| Common Name: | LPS COLD GALVANIZE, 05128 |
| Manufacturer: | ITW PRO BRANDS |
| SDS Revision Date: | 9/8/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 49CT34 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LPS(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: LPS(R*) COLD GALVANIZE
OTHER MEANS OF IDENTIFICATION:
PART NUMBER: 05128
RECOMMENDED USE:
A ZINC RICH INDUSTRIAL MAINTENANCE PRIMER DESIGNED FOR RUST AND CORROSION
PROTECTION.
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURER:
COMPANY NAME: ITW PRO BRANDS
ADDRESS:
4647 HUGH HOWELL RD.
TUCKER, GA 30084
COUNTRY: (U.S.A.)
TEL: +1 770-243-8800
IN CASE OF EMERGENCY:
1-800-424-9300 (INSIDE U.S.)
+001 703-527-3887 (OUTSIDE U.S.)
WEBSITE: WWW.LPSLABS.COM
E-MAIL: LPSSDS@ITWPROBRANDS.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE LIQUIDS: CATEGORY 2
HEALTH HAZARDS:
ACUTE TOXICITY, DERMAL: CATEGORY 4
ACUTE TOXICITY, INHALATION: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
SENSITIZATION, SKIN: CATEGORY 1B
CARCINOGENICITY: CATEGORY 2
REPRODUCTIVE TOXICITY: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE:
CATEGORY 1 (CENTRAL NERVOUS SYSTEM)
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE:
CATEGORY 2 (AUDITORY ORGAN, LUNG, KIDNEY)
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
HIGHLY FLAMMABLE LIQUID AND VAPOR. HARMFUL IN CONTACT WITH SKIN. HARMFUL IF
INHALED. CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE
AN ALLERGIC SKIN REACTION. SUSPECTED OF CAUSING CANCER. SUSPECTED OF
DAMAGING FERTILITY OR THE UNBORN CHILD. CAUSES DAMAGE TO ORGANS (CENTRAL
NERVOUS SYSTEM) THROUGH PROLONGED OR REPEATED EXPOSURE. MAY CAUSE DAMAGE TO
ORGANS (AUDITORY ORGAN, LUNG, KIDNEY) THROUGH PROLONGED OR REPEATED
EXPOSURE.
PRECAUTIONARY STATEMENT:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN
FLAMES/HOT SURFACES. - NO SMOKING. KEEP CONTAINER TIGHTLY CLOSED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT. USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. DO NOT BREATHE MIST
OR VAPOR. WASH THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN
USING THIS PRODUCT. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR
PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. CALL A POISON CENTER/DOCTOR IF YOU FEEL
UNWELL.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE REUSE.
IN CASE OF FIRE: USE APPROPRIATE MEDIA TO EXTINGUISH.
STORAGE: STORE IN A WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE KNOWN.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
METALLIC ZINC 7440-66-6 60 - 70
ACETONE 67-64-1 5 - 10
XYLENE 1330-20-7 1 - 10
ETHYLBENZENE 100-41-4 1 - 3
MINERAL SPIRITS 8052-41-3 1 - 3
REGULAR STODDARD
SOLVENT
ZINC OXIDE 1314-13-2 1 - 3
TOLUENE 108-88-3 0.1 - 1
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. CALL A POISON CENTER
OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN WITH SOAP AND WATER.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL. IN CASE OF ECZEMA OR OTHER
SKIN DISORDERS: SEEK MEDICAL ATTENTION AND TAKE ALONG THESE INSTRUCTIONS.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION: RINSE MOUTH. GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
NARCOSIS. BEHAVIORAL CHANGES. DECREASE IN MOTOR FUNCTIONS. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. COUGHING. DISCOMFORT IN THE CHEST. SHORTNESS OF BREATH.
SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN ALLERGIC SKIN
REACTION. DERMATITIS. RASH. EDEMA. PROLONGED EXPOSURE MAY CAUSE CHRONIC
EFFECTS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY.
THERMAL BURNS:
FLUSH WITH WATER IMMEDIATELY. WHILE FLUSHING, REMOVE CLOTHES WHICH DO NOT
ADHERE TO AFFECTED AREA. CALL AN AMBULANCE. CONTINUE FLUSHING DURING
TRANSPORT TO HOSPITAL. KEEP VICTIM WARM. KEEP VICTIM UNDER OBSERVATION.
SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
TAKE OFF ALL CONTAMINATED CLOTHING IMMEDIATELY. IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW
THE LABEL WHERE POSSIBLE). ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW THIS
SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. DRY CHEMICAL POWDER. DRY SAND. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR. VAPORS MAY TRAVEL CONSIDERABLE
DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. DURING FIRE, GASES
HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES. MOVE CONTAINERS FROM
FIRE AREA IF YOU CAN DO SO WITHOUT RISK.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS.
GENERAL FIRE HAZARDS: HIGHLY FLAMMABLE LIQUID AND VAPOR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR
FLAMES IN IMMEDIATE AREA). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
CLOTHING DURING CLEAN-UP. DO NOT BREATHE MIST OR VAPOR. DO NOT TOUCH
DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE
PROTECTIVE CLOTHING. VENTILATE CLOSED SPACES BEFORE ENTERING THEM. LOCAL
AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED.
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM
SPILLED MATERIAL. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. USE
ONLY NON-SPARKING TOOLS. THE PRODUCT IS IMMISCIBLE WITH WATER AND WILL
SPREAD ON THE WATER SURFACE. PREVENT ENTRY INTO WATERWAYS, SEWER, BASEMENTS
OR CONFINED AREAS.
LARGE SPILLS:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. DIKE THE SPILLED
MATERIAL, WHERE THIS IS POSSIBLE. USE A NON-COMBUSTIBLE MATERIAL LIKE
VERMICULITE, SAND OR EARTH TO SOAK UP THE PRODUCT AND PLACE INTO A
CONTAINER FOR LATER DISPOSAL. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH
WATER.
SMALL SPILLS:
ABSORB WITH EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL AND TRANSFER TO
CONTAINERS FOR LATER DISPOSAL. WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH,
FLEECE). CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. PUT MATERIAL IN
SUITABLE, COVERED, LABELED CONTAINERS. FOR WASTE DISPOSAL, SEE SECTION 13
OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT HANDLE, STORE OR OPEN
NEAR AN OPEN FLAME, SOURCES OF HEAT OR SOURCES OF IGNITION. PROTECT
MATERIAL FROM DIRECT SUNLIGHT. EXPLOSION-PROOF GENERAL AND LOCAL EXHAUST
VENTILATION. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES. ALL
EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE GROUNDED. USE NON-SPARKING
TOOLS AND EXPLOSION-PROOF EQUIPMENT. DO NOT BREATHE MIST OR VAPOR. AVOID
CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID PROLONGED EXPOSURE. WHEN
USING, DO NOT EAT, DRINK OR SMOKE. PREGNANT OR BREASTFEEDING WOMEN MUST NOT
HANDLE THIS PRODUCT. SHOULD BE HANDLED IN CLOSED SYSTEMS, IF POSSIBLE. USE
ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR APPROPRIATE PERSONAL
PROTECTIVE EQUIPMENT. WASH HANDS THOROUGHLY AFTER HANDLING. WASH
CONTAMINATED CLOTHING BEFORE REUSE. OBSERVE GOOD INDUSTRIAL HYGIENE
PRACTICES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. PREVENT
ELECTROSTATIC CHARGE BUILD-UP BY USING COMMON BONDING AND GROUNDING
TECHNIQUES. STORE IN A COOL, DRY PLACE OUT OF DIRECT SUNLIGHT. STORE IN
ORIGINAL TIGHTLY CLOSED CONTAINER. STORE IN A WELL-VENTILATED PLACE. KEEP
IN AN AREA EQUIPPED WITH SPRINKLERS. STORE AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
THE FOLLOWING CONSTITUENTS ARE THE ONLY CONSTITUENTS OF THE PRODUCT WHICH
HAVE A PEL, TLV OR OTHER RECOMMENDED EXPOSURE LIMIT. AT THIS TIME, THE
OTHER CONSTITUENTS HAVE NO KNOWN EXPOSURE LIMITS.
U.S. - OSHA:
COMPONENTS TYPE VALUE FORM
DISTILLATES PETROLEUM, PEL 5 MG/M3 OIL MIST
HYDROTREATED LIGHT
(CAS 64742-47-8)
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE FORM
ACETONE (CAS 67-64-1) PEL 2400 MG/M3
1000 PPM
ETHYLBENZENE PEL 435 MG/M3
(CAS 100-41-4) 100 PPM
MINERAL SPIRITS REGULAR PEL 2900 MG/M3
STODDARD SOLVENT 500 PPM
(CAS 8052-41-3)
XYLENE (CAS 1330-20-7) PEL 435 MG/M3
100 PPM
ZINC OXIDE PEL 5 MG/M3 RESPIRABLE FRACTION.
(CAS 1314-13-2) 5 MG/M3 FUME.
15 MG/M3 TOTAL DUST.
US. OSHA TABLE Z-2 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
TOLUENE (CAS 108-88-3) CEILING 300 PPM
TWA 200 PPM
ACGIH:
COMPONENTS TYPE VALUE FORM
DISTILLATES PETROLEUM, TWA 5 MG/M3 OIL MIST
HYDROTREATED LIGHT
(CAS 64742-47-8)
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE FORM
ACETONE (CAS 67-64-1) STEL 500 PPM
TWA 250 PPM
ETHYLBENZENE TWA 20 PPM
(CAS 100-41-4)
MINERAL SPIRITS REGULAR TWA 100 PPM
STODDARD SOLVENT
(CAS 8052-41-3)
TOLUENE (CAS 108-88-3) TWA 20 PPM
XYLENE (CAS 1330-20-7) STEL 150 PPM
TWA 100 PPM
ZINC OXIDE STEL 10 MG/M3 RESPIRABLE FRACTION.
(CAS 1314-13-2) TWA 2 MG/M3 RESPIRABLE FRACTION.
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE FORM
ACETONE (CAS 67-64-1) TWA 590 MG/M3
250 PPM
ETHYLBENZENE STEL 545 MG/M3
(CAS 100-41-4) 125 PPM
TWA 435 MG/M3
100 PPM
MINERAL SPIRITS REGULAR CEILING 1800 MG/M3
STODDARD SOLVENT TWA 350 MG/M3
(CAS 8052-41-3)
TOLUENE (CAS 108-88-3) STEL 560 MG/M3
150 PPM
TWA 375 MG/M3
100 PPM
ZINC OXIDE CEILING 15 MG/M3 DUST.
(CAS 1314-13-2)
STEL 10 MG/M3 FUME.
TWA 5 MG/M3 DUST.
5 MG/M3 FUME.
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING
TIME
ACETONE (CAS 67-64-1) 25 MG/L ACETONE URINE *
ETHYLBENZENE 0.15 G/G SUM OF CREATININE *
(CAS 100-41-4) MANDELIC ACID IN
AND URINE
PHENYLGLYOX-
YLIC ACID
TOLUENE 0.3 MG/G O-CRESOL, CREATININE *
(CAS 108-88-3) WITH IN
HYDROLYSIS URINE
0.03 MG/L TOLUENE URINE *
0.02 MG/L TOLUENE BLOOD *
XYLENE 1.5 G/G METHYLHIP- CREATININE *
(CAS 1330-20-7) PURIC ACIDS IN URINE
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
EXPOSURE GUIDELINES:
US - CALIFORNIA OELS: SKIN DESIGNATION
TOLUENE (CAS 108-88-3): CAN BE ABSORBED THROUGH THE SKIN.
US - MINNESOTA HAZ SUBS: SKIN DESIGNATION APPLIES
TOLUENE (CAS 108-88-3): SKIN DESIGNATION APPLIES.
APPROPRIATE ENGINEERING CONTROLS:
EXPLOSION-PROOF GENERAL AND LOCAL EXHAUST VENTILATION. GOOD GENERAL
VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION
RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS
ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO
MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE
LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE
LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER MUST BE AVAILABLE WHEN
HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION: WEAR APPROPRIATE CHEMICAL RESISTANT GLOVES.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON IS
RECOMMENDED.
RESPIRATORY PROTECTION:
CHEMICAL RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE AND FULL FACEPIECE.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
OBSERVE ANY MEDICAL SURVEILLANCE REQUIREMENTS. WHEN USING DO NOT SMOKE.
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER
HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: LIQUID.
COLOR: GREY.
ODOR: AROMATIC. HYDROCARBON-LIKE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
FLASH POINT: <73.4 DEG. F (<23.0 DEG. C)
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: >1 KPA @ 25 DEG. C
VAPOR DENSITY: >1 (AIR = 1)
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES):
SOLUBILITY (WATER): INSOLUBLE IN WATER
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: 3000 - 4500 CST
OTHER INFORMATION:
DENSITY: 18.97 G/CM3
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
OXIDIZING PROPERTIES: NOT OXIDIZING.
PERCENT VOLATILE: 25.7%
SPECIFIC GRAVITY: 2.27 @ 25 DEG. C
VOC:
335.5 G/L PER U.S. STATE AND FEDERAL ARCHITECTURAL COATING REGULATIONS.
CARB
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID:