| Common Name: | PEAK READYUSE 50/50 PREDILUTED ANTIFREEZE & COOLANT |
| Manufacturer: | OLD WORLD INDUSTRIES |
| SDS Revision Date: | 10/14/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 48ZE68 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
PEAK READYUSE 50/50 PREDILUTED ANTIFREEZE & COOLANT
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
PRODUCT NAME: PEAK READYUSE 50/50 PREDILUTED ANTIFREEZE & COOLANT
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: ANTIFREEZE & COOLANT
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
OLD WORLD INDUSTRIES, LLC
4065 COMMERCIAL AVE.
NORTHBROOK, IL 60062
USA
T: (847) 559-2000
WWW.OLDWORLDIND.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER: (800) 424-9300; (703) 527 3887 (INTERNATIONAL) CHEMTREC
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
ACUTE TOX. 4 (ORAL): H302
STOT RE 2: H373
FULL TEXT OF H-STATEMENTS: SEE SECTION 16
2.2. LABEL ELEMENTS:
GHS-US LABELLING:
HAZARD PICTOGRAMS (GHS-US):
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): WARNING
HAZARD STATEMENTS (GHS-US):
H302: HARMFUL IF SWALLOWED
H373:
MAY CAUSE DAMAGE TO ORGANS (KIDNEYS) THROUGH PROLONGED OR REPEATED EXPOSURE
(ORAL)
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P260: DO NOT BREATHE MIST, SPRAY, VAPORS
P264: WASH AFFECTED AREAS THOROUGHLY AFTER HANDLING
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
P280: WEAR PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED
P301+P310:
IF SWALLOWED: IMMEDIATELY CALL DOCTOR/PHYSICIAN OR POISON CENTER
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER, IN A SAFE MANNER, TO APPROPRIATE WASTE
DISPOSAL FACILITY, IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL
REGULATIONS
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % BY WT GHS-US CLASSIFICATION
ETHYLENE GLYCOL (CAS NO): 107-21-1 <=50 ACUTE TOX. 4 (ORAL), H302
WATER (CAS NO): 7732-18-5 <50 NOT CLASSIFIED
DIETHYLENE (CAS NO): 111-46-6 <3 ACUTE TOX. 4 (ORAL), H302
GLYCOL STOT RE 2, H373
DENATONIUM (CAS NO): 3734-33-6 30 - 50 ACUTE TOX. 4 (ORAL), H302
BENZOATE PPM SKIN IRRIT. 2, H315
EYE IRRIT. 2A, H319
STOT SE 3, H335
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
IF BREATHING IS DIFFICULT, REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A
POSITION COMFORTABLE FOR BREATHING. SEEK IMMEDIATE MEDICAL ADVICE. ALLOW
THE VICTIM TO REST. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. WASH WITH PLENTY OF SOAP AND WATER. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
IF SKIN IRRITATION OCCURS:
RINSE IMMEDIATELY WITH PLENTY OF WATER (FOR AT LEAST 15 MINUTES). GET
MEDICAL ADVICE/ATTENTION. SPECIFIC TREATMENT (SEE SUPPLEMENTAL FIRST AID
INSTRUCTIONS ON THIS LABEL).
FIRST-AID MEASURES AFTER EYE CONTACT:
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. RINSE
IMMEDIATELY WITH PLENTY OF WATER FOR 15 MINUTES, LIFTING LOWER AND UPPER
LIDS.
IF EYE IRRITATION PERSISTS:
RINSE IMMEDIATELY WITH PLENTY OF WATER. GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER INGESTION:
OBTAIN EMERGENCY MEDICAL ATTENTION. RINSE MOUTH. DO NOT INDUCE VOMITING. IF
THE PERSON IS FULLY CONSCIOUS, MAKE HIM/HER DRINK TWO GLASSES OF WATER.
NEVER GIVE AN UNCONSCIOUS PERSON ANYTHING TO DRINK. CALL A POISON CENTER
OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL. IF MEDICAL ADVICE IS DELAYED, AND
IF THE PERSON HAS SWALLOWED A MODERATE VOLUME OF MATERIAL (A FEW OUNCES),
THEN GIVE THREE TO FOUR OUNCES OF HARD LIQUOR, SUCH AS WHISKEY. FOR
CHILDREN, GIVE PROPORTIONALLY LESS LIQUOR, ACCORDING TO WEIGHT.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES: CAUSES DAMAGE TO ORGANS (KIDNEYS) ORAL.
