
PRINT DATE: 06/07/2023
DDP SPECIALTY ELECTRONIC MATERIALS US, LLC ENCOURAGES AND EXPECTS YOU
TO READ AND UNDERSTAND THE ENTIRE (M)SDS, AS THERE IS IMPORTANT
INFORMATION THROUGHOUT THE DOCUMENT. WE EXPECT YOU TO FOLLOW THE
PRECAUTIONS IDENTIFIED IN THIS DOCUMENT UNLESS YOUR USE CONDITIONS
WOULD NECESSITATE OTHER APPROPRIATE METHODS OR ACTIONS.
| 1. IDENTIFICATION |  |
PRODUCT NAME: FROTH-PAK(TM) HIGH DENSITY ISO HFO 115BF CYLINDER
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
IDENTIFIED USES:
FOR INDUSTRIAL USE. WE RECOMMEND THAT YOU USE THIS PRODUCT IN A MANNER
CONSISTENT WITH THE LISTED USE. IF YOUR INTENDED USE IS NOT CONSISTENT
WITH THE STATED USE, PLEASE CONTACT YOUR SALES OR TECHNICAL SERVICE
REPRESENTATIVE.
COMPANY IDENTIFICATION:
DDP SPECIALTY ELECTRONIC MATERIALS US, LLC
974 CENTRE ROAD, BUILDING 730,
WILMINGTON DE 19805
UNITED STATES
CUSTOMER INFORMATION NUMBER: 833-338-7668
SDSQUESTION-NA@DUPONT.COM
EMERGENCY TELEPHONE NUMBER:
24-HOUR EMERGENCY CONTACT: 1-800-424-9300
LOCAL EMERGENCY CONTACT: 800-424-9300
| 2. HAZARDS IDENTIFICATION | |
HAZARD CLASSIFICATION:
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910.1200
GASES UNDER PRESSURE - LIQUEFIED GAS
ACUTE TOXICITY - CATEGORY 4 - INHALATION
SKIN IRRITATION - CATEGORY 2
EYE IRRITATION - CATEGORY 2B
RESPIRATORY SENSITISATION - CATEGORY 1
SKIN SENSITISATION - CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE - CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE - CATEGORY 2
- INHALATION
SIMPLE ASPHYXIANT
LABEL ELEMENTS:
HAZARD PICTOGRAMS:
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER!
HAZARDS:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SKIN AND EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
HARMFUL IF INHALED.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DAMAGE TO ORGANS (RESPIRATORY TRACT) THROUGH PROLONGED OR
REPEATED EXPOSURE IF INHALED.
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE MIST OR VAPOURS.
WASH SKIN THOROUGHLY AFTER HANDLING.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
WEAR PROTECTIVE GLOVES.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
CALL A POISON CENTER/ DOCTOR IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ ATTENTION.
IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER/ DOCTOR.
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/ CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NO DATA AVAILABLE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
THIS PRODUCT IS A MIXTURE.
COMPONENT CASRN CONCENTRATION
DIPHENYLMETHANE DIISOCYANATE, 9016-87-9 >60.0 - <=80.0%
ISOMERS AND HOMOLOGUES
4,4' -METHYLENEDIPHENYL DIISOCYANATE 101-68-8 >20.0 - <=40.0%
TRANS-1-CHLORO-3,3,3-TRIFLUOROPROPENE 102687-65-0 >0.0 - <20.0%
CARBON DIOXIDE 124-38-9 >=1.0 - <5.0%
NITROGEN 7727-37-9 >=0.1 - <2.0 %
NOTE:
NOTE: CAS 101-68-8 IS AN MDI ISOMER THAT IS PART OF CAS 9016-87-9.
| 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
FIRST AID RESPONDERS SHOULD PAY ATTENTION TO SELF-PROTECTION AND USE THE
RECOMMENDED PROTECTIVE CLOTHING (CHEMICAL RESISTANT GLOVES, SPLASH
PROTECTION). IF POTENTIAL FOR EXPOSURE EXISTS REFER TO SECTION 8 FOR
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT.
INHALATION:
MOVE PERSON TO FRESH AIR; IF EFFECTS OCCUR, CONSULT A PHYSICIAN.
SKIN CONTACT: WASH SKIN THOROUGHLY WITH SOAP AND WATER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ADVICE/ ATTENTION. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF
THE WORKPLACE. WASH THOROUGHLY AFTER HANDLING.
EYE CONTACT:
IMMEDIATELY FLUSH EYE(S) WITH PLENTY OF WATER. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION IF
IRRITATION PERSISTS. EYE WASH FOUNTAIN SHOULD BE LOCATED IN IMMEDIATE
WORK AREA.
INGESTION:
IF SWALLOWED, SEEK MEDICAL ATTENTION. DO NOT INDUCE VOMITING UNLESS
DIRECTED TO DO SO BY MEDICAL PERSONNEL.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ASIDE FROM THE INFORMATION FOUND UNDER DESCRIPTION OF FIRST AID
MEASURES (ABOVE) AND INDICATION OF IMMEDIATE MEDICAL ATTENTION
AND SPECIAL TREATMENT NEEDED (BELOW), ANY ADDITIONAL IMPORTANT
SYMPTOMS AND EFFECTS ARE DESCRIBED IN SECTION 11: TOXICOLOGY
INFORMATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOTES TO PHYSICIAN: NO SPECIFIC ANTIDOTE, TREAT SYMPTOMATICALLY.
| 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG OR FINE SPRAY. DRY CHEMICAL FIRE EXTINGUISHERS. CARBON DIOXIDE
FIRE EXTINGUISHERS. FOAM. ALCOHOL RESISTANT FOAMS (ATC TYPE) ARE
PREFERRED. GENERAL PURPOSE SYNTHETIC FOAMS (INCLUDING AFFF) OR PROTEIN
FOAMS MAY FUNCTION, BUT WILL BE LESS EFFECTIVE.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE DIRECT WATER STREAM. MAY SPREAD FIRE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HAZARDOUS COMBUSTION PRODUCTS:
DURING A FIRE, SMOKE MAY CONTAIN THE ORIGINAL MATERIAL IN ADDITION
TO COMBUSTION PRODUCTS OF VARYING COMPOSITION WHICH MAY BE TOXIC
AND/OR IRRITATING.
COMBUSTION PRODUCTS MAY INCLUDE AND ARE NOT LIMITED TO:
NITROGEN OXIDES. ISOCYANATES. HYDROGEN CYANIDE. CARBON MONOXIDE.
CARBON DIOXIDE. HYDROGEN HALIDES. HALOGENATED HYDROCARBONS.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
SOME COMPONENTS OF THIS PRODUCT WILL BURN IN A FIRE SITUATION. PRODUCT
REACTS WITH WATER. REACTION MAY PRODUCE HEAT AND/OR GASES. THIS REACTION
MAY BE VIOLENT. CONTAINER MAY RUPTURE FROM GAS GENERATION IN A FIRE
SITUATION. BLOWING AGENT VAPORIZES QUICKLY AT ROOM TEMPERATURE. VIOLENT
STEAM GENERATION OR ERUPTION MAY OCCUR UPON APPLICATION OF DIRECT WATER
STREAM TO HOT LIQUIDS. DENSE SMOKE IS PRODUCED WHEN PRODUCT BURNS.
