| Common Name: | VALVE REGULATED LEAD-ACID RECHARGEABLE BATTERY, MAINTENANCE FREE BATTERY |
| Manufacturer: | B.B. BATTERY |
| SDS Revision Date: | 5/5/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 2XLD6, 304K70, 490P87, 490P88, 490P89, 490P90, 490P91, 55MJ53 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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BB(R*)
B.B. BATTERY CO., LTD.
SAFETY DATA SHEET
VALVE REGULATED LEAD-ACID RECHARGEABLE BATTERY
DATE: MAY. 5, 2016
| SECTION 1: PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
VALVE REGULATED LEAD-ACID RECHARGEABLE BATTERY, MAINTENANCE FREE BATTERY
COMPANY: B.B. BATTERY CO., LTD.
ADDRESS:
CHINA:
CHENGDONG TRIAL AREA
HUANGGANG TOWN
RAOPING COUNTY
GUANGDONG PROVINCE, 515700
P.R.CHINA
US OFFICE:
6415 RANDOLPH STREET
COMMERCE, CA 90040
E-MAIL: FACTORY@BB-BATTERY.COM
TEL:
CHINA: +86-768-7601001 OR +86-768-7601002
US OFFICE: 323-278-1900
FAX:
CHINA: +86-768-7601469
US OFFICE: 323-278-1268
CHEMICAL FAMILY:
THIS PRODUCT IS A WET LEAD ACID STORAGE BATTERY. MAY ALSO INCLUDE GEL
ABSORBED ELECTROLYTE TYPE LEAD ACID BATTERY TYPES.
| SECTION 2: HAZARDS IDENTIFICATION | |
GHS LABEL ELEMENTS:
EXCLAMATION MARK
HEALTH HAZARD
FLAME
CORROSION
ENVIRONMENT
SIGNAL WORD: DANGER
CATEGORY GHS CODES DESCRIPTION
HEALTH:
STOT RE 2 H302 HARMFUL IF SWALLOWED.
ACUTE TOX. 4
REPR. 1A H314 CAUSES SEVERE SKIN BURNS AND EYE
SKIN CORR. 1A DAMAGE.
FLAM. GAS 1
AQUATIC CHRONIC 1 H332 HARMFUL IF INHALED.
AQUATIC ACUTE 1
H360 MAY DAMAGE FERTILITY OR THE UNBORN
CHILD.
H373 MAY CAUSE DAMAGE TO ORGANS THROUGH
PROLONGED OR REPUTED EXPOSURE.
H220 EXTREMELY FLAMMABLE GAS (HYDROGEN)
H410 VERY TOXIC TO AQUATIC LIFE WITH LONG
LASTING EFFECTS.
P260 DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY
P301/330/331 IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING.
P303/361/353 IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL
CONTAMINATED CLOTHING. RINSE SKIN
WITH WATER/SHOWER.
P304/340 IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP
AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
P305/351/338 IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL
MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE
RINSING.
P310 IMMEDIATELY CALL A POISON CENTER OR
DOCTOR/PHYSICIAN.
HANDLING:
P210 KEEP AWAY FROM HEAT/SPARKS/OPEN
FLAMES/HOT SURFACES. NO SMOKING
P260 DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY
P264 WASH THOROUGHLY AFTER HANDLING.
P280 WEAR PROTECTIVE GLOVES/PROTECTIVE
CLOTHING/EYE PROTECTION/FACE
PROTECTION.
P403 STORE IN WELL-VENTILATED AREA
P405 STORE LOCKED UP.
P391 COLLECT SPILLAGE
P273 AVOID RELEASE TO THE ENVIRONMENT
P501 DISPOSE OF CONTENTS/CONTAINER IN
ACCORDANCE WITH LOCAL/REGIONAL/
NATIONAL/INTERNATIONAL REGULATION.