SYMPTOMS/INJURIES AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS/INJURIES AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH
HAZARD. THE LETHAL DOSE IN HUMANS IS ESTIMATED TO BE 100 ML (3 OZ).
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
A MORE EFFECTIVE INTRAVENOUS ANTIDOTE FOR PHYSICIAN USES IS
4-METHYLPYRAZAOLE, A POTENT INHIBITOR OF ALCOHOL DEHYDROGENASES, WHICH
EFFECTIVELY BLOCKS THE FORMATION OF TOXIC METABOLITES OF ETHYLENE GLYCOL.
IT HAS BEEN USED TO DECREASE THE METABOLIC CONSEQUENCES OF ETHYLENE GLYCOL
POISONING BEFORE METABOLIC ACIDOSIS COMA, SEIZURES, AND RENAL FAILURE HAVE
OCCURED.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FINE WATER SPRAY. ALCOHOL-RESISTANT FOAM. FOAM. CARBON DIOXIDE. DRY
CHEMICAL POWDER. SAND. DRY POWDER. WATER FOG.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A HEAVY WATER STREAM. MAY SPREAD FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD:
DURING A FIRE, SMOKE MAY CONTAIN THE ORIGINAL MATERIAL IN ADDITION TO
COMBUSTION PRODUCTS OF VARYING COMPOSITION WHICH MAY BE TOXIC AND/OR
IRRITATING.
COMBUSTION PRODUCTS MAY INCLUDE AND ARE NOT LIMITED TO:
CARBON MONOXIDE. CARBON DIOXIDE.
REACTIVITY: NO DANGEROUS REACTIONS KNOWN UNDER NORMAL CONDITIONS OF USE.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS:
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA).
PROTECTIVE FIRE FIGHTING CLOTHING (INCLUDES FIRE-FIGHTING HELMET, COAT,
PANTS, BOOTS AND GLOVES).
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. REFER TO SECTION 8.2.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH AFFECTED AREAS
THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM: HEAT SOURCES.
KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT STORE NEAR FOOD, FOODSTUFFS,
DRUGS OR POTABLE WATER SUPPLIES. DO NOT CUT, DRILL, WELD, USE A BLOWTORCH
ON, ETC. CONTAINERS EVEN WHEN EMPTY. PRODUCT MAY BECOME SOLID AT
TEMPERATURES BELOW -37 DEG. C (-34 DEG. F).
INCOMPATIBLE PRODUCTS:
KEEP AWAY FROM STRONG ACIDS, STRONG BASES AND OXIDIZING AGENTS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION.
7.3. SPECIFIC END USE(S): NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
ETHYLENE GLYCOL (107-21-1):
ACGIH:
ACGIH TWA (MG/M3): 10 MG/M3
ACGIH:
REMARK (ACGIH): UPPER RESPIRATORY TRACT (URT) & EYE IRRITANT
OSHA: NOT APPLICABLE
8.2. EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
AVOID ALL UNNECESSARY EXPOSURE. GLOVES. SAFETY GLASSES.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES.
RESPIRATORY PROTECTION:
IF EXPOSED TO LEVELS ABOVE EXPOSURE LIMITS WEAR APPROPRIATE RESPIRATORY
PROTECTION.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
COLOR: GREEN
ODOR: MILD
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 10.5 - 11
RELATIVE EVAPORATION RATE (BUTYLACETATE=1): NIL
FREEZING POINT: -37 DEG. C (-34 DEG. F)
BOILING POINT: 107 DEG. C (224 DEG. F)
FLASH POINT: 116 DEG. C (241 DEG. F) [100% ETHYLENE GLYCOL] ASTM D56
AUTO-IGNITION TEMPERATURE:
400 DEG. C (752 DEG. F) [100% ETHYLENE GLYCOL] LITERATURE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOR PRESSURE: <0.1 MMHg @ 20 DEG. C
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
SPECIFIC GRAVITY: 1.07
DENSITY: 1.07 KG/L (8.9 LBS/GAL)
SOLUBILITY:
WATER: COMPLETE
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NOT APPLICABLE.