ADVICE FOR FIREFIGHTERS:
FIRE FIGHTING PROCEDURES:
KEEP PEOPLE AWAY. ISOLATE FIRE AND DENY UNNECESSARY ENTRY. STAY UPWIND.
KEEP OUT OF LOW AREAS WHERE GASES (FUMES) CAN ACCUMULATE. WATER IS NOT
RECOMMENDED, BUT MAY BE APPLIED IN LARGE QUANTITIES AS A FINE SPRAY
WHEN OTHER EXTINGUISHING AGENTS ARE NOT AVAILABLE. DO NOT USE DIRECT
WATER STREAM. MAY SPREAD FIRE. FIGHT FIRE FROM PROTECTED LOCATION OR
SAFE DISTANCE. CONSIDER THE USE OF UNMANNED HOSE HOLDERS OR MONITOR
NOZZLES. IMMEDIATELY WITHDRAW ALL PERSONNEL FROM THE AREA IN CASE OF
RISING SOUND FROM VENTING SAFETY DEVICE OR DISCOLORATION OF THE CONTAINER.
MOVE CONTAINER FROM FIRE AREA IF THIS IS POSSIBLE WITHOUT HAZARD. USE WATER
SPRAY TO COOL FIRE-EXPOSED CONTAINERS AND FIRE-AFFECTED ZONE UNTIL FIRE IS
OUT. CONTAIN FIRE WATER RUN-OFF IF POSSIBLE. FIRE WATER RUN-OFF, IF NOT
CONTAINED, MAY CAUSE ENVIRONMENTAL DAMAGE. REVIEW THE "ACCIDENTAL RELEASE
MEASURES" AND THE "ECOLOGICAL INFORMATION" SECTIONS OF THIS (M)SDS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
WEAR POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND
PROTECTIVE FIRE FIGHTING CLOTHING (INCLUDES FIRE FIGHTING HELMET, COAT,
TROUSERS, BOOTS, AND GLOVES). AVOID CONTACT WITH THIS MATERIAL DURING
FIRE FIGHTING OPERATIONS. IF CONTACT IS LIKELY, CHANGE TO FULL CHEMICAL
RESISTANT FIRE FIGHTING CLOTHING WITH SELF-CONTAINED BREATHING APPARATUS.
IF THIS IS NOT AVAILABLE, WEAR FULL CHEMICAL RESISTANT CLOTHING WITH
SELF-CONTAINED BREATHING APPARATUS AND FIGHT FIRE FROM A REMOTE LOCATION.
FOR PROTECTIVE EQUIPMENT IN POST-FIRE OR NON-FIRE CLEAN-UP SITUATIONS,
REFER TO THE RELEVANT SECTIONS.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ISOLATE AREA. KEEP UNNECESSARY AND UNPROTECTED PERSONNEL FROM ENTERING
THE AREA. REFER TO SECTION 7, HANDLING, FOR ADDITIONAL PRECAUTIONARY
MEASURES. KEEP PERSONNEL OUT OF LOW AREAS. KEEP PERSONNEL OUT OF CONFINED
OR POORLY VENTILATED AREAS. KEEP UPWIND OF SPILL. VENTILATE AREA OF LEAK
OR SPILL. CONFINED SPACE ENTRY PROCEDURES MUST BE FOLLOWED BEFORE ENTERING
THE AREA. SEE SECTION 10 FOR MORE SPECIFIC INFORMATION. SPILLED MATERIAL
MAY CAUSE A SLIPPING HAZARD. USE APPROPRIATE SAFETY EQUIPMENT. FOR
ADDITIONAL INFORMATION, REFER TO SECTION 8, EXPOSURE CONTROLS AND PERSONAL
PROTECTION.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FROM ENTERING INTO SOIL, DITCHES, SEWERS, WATERWAYS AND/OR
GROUNDWATER. SEE SECTION 12, ECOLOGICAL INFORMATION.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
DO NOT USE ABSORBENT MATERIALS SUCH AS:
CEMENT POWDER (NOTE: MAY GENERATE HEAT). CONTAIN SPILLED MATERIAL IF
POSSIBLE.
ABSORB WITH MATERIALS SUCH AS:
DIRT. VERMICULITE. SAND. CLAY. COLLECT IN SUITABLE AND PROPERLY LABELED
OPEN CONTAINERS. ISOLATE AREA UNTIL GAS HAS DISPERSED. APPLY VAPOR
SUPPRESSION FOAMS UNTIL SPILL CAN BE CLEANED UP. KNOCK DOWN AND DILUTE
VAPORS WITH WATER FOG OR SPRAY. SEE SECTION 13, DISPOSAL CONSIDERATIONS,
FOR ADDITIONAL INFORMATION.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH EYES. AVOID BREATHING VAPOR. DO NOT ENTER CONFINED
SPACES UNLESS ADEQUATELY VENTILATED. WASH THOROUGHLY AFTER HANDLING.
KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. THIS MATERIAL
IS HYGROSCOPIC IN NATURE. SEE SECTION 8, EXPOSURE CONTROLS AND PERSONAL
PROTECTION.
SPILLS OF THESE ORGANIC MATERIALS ON HOT FIBROUS INSULATIONS MAY LEAD
TO LOWERING OF THE AUTOIGNITION TEMPERATURES POSSIBLY RESULTING IN
SPONTANEOUS COMBUSTION.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
CONDITIONS FOR SAFE STORAGE:
MINIMIZE SOURCES OF IGNITION, SUCH AS STATIC BUILD-UP, HEAT, SPARK OR
FLAME. FLAMMABLE VAPORS MAY ACCUMULATE IN SOME STORAGE SITUATIONS.
PROTECT FROM ATMOSPHERIC MOISTURE. STORE IN A DRY PLACE. AVOID PROLONGED
EXPOSURE TO HEAT AND AIR. AVOID TEMPERATURES ABOVE 50 DEG. C (122 DEG. F)
SEE SECTION 10 FOR MORE SPECIFIC INFORMATION.
STORAGE STABILITY:
STORAGE PERIOD: 15 MONTH
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
IF EXPOSURE LIMITS EXIST, THEY ARE LISTED BELOW. IF NO EXPOSURE
LIMITS ARE DISPLAYED, THEN NO VALUES ARE APPLICABLE.
COMPONENT REGULATION TYPE OF LISTING VALUE
4,4' -METHY- DOW IHG TWA 0.005 PPM
LENEDIPHENYL
DIISOCYANATE
DOW IHG STEL 0.02 PPM
ACGIH TWA 0.005 PPM
FURTHER INFORMATION:
RESP SENS: RESPIRATORY SENSITIZATION
OSHA Z-1 C 0.2 MG/M3
0.02 PPM
FURTHER INFORMATION:
(B):
THE VALUE IN MG/M3 IS
APPROXIMATE.; DETERMINED FROM
BREATHING-ZONE AIR SAMPLES.
(C): CEILING LIMIT IS TO BE
OSHA P0 C 0.2 MG/M3
0.02 PPM
TRANS-1-CHLORO- US WEEL TWA 800 PPM
3,3,3-
TRIFLUOROPROPENE
CARBON DIOXIDE DOW IHG TWA 5,000 PPM
DOW IHG STEL 30,000 PPM
ACGIH TWA 5,000 PPM
FURTHER INFORMATION:
ASPHYXIA: ASPHYXIA
ACGIH STEL 30,000 PPM
FURTHER INFORMATION:
ASPHYXIA: ASPHYXIA
OSHA Z-1 TWA 9,000 MG/M3
5,000 PPM
FURTHER INFORMATION:
(B): THE VALUE IN MG/M3 IS
APPROXIMATE
CAL PEL PEL 9,000 MG/M3
5,000 PPM
CAL PEL STEL 54,000 MG/M3
30,000 PPM
NITROGEN ACGIH SEE FURTHER
INFORMATION
FURTHER INFORMATION:
ASPHYXIA; ():
ADOPTED VALUES OR NOTATIONS ENCLOSED
ARE THOSE FOR WHICH
CHANGES ARE PROPOSED IN THE NIC;
SEE NOTICE OF INTENDED CHANGES (NIC);
D:
SIMPLE ASPHYXIANT; SEE DISCUSSION
COVERING MINIMAL OXYGEN CONTENT FOUND
IN THE 'DEFINITIONS AND NOTATIONS'
SECTION FOLLOWING THE NIC TABLES
CAL PEL SEE FURTHER
INFORMATION
FURTHER INFORMATION:
(H):
A NUMBER OF GASES AND VAPORS, WHEN
PRESENT IN HIGH CONCENTRATIONS, ACT
PRIMARILY AS ASPHYXIANTS WITHOUT OTHER
ADVERSE EFFECTS. A CONCENTRATION LIMIT
IS NOT INCLUDED FOR EACH MATERIAL
BECAUSE THE LIMITING FACTOR IS THE
AVAILABLE OXYGEN. (SEVERAL OF THESE
MATERIALS PRESENT FIRE OR EXPLOSION
HAZARDS.)
EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
USE ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVEL BELOW EXPOSURE
LIMIT REQUIREMENTS OR GUIDELINES. IF THERE ARE NO APPLICABLE EXPOSURE
LIMIT REQUIREMENTS OR GUIDELINES, USE ONLY WITH ADEQUATE VENTILATION.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
INDIVIDUAL PROTECTION MEASURES:
EYE/FACE PROTECTION:
USE CHEMICAL GOGGLES. IF EXPOSURE CAUSES EYE DISCOMFORT, USE A FULL-FACE
RESPIRATOR.
SKIN PROTECTION:
HAND PROTECTION: USE GLOVES CHEMICALLY RESISTANT TO THIS MATERIAL.
OTHER PROTECTION:
USE PROTECTIVE CLOTHING CHEMICALLY RESISTANT TO THIS MATERIAL. SELECTION
OF SPECIFIC ITEMS SUCH AS FACE SHIELD, BOOTS, APRON, OR FULL BODY SUIT
WILL DEPEND ON THE TASK.
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION SHOULD BE WORN WHEN THERE IS A POTENTIAL TO EXCEED
THE EXPOSURE LIMIT REQUIREMENTS OR GUIDELINES. IF THERE ARE NO APPLICABLE
EXPOSURE LIMIT REQUIREMENTS OR GUIDELINES, USE AN APPROVED RESPIRATOR.
WHEN RESPIRATORY PROTECTION IS REQUIRED, USE AN APPROVED POSITIVE-PRESSURE
SELF-CONTAINED BREATHING APPARATUS OR POSITIVE-PRESSURE AIRLINE WITH
AUXILIARY SELF-CONTAINED AIR SUPPLY. FOR EMERGENCY CONDITIONS, USE AN
APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS. IN CONFINED
OR POORLY VENTILATED AREAS, USE AN APPROVED SELF-CONTAINED BREATHING
APPARATUS OR POSITIVE PRESSURE AIR LINE WITH AUXILIARY SELF-CONTAINED AIR
SUPPLY.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUEFIED GAS
COLOR: BROWN
ODOR: MUSTY
ODOR THRESHOLD: ODOR IS INADEQUATE WARNING OF EXCESSIVE EXPOSURE.
PH: NO DATA AVAILABLE
MELTING POINT/RANGE: NO DATA AVAILABLE.
FREEZING POINT: NO DATA AVAILABLE.
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
EVAPORATION RATE (BUTYL ACETATE = 1): NOT AVAILABLE
FLAMMABILITY (SOLID, GAS):
NOT APPLICABLE TO LIQUIDS NO INFORMATION AVAILABLE.
LOWER EXPLOSION LIMIT: LIQUID.
UPPER EXPLOSION LIMIT: LIQUID.
VAPOR PRESSURE: NOT AVAILABLE
RELATIVE VAPOR DENSITY (AIR = 1): NO DATA AVAILABLE
RELATIVE DENSITY (WATER = 1): 1.24 AT 25 DEG. C (77 DEG. F) ESTIMATED.
WATER SOLUBILITY: INSOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
KINEMATIC VISCOSITY: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO OXIDISING PROPERTIES
MOLECULAR WEIGHT: NO DATA AVAILABLE
NOTE:
THE PHYSICAL DATA PRESENTED ABOVE ARE TYPICAL VALUES AND SHOULD NOT
BE CONSTRUED AS A SPECIFICATION.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE
CHEMICAL STABILITY:
STABLE UNDER RECOMMENDED STORAGE CONDITIONS. SEE STORAGE, SECTION 7.
POSSIBILITY OF HAZARDOUS REACTIONS:
CAN OCCUR. ELEVATED TEMPERATURES CAN CAUSE HAZARDOUS POLYMERIZATION.
POLYMERIZATION CAN BE CATALYZED BY: STRONG BASES. WATER.
CONDITIONS TO AVOID:
EXPOSURE TO ELEVATED TEMPERATURES CAN CAUSE PRODUCT TO DECOMPOSE. ELEVATED
TEMPERATURES CAN CAUSE PRESSURE BUILDUP IN CLOSED CONTAINERS DUE TO THE
RELEASE OF BLOWING AGENTS. GENERATION OF GAS DURING DECOMPOSITION CAN
CAUSE PRESSURE IN CLOSED SYSTEMS. PRESSURE BUILD-UP CAN BE RAPID. AVOID
MOISTURE. MATERIAL REACTS SLOWLY WITH WATER, RELEASING CARBON DIOXIDE
WHICH CAN CAUSE PRESSURE BUILDUP AND RUPTURE OF CLOSED CONTAINERS.
ELEVATED TEMPERATURES ACCELERATE THIS REACTION.
INCOMPATIBLE MATERIALS:
AVOID CONTACT WITH: ACIDS. ALCOHOLS. AMINES. WATER. AMMONIA. BASES. METAL
COMPOUNDS. MOIST AIR. STRONG OXIDIZERS. DIISOCYANATES REACT WITH MANY
MATERIALS AND THE RATE OF REACTION INCREASES WITH TEMPERATURE AS WELL
AS INCREASED CONTACT; THESE REACTIONS CAN BECOME VIOLENT. CONTACT IS
INCREASED BY STIRRING OR IF THE OTHER MATERIAL MIXES WITH THE
DIISOCYANATE. DIISOCYANATES ARE NOT SOLUBLE IN WATER AND SINK TO THE
BOTTOM, BUT REACT SLOWLY AT THE INTERFACE. THE REACTION FORMS CARBON
DIOXIDE GAS AND A LAYER OF SOLID POLYUREA. REACTION WITH WATER WILL
GENERATE CARBON DIOXIDE AND HEAT.
AVOID CONTACT WITH METALS SUCH AS: ALUMINUM. ZINC. BRASS. TIN. COPPER.