NOTE:
THE BATTERY HAS PASSED THE VIBRATION TEST, PRESSURE DIFFERENTIAL TEST AND
LEAKAGE TEST AT 55 DEG. C ACCORDING TO RECOMMENDATIONS ON THE TRANSPORT
OF DANGEROUS GOODS MODEL REGULATION 18TH SPECIAL PROVISION 238. IT IS NOT
RESTRICTED TO IATA DANGEROUS GOODS REGULATION (DGR) 57TH ACCORDING TO
SPECIAL PROVISION A67 AND IS NOT RESTRICTED TO IMDG CODE ACCORDING TO
SPECIAL PROVISION 238.
| SECTION 3: INFORMATION ON INGREDIENTS | |
PRODUCT NAME:
VALVE REGULATED LEAD-ACID RECHARGEABLE BATTERY, MAINTENANCE FREE BATTERY
INGREDIENT CAS NO. CONCENTRATION HAZARDOUS
(% BY WT.) LABEL
INORGANIC LEAD/LEAD COMPOUNDS 7439-92-1 APPROX. 72% T
SULFURIC ACID 7664-93-9 APPROX. 20% C
FIBERGLASS SEPARATOR 65997-17-3 APPROX. 2% /
SILICON DIOXIDE 7631-86-9 APPROX. 10% /
(GEL BATTERIES ONLY) OF ACID WT.
CONTAINER PLASTIC (ABS OR PP) 9003-56-9 APPROX. 5% /
(ABS)
9003-07-0 /
(PP)
NOTE:
INORGANIC LEAD AND ELECTROLYTE (WATER AND SULFURIC ACID SOLUTION) ARE THE
PRIMARY COMPONENTS OF EVERY BATTERY MANUFACTURED BY BB BATTERY. OTHER
INGREDIENTS MAY BE PRESENT DEPENDENT UPON BATTERY TYPE. ABS IS THE PRIMARY
CASE MATERIAL OF TELECOM AND COMMERCIAL BATTERIES.
| SECTION 4: FIRST-AID MEASURES | |
TAKE PROPER PRECAUTIONS TO ENSURE YOU OWN HEALTH AND SAFETY BEFORE
ATTEMPTING TO RESCUE A VICTIM AND PROVIDE FIRST AID.
SKIN CONTACT:
ELECTROLYTE:
FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES; REMOVE
CONTAMINATED CLOTHING COMPLETELY, INCLUDING SHOES, AND DO NOT WEAR AGAIN
UNTIL CLEANED. IF ACID IS SPLASHED ON SHOES, REMOVE AND DISCARD IF THEY
CONTAIN LEATHER.
LEAD COMPOUNDS:
WASH IMMEDIATELY WITH SOAP AND WATER. LEAD COMPOUNDS ARE NOT READILY
ABSORBED THROUGH THE SKIN.
EYE CONTACT:
ELECTROLYTE AND LEAD COMPOUNDS:
FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES;
CONSULT PHYSICIAN IMMEDIATELY.
INHALATION EXPOSURE:
ELECTROLYTE:
TO WRAP IN A BLANKET THE PATIENT IMMEDIATELY, WHEN THE INHALATION OF
SULFURIC ACID MIST OR VAPOR, THEN TRANSFER FROM THE INHALED LOCATION TO A
PLACE WHERE FRESH AIR CAN BE OBTAINED. TO GET MEDICAL ADVICE / ATTENTION
IMMEDIATELY.
LEAD COMPOUNDS:
REMOVE FROM EXPOSURE, GARGLE, WASH NOSE AND LIPS; CONSULT PHYSICIAN.
ORAL EXPOSURE:
ELECTROLYTE:
IF SWALLOWED THIS LIQUID, WASH YOUR MOUTH WITH PLENTY OF WATER IMMEDIATELY
THEN TO DRINK PLENTY OF WATER AND OBTAIN MEDICAL ADVICE OR ATTENTION. DO
NOT INDUCE VOMITING WHEN SWALLOWED. IN ADDITION, NOT PERFORM ANY ACTION,
SUCH AS NEUTRALIZATION PROCESS.
