| Common Name: | FINAL CHARGE GLOBAL 50/50 PREDILUTED ANTIFREEZE AND COOLANT |
| Manufacturer: | OLD WORLD INDUSTRIES |
| SDS Revision Date: | 11/1/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 48ZE80, 48ZE81 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
FINAL CHARGE GLOBAL 50/50 PREDILUTED ANTIFREEZE AND COOLANT
REVISION DATE: 11/01/2019
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
PRODUCT NAME: FINAL CHARGE GLOBAL 50/50 PREDILUTED ANTIFREEZE AND COOLANT
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: HEAVY DUTY ENGINE COOLANT
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
OLD WORLD INDUSTRIES, LLC
3100 SANDERS ROAD NORTHBROOK, IL 60062
USA
T: (847) 559-2000
WWW.OLDWORLDIND.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
800 424 9300 (UNITED STATES)
00 1 703 527 3887 (INTERNATIONAL) CHEMTREC
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
ACUTE TOXICITY (ORAL), CATEGORY 4:
H302: HARMFUL IF SWALLOWED.
REPRODUCTIVE TOXICITY, CATEGORY 2:
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, CATEGORY 2:
H373:
MAY CAUSE DAMAGE TO ORGANS (KIDNEYS) THROUGH PROLONGED OR REPEATED
EXPOSURE (ORAL).
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. LABEL ELEMENTS:
GHS-US LABELLING:
HAZARD PICTOGRAMS (GHS-US):
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): WARNING
HAZARD STATEMENTS (GHS-US):
HARMFUL IF SWALLOWED.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
MAY CAUSE DAMAGE TO ORGANS (KIDNEYS) THROUGH PROLONGED OR REPEATED
EXPOSURE (ORAL).
PRECAUTIONARY STATEMENTS (GHS-US):
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE MIST, SPRAY, VAPORS
WASH AFFECTED AREAS THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WEAR PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
IF SWALLOWED: IMMEDIATELY CALL A DOCTOR, A POISON CENTER
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORE LOCKED UP.
DISPOSE OF CONTENTS/CONTAINER TO APPROPRIATE WASTE DISPOSAL FACILITY, IN
ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCES: NOT APPLICABLE
3.2. MIXTURES:
NAME PRODUCT IDENTIFIER % BY WT GHS-US CLASSIFICATION
ETHYLENE (CAS-NO.) 107-21-1 <=50 ACUTE TOX. 4 (ORAL),
GLYCOL H302
WATER (CAS-NO.) 7732-18-5 <50 NOT CLASSIFIED
DIETHYLENE (CAS-NO.) 111-46-6 <3 ACUTE TOX. 4 (ORAL),
GLYCOL H302
STOT RE 2, H373
POTASSIUM (CAS-NO.) 16518-26-6 <2 REPR. 2, H361
P-TERT-BUT-
YLBENZOATE
DENATONIUM (CAS-NO.) 3734-33-6 0.003 - 0.005 ACUTE TOX. 4 (ORAL),
BENZOATE [30 - 50 PPM] H302
SKIN IRRIT. 2, H315
EYE IRRIT. 2A, H319
STOT SE 3, H335
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
IF BREATHING IS DIFFICULT, REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN
A POSITION COMFORTABLE FOR BREATHING. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE.
FIRST-AID MEASURES AFTER SKIN CONTACT:
WASH SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
IF SKIN IRRITATION OCCURS:
RINSE IMMEDIATELY WITH PLENTY OF WATER (FOR AT LEAST 15 MINUTES), GET
MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER EYE CONTACT:
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. RINSE
IMMEDIATELY WITH PLENTY OF WATER FOR 15 MINUTES, LIFTING LOWER AND UPPER
LIDS.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE AND ATTENTION.