GALVANIZED METALS. AVOID CONTACT WITH ABSORBENT MATERIALS SUCH AS:
MOIST ORGANIC ABSORBENTS. AVOID UNINTENDED CONTACT WITH POLYOLS. THE
REACTION OF POLYOLS AND ISOCYANATES GENERATE HEAT.
HAZARDOUS DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS DEPEND UPON TEMPERATURE, AIR SUPPLY AND THE
PRESENCE OF OTHER MATERIALS. GASES ARE RELEASED DURING DECOMPOSITION.
| 11. TOXICOLOGICAL INFORMATION | |
TOXICOLOGICAL INFORMATION APPEARS IN THIS SECTION WHEN SUCH DATA
IS AVAILABLE.
ACUTE TOXICITY:
ACUTE ORAL TOXICITY:
PRODUCT TEST DATA NOT AVAILABLE. REFER TO COMPONENT DATA.
ACUTE DERMAL TOXICITY:
PRODUCT TEST DATA NOT AVAILABLE. REFER TO COMPONENT DATA.
ACUTE INHALATION TOXICITY:
PRODUCT TEST DATA NOT AVAILABLE. REFER TO COMPONENT DATA.
SKIN CORROSION/IRRITATION:
PRODUCT TEST DATA NOT AVAILABLE. REFER TO COMPONENT DATA.
SERIOUS EYE DAMAGE/EYE IRRITATION:
PRODUCT TEST DATA NOT AVAILABLE. REFER TO COMPONENT DATA.
SENSITIZATION:
PRODUCT TEST DATA NOT AVAILABLE. REFER TO COMPONENT DATA.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE):
PRODUCT TEST DATA NOT AVAILABLE. REFER TO COMPONENT DATA.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE):
PRODUCT TEST DATA NOT AVAILABLE. REFER TO COMPONENT DATA.
CARCINOGENICITY:
PRODUCT TEST DATA NOT AVAILABLE. REFER TO COMPONENT DATA.
TERATOGENICITY:
PRODUCT TEST DATA NOT AVAILABLE. REFER TO COMPONENT DATA.
REPRODUCTIVE TOXICITY:
PRODUCT TEST DATA NOT AVAILABLE. REFER TO COMPONENT DATA.
MUTAGENICITY:
PRODUCT TEST DATA NOT AVAILABLE. REFER TO COMPONENT DATA.
ASPIRATION HAZARD:
PRODUCT TEST DATA NOT AVAILABLE. REFER TO COMPONENT DATA.
COMPONENTS INFLUENCING TOXICOLOGY:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
ACUTE ORAL TOXICITY:
TYPICAL FOR THIS FAMILY OF MATERIALS. LD50, RAT, >10,000 MG/KG
ACUTE DERMAL TOXICITY:
TYPICAL FOR THIS FAMILY OF MATERIALS. LD50, RABBIT, >9,400 MG/KG
ACUTE INHALATION TOXICITY: LC50, RAT, 4 HOUR, DUST/MIST, 0.49 MG/L
FOR SIMILAR MATERIAL(S):
4,4'-METHYLENEDIPHENYL DIISOCYANATE (CAS 101-68-8). LC50, RAT, 1 HOUR,
AEROSOL, 2.24 MG/L
FOR SIMILAR MATERIAL(S):
2,4'-DIPHENYLMETHANE DIISOCYANATE (CAS 5873-54-1). LC50, RAT, 4 HOUR,
AEROSOL, 0.387 MG/L
SKIN CORROSION/IRRITATION:
PROLONGED CONTACT MAY CAUSE SLIGHT SKIN IRRITATION WITH LOCAL REDNESS.
MAY STAIN SKIN.
SERIOUS EYE DAMAGE/EYE IRRITATION:
MAY CAUSE MODERATE EYE IRRITATION.
MAY CAUSE SLIGHT TEMPORARY CORNEAL INJURY.
SENSITIZATION:
SKIN CONTACT MAY CAUSE AN ALLERGIC SKIN REACTION.
ANIMAL STUDIES HAVE SHOWN THAT SKIN CONTACT WITH ISOCYANATES MAY PLAY A
ROLE IN RESPIRATORY SENSITIZATION.
MAY CAUSE ALLERGIC RESPIRATORY REACTION.
MDI CONCENTRATIONS BELOW THE EXPOSURE GUIDELINES MAY CAUSE ALLERGIC
RESPIRATORY REACTIONS IN INDIVIDUALS ALREADY SENSITIZED.
ASTHMA-LIKE SYMPTOMS MAY INCLUDE COUGHING, DIFFICULT BREATHING AND A
FEELING OF TIGHTNESS IN THE CHEST. OCCASIONALLY, BREATHING DIFFICULTIES
MAY BE LIFE THREATENING.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE):
MAY CAUSE RESPIRATORY IRRITATION.
ROUTE OF EXPOSURE: INHALATION
TARGET ORGANS: RESPIRATORY TRACT
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE):
TISSUE INJURY IN THE UPPER RESPIRATORY TRACT AND LUNGS HAS BEEN OBSERVED
IN LABORATORY ANIMALS AFTER REPEATED EXCESSIVE EXPOSURES TO MDI/POLYMERIC
MDI AEROSOLS.
CARCINOGENICITY:
LUNG TUMORS HAVE BEEN OBSERVED IN LABORATORY ANIMALS EXPOSED TO RESPIRABLE
AEROSOL DROPLETS OF MDI/POLYMERIC MDI (6 MG/M3) FOR THEIR LIFETIME. TUMORS
OCCURRED CONCURRENTLY WITH RESPIRATORY IRRITATION AND LUNG INJURY. CURRENT
EXPOSURE GUIDELINES ARE EXPECTED TO PROTECT AGAINST THESE EFFECTS REPORTED
FOR MDI.
TERATOGENICITY:
IN LABORATORY ANIMALS, MDI/POLYMERIC MDI DID NOT CAUSE BIRTH DEFECTS;
OTHER FETAL EFFECTS OCCURRED ONLY AT HIGH DOSES WHICH WERE TOXIC TO
THE MOTHER.
REPRODUCTIVE TOXICITY: NO RELEVANT DATA FOUND.
MUTAGENICITY:
GENETIC TOXICITY DATA ON MDI ARE INCONCLUSIVE. MDI WAS WEAKLY POSITIVE
IN SOME IN VITRO STUDIES; OTHER IN VITRO STUDIES WERE NEGATIVE. ANIMAL
MUTAGENICITY STUDIES WERE PREDOMINANTLY NEGATIVE.
ASPIRATION HAZARD:
BASED ON PHYSICAL PROPERTIES, NOT LIKELY TO BE AN ASPIRATION HAZARD.
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
ACUTE ORAL TOXICITY:
LD50, RAT, >2,000 MG/KG NO DEATHS OCCURRED AT THIS CONCENTRATION.
ACUTE DERMAL TOXICITY: LD50, RABBIT, > 9,400 MG/KG
ACUTE INHALATION TOXICITY: LC50, RAT, 1 HOUR, DUST/MIST, 2.24 MG/L
SKIN CORROSION/IRRITATION:
PROLONGED CONTACT MAY CAUSE MODERATE SKIN IRRITATION WITH LOCAL REDNESS.
REPEATED CONTACT MAY CAUSE MODERATE SKIN IRRITATION WITH LOCAL REDNESS.