LEAD COMPOUNDS: CONSULT PHYSICIAN IMMEDIATELY.
| SECTION 5: FIRE FIGHTING MEASURES | |
FLASH POINT: NOT APPLICABLE
FLAMMABLE LIMITS:
LEL: 4.1% (HYDROGEN GAS IN AIR)
UEL: 74.1%
EXTINGUISHING MEDIA:
SMALL FIRE: FOAM HALOGEN AND/OR NONINFLAMMABLE GAS FIRE EXTINGUISHER
BIG FIRE:
LARGE QUANTITIES OF SPRINKLED AND/OR ATOMIZED WATER. (IN THIS CASE TO
PREVENT ENVIRONMENTAL DAMAGE, FLUSH WATER HAS TO TREAT APPROPRIATELY.)
PARTICULAR HAZARDS:
IRRITATE, CORROSIVE AND/OR TOXICITY GASES MAY BREAK OUT FROM THE BURNING
BATTERY.
PROPER FIRE FIGHTING:
IF POSSIBLE, TURN OFF THEIR POWER FIRST WHEN BATTERIES ARE ON CHARGE OR
REMOVE IGNITION SOURCE AND REMOVE BATTERIES FROM THE FIRE PLACE. EXTINGUISH
OUT THE FIRE FROM WHERE WELL AIR FLOW AND WINDWARD. EXTINCTION WATER HAS
TO TREAT APPROPRIATELY FOR PREVENTING ENVIRONMENTAL DAMAGE. COOL DOWN
ENOUGH THE BURNT BATTERIES WITH PLENTY AMOUNT OF WATER. TRY TO PUT OUT
FIRE IN EARLY STAGE. IN THIS CASE TO USE PROTECTORS WRITTEN BELOW.
FIRE FIGHTING PROCEDURES:
USE POSITIVE PRESSURE, SELF-CONTAINED BREATHING APPARATUS. BEWARE OF ACID
SPLATTER DURING WATER APPLICATION AND WEAR ACID-RESISTANT CLOTHING, GLOVES,
FACE AND EYE PROTECTION. IF BATTERIES ARE ON CHARGE, SHUT OFF POWER TO THE
CHARGING EQUIPMENT, BUT, NOTE THAT STRINGS OF SERIES CONNECTED BATTERIES
MAY STILL POSE RISK OF ELECTRIC SHOCK EVEN WHEN CHARGING EQUIPMENT IS SHUT
DOWN.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
HUMAN BODY:
DO NOT TOUCH THE SPILLED ELECTROLYTE, AND WALK AROUND THE SPILLAGE PLACE.
KEEP OUT OUTSIDERS FROM THE SPILLAGE PLACE.
ENVIRONMENT:
SPILLED ELECTROLYTE HAS TO TREAT APPROPRIATELY FOR PREVENTING ENVIRONMENTAL
DAMAGE, SUCH AS DIRECT OUT FLOWING OF THE SPILLED ELECTROLYTE INTO THE
RIVER, DRAIN, ETC..
NEUTRALIZATION:
NEUTRALIZE SPILLED ELECTROLYTE WITH SODIUM BICARBONATE, LIME, ETC. AND
FLUSH WITH LARGE QUANTITIES OF WATER. IN THIS CASE TO USE PROTECTORS
PROPERLY.
| SECTION 7: HANDLING AND STORAGE | |
HANDLING:
KEEP AWAY FROM IGNITION SOURCES, HEAT AND FLAME. SUCH BATTERIES MUST BE
PACKED IN INNER PACKAGES IN SUCH A MANNER AS TO EFFECTIVELY PREVENT SHORT
CIRCUITS AND TO PREVENT MOVEMENT WHICH COULD LEAD TO SHORT CIRCUITS. AVOID
MECHANICAL OR ELECTRICAL ABUSE AND OVERCHARGE. MORE THAN A MOMENTARY SHORT
CIRCUIT WILL GENERALLY REDUCE THE BATTERY SERVICE LIFE. AVOID REVERSING
BATTERY POLARITY WITHIN THE BATTERY ASSEMBLY.
STORAGE:
STORE IN A COOL; WELL-VENTILATED AREA. KEEP AWAY FROM IGNITION SOURCES,
HEAT AND FLAME. SUCH BATTERIES MUST BE PACKED IN INNER PACKAGES IN SUCH A
MANNER AS TO EFFECTIVELY PREVENT SHORT CIRCUITS AND TO PREVENT MOVEMENT
WHICH COULD LEAD TO SHORT CIRCUITS.
