| Common Name: | DYKEM SUDZ OFF 44 - ALL COLORS, BLACK (44985, 91985), BLUE (44938, 91938), GREEN |
| Manufacturer: | ITW PRO BRANDS |
| SDS Revision Date: | 4/16/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 49AY17, 49AY18, 49AY19, 49AY21, 4TKJ2, 8ARE9, 9F183 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
ITW PRO BRANDS
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: DYKEM(R*) SUDZ OFF(R*) 44 -ALL COLORS
OTHER MEANS OF IDENTIFICATION:
PART NUMBER:
BLACK (44985, 91985), BLUE (44938, 91938), GREEN (44371, 91371), RED
(44939, 91939), WHITE (44146, 91146), YELLOW (44694, 91694)
SYNONYMS:
FORMULA CODE(S):
* Z985 (BLACK), X938 (BLUE) * Y371 (GREEN), X939 (RED) * Z146 (WHITE), Z694
(YELLOW)
RECOMMENDED USE: SOLVENT BASED MARKER
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURER:
COMPANY NAME: ITW PRO BRANDS
ADDRESS:
805 E. OLD 56 HIGHWAY
OLATHE, KS 66061
COUNTRY: (U.S.A.)
TEL: +1 800-443-9536
IN CASE OF EMERGENCY: 1-800-535-5053 (INFOTRAC)
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE LIQUIDS: CATEGORY 3
HEALTH HAZARDS:
ACUTE TOXICITY, INHALATION: CATEGORY 4
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
CORROSION
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
FLAMMABLE LIQUID AND VAPOR. CAUSES SERIOUS EYE DAMAGE. HARMFUL IF INHALED.
MAY CAUSE DROWSINESS OR DIZZINESS.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. -NO SMOKING. KEEP
CONTAINER TIGHTLY CLOSED. GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT. USE ONLY
NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
AVOID BREATHING MIST OR VAPOR. USE ONLY OUTDOORS OR IN A WELL-VENTILATED
AREA. WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER/DOCTOR.
IN CASE OF FIRE: USE APPROPRIATE MEDIA TO EXTINGUISH.
STORAGE:
KEEP COOL. STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
1-PROPANOL 71-23-8 50 - 60
TITANIUM DIOXIDE 13463-67-7 20 - 30
DIACETONE ALCOHOL 123-42-2 1 - 10
[4-[4-(DIETHYLAMINO)-ALPHA- 2390-60-5 1 - 3
[4-(ETHYLAMINO)-1-NAPTHYL]-
BENZYLIDENE]CYCLOHEXA-2,5-D
ALUMINUM HYDROXIDE 21645-51-2 1 - 3
BENZENAMINE, 4-4'- 6358-36-7 1 - 3
CARBONIMIDOYLBIS[N,N-DIETHYL-,
MONOHYDROCHLORIDE
SILICA, AMORPHOUS 7631-86-9 1 - 3
SOLVENT RED 70851-41-1 1 - 3
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. CALL A POISON CENTER
OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL
ATTENTION IMMEDIATELY.
INGESTION: RINSE MOUTH. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. DIARRHEA.
SEVERE EYE IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS,
SWELLING, AND BLURRED VISION. PERMANENT EYE DAMAGE INCLUDING BLINDNESS
COULD RESULT.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. THERMAL
BURNS: FLUSH WITH WATER IMMEDIATELY. WHILE FLUSHING, REMOVE CLOTHES WHICH
DO NOT ADHERE TO AFFECTED AREA. CALL AN AMBULANCE. CONTINUE FLUSHING DURING
TRANSPORT TO HOSPITAL. KEEP VICTIM WARM. KEEP VICTIM UNDER OBSERVATION.
SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
TAKE OFF ALL CONTAMINATED CLOTHING IMMEDIATELY. ENSURE THAT MEDICAL
PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS
TO PROTECT THEMSELVES. WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. ALCOHOL RESISTANT FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE
(CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR. VAPORS MAY TRAVEL CONSIDERABLE
DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. DURING FIRE, GASES
HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES. MOVE CONTAINERS FROM
FIRE AREA IF YOU CAN DO SO WITHOUT RISK.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS.
GENERAL FIRE HAZARDS: FLAMMABLE LIQUID AND VAPOR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR
FLAMES IN IMMEDIATE AREA). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
CLOTHING DURING CLEAN-UP. AVOID INHALATION OF VAPORS AND SPRAY MISTS. DO
NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE
PROTECTIVE CLOTHING. VENTILATE CLOSED SPACES BEFORE ENTERING THEM. LOCAL
AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED.
FOR PERSONAL PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
USE WATER SPRAY TO REDUCE VAPORS OR DIVERT VAPOR CLOUD DRIFT. ELIMINATE ALL
IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE AREA).
KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED MATERIAL. TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. USE ONLY NON-SPARKING
TOOLS.
LARGE SPILLS:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. DIKE THE SPILLED
MATERIAL, WHERE THIS IS POSSIBLE. USE A NON-COMBUSTIBLE MATERIAL LIKE
VERMICULITE, SAND OR EARTH TO SOAK UP THE PRODUCT AND PLACE INTO A
CONTAINER FOR LATER DISPOSAL. FOLLOWING PRODUCT RECOVERY, FLUSH AREA
WITH WATER.
SMALL SPILLS:
ABSORB WITH EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL AND TRANSFER TO
CONTAINERS FOR LATER DISPOSAL. WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH,
FLEECE). CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
DO NOT HANDLE, STORE OR OPEN NEAR AN OPEN FLAME, SOURCES OF HEAT OR SOURCES
OF IGNITION. PROTECT MATERIAL FROM DIRECT SUNLIGHT. WHEN USING DO NOT
SMOKE. EXPLOSION-PROOF GENERAL AND LOCAL EXHAUST VENTILATION. TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. ALL EQUIPMENT USED WHEN
HANDLING THE PRODUCT MUST BE GROUNDED. USE NON-SPARKING TOOLS AND
EXPLOSION-PROOF EQUIPMENT. DO NOT GET THIS MATERIAL IN CONTACT WITH EYES.
AVOID INHALATION OF VAPORS AND SPRAY MISTS. AVOID PROLONGED EXPOSURE. USE
ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR APPROPRIATE PERSONAL
PROTECTIVE EQUIPMENT. OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. PREVENT
ELECTROSTATIC CHARGE BUILD-UP BY USING COMMON BONDING AND GROUNDING
TECHNIQUES. STORE IN A COOL, DRY PLACE OUT OF DIRECT SUNLIGHT. STORE IN
ORIGINAL TIGHTLY CLOSED CONTAINER. STORE IN A WELL-VENTILATED PLACE. KEEP
IN AN AREA EQUIPPED WITH SPRINKLERS. STORE AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
THE FOLLOWING CONSTITUENTS ARE THE ONLY CONSTITUENTS OF THE PRODUCT WHICH
HAVE A PEL, TLV OR OTHER RECOMMENDED EXPOSURE LIMIT. AT THIS TIME, THE
OTHER CONSTITUENTS HAVE NO KNOWN EXPOSURE LIMITS.
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE FORM
1-PROPANOL (CAS 71-23-8) PEL 500 MG/M3
200 PPM
DIACETONE ALCOHOL (CAS 123-42-2) PEL 240 MG/M3
50 PPM
TITANIUM DIOXIDE (CAS 13463-67-7) PEL 15 MG/M3 TOTAL DUST.
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
1-PROPANOL (CAS 71-23-8) TWA 100 PPM
DIACETONE ALCOHOL (CAS 123-42-2) TWA 50 PPM
TITANIUM DIOXIDE (CAS 13463-67-7) TWA 10 MG/M3
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
1-PROPANOL (CAS 71-23-8) STEL 625 MG/M3
250 PPM
TWA 500 MG/M3
200 PPM
DIACETONE ALCOHOL (CAS 123-42-2) TWA 240 MG/M3
50 PPM
SILICA, AMORPHOUS (CAS 7631-86-9) TWA 6 MG/M3
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
EXPOSURE GUIDELINES:
US - CALIFORNIA OELS: SKIN DESIGNATION
1-PROPANOL (CAS 71-23-8): CAN BE ABSORBED THROUGH THE SKIN.
US - MINNESOTA HAZ SUBS: SKIN DESIGNATION APPLIES
1-PROPANOL (CAS 71-23-8): SKIN DESIGNATION APPLIES.
US NIOSH POCKET GUIDE TO CHEMICAL HAZARDS: SKIN DESIGNATION
1-PROPANOL (CAS 71-23-8): CAN BE ABSORBED THROUGH THE SKIN.
APPROPRIATE ENGINEERING CONTROLS:
EXPLOSION-PROOF GENERAL AND LOCAL EXHAUST VENTILATION. GOOD GENERAL
VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION
RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS
ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO
MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE
LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE
LEVEL. PROVIDE EYEWASH STATION.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION: WEAR APPROPRIATE CHEMICAL RESISTANT GLOVES.
OTHER: WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING.
RESPIRATORY PROTECTION:
USE A POSITIVE-PRESSURE AIR-SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL
FOR AN UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR ANY OTHER
CIRCUMSTANCES WHERE AIR-PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING DO NOT SMOKE. ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES,
SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE EATING, DRINKING,
AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO
REMOVE CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: LIQUID.
COLOR: VARIOUS.
ODOR: ALCOHOLIC.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: 207 DEG. F (97.22 DEG. C)
FLASH POINT: 77.0 DEG. F (25.0 DEG. C) TAG CLOSED CUP
EVAPORATION RATE: 1.3 (BUAC = 1)
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 2.1%
FLAMMABILITY LIMIT - UPPER (%): 13.7%
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: >1
RELATIVE DENSITY: <1 @ 70 DEG. F
SOLUBILITY(IES):
SOLUBILITY (WATER): 70 -80%
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
OTHER INFORMATION:
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
OXIDIZING PROPERTIES: NOT OXIDIZING.
VOC:
Z694 YELLOW: 49.22%, 568 G/L
Y371 GREEN: 91.25%, 750 G/L
Z146 WHITE: 49.16%, 564 G/L
Z985 BLACK: 88%, 791 G/L
X939 RED: 92.12%, 771 G/L
X938 BLUE: 89.65%, 737 G/L
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID:
AVOID HEAT, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. AVOID
TEMPERATURES EXCEEDING THE FLASH POINT. CONTACT WITH INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
HARMFUL IF INHALED. MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA,
VOMITING.
SKIN CONTACT: NO ADVERSE EFFECTS DUE TO SKIN CONTACT ARE EXPECTED.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. DIARRHEA.
SEVERE EYE IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS,
SWELLING, AND BLURRED VISION. PERMANENT EYE DAMAGE INCLUDING BLINDNESS
COULD RESULT.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: HARMFUL IF INHALED.
COMPONENTS SPECIES TEST RESULTS
1-PROPANOL (CAS 71-23-8):
ACUTE:
DERMAL:
LD50 RABBIT 4032 MG/KG, 24 HOURS
ORAL:
LD50 RAT 1870 MG/KG
ALUMINUM HYDROXIDE (CAS 21645-51-2):
ACUTE:
ORAL:
LD50 RAT >2000 MG/KG
DIACETONE ALCOHOL (CAS 123-42-2):
ACUTE:
DERMAL:
LD50 RAT >1875 MG/KG, 24 HOURS
ORAL:
LD50 RAT 3002 MG/KG
SILICA, AMORPHOUS (CAS 7631-86-9):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG, 24 HOURS
ORAL:
LD50 RAT >3300 MG/KG
TITANIUM DIOXIDE (CAS 13463-67-7):
ACUTE:
INHALATION:
LC50 RAT >2.28 MG/L, 4 HOURS
ORAL:
LD50 RAT >2000 MG/KG
SKIN CORROSION/IRRITATION:
PROLONGED SKIN CONTACT MAY CAUSE TEMPORARY IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE DAMAGE.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: RISK OF CANCER CANNOT BE EXCLUDED WITH PROLONGED EXPOSURE.
ACGIH CARCINOGENS:
1-PROPANOL (CAS 71-23-8): A4 NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
TITANIUM DIOXIDE (CAS 13463-67-7):
A4 NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
SILICA, AMORPHOUS (CAS 7631-86-9):
3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
TITANIUM DIOXIDE (CAS 13463-67-7): 2B POSSIBLY CARCINOGENIC TO HUMANS.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS: NOT LISTED.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS AND DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT AN ASPIRATION HAZARD.
CHRONIC EFFECTS:
PROLONGED INHALATION MAY BE HARMFUL. PROLONGED EXPOSURE MAY CAUSE CHRONIC
EFFECTS.
FURTHER INFORMATION: SYMPTOMS MAY BE DELAYED.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT CLASSIFIED AS ENVIRONMENTALLY HAZARDOUS. HOWEVER, THIS
DOES NOT EXCLUDE THE POSSIBILITY THAT LARGE OR FREQUENT SPILLS CAN HAVE A
HARMFUL OR DAMAGING EFFECT ON THE ENVIRONMENT.