MAY STAIN SKIN.
SERIOUS EYE DAMAGE/EYE IRRITATION:
MAY CAUSE MODERATE EYE IRRITATION.
MAY CAUSE SLIGHT TEMPORARY CORNEAL INJURY.
SENSITIZATION:
SKIN CONTACT MAY CAUSE AN ALLERGIC SKIN REACTION.
ANIMAL STUDIES HAVE SHOWN THAT SKIN CONTACT WITH ISOCYANATES MAY PLAY A
ROLE IN RESPIRATORY SENSITIZATION.
MAY CAUSE ALLERGIC RESPIRATORY REACTION.
MDI CONCENTRATIONS BELOW THE EXPOSURE GUIDELINES MAY CAUSE ALLERGIC
RESPIRATORY REACTIONS IN INDIVIDUALS ALREADY SENSITIZED.
ASTHMA-LIKE SYMPTOMS MAY INCLUDE COUGHING, DIFFICULT BREATHING AND A
FEELING OF TIGHTNESS IN THE CHEST. OCCASIONALLY, BREATHING DIFFICULTIES
MAY BE LIFE THREATENING.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE):
MAY CAUSE RESPIRATORY IRRITATION.
ROUTE OF EXPOSURE: INHALATION
TARGET ORGANS: RESPIRATORY TRACT
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE):
TISSUE INJURY IN THE UPPER RESPIRATORY TRACT AND LUNGS HAS BEEN OBSERVED
IN LABORATORY ANIMALS AFTER REPEATED EXCESSIVE EXPOSURES TO MDI/POLYMERIC
MDI AEROSOLS.
CARCINOGENICITY:
LUNG TUMORS HAVE BEEN OBSERVED IN LABORATORY ANIMALS EXPOSED TO RESPIRABLE
AEROSOL DROPLETS OF MDI/POLYMERIC MDI (6 MG/M3) FOR THEIR LIFETIME.
TUMORS OCCURRED CONCURRENTLY WITH RESPIRATORY IRRITATION AND LUNG INJURY.
CURRENT EXPOSURE GUIDELINES ARE EXPECTED TO PROTECT AGAINST THESE EFFECTS
REPORTED FOR MDI.
TERATOGENICITY:
HAS BEEN TOXIC TO THE FETUS IN LABORATORY ANIMALS AT DOSES TOXIC TO THE
MOTHER. DID NOT CAUSE BIRTH DEFECTS IN LABORATORY ANIMALS.
REPRODUCTIVE TOXICITY: NO RELEVANT DATA FOUND.
MUTAGENICITY:
GENETIC TOXICITY DATA ON MDI ARE INCONCLUSIVE. MDI WAS WEAKLY
POSITIVE IN SOME IN VITRO STUDIES; OTHER IN VITRO STUDIES WERE
NEGATIVE. ANIMAL MUTAGENICITY STUDIES WERE PREDOMINANTLY NEGATIVE.
ASPIRATION HAZARD:
BASED ON PHYSICAL PROPERTIES, NOT LIKELY TO BE AN ASPIRATION HAZARD.
TRANS-1-CHLORO-3,3,3-TRIFLUOROPROPENE:
ACUTE ORAL TOXICITY: SINGLE DOSE ORAL LD50 HAS NOT BEEN DETERMINED.
ACUTE DERMAL TOXICITY: THE DERMAL LD50 HAS NOT BEEN DETERMINED.
ACUTE INHALATION TOXICITY: LC50, RAT, 4 HOUR, GAS, 120000 PPM
SKIN CORROSION/IRRITATION:
BRIEF CONTACT IS ESSENTIALLY NONIRRITATING TO SKIN.
SERIOUS EYE DAMAGE/EYE IRRITATION: NO RELEVANT DATA FOUND.
SENSITIZATION:
DID NOT CAUSE ALLERGIC SKIN REACTIONS WHEN TESTED IN HUMANS.
FOR RESPIRATORY SENSITIZATION: NO RELEVANT DATA FOUND.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE):
EVALUATION OF AVAILABLE DATA SUGGESTS THAT THIS MATERIAL IS NOT
AN STOT-SE TOXICANT.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE):
BASED ON AVAILABLE DATA, REPEATED EXPOSURES ARE NOT ANTICIPATED TO
CAUSE SIGNIFICANT ADVERSE EFFECTS.
CARCINOGENICITY: NO RELEVANT DATA FOUND.
TERATOGENICITY: NO RELEVANT DATA FOUND.
REPRODUCTIVE TOXICITY: NO RELEVANT DATA FOUND.
MUTAGENICITY:
THIS MATERIAL WAS NOT MUTAGENIC IN AN AMES BACTERIAL ASSAY.
ASPIRATION HAZARD:
BASED ON AVAILABLE INFORMATION, ASPIRATION HAZARD COULD NOT BE
DETERMINED.
CARBON DIOXIDE:
ACUTE ORAL TOXICITY:
SINGLE DOSE ORAL LD50 HAS NOT BEEN DETERMINED.
ACUTE DERMAL TOXICITY:
THE DERMAL LD50 HAS NOT BEEN DETERMINED.
ACUTE INHALATION TOXICITY:
LC50, RAT, 4 HRS, GAS, 58750 PPM
SKIN CORROSION/IRRITATION:
NO HAZARD FROM GAS.
SKIN CONTACT WITH THE SOLID ("DRY ICE") MAY CAUSE FROSTBITE.
LIQUID MAY CAUSE FROSTBITE UPON SKIN CONTACT.
SERIOUS EYE DAMAGE/EYE IRRITATION:
NO HAZARD FROM GAS.
EYE CONTACT WITH THE SOLID ("DRY ICE") MAY CAUSE FREEZE BURNS.
LIQUID MAY CAUSE FROSTBITE.
SENSITIZATION:
NO RELEVANT DATA FOUND.
FOR RESPIRATORY SENSITIZATION:
NO RELEVANT DATA FOUND.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE):
AVAILABLE DATA ARE INADEQUATE TO DETERMINE SINGLE EXPOSURE SPECIFIC
TARGET ORGAN TOXICITY.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE):
EXPERIMENTS WITH HUMANS AND ANIMALS SUGGEST THAT CONTINUED EXPOSURE TO
1.5% CARBON DIOXIDE MAY ALTER PHYSIOLOGICAL PROCESSES, SUCH AS ACID-BASE
AND ELECTROLYTE BALANCE IN THE BLOOD, CALCIUM-PHOSPHORUS METABOLISM, AND
NEUROENDROCRINE ACTIVITY.
CARCINOGENICITY:
AVAILABLE DATA ARE INADEQUATE TO EVALUATE CARCINOGENICITY.
TERATOGENICITY:
AVAILABLE DATA ARE INADEQUATE FOR EVALUATION OF POTENTIAL TO CAUSE BIRTH
DEFECTS.
REPRODUCTIVE TOXICITY:
AVAILABLE DATA ARE INADEQUATE TO DETERMINE EFFECTS ON REPRODUCTION.
MUTAGENICITY: NO RELEVANT DATA FOUND.
ASPIRATION HAZARD:
BASED ON PHYSICAL PROPERTIES, NOT LIKELY TO BE AN ASPIRATION HAZARD.
NITROGEN:
ACUTE ORAL TOXICITY:
SINGLE DOSE ORAL LD50 HAS NOT BEEN DETERMINED.