OXIDIZING PROPERTIES: NOT APPLICABLE.
EXPLOSIVE LIMITS: NOT APPLICABLE.
9.2. OTHER INFORMATION:
VOC CONTENT: 0.00%
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
NO DANGEROUS REACTIONS KNOWN UNDER NORMAL CONDITIONS OF USE.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
EXTREMELY HIGH OR LOW TEMPERATURES. KEEP AWAY FROM ANY FLAMES OR SPARKING
SOURCE.
10.5. INCOMPATIBLE MATERIALS:
KEEP AWAY FROM STRONG ACIDS, STRONG BASES AND OXIDIZING AGENTS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON DIOXIDE. CARBON MONOXIDE. FUME. ALCOHOLS. ALDEHYDES. ETHERS.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
ORAL: HARMFUL IF SWALLOWED.
DENATONIUM BENZOATE (3734-33-6):
LD50 ORAL RAT: 584.00 MG/KG (RAT; LITERATURE STUDY)
LD50 DERMAL RABBIT: >2,000.00 MG/KG (RABBIT; LITERATURE STUDY)
ATE US (ORAL): 584.00 MG/KG BODYWEIGHT
ETHYLENE GLYCOL (107-21-1):
LD50 ORAL RAT: >5,000.00 MG/KG (RAT; LITERATURE STUDY)
ATE US (ORAL): 500.00 MG/KG BODYWEIGHT
DIETHYLENE GLYCOL (111-46-6):
LD50 DERMAL RABBIT: 11,890.00 MG/KG (RABBIT)
ATE US (ORAL): 500.00 MG/KG BODYWEIGHT
ATE US (DERMAL): 11,890.00 MG/KG BODYWEIGHT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: 10.5 - 11
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: 10.5 - 11
RESPIRATORY OR SKIN SENSITISATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
MAY CAUSE DAMAGE TO ORGANS (KIDNEYS) THROUGH PROLONGED OR REPEATED EXPOSURE
(ORAL).
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET. HARMFUL
IF SWALLOWED.
SYMPTOMS/INJURIES AFTER SKIN CONTACT: CAUSES SKIN IRRITATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS/INJURIES AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH
HAZARD. THE LETHAL DOSE IN HUMANS IS ESTIMATED TO BE 100 ML (3 OZ).
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
DENATONIUM BENZOATE (3734-33-6):
LC50 FISH 1: >1,000.00 MG/L (LC50; 96 H; SALMO GAIRDNERI)
EC50 DAPHNIA 1: 13.00 MG/L (EC50; 48 H; DAPHNIA MAGNA)
ETHYLENE GLYCOL (107-21-1):
EC50 DAPHNIA 1: >10,000.00 MG/L (EC50; 24 H)
LC50 FISH 2: 40,761.00 MG/L (LC50; 96 H; SALMO GAIRDNERI)
DIETHYLENE GLYCOL (111-46-6):
LC50 FISH 1: >5,000.00 PPM (LC50; 24 H)
EC50 DAPHNIA 1: >10,000.00 MG/L (EC50; 24 H)
12.2. PERSISTENCE AND DEGRADABILITY:
DENATONIUM BENZOATE (3734-33-6):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY IN WATER:
NO DATA AVAILABLE. NO (TEST) DATA ON MOBILITY OF THE SUBSTANCE AVAILABLE.
ETHYLENE GLYCOL (107-21-1):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.47 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.24 G O2/G SUBSTANCE
THOD: 1.29 G O2/G SUBSTANCE
BOD (% OF THOD): 0.36
DIETHYLENE GLYCOL (111-46-6):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. HIGHLY MOBILE IN
SOIL. PHOTOLYSIS IN THE AIR.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.02 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.51 G O2/G SUBSTANCE
THOD: 1.51 G O2/G SUBSTANCE
BOD (% OF THOD): 0.02
12.3. BIOACCUMULATIVE POTENTIAL:
DENATONIUM BENZOATE (3734-33-6):
BCF FISH 1: 1.4 - 3.6 (BCF; BCFBAF V3.00)
LOG POW: 1.78 (ESTIMATED VALUE)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
ETHYLENE GLYCOL (107-21-1):
BCF FISH 1: 10.00 (BCF; 72 H)
BCF OTHER AQUATIC ORGANISMS 1: 0.21 - 0.6 (BCF)
BCF OTHER AQUATIC ORGANISMS 2: 190.00 (BCF; 24 H)
LOG POW: -1.34 (EXPERIMENTAL VALUE)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
DIETHYLENE GLYCOL (111-46-6):
BCF FISH 1:
100.00 (BCF; OTHER; 3 DAYS; LEUCISCUS MELANOTUS; STATIC SYSTEM; FRESH
WATER; EXPERIMENTAL VALUE)
LOG POW: -1.98 (CALCULATED; OTHER)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
12.4. MOBILITY IN SOIL:
ETHYLENE GLYCOL (107-21-1):
SURFACE TENSION: 0.05 N/M (20 DEG. C / 68 DEG. F)
DIETHYLENE GLYCOL (111-46-6):
SURFACE TENSION: 0.05 N/M
LOG KOC:
KOC,SRC PCKOCWIN V1.66; 1; CALCULATED VALUE; LOG KOC; SRC PCKOCWIN V1.66;
0; CALCULATED VALUE
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON OZONE LAYER: NO KNOWN EFFECT ON THE OZONE LAYER
EFFECT ON GLOBAL WARMING:
NO KNOWN ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE OF CONTENTS/CONTAINER, IN A SAFE MANNER, TO APPROPRIATE WASTE
DISPOSAL FACILITY, IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL
REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION:
UN3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S., 9, III
UN-NO. (DOT): UN3082
PROPER SHIPPING NAME (DOT):
ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S.
TRANSPORT HAZARD CLASS(ES) (DOT):
9 - CLASS 9 - MISCELLANEOUS HAZARDOUS MATERIAL 49 CFR 173.140
HAZARD LABELS (DOT): 9 - CLASS 9 (MISCELLANEOUS DANGEROUS MATERIALS)
CLASS 9, CLASS/DIVISION 9
PACKING GROUP III
PACKING GROUP (DOT): III - MINOR DANGER
DOT PACKAGING NON BULK (49 CFR 173.XXX): 203
DOT PACKAGING BULK (49 CFR 173.XXX): 241
DOT SYMBOLS: G - IDENTIFIES PSN REQUIRING A TECHNICAL NAME
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 155
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): NO LIMIT
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): NO LIMIT
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
OTHER INFORMATION:
NON BULK:
NOT REGULATED BY THE US D.O.T. (IN QUANTITIES UNDER 5,000 LBS IN ANY ONE
INNER PACKAGE).
TDG: REFER TO CURRENT TDG CANADA FOR FURTHER CANADIAN REGULATIONS
TRANSPORT BY SEA:
PROPER SHIPPING NAME (IMDG):
NOT REGULATED BY IMDG (IN QUANTITIES UNDER 5,000 LBS IN ANY ONE INNER
PACKAGE)
AIR TRANSPORT:
PROPER SHIPPING NAME (IATA):
NOT REGULATED BY IATA (IN QUANTITIES UNDER 5,000 LBS IN ANY ONE INNER
PACKAGE)
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
PEAK READYUSE 50/50 PREDILUTED ANTIFREEZE & COOLANT:
EPA TSCA REGULATORY FLAG:
TOXIC SUBSTANCES CONTROL ACT (TSCA):
THE INTENTIONAL INGREDIENTS OF THIS PRODUCT ARE LISTED
DENATONIUM BENZOATE (3734-33-6):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
ETHYLENE GLYCOL (107-21-1):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
EPA TSCA REGULATORY FLAG:
T - T - INDICATES A SUBSTANCE THAT IS THE SUBJECT OF A SECTION 4 TEST RULE
UNDER TSCA.
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB(S)
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
ETHYLENE GLYCOL IS SUBJECT TO TIER I AND/OR TIER II ANNUAL INVENTORY
REPORTING.
SARA SECTION 313 - EMISSION REPORTING:
ETHYLENE GLYCOL IS SUBJECT TO FORM R REPORTING REQUIREMENTS.
