| Common Name: | LOCTITE 518 VRM 6ML, 2096062 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 8/4/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 49CR92 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 001.0
ISSUE DATE: 08/04/2015
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE 518 VRM 6ML
PRODUCT TYPE: ANAEROBIC ADHESIVE
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 2096062
ITEM NUMBER: 2096062
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
WEAR EYE AND FACE PROTECTION. WEAR PROTECTIVE GLOVES.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: NOT PRESCRIBED
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
POLYURETHANE METHACRYLATE RESIN UNKNOWN 30 - 60
SUBSTITUTED HYDROXYALKYL METHACRYLATE PROPRIETARY 10 - 30
METHACRYLATE MONOMER PROPRIETARY 10 - 30
2-HYDROXYETHYL METHACRYLATE 868-77-9 5 - 10
SILICA, AMORPHOUS, FUMED, CRYSTAL-FREE 112945-52-5 5 - 10
SACCHARIN 81-07-2 1 - 5
POLYGLYCOL DIMETHACRYLATE PROPRIETARY 1 - 5
1-ACETYL-2-PHENYLHYDRAZINE 114-83-0 0.1 - 1
ACRYLIC ACID OLIGOMERS UNKNOWN 0.1 - 1
ACRYLIC ACID 79-10-7 0.1 - 1
METHACRYLIC ACID 79-41-4 0.1 - 1
*EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH CLOTHING BEFORE REUSE. GET
MEDICAL ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
UNCONTROLLED POLYMERIZATION MAY OCCUR AT HIGH TEMPERATURES RESULTING IN
EXPLOSIONS OR RUPTURE OF STORAGE CONTAINERS.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. IRRITATING ORGANIC VAPOURS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEANUP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA
GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP AS MUCH MATERIAL
AS POSSIBLE. STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL.
REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO
CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
KEEP CONTAINER CLOSED. REFER TO SECTION 8.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
POLYURETHANE METHACRYLATE NONE NONE NONE NONE
RESIN
SUBSTITUTED HYDROXYALKYL NONE NONE NONE NONE
METHACRYLATE
METHACRYLATE MONOMER NONE NONE NONE NONE
2-HYDROXYETHYL NONE NONE NONE 3 PPM
METHACRYLATE CEILING
SILICA, AMORPHOUS, 10 MG/M3 TWA 20 MPPCF TWA NONE NONE
FUMED, CRYSTAL-FREE INHALABLE 0.8 MG/M3 TWA
DUST.
3 MG/M3 TWA
RESPIRABLE
FRACTION.
SACCHARIN NONE NONE NONE NONE
POLYGLYCOL DIMETHACRYLATE NONE NONE NONE NONE
1-ACETYL-2- NONE NONE NONE NONE
PHENYLHYDRAZINE
ACRYLIC ACID OLIGOMERS NONE NONE NONE NONE
ACRYLIC ACID 2 PPM TWA NONE NONE 1 PPM
(SKIN) TWA
3 PPM
STEL
(SKIN)
METHACRYLIC ACID 20 PPM TWA NONE NONE NONE
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT. NEOPRENE GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID, GEL-LIKE
COLOR: RED
ODOR: MILD
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: >150 DEG. C (>302 DEG. 3)
MELTING POINT / RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.1
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: >100 DEG. C (>212 DEG. F) NO METHOD
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: <3%
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS:
NONE UNDER NORMAL PROCESSING. POLYMERIZATION MAY OCCUR AT ELEVATED
TEMPERATURE OR IN THE PRESENCE OF INCOMPATIBLE MATERIALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. IRRITATING ORGANIC VAPOURS.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. STRONG REDUCING AGENTS. FREE RADICAL INITIATORS.
ACIDS AND BASES. INERT GASES. OXYGEN SCAVENGERS. AMINES.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
ELEVATED TEMPERATURES. HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION.
STORE AWAY FROM INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF VAPORS OR MISTS OF THE PRODUCT MAY BE IRRITATING TO THE
RESPIRATORY SYSTEM.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
POLYURETHANE METHACRYLATE NONE IRRITANT, ALLERGEN
RESIN
SUBSTITUTED HYDROXYALKYL NONE IRRITANT, ALLERGEN
METHACRYLATE
METHACRYLATE MONOMER NONE NO RECORDS
2-HYDROXYETHYL ORAL LD50 (RAT): IRRITANT, ALLERGEN
METHACRYLATE 11.2 G/KG
ORAL LD50 (RAT):
5,050 MG/KG
SILICA, AMORPHOUS, FUMED, NONE NUISANCE DUST
CRYSTAL-FREE
SACCHARIN NONE NO TARGET ORGANS
POLYGLYCOL DIMETHACRYLATE NONE ALLERGEN, IRRITANT
1-ACETYL-2-PHENYLHYDRAZINE NONE ALLERGEN, BLOOD,
KIDNEY, MUTAGEN, SOME
EVIDENCE OF
CARCINOGENICITY
ACRYLIC ACID OLIGOMERS NONE IRRITANT, ALLERGEN
ACRYLIC ACID ORAL LD50 (RAT): ALLERGEN, CORROSIVE,
33.5 MG/KG IRRITANT, KIDNEY, LIVER
ORAL LD50 (RAT):
2.5 G/KG
ORAL LD50 (RAT):
193 MG/KG
ORAL LD50 (RAT):
1,250 MG/KG
INHALATION LC50
(RAT, 4 H):
1,200 MG/L
METHACRYLIC ACID ORAL LD50 (RABBIT): CORROSIVE, IRRITANT,
1,200 MG/KG ALLERGEN
ORAL LD50 (RAT):
1,060 MG/KG
ORAL LD50 (RAT):
2,224 MG/KG
DERMAL LD50 (RABBIT):
500 MG/KG
INHALATION LC50
(RAT, 4 H): 7.1 MG/L
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
POLYURETHANE METHACRYLATE NO NO NO
RESIN
SUBSTITUTED HYDROXYALKYL NO NO NO
METHACRYLATE
METHACRYLATE MONOMER NO NO NO
2-HYDROXYETHYL NO NO NO
METHACRYLATE
SILICA, AMORPHOUS, FUMED, NO NO NO
CRYSTAL-FREE
SACCHARIN NO NO NO
POLYGLYCOL DIMETHACRYLATE NO NO NO
1-ACETYL-2- NO NO NO
PHENYLHYDRAZINE
ACRYLIC ACID OLIGOMERS NO NO NO
ACRYLIC ACID NO NO NO
METHACRYLIC ACID NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372).
SACCHARIN (CAS# 81-07-2).
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO
CAUSE CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ONE OR MORE COMPONENTS ARE NOT LISTED ON, AND ARE NOT EXEMPT FROM LISTING
ON EITHER THE DOMESTIC SUBSTANCES LIST OR THE NON-DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: SHEILA GINES, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 08/04/2015
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.