ACUTE DERMAL TOXICITY:
THE DERMAL LD50 HAS NOT BEEN DETERMINED.
ACUTE INHALATION TOXICITY:
NO ADVERSE EFFECTS ARE ANTICIPATED FROM INHALATION. IN CONFINED OR
POORLY VENTILATED AREAS, VAPOR CAN EASILY ACCUMULATE AND CAN CAUSE
UNCONSCIOUSNESS AND DEATH DUE TO DISPLACEMENT OF OXYGEN.
AS PRODUCT: THE LC50 HAS NOT BEEN DETERMINED.
SKIN CORROSION/IRRITATION:
ESSENTIALLY NONIRRITATING TO SKIN.
LIQUID MAY CAUSE FROSTBITE UPON SKIN CONTACT.
SERIOUS EYE DAMAGE/EYE IRRITATION:
ESSENTIALLY NONIRRITATING TO EYES.
LIQUID MAY CAUSE FROSTBITE.
LIQUID MAY CAUSE SEVERE EYE IRRITATION WITH CORNEAL INJURY.
CORNEAL BURNS MAY OCCUR.
SENSITIZATION:
FOR SKIN SENSITIZATION: NO RELEVANT DATA FOUND.
FOR RESPIRATORY SENSITIZATION: NO RELEVANT DATA FOUND.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE):
NO RELEVANT DATA FOUND.
CARCINOGENICITY: NO RELEVANT DATA FOUND.
TERATOGENICITY: NO RELEVANT DATA FOUND.
REPRODUCTIVE TOXICITY: NO RELEVANT DATA FOUND.
MUTAGENICITY: NO RELEVANT DATA FOUND.
ASPIRATION HAZARD:
BASED ON PHYSICAL PROPERTIES, NOT LIKELY TO BE AN ASPIRATION HAZARD.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION APPEARS IN THIS SECTION WHEN SUCH DATA
IS AVAILABLE.
TOXICITY:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
ACUTE TOXICITY TO FISH:
THE MEASURED ECOTOXICITY IS THAT OF THE HYDROLYZED PRODUCT, GENERALLY
UNDER CONDITIONS MAXIMIZING PRODUCTION OF SOLUBLE SPECIES.
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
LC50, DANIO RERIO (ZEBRA FISH), STATIC TEST, 96 HOUR, >1,000 MG/L, OECD
TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 24 HOUR, >1,000 MG/L, OECD
TEST GUIDELINE 202 OR EQUIVALENT
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
NOEC, DESMODESMUS SUBSPICATUS (GREEN ALGAE), STATIC TEST, 72 HOUR,
GROWTH RATE INHIBITION, 1,640 MG/L, OECD TEST GUIDELINE 201 OR
EQUIVALENT
TOXICITY TO BACTERIA:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, ACTIVATED SLUDGE, STATIC TEST, 3 HOUR, RESPIRATION RATES.,
>100 MG/L
TOXICITY TO SOIL-DWELLING ORGANISMS:
EC50, EISENIA FETIDA (EARTHWORMS), BASED ON INFORMATION FOR A SIMILAR
MATERIAL:, 14 D, >1,000 MG/KG
TOXICITY TO TERRESTRIAL PLANTS:
EC50, AVENA SATIVA (OATS), GROWTH INHIBITION, 1,000 MG/L
EC50, LACTUCA SATIVA (LETTUCE), GROWTH INHIBITION, 1,000 MG/L
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
ACUTE TOXICITY TO FISH:
THE MEASURED ECOTOXICITY IS THAT OF THE HYDROLYZED PRODUCT, GENERALLY
UNDER CONDITIONS MAXIMIZING PRODUCTION OF SOLUBLE SPECIES.
MATERIAL IS PRACTICALLY NON-TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50/EL50/LL50 >100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
LC50, DANIO RERIO (ZEBRA FISH), STATIC TEST, 96 HOUR, >1,000 MG/L, OECD
TEST GUIDELINE 203 OR EQUIVALENT
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, DAPHNIA MAGNA (WATER FLEA), STATIC TEST, 24 HOUR, >1,000 MG/L, OECD
TEST GUIDELINE 202 OR EQUIVALENT
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
NOEC, DESMODESMUS SUBSPICATUS (GREEN ALGAE), STATIC TEST, 72 HOUR, GROWTH
RATE INHIBITION, 1,640 MG/L, OECD TEST GUIDELINE 201 OR EQUIVALENT
TOXICITY TO BACTERIA:
BASED ON INFORMATION FOR A SIMILAR MATERIAL:
EC50, ACTIVATED SLUDGE, STATIC TEST, 3 HOUR, RESPIRATION RATES., >100 MG/L
TOXICITY TO SOIL-DWELLING ORGANISMS:
EC50, EISENIA FETIDA (EARTHWORMS), BASED ON INFORMATION FOR A SIMILAR
MATERIAL: 14 D, >1,000 MG/KG
TOXICITY TO TERRESTRIAL PLANTS:
EC50, AVENA SATIVA (OATS), GROWTH INHIBITION, 1,000 MG/L
EC50, LACTUCA SATIVA (LETTUCE), GROWTH INHIBITION, 1,000 MG/L
TRANS-1-CHLORO-3,3,3-TRIFLUOROPROPENE:
ACUTE TOXICITY TO FISH:
MATERIAL IS SLIGHTLY TOXIC TO AQUATIC ORGANISMS ON AN ACUTE BASIS
(LC50/EC50 BETWEEN 10 AND 100 MG/L IN THE MOST SENSITIVE SPECIES TESTED).
LC50, ONCORHYNCHUS MYKISS (RAINBOW TROUT), STATIC, 96 HOUR, 38 MG/L,
OECD TEST GUIDELINE 203
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
EC50, DAPHNIA MAGNA, 48 HOUR, 82 MG/L, OECD TEST GUIDELINE 202
ACUTE TOXICITY TO ALGAE/AQUATIC PLANTS:
EC50, PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE), 72 HOUR, GROWTH
INHIBITION, 106.7 MG/L
NOEC, PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE), 72 HOUR, GROWTH
RATE, 115 MG/L
CARBON DIOXIDE:
ACUTE TOXICITY TO FISH:
MAY DECREASE PH OF AQUATIC SYSTEMS TO <PH 5 WHICH MAY BE TOXIC TO AQUATIC
ORGANISMS.
LC0, ONCORHYNCHUS MYKISS (RAINBOW TROUT), 1 HOUR, 240 MG/L, METHOD NOT
SPECIFIED.
ACUTE TOXICITY TO AQUATIC INVERTEBRATES:
BASED ON DATA FROM SIMILAR MATERIALS
NOEC, DAPHNIA MAGNA (WATER FLEA), 48 HOUR, >100 MG/L
NITROGEN:
ACUTE TOXICITY TO FISH:
NOT EXPECTED TO BE ACUTELY TOXIC TO AQUATIC ORGANISMS.
PERSISTENCE AND DEGRADABILITY:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
BIODEGRADABILITY:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MATERIAL REACTS WITH
WATER FORMING PREDOMINANTLY INSOLUBLE POLYUREAS WHICH APPEAR TO BE
STABLE. IN THE ATMOSPHERIC ENVIRONMENT, MATERIAL IS EXPECTED TO HAVE
A SHORT TROPOSPHERIC HALF-LIFE, BASED ON CALCULATIONS AND BY ANALOGY
WITH RELATED DIISOCYANATES.