FIRST-AID MEASURES AFTER INGESTION:
OBTAIN EMERGENCY MEDICAL ATTENTION. RINSE MOUTH. IF THE PERSON IS
FULLY CONSCIOUS, MAKE HIM/HER DRINK TWO GLASSES OF WATER. NEVER GIVE
AN UNCONSCIOUS PERSON ANYTHING TO DRINK. DO NOT INDUCE VOMITING. CALL
A POISON CENTER/DOCTOR/PHYSICIAN IF YOU FEEL UNWELL. IF MEDICAL ADVICE
IS DELAYED, AND IF THE PERSON HAS SWALLOWED A MODERATE VOLUME OF MATERIAL
(A FEW OUNCES), THEN GIVE THREE TO FOUR OUNCES OF HARD LIQUOR, SUCH AS
WHISKEY. FOR CHILDREN, GIVE PROPORTIONALLY LESS LIQUOR, ACCORDING TO
WEIGHT.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/EFFECTS:
CAUSES DAMAGE TO ORGANS (KIDNEYS) ORAL. SUSPECTED OF DAMAGING FERTILITY OR
THE UNBORN CHILD.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: MAY CAUSE MODERATE IRRITATION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
DIRECT CONTACT WITH THE EYES IS LIKELY TO BE IRRITATING.
SYMPTOMS/EFFECTS AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH
HAZARD. THE LETHAL DOSE IN HUMANS IS ESTIMATED TO BE 100 ML (3 OZ).
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
A MORE EFFECTIVE INTRAVENOUS ANTIDOTE FOR PHYSICIAN USES IS
4-METHYLPYRAZAOLE, A POTENT INHIBITOR OF ALCOHOL DEHYDROGENASES, WHICH
EFFECTIVELY BLOCKS THE FORMATION OF TOXIC METABOLITES OF ETHYLENE GLYCOL.
IT HAS BEEN USED TO DECREASE THE METABOLIC CONSEQUENCES OF ETHYLENE GLYCOL
POISONING BEFORE METABOLIC ACIDOSIS COMA, SEIZURES, AND RENAL FAILURE HAVE
OCCURED.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FINE WATER SPRAY. FOAM. CARBON DIOXIDE. DRY CHEMICAL POWDER.
SAND.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A HEAVY WATER STREAM. MAY SPREAD FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD:
DURING A FIRE, SMOKE MAY CONTAIN THE ORIGINAL MATERIAL IN ADDITION TO
COMBUSTION PRODUCTS OF VARYING COMPOSITION WHICH MAY BE TOXIC AND/OR
IRRITATING.
COMBUSTION PRODUCTS MAY INCLUDE AND ARE NOT LIMITED TO:
CARBON MONOXIDE. CARBON DIOXIDE. PRODUCT IS NOT FLAMMABLE OR COMBUSTIBLE
BUT MAY BURN UNDER FIRE CONDITIONS.
REACTIVITY:
NO DANGEROUS REACTIONS KNOWN UNDER NORMAL CONDITIONS OF USE.
5.3. SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE FIGHTING WATER FROM ENTERING
THE ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. REFER TO SECTION 8.2.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE.
SMALL QUANTITIES OF LIQUID SPILL:
TAKE UP IN NON-COMBUSTIBLE ABSORBENT MATERIAL AND SHOVEL INTO CONTAINER
FOR DISPOSAL. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
FOR FURTHER INFORMATION REFER TO SECTION 13.
FOR FURTHER INFORMATION REFER TO SECTION 8:
"EXPOSURE CONTROLS/PERSONAL PROTECTION".
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. OBTAIN SPECIAL INSTRUCTIONS
BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH AFFECTED AREAS
THOROUGHLY AFTER HANDLING.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE
AWAY FROM:
HEAT SOURCES. DIRECT SUNLIGHT. KEEP CONTAINER CLOSED WHEN NOT IN USE.
PRODUCT MAY BECOME SOLID AT TEMPERATURES BELOW -37 DEG. C (-34 DEG. F).
DO NOT STORE NEAR FOOD, FOODSTUFFS, DRUGS OR POTABLE WATER SUPPLIES. DO
NOT CUT, DRILL, WELD, USE A BLOWTORCH ON, ETC. CONTAINERS EVEN WHEN EMPTY.
INCOMPATIBLE PRODUCTS:
KEEP AWAY FROM STRONG ACIDS, STRONG BASES AND OXIDIZING AGENTS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION.