COMPONENTS SPECIES TEST RESULTS
1-PROPANOL (CAS 71-23-8):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 3339 -3977 MG/L, 48 HOURS
FISH LC50 BLEAK (ALBURNUS ALBURNUS) 3000 -4000 MG/L, 96 HOURS
DIACETONE ALCOHOL (CAS 123-42-2):
AQUATIC:
FISH LC50 BLUEGILL (LEPOMIS 420 MG/L, 96 HOURS
MACROCHIRUS)
TITANIUM DIOXIDE (CAS 13463-67-7):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) >1000 MG/L, 48 HOURS
FISH LC50 MUMMICHOG (FUNDULUS >1000 MG/L, 96 HOURS
HETEROCLITUS)
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF ANY INGREDIENTS IN THE
MIXTURE.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
1-PROPANOL: 0.25
DIACETONE ALCOHOL: -0.098
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS: NONE KNOWN.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1263
UN PROPER SHIPPING NAME:
PAINT RELATED MATERIAL INCLUDING PAINT THINNING, DRYING, REMOVING, OR
REDUCING COMPOUND
TRANSPORT HAZARD CLASS(ES):
CLASS: 3
SUBSIDIARY RISK:
LABEL(S): 3
PACKING GROUP: III
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: B1, B52, IB3, T2, TP1, TP29
PACKAGING EXCEPTIONS: 150
PACKAGING NON BULK: 173
PACKAGING BULK: 242
IATA:
UN NUMBER: UN1263
UN PROPER SHIPPING NAME:
PAINT RELATED MATERIAL (INCLUDING PAINT THINNING OR REDUCING COMPOUNDS)
TRANSPORT HAZARD CLASS(ES):
CLASS: 3
SUBSIDIARY RISK:
PACKING GROUP: III
ENVIRONMENTAL HAZARDS: NO.
ERG CODE: 3L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED WITH RESTRICTIONS.
CARGO AIRCRAFT ONLY: ALLOWED WITH RESTRICTIONS.
IMDG:
UN NUMBER: UN1263
UN PROPER SHIPPING NAME:
PAINT (INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC, VARNISH, POLISH,
LIQUID FILLER AND LIQUID LACQUER BASE) OR PAINT RELATED MATERIAL (INCLUDING
PAINT THINNING OR REDUCING COMPOUND)
TRANSPORT HAZARD CLASS(ES):
CLASS: 3
SUBSIDIARY RISK:
PACKING GROUP: III
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO.
EMS: F-E, S-E
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT ESTABLISHED.
DOT: FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
IATA; IMDG: CLASS 3, FLAMMABLE LIQUIDS
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4): NOT LISTED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
CLASSIFIED HAZARD CATEGORIES:
FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
SERIOUS EYE DAMAGE OR EYE IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SARA 313 (TRI REPORTING): NOT REGULATED.
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FEMA PRIORITY SUBSTANCES RESPIRATORY HEALTH AND SAFETY IN THE FLAVOR
MANUFACTURING WORKPLACE: 1-PROPANOL (CAS 71-23-8): LOW PRIORITY
US STATE REGULATIONS:
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
1-PROPANOL (CAS 71-23-8)
DIACETONE ALCOHOL (CAS 123-42-2)
TITANIUM DIOXIDE (CAS 13463-67-7)
CALIFORNIA PROPOSITION 65:
WARNING:
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 2016
(PROPOSITION 65): THIS MATERIAL IS NOT KNOWN TO CONTAIN ANY CHEMICALS
CURRENTLY LISTED AS CARCINOGENS OR REPRODUCTIVE TOXINS.
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
TITANIUM DIOXIDE (CAS 13463-67-7)
INTERNATIONAL INVENTORIES:
COUNTRY(S) INVENTORY NAME ON INVENTORY
OR REGION (YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL NO
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) NO
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL NO
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING YES
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW NO
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) NO
NEW ZEALAND NEW ZEALAND INVENTORY NO
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS NO
AND CHEMICAL SUBSTANCES (PICCS)
TAIWAN TAIWAN TOXIC CHEMICAL SUBSTANCES NO
(TCS)
UNITED STATES TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
& PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 04-16-2018
VERSION #: 01
DISCLAIMER:
ITW PRO BRANDS CANNOT ANTICIPATE ALL CONDITIONS UNDER WHICH THIS
INFORMATION AND ITS PRODUCT, OR THE PRODUCTS OF OTHER MANUFACTURERS IN
COMBINATION WITH ITS PRODUCT, MAY BE USED. IT IS THE USER'S RESPONSIBILITY
TO ENSURE SAFE CONDITIONS FOR HANDLING, STORAGE AND DISPOSAL OF THE
PRODUCT, AND TO ASSUME LIABILITY FOR LOSS, INJURY, DAMAGE OR EXPENSE DUE TO
IMPROPER USE. THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT
TO THE BEST OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS
PUBLICATION. THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE
HANDLING, USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE
AND IS NOT TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE
INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE
VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN
ANY PROCESS, UNLESS SPECIFIED IN THE TEXT.
REVISION INFORMATION:
PRODUCT AND COMPANY IDENTIFICATION: ALTERNATE TRADE NAMES
COMPOSITION / INFORMATION ON INGREDIENTS: DISCLOSURE OVERRIDES
PHYSICAL & CHEMICAL PROPERTIES: MULTIPLE PROPERTIES
REGULATORY INFORMATION: CALIFORNIA PROPOSITION 65
MATERIAL NAME: DYKEM(R*) SUDZ OFF(R*) 44 - ALL COLORS
SDS US