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: 0 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 302C OR EQUIVALENT
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
BIODEGRADABILITY:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MATERIAL REACTS WITH WATER
FORMING PREDOMINANTLY INSOLUBLE POLYUREAS WHICH APPEAR TO BE STABLE. IN
THE ATMOSPHERIC ENVIRONMENT, MATERIAL IS EXPECTED TO HAVE A SHORT
TROPOSPHERIC HALF-LIFE, BASED ON CALCULATIONS AND BY ANALOGY WITH RELATED
DIISOCYANATES.
10-DAY WINDOW: NOT APPLICABLE
BIODEGRADATION: 0 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 302C OR EQUIVALENT
TRANS-1-CHLORO-3,3,3-TRIFLUOROPROPENE:
BIODEGRADABILITY:
MATERIAL IS NOT READILY BIODEGRADABLE ACCORDING TO OECD/EEC GUIDELINES
BIODEGRADATION: 0 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301D
CARBON DIOXIDE:
BIODEGRADABILITY: BIODEGRADATION IS NOT APPLICABLE.
NITROGEN:
BIODEGRADABILITY:
BIODEGRADATION IS NOT APPLICABLE. MAY DECREASE THE DISSOLVED OXYGEN
(DO) CONTENT OF NATURAL WATERS.
BIOACCUMULATIVE POTENTIAL:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3). REACTS WITH
WATER. IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED
TO BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
BIOCONCENTRATION FACTOR (BCF): 92 CYPRINUS CARPIO (CARP) 28 D
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3). REACTS WITH
WATER. IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED
TO BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
BIOCONCENTRATION FACTOR (BCF): 92 CYPRINUS CARPIO (CARP) 28 D
TRANS-1-CHLORO-3,3,3-TRIFLUOROPROPENE:
BIOACCUMULATION: NO RELEVANT DATA FOUND.
CARBON DIOXIDE:
BIOACCUMULATION:
BIOCONCENTRATION POTENTIAL IS LOW (BCF <100 OR LOG POW <3).
PARTITION COEFFICIENT N-OCTANOL/WATER(LOG POW): 0.83 MEASURED
NITROGEN:
BIOACCUMULATION:
PARTITIONING FROM WATER TO N-OCTANOL IS NOT APPLICABLE.
MOBILITY IN SOIL:
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND HOMOLOGUES:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED TO
BE LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
4,4' -METHYLENEDIPHENYL DIISOCYANATE:
IN THE AQUATIC AND TERRESTRIAL ENVIRONMENT, MOVEMENT IS EXPECTED TO BE
LIMITED BY ITS REACTION WITH WATER FORMING PREDOMINANTLY INSOLUBLE
POLYUREAS.
TRANS-1-CHLORO-3,3,3-TRIFLUOROPROPENE: NO RELEVANT DATA FOUND.
CARBON DIOXIDE: NO RELEVANT DATA FOUND.
NITROGEN: NO DATA AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER.
ALL DISPOSAL PRACTICES MUST BE IN COMPLIANCE WITH ALL FEDERAL, STATE/
PROVINCIAL AND LOCAL LAWS AND REGULATIONS. REGULATIONS MAY VARY IN
DIFFERENT LOCATIONS. WASTE CHARACTERIZATIONS AND COMPLIANCE WITH
APPLICABLE LAWS ARE THE RESPONSIBILITY SOLELY OF THE WASTE GENERATOR.
AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL.
THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED
IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: COMPOSITION
INFORMATION.
FOR UNUSED & UNCONTAMINATED PRODUCT, THE PREFERRED OPTIONS INCLUDE
SENDING TO A LICENSED, PERMITTED:
RECYCLER. RECLAIMER.
INCINERATOR OR OTHER THERMAL DESTRUCTION DEVICE. FOR ADDITIONAL
INFORMATION, REFER TO:
HANDLING & STORAGE INFORMATION, MSDS SECTION 7 STABILITY & REACTIVITY
INFORMATION, MSDS SECTION10 REGULATORY INFORMATION, MSDS SECTION 15
| 14. TRANSPORT INFORMATION | |
DOT:
PROPER SHIPPING NAME:
CHEMICAL UNDER PRESSURE, N.O.S.(CARBON DIOXIDE, NITROGEN)
UN NUMBER: UN 3500
CLASS: 2.2
PACKING GROUP:
REPORTABLE QUANTITY: MDI
CLASSIFICATION FOR SEA TRANSPORT (IMO-IMDG):
PROPER SHIPPING NAME:
CHEMICAL UNDER PRESSURE, N.O.S.(CARBON DIOXIDE, NITROGEN)
UN NUMBER: UN 3500
CLASS: 2.2
PACKING GROUP:
MARINE POLLUTANT: NO
TRANSPORT IN BULK ACCORDING TO ANNEX I OR II OF MARPOL 73/78 AND THE IBC
OR IGC CODE:
CONSULT IMO REGULATIONS BEFORE TRANSPORTING OCEAN BULK
CLASSIFICATION FOR AIR TRANSPORT (IATA/ICAO):
PROPER SHIPPING NAME:
CHEMICAL UNDER PRESSURE, N.O.S.(CARBON DIOXIDE, NITROGEN)
UN NUMBER: UN 3500
CLASS: 2.2
PACKING GROUP:
THIS INFORMATION IS NOT INTENDED TO CONVEY ALL SPECIFIC REGULATORY OR
OPERATIONAL REQUIREMENTS/INFORMATION RELATING TO THIS PRODUCT.
TRANSPORTATION CLASSIFICATIONS MAY VARY BY CONTAINER VOLUME AND MAY
BE INFLUENCED BY REGIONAL OR COUNTRY VARIATIONS IN REGULATIONS.
ADDITIONAL TRANSPORTATION SYSTEM INFORMATION CAN BE OBTAINED THROUGH
AN AUTHORIZED SALES OR CUSTOMER SERVICE REPRESENTATIVE. IT IS THE
RESPONSIBILITY OF THE TRANSPORTING ORGANIZATION TO FOLLOW ALL
APPLICABLE LAWS, REGULATIONS AND RULES RELATING TO THE TRANSPORTATION
OF THE MATERIAL.
| 15. REGULATORY INFORMATION | |
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III
(EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986)
SECTIONS 311 AND 312
GASES UNDER PRESSURE
SIMPLE ASPHYXIANT
ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
SKIN CORROSION OR IRRITATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
RESPIRATORY OR SKIN SENSITISATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III
(EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986)
SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES WHICH ARE SUBJECT
TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND WHICH ARE
LISTED IN 40 CFR 372.
COMPONENTS CASRN
DIPHENYLMETHANE DIISOCYANATE, ISOMERS AND 9016-87-9
HOMOLOGUES
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY
ACT OF 1980 (CERCLA) SECTION 103:
CALCULATED RQ EXCEEDS REASONABLY ATTAINABLE UPPER LIMIT.
COMPONENTS CASRN RQ (RCRA CODE)
4,4' -METHYLENEDIPHENYL DIISOCYANATE 101-68-8 5000 LBS RQ
PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
THE FOLLOWING CHEMICALS ARE LISTED BECAUSE OF THE ADDITIONAL
REQUIREMENTS OF PENNSYLVANIA LAW:
COMPONENTS CASRN
CARBON DIOXIDE 124-38-9
CALIFORNIA PROP. 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS, OR ANY OTHER REPRODUCTIVE
HARM.