7.3. SPECIFIC END USE(S): NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
DENATONIUM BENZOATE (3734-33-6): NOT APPLICABLE
ETHYLENE GLYCOL (107-21-1):
ACGIH:
LOCAL NAME: ETHYLENE GLYCOL
ACGIH:
ACGIH TWA (MG/M3): 10 MG/M3
ACGIH:
ACGIH TWA (PPM): 25 PPM (VAPOR FRACTION)
ACGIH:
ACGIH STEL (MG/M3): 10 MG/M3 (INHALABLE FRACTION, AEROSOL ONLY)
ACGIH:
ACGIH STEL (PPM): 50 PPM (VAPOR FRACTION)
ACGIH:
REMARK (ACGIH): UPPER RESPIRATORY TRACT & EYE IRRITANT
ACGIH:
REGULATORY REFERENCE: ACGIH 2018
DIETHYLENE GLYCOL (111-46-6): NOT APPLICABLE
WATER (7732-18-5): NOT APPLICABLE
POTASSIUM P-TERT-BUTYLBENZOATE (16518-26-6): NOT APPLICABLE
8.2. APPROPRIATE ENGINEERING CONTROLS: NO ADDITIONAL INFORMATION AVAILABLE
8.3. INDIVIDUAL PROTECTION MEASURES/PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
AVOID ALL UNNECESSARY EXPOSURE. GLOVES. SAFETY GLASSES.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION NOT REQUIRED IN NORMAL CONDITIONS. IF EXPOSED TO
LEVELS ABOVE EXPOSURE LIMITS WEAR APPROPRIATE RESPIRATORY PROTECTION.
GLOVES
SAFETY GLASSES
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
MOLECULAR MASS: 62.07 G/MOL ETHYLENE GLYCOL
COLOR: RED
ODOR: MILD
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 8.6
RELATIVE EVAPORATION RATE (BUTYLACETATE=1): NIL
FREEZING POINT: -37 DEG. C (-34 DEG. F)
BOILING POINT: 107 DEG. C (224 DEG. F)
FLASH POINT: 116 DEG. C (241 DEG. F) [100% ETHYLENE GLYCOL] ASTM D56
AUTO-IGNITION TEMPERATURE:
400 DEG. C (752 DEG. F) [100% ETHYLENE GLYCOL] LITERATURE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOR PRESSURE: <0.1 MM Hg @ 20 DEG. C
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
SPECIFIC GRAVITY: 1.07
DENSITY: 1.07 KG/L (8.91 LBS/GAL)
SOLUBILITY:
WATER: COMPLETE
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE LIMITS: NOT APPLICABLE
EXPLOSIVE PROPERTIES: NOT APPLICABLE.
OXIDIZING PROPERTIES: NOT APPLICABLE.
9.2. OTHER INFORMATION:
VOC CONTENT: 0
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
NO DANGEROUS REACTIONS KNOWN UNDER NORMAL CONDITIONS OF USE.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTIONS KNOWN UNDER NORMAL CONDITIONS OF USE.
10.4. CONDITIONS TO AVOID:
EXTREMELY HIGH OR LOW TEMPERATURES. KEEP AWAY FROM ANY FLAMES OR SPARKING
SOURCE.
10.5. INCOMPATIBLE MATERIALS:
KEEP AWAY FROM STRONG ACIDS, STRONG BASES AND OXIDIZING AGENTS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
ALCOHOLS. ALDEHYDES. CARBON DIOXIDE. CARBON MONOXIDE. ETHERS. FUME.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
FINAL CHARGE GLOBAL 50/50 PREDILUTED ANTIFREEZE AND COOLANT:
ATE US (ORAL): 500 MG/KG BODYWEIGHT
DENATONIUM BENZOATE (3734-33-6):
LD50 ORAL RAT: 584 MG/KG (RAT, LITERATURE STUDY, ORAL)
LD50 DERMAL RABBIT: >2000 MG/KG (RABBIT, LITERATURE STUDY, DERMAL)
ATE US (ORAL): 584 MG/KG BODYWEIGHT
ETHYLENE GLYCOL (107-21-1):
LD50 ORAL RAT:
7712 MG/KG BODYWEIGHT (ACCORDING TO BASF-INTERNAL STANDARDS, RAT,
MALE / FEMALE, EXPERIMENTAL VALUE, AQUEOUS SOLUTION, ORAL, 7 DAY(S))
LC50 INHALATION RAT (MG/L):
>2.5 MG/L (6 H, RAT, MALE / FEMALE, EXPERIMENTAL VALUE, INHALATION
(AEROSOL))
ATE US (ORAL): 500 MG/KG BODYWEIGHT
DIETHYLENE GLYCOL (111-46-6):
LD50 ORAL RAT:
19600 MG/KG BODYWEIGHT (OECD 401:
ACUTE ORAL TOXICITY, RAT, MALE, EXPERIMENTAL VALUE, ORAL)
LD50 DERMAL RABBIT: 11890 MG/KG (RABBIT, DERMAL)
LC50 INHALATION RAT (MG/L):
>4.6 MG/L/4H (OTHER, 4 H, RAT, WEIGHT OF EVIDENCE)
ATE US (ORAL): 500 MG/KG BODYWEIGHT
ATE US (DERMAL): 11890 MG/KG BODYWEIGHT
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: 8.6
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: 8.6
RESPIRATORY OR SKIN SENSITISATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
STOT-SINGLE EXPOSURE: NOT CLASSIFIED
STOT-REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS (KIDNEYS) THROUGH PROLONGED OR REPEATED
EXPOSURE (ORAL).