DIETHYLENE GLYCOL (111-46-6):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
WHMIS CLASSIFICATION:
CLASS D DIVISION 2 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]:
NO ADDITIONAL INFORMATION AVAILABLE
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC [DSD] OR 1999/45/EC [DPD]:
NOT CLASSIFIED
NATIONAL REGULATIONS:
PEAK READYUSE 50/50 PREDILUTED ANTIFREEZE & COOLANT:
DSL (CANADA): THE INTENTIONAL INGREDIENTS OF THIS PRODUCT ARE LISTED
ECL (SOUTH KOREA): THE INTENTIONAL INGREDIENTS OF THIS PRODUCT ARE LISTED.
EINECS (EUROPE): THE INTENTIONAL INGREDIENTS OF THIS PRODUCT ARE LISTED
ENCS (JAPAN): THE INTENTIONAL INGREDIENTS OF THIS PRODUCT ARE LISTED
15.3. US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS, OR MAY CONTAIN, SUBSTANCE(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, DEVELOPMENTAL TOXICITY AND/OR REPRODUCTIVE
TOXICITY
ETHYLENE GLYCOL (107-21-1):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NON-SIGNIFICANT RISK LEVEL (NSRL):
ETHYLENE GLYCOL (107-21-1):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
DIETHYLENE GLYCOL (111-46-6):
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
| SECTION 16: OTHER INFORMATION | |
FULL TEXT OF H-STATEMENTS:
ACUTE TOX. 4 (ORAL): ACUTE TOXICITY (ORAL), CATEGORY 4
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION, CATEGORY 2A
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION, CATEGORY 2
STOT RE 2: SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, CATEGORY 2
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, CATEGORY 3, RESPIRATORY
TRACT IRRITATION
H302: HARMFUL IF SWALLOWED
H315: CAUSES SKIN IRRITATION
H319: CAUSES SERIOUS EYE IRRITATION
H335: MAY CAUSE RESPIRATORY IRRITATION
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
NFPA HEALTH HAZARD 1 - EXPOSURE COULD CAUSE IRRITATION BUT ONLY MINOR
RESIDUAL INJURY EVEN IF NO TREATMENT IS GIVEN.
NFPA FIRE HAZARD 1 - MUST BE PREHEATED BEFORE IGNITION CAN OCCUR.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND ARE NOT REACTIVE WITH WATER.
HMIS III RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY 1 SLIGHT HAZARD - MATERIALS THAT MUST BE PREHEATED
BEFORE IGNITION WILL OCCUR. INCLUDES LIQUIDS, SOLIDS
AND SEMI SOLIDS HAVING A FLASH POINT ABOVE 200 DEG. F
(93 DEG. C). (CLASS IIIB)
PHYSICAL 0 MINIMAL HAZARD - MATERIALS THAT ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS, AND WILL NOT REACT WITH
WATER, POLYMERIZE, DECOMPOSE, CONDENSE, OR
SELF-REACT. NON-EXPLOSIVES.
PERSONAL PROTECTION B - SAFETY GLASSES, GLOVES
SDS GHS US (GHS HAZCOM 2012) OWI
OLD WORLD INDUSTRIES, LLC MAKES NO WARRANTY, REPRESENTATION OR GUARANTEE AS
TO THE ACCURACY, SUFFICIENCY OR COMPLETENESS OF THE MATERIAL SET FORTH
HEREIN. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SAFETY, TOXICITY
AND SUITABILITY OF HIS OWN USE, HANDLING AND DISPOSAL OF THIS PRODUCT.
SINCE ACTUAL USE BY OTHERS IS BEYOND OUR CONTROL, NO WARRANTY, EXPRESSED OR
IMPLIED, IS MADE BY OLD WORLD INDUSTRIES, LLC AS TO THE EFFECTS OF SUCH
USE, THE RESULTS TO BE OBTAINED OR THE SAFETY AND TOXICITY OF THIS PRODUCT,
NOR DOES OLD WORLD INDUSTRIES, LLC ASSUME LIABILITY ARISING OUT OF THE USE
BY OTHERS OF THIS PRODUCT REFERRED TO HEREIN. THE DATA IN THIS SDS RELATES
ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN AND DOES NOT RELATE TO USE
IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PROCESS.
10/14/2015
EN (ENGLISH)