UNITED STATES TSCA INVENTORY (TSCA):
ALL COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE INVENTORY
LISTING REQUIREMENTS OF THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA)
CHEMICAL SUBSTANCE INVENTORY.
| 16. OTHER INFORMATION | |
HAZARD RATING SYSTEM:
HMIS:
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 3
* = CHRONIC EFFECTS (SEE HAZARDS IDENTIFICATION)
REVISION:
IDENTIFICATION NUMBER:
12083862 / A749 / ISSUE DATE: 02/16/2022 / VERSION: 1.0
MOST RECENT REVISION(S) ARE NOTED BY THE BOLD, DOUBLE BARS IN LEFT-HAND
MARGIN THROUGHOUT THIS DOCUMENT.
LEGEND:
ACGIH: USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
C: CEILING LIMIT
CAL PEL:
CALIFORNIA PERMISSIBLE EXPOSURE LIMITS FOR CHEMICAL CONTAMINANTS
(TITLE 8, ARTICLE 107)
DOW IHG: DOW INDUSTRIAL HYGIENE GUIDELINE
OSHA P0:
USA. TABLE Z-1-A LIMITS FOR AIR CONTAMINANTS (1989 VACATED VALUES)
OSHA Z-1:
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z-1 LIMITS FOR AIR
CONTAMINANTS
PEL: PERMISSIBLE EXPOSURE LIMIT
STEL: SHORT-TERM EXPOSURE LIMIT
TWA: 8-HR TWA
US WEEL: USA. WORKPLACE ENVIRONMENTAL EXPOSURE LEVELS (WEEL)
FULL TEXT OF OTHER ABBREVIATIONS:
AIIC: AUSTRALIAN INVENTORY OF INDUSTRIAL CHEMICALS;
ASTM: AMERICAN SOCIETY FOR THE TESTING OF MATERIALS;
BW: BODY WEIGHT;
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY
ACT;
CMR: CARCINOGEN, MUTAGEN OR REPRODUCTIVE TOXICANT;
DIN: STANDARD OF THE GERMAN INSTITUTE FOR STANDARDISATION;
DOT: DEPARTMENT OF TRANSPORTATION;
DSL: DOMESTIC SUBSTANCES LIST (CANADA);
ECX: CONCENTRATION ASSOCIATED WITH X% RESPONSE;
EHS: EXTREMELY HAZARDOUS SUBSTANCE;
ELX: LOADING RATE ASSOCIATED WITH X% RESPONSE;
EMS: EMERGENCY SCHEDULE;
ENCS: EXISTING AND NEW CHEMICAL SUBSTANCES (JAPAN);
ERCX: CONCENTRATION ASSOCIATED WITH X% GROWTH RATE RESPONSE;
ERG: EMERGENCY RESPONSE GUIDE;
GHS: GLOBALLY HARMONIZED SYSTEM;
GLP: GOOD LABORATORY PRACTICE;
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM;
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER;
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION;
IBC:
INTERNATIONAL CODE FOR THE CONSTRUCTION AND EQUIPMENT OF SHIPS
CARRYING DANGEROUS CHEMICALS IN BULK;
IC50: HALF MAXIMAL INHIBITORY CONCENTRATION;
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION;
IECSC: INVENTORY OF EXISTING CHEMICAL SUBSTANCES IN CHINA;
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS;
IMO: INTERNATIONAL MARITIME ORGANIZATION;
ISHL: INDUSTRIAL SAFETY AND HEALTH LAW (JAPAN);
ISO: INTERNATIONAL ORGANISATION FOR STANDARDIZATION;
KECI: KOREA EXISTING CHEMICALS INVENTORY;
LC50: LETHAL CONCENTRATION TO 50 % OF A TEST POPULATION;
LD50: LETHAL DOSE TO 50% OF A TEST POPULATION (MEDIAN LETHAL DOSE);
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS;
MSHA: MINE SAFETY AND HEALTH ADMINISTRATION;
N.O.S.: NOT OTHERWISE SPECIFIED;
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION;
NO(A)EC: NO OBSERVED (ADVERSE) EFFECT CONCENTRATION;
NO(A)EL: NO OBSERVED (ADVERSE) EFFECT LEVEL;
NOELR: NO OBSERVABLE EFFECT LOADING RATE;
NTP: NATIONAL TOXICOLOGY PROGRAM;
NZIOC: NEW ZEALAND INVENTORY OF CHEMICALS;
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT;
OPPTS: OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION;
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC SUBSTANCE;
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES;
(Q)SAR: (QUANTITATIVE) STRUCTURE ACTIVITY RELATIONSHIP;
RCRA: RESOURCE CONSERVATION AND RECOVERY ACT;
REACH:
REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL CONCERNING THE REGISTRATION, EVALUATION, AUTHORISATION AND
RESTRICTION OF CHEMICALS;
RQ: REPORTABLE QUANTITY;
SADT: SELF-ACCELERATING DECOMPOSITION TEMPERATURE;
SARA: SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT;
SDS: SAFETY DATA SHEET;
TCSI: TAIWAN CHEMICAL SUBSTANCE INVENTORY;
TECI: THAILAND EXISTING CHEMICALS INVENTORY;
TSCA: TOXIC SUBSTANCES CONTROL ACT (UNITED STATES);
UN: UNITED NATIONS;
UNRTDG:
UNITED NATIONS RECOMMENDATIONS ON THE TRANSPORT OF DANGEROUS GOODS;
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
INFORMATION SOURCE AND REFERENCES:
THIS SDS IS PREPARED BY PRODUCT REGULATORY SERVICES AND HAZARD
COMMUNICATIONS GROUPS FROM INFORMATION SUPPLIED BY INTERNAL
REFERENCES WITHIN OUR COMPANY.
DDP SPECIALTY ELECTRONIC MATERIALS US, LLC URGES EACH CUSTOMER OR
RECIPIENT OF THIS (M)SDS TO STUDY IT CAREFULLY AND CONSULT APPROPRIATE
EXPERTISE, AS NECESSARY OR APPROPRIATE, TO BECOME AWARE OF AND
UNDERSTAND THE DATA CONTAINED IN THIS (M)SDS AND ANY HAZARDS ASSOCIATED
WITH THE PRODUCT. THE INFORMATION HEREIN IS PROVIDED IN GOOD FAITH AND
BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE DATE SHOWN ABOVE. HOWEVER,
NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. REGULATORY REQUIREMENTS ARE
SUBJECT TO CHANGE AND MAY DIFFER BETWEEN VARIOUS LOCATIONS. IT IS THE
BUYER'S/USER'S RESPONSIBILITY TO ENSURE THAT HIS ACTIVITIES COMPLY WITH
ALL FEDERAL, STATE, PROVINCIAL OR LOCAL LAWS. THE INFORMATION PRESENTED
HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED. SINCE CONDITIONS FOR USE
OF THE PRODUCT ARE NOT UNDER THE CONTROL OF THE MANUFACTURER, IT IS THE
BUYER'S/USER'S DUTY TO DETERMINE THE CONDITIONS NECESSARY FOR THE SAFE
USE OF THIS PRODUCT. DUE TO THE PROLIFERATION OF SOURCES FOR
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