MATERIALS TO AVOID: STRONG OXIDANT, COMBUSTIBLE MATERIALS AND CORROSIVES.
CHARGING:
THERE IS A POSSIBLE RISK OF ELECTRIC SHOCK FROM CHARGING EQUIPMENT AND FROM
STRINGS OF SERIES CONNECTED BATTERIES, WHETHER OR NOT BEING CHARGED.
SHUT-OFF POWER TO CHARGERS WHENEVER NOT IN USE AND BEFORE DETACHMENT OF
ANY CIRCUIT CONNECTIONS. BATTERIES BEING CHARGED WILL GENERATE AND RELEASE
FLAMMABLE HYDROGEN GAS. CHARGING SPACE SHOULD BE VENTILATED. KEEP BATTERY
VENT CAPS IN POSITION. PROHIBIT SMOKING AND AVOID CREATION OF FLAMES AND
SPARKS NEARBY. WEAR FACE AND EYE PROTECTION WHEN NEAR BATTERIES BEING
CHARGED.
| SECTION 8: EXPOSURE CONTROL AND PERSONAL PROTECTION | |
NOT APPLICABLE FOR VALVE REGULATED LEAD ACID BATTERY.
| SECTION 9: PHYSICAL/CHEMICAL PROPERTIES | |
NOT APPLICABLE FOR VALVE REGULATED LEAD ACID BATTERY.
REFERENCE (COMPONENT):
ELECTROLYTE (SULFURIC ACID) LEAD
APPEARANCE CLEAR SILVERY SOLID
SPECIFIC GRAVITY 1.280 - 1.380 (38 - 48%) 11.3
BOILING POINT 112 DEG. C (38%) 1740 DEG. C
MELTING POINT -40 DEG. C OR BELOW 327 DEG. C
SOLIDIFYING POINT -56.4 DEG. C (34.6%)
VAPOR PRESSURE 3.17 KPA (30%) 0.1 PA OR LESS
(25 DEG. C)
| SECTION 10: STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
MATERIALS TO AVOID: STRONG OXIDANT, CORROSIVES.
CONDITIONS TO AVOID:
AVOID EXPOSURE TO HEAT AND OPEN FLAME, AVOID MECHANICAL OR ELECTRICAL ABUSE
AND OVERCHARGE. PREVENT SHORT CIRCUITS. PREVENT MOVEMENT WHICH COULD LEAD
TO SHORT CIRCUITS.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
SULFUR OXIDES, SULFURIC ACID MIST, METAL OXIDES.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
ROUTES OF ENTRY:
ELECTROLYTE:
HARMFUL BY ALL ROUTES OF ENTRY. UNDER NORMAL CONDITIONS OF USE, SULFURIC
ACID VAPORS AND MIST ARE NOT GENERATED. SULFURIC ACID VAPORS AND MIST MAY
BE GENERATED WHEN PRODUCT IS OVERHEATED, OXIDIZED, OR OTHERWISE PROCESSED
OR DAMAGED.
LEAD COMPOUNDS:
UNDER NORMAL CONDITIONS OF USE, LEAD DUST, VAPORS, AND FUMES ARE NOT
GENERATED. HAZARDOUS EXPOSURE CAN OCCUR ONLY WHEN PRODUCT IS HEATED ABOVE
THE MELTING POINT, OXIDIZED OR OTHERWISE PROCESSED OR DAMAGED TO CREATE
DUST, VAPOR, OR FUME.