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/EFFECTS:
CAUSES DAMAGE TO ORGANS (KIDNEYS) ORAL. SUSPECTED OF DAMAGING FERTILITY
OR THE UNBORN CHILD.
SYMPTOMS/EFFECTS AFTER SKIN CONTACT: MAY CAUSE MODERATE IRRITATION.
SYMPTOMS/EFFECTS AFTER EYE CONTACT:
DIRECT CONTACT WITH THE EYES IS LIKELY TO BE IRRITATING.
SYMPTOMS/EFFECTS AFTER INGESTION:
SWALLOWING A SMALL QUANTITY OF THIS MATERIAL WILL RESULT IN SERIOUS HEALTH
HAZARD. THE LETHAL DOSE IN HUMANS IS ESTIMATED TO BE 100 ML (3 OZ).
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
DENATONIUM BENZOATE (3734-33-6):
LC50 FISH 1: >1,000.00 MG/L (96 H, SALMO GAIRDNERI, LITERATURE STUDY)
EC50 DAPHNIA 1: 13.00 MG/L (48 H, DAPHNIA MAGNA, LITERATURE STUDY)
ETHYLENE GLYCOL (107-21-1):
LC50 FISH 1: 40,761.00 MG/L (96 H, SALMO GAIRDNERI, STATIC SYSTEM)
EC50 DAPHNIA 1: >10,000.00 MG/L (24 H, DAPHNIA MAGNA)
DIETHYLENE GLYCOL (111-46-6):
LC50 FISH 1: >5,000.00 PPM (24 H, CARASSIUS AURATUS)
EC50 DAPHNIA 1: >10,000.00 MG/L (24 H, DAPHNIA MAGNA)
LC50 FISH 2:
75,200.00 MG/L (OTHER, 96 H, PIMEPHALES PROMELAS, FLOW-THROUGH SYSTEM,
EXPERIMENTAL VALUE)
EC50 DAPHNIA 2:
>10,000.00 MG/L (DIN 38412-11, 24 H, DAPHNIA MAGNA, STATIC SYSTEM, FRESH
WATER, EXPERIMENTAL VALUE)
12.2. PERSISTENCE AND DEGRADABILITY:
DENATONIUM BENZOATE (3734-33-6):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY IN WATER:
NO DATA AVAILABLE. NO (TEST) DATA ON MOBILITY OF THE SUBSTANCE AVAILABLE.
ETHYLENE GLYCOL (107-21-1):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABLE IN THE SOIL. READILY BIODEGRADABLE IN WATER.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.47 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.24 G O2/G SUBSTANCE
THOD: 1.29 G O2/G SUBSTANCE
BOD (% OF THOD): 0.36
DIETHYLENE GLYCOL (111-46-6):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABLE IN THE SOIL. BIODEGRADABLE IN WATER.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.02 G O2/G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.51 G O2/G SUBSTANCE
THOD: 1.51 G O2/G SUBSTANCE
BOD (% OF THOD): 0.02
12.3. BIOACCUMULATIVE POTENTIAL:
DENATONIUM BENZOATE (3734-33-6):
LOG POW: 1.78 (ESTIMATED VALUE)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
ETHYLENE GLYCOL (107-21-1):
BCF FISH 1: 10.00 (72 H, LEUCISCUS IDUS)
BCF OTHER AQUATIC ORGANISMS 1: 0.21 - 0.6 (PROCAMBARUS SP., CHRONIC)
BCF OTHER AQUATIC ORGANISMS 2: 190.00 (24 H, ALGAE)
LOG POW: -1.34 (EXPERIMENTAL VALUE)
BIOACCUMULATIVE POTENTIAL: NOT BIOACCUMULATIVE.
DIETHYLENE GLYCOL (111-46-6):
BCF FISH 1:
100.00 (OTHER, 3 DAY(S), LEUCISCUS MELANOTUS, STATIC SYSTEM, FRESH WATER,
EXPERIMENTAL VALUE)
LOG POW: -1.98 (CALCULATED, OTHER)
BIOACCUMULATIVE POTENTIAL: NOT BIOACCUMULATIVE.
12.4. MOBILITY IN SOIL:
DENATONIUM BENZOATE (3734-33-6):
ECOLOGY - SOIL: NO (TEST)DATA ON MOBILITY OF THE SUBSTANCE AVAILABLE.
ETHYLENE GLYCOL (107-21-1):
SURFACE TENSION: 48.00 MN/M (20 DEG. C)
ECOLOGY - SOIL: NO (TEST)DATA ON MOBILITY OF THE SUBSTANCE AVAILABLE.
DIETHYLENE GLYCOL (111-46-6):
SURFACE TENSION: 0.05 N/M
LOG KOC: 0.00 (LOG KOC, SRC PCKOCWIN V1.66, CALCULATED VALUE)
ECOLOGY - SOIL: HIGHLY MOBILE IN SOIL.
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON THE OZONE LAYER: NO KNOWN EFFECT ON THE OZONE LAYER
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
PRODUCT/PACKAGING DISPOSAL RECOMMENDATIONS:
DISPOSE OF CONTENTS/CONTAINER TO APPROPRIATE WASTE DISPOSAL FACILITY, IN
ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT
NON BULK (IN QUANTITIES UNDER 5,000 LBS IN ANY ONE INNER PACKAGE):
NOT REGULATED BY THE US DOT
BULK (IN QUANTITIES 5,000 LBS OR OVER IN ANY ONE INNER PACKAGE):
TRANSPORT DOCUMENT DESCRIPTION:
UN3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S.
(ETHYLENE GLYCOL), 9, III
UN-NO.(DOT): UN3082
PROPER SHIPPING NAME (DOT):
ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S.
ETHYLENE GLYCOL
CLASS (DOT):
9 - CLASS 9 - MISCELLANEOUS HAZARDOUS MATERIAL 49 CFR 173.140
PACKING GROUP (DOT): III - MINOR DANGER
HAZARD LABELS (DOT): 9 - CLASS 9 (MISCELLANEOUS DANGEROUS MATERIALS)
DOT PACKAGING NON BULK (49 CFR 173.XXX): 203
DOT PACKAGING BULK (49 CFR 173.XXX): 241
DOT SYMBOLS: G - IDENTIFIES PSN REQUIRING A TECHNICAL NAME
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 155
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): NO LIMIT
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): NO LIMIT
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED ''ON DECK'' OR ''UNDER DECK'' ON A CARGO
VESSEL AND ON A PASSENGER VESSEL.
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
TRANSPORTATION OF DANGEROUS GOODS:
REFER TO CURRENT TDG CANADA FOR FURTHER CANADIAN REGULATIONS:
TRANSPORT BY SEA:
IN ACCORDANCE WITH IMDG / IMO:
PROPER SHIPPING NAME (IMDG):
NOT REGULATED BY IMDG (IN QUANTITES UNDER 5,000 LBS IN ANY ONE INNER
PACKAGE)
AIR TRANSPORT:
IN ACCORDANCE WITH IATA / ICAO:
PROPER SHIPPING NAME (IATA):
NOT REGULATED BY IATA (IN QUANTITES UNDER 5,000 LBS IN ANY ONE INNER
PACKAGE)
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
FINAL CHARGE GLOBAL 50/50 PREDILUTED ANTIFREEZE AND COOLANT:
EPA TSCA REGULATORY FLAG:
TOXIC SUBSTANCES CONTROL ACT (TSCA):
THE INTENTIONAL INGREDIENTS OF THIS PRODUCT ARE LISTED
DENATONIUM BENZOATE (3734-33-6):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
ETHYLENE GLYCOL (107-21-1):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
EPA TSCA REGULATORY FLAG:
T - INDICATES A SUBSTANCE THAT IS THE SUBJECT OF A SECTION 4 TEST RULE
UNDER TSCA.
CERCLA RQ: 5000 LB(S)
SARA SECTION 311/312 HAZARD CLASSES:
REFER TO SECTION 2 FOR THE OSHA HAZARD CLASSIFICATION ETHYLENE GLYCOL IS
SUBJECT TO TIER I AND/OR TIER II ANNUAL INVENTORY REPORTING.
SARA SECTION 313 - EMISSION REPORTING:
ETHYLENE GLYCOL IS SUBJECT TO FORM R REPORTING REQUIREMENTS.
DIETHYLENE GLYCOL (111-46-6):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
WATER (7732-18-5):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
FINAL CHARGE GLOBAL 50/50 PREDILUTED ANTIFREEZE AND COOLANT:
WHMIS CLASSIFICATION:
THIS SDS HAS BEEN PREPARED ACCORDING TO THE CRITERIA OF THE HAZARDOUS
PRODUCTS REGULATIONS (HPR) (WHMIS 2015) AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE HPR. APPLICABLE GHS INFORMATION IS LISTED IN
SECTION 2.2 OF THIS SDS.
POTASSIUM P-TERT-BUTYLBENZOATE (16518-26-6):
LISTED ON THE CANADIAN NDSL (NON-DOMESTIC SUBSTANCES LIST)
15.3. US STATE REGULATIONS:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO ETHYLENE GLYCOL, WHICH IS KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
FOR MORE INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
ETHYLENE GLYCOL (107-21-1):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANT RISK LEVEL (NSRL):
MAXIMUM ALLOWABLE DOSE LEVEL (MADL): (INGESTED) 8,700 (ORAL) (MICRO)G/DAY
ETHYLENE GLYCOL (107-21-1):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
DIETHYLENE GLYCOL (111-46-6):
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 11/01/2019
FULL TEXT OF H-STATEMENTS:
H302: HARMFUL IF SWALLOWED.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
NFPA HEALTH HAZARD 1 - MATERIALS THAT, UNDER EMERGENCY CONDITIONS, CAN
CAUSE SIGNIFICANT IRRITATION.
NFPA FIRE HAZARD 1 - MATERIALS THAT MUST BE PREHEATED BEFORE IGNITION
CAN OCCUR.
NFPA REACTIVITY 0 - MATERIAL THAT IN THEMSELVES ARE NORMALLY STABLE,
EVEN UNDER FIRE CONDITIONS.
SDS GHS US (GHS HAZCOM 2012) OWI
OLD WORLD INDUSTRIES, LLC MAKES NO WARRANTY, REPRESENTATION OR GUARANTEE
AS TO THE ACCURACY, SUFFICIENCY OR COMPLETENESS OF THE MATERIAL SET FORTH
HEREIN. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SAFETY, TOXICITY
AND SUITABILITY OF HIS OWN USE, HANDLING AND DISPOSAL OF THIS PRODUCT.
SINCE ACTUAL USE BY OTHERS IS BEYOND OUR CONTROL, NO WARRANTY, EXPRESSED
OR IMPLIED, IS MADE BY OLD WORLD INDUSTRIES, LLC AS TO THE EFFECTS OF
SUCH USE, THE RESULTS TO BE OBTAINED OR THE SAFETY AND TOXICITY OF THIS
PRODUCT, NOR DOES OLD WORLD INDUSTRIES, LLC ASSUME LIABILITY ARISING OUT
OF THE USE BY OTHERS OF THIS PRODUCT REFERRED TO HEREIN. THE DATA IN THIS
SDS RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN AND DOES NOT
RELATE TO USE IN COMBINATION WITH ANY OTHER MATERIAL OR IN ANY PROCESS.
EN (ENGLISH)