ACUTE TOXICITY:
INHALATION LD50:
ELECTROLYTE:
LC50 RAT: 375 MG/M3
LC50:
GUINEA PIG: 510 MG/M3
ELEMENTAL LEAD:
ACUTE TOXICITY POINT ESTIMATE: 4500 PPMV (BASED ON LEAD BULLION)
ORAL LD50:
ELECTROLYTE:
RAT: 2140 MG/KG
ELEMENTAL LEAD:
ACUTE TOXICITY ESTIMATE (ATE):
500 MG/KG BODY WEIGHT (BASED ON LEAD BULLION)
CORRESPOND TO SECTION 3
| SECTION 12: ECOLOGICAL INFORMATION | |
ENVIRONMENTAL FATE:
LEAD IS VERY PERSISTENT IN SOIL AND SEDIMENTS. NO DATA ON ENVIRONMENTAL
DEGRADATION. MOBILITY OF METALLIC LEAD BETWEEN ECOLOGICAL COMPARTMENTS IS
SLOW. BIOACCUMULATION OF LEAD OCCURS IN AQUATIC AND TERRESTRIAL ANIMALS
AND PLANTS BUT LITTLE BIOACCUMULATION OCCURS THROUGH THE FOOD CHAIN. MOST
STUDIES INCLUDE LEAD COMPOUNDS AND NOT ELEMENTAL LEAD.
ENVIRONMENTAL TOXICITY:
AQUATIC TOXICITY:
SULFURIC ACID:
24-HR LC50, FRESHWATER FISH (BRACHYDANIO RERIO): 82 MG/L
96 HR- LOEC, FRESHWATER FISH (CYPRINUS CARPIO): 22 MG/L
LEAD:
48 HR LC50 (MODELED FOR AQUATIC INVERTEBRATES):
<1 MG/L, BASED ON LEAD BULLION
| SECTION 13: DISPOSAL CONSIDERATIONS | |
APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE:
LEAD-ACID BATTERIES ARE COMPLETELY RECYCLABLE. RETURN WHOLE SCRAP BATTERIES
TO DISTRIBUTOR, MANUFACTURER OR LEAD SMELTER FOR RECYCLING. FOR NEUTRALIZED
SPILLS, PLACE RESIDUE IN ACID-RESISTANT CONTAINERS WITH SORBENT MATERIAL,
SAND OR EARTH AND DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS FOR ACID AND LEAD COMPOUNDS. CONTACT LOCAL AND/OR STATE
ENVIRONMENTAL OFFICIALS REGARDING DISPOSAL INFORMATION.
| SECTION 14: TRANSPORT INFORMATION | |
WE HEREBY CERTIFY THAT ALL B.B. VALVE REGULATED LEAD-ACID RECHARGEABLE
BATTERIES CONFORM TO THE UN2800 CLASSIFICATION AS "BATTERIES, WET,
NON-SPILLABLE, AND ELECTRIC STORAGE" AS A RESULT OF PASSING THE VIBRATION
AND PRESSURE DIFFERENTIAL TEST DESCRIBED IN D.O.T., 49 CFR 173.159(F), AND
IMO/IMDG, AND ICAO/IATA PACKING INSTRUCTION 872 AND NOTE A48, A67, A164
AND A183. THE BATTERIES ARE NOT RESTRICTED TO IMO/IMDG CODE ACCORDING TO
SPECIAL PROVISION 238.
B.B. BATTERIES HAVING MET THE RELATED CONDITIONS ARE EXEMPT FROM HAZARDOUS
GOODS REGULATIONS FOR THE PURPOSE OF TRANSPORTATION BY DOT, AND IATA/ICAO,
AND THEREFORE ARE UNRESTRICTED FOR TRANSPORTATION BY ANY MEANS. FOR ALL
MODES OF TRANSPORTATION, EACH BATTERY OUTER PACKAGE IS LABELED
"NON-SPILLABLE". ALL OUR BATTERIES ARE MARKED NON-SPILLABLE.
| SECTION 15: REGULATORY INFORMATION | |
EU REGULATION:
IN ACCORDANCE WITH EU2006/66/EC BATTERY DIRECTIVE, VRLA BATTERIES SHOULD
PRESENT CROSSED-OUT WHEELED BIN SYMBOL OF LEAD TOGETHER WITH THE ISO
RECYCLING SYMBOL. DOES NOT CONTAIN ANY MERCURY, HG, (<0.0005%) OR
CADMIUM, Cd, (<0.002%).
PB
LEAD RETURN RECYCLE
| SECTION 16: OTHER INFORMATION | |
PRODUCTS SUCH AS BATTERIES ARE NOT IN THE SCOPE OF REGULATION WHICH
REQUIRES THE PUBLICATION OF AN EU SAFETY DATA SHEET (91/155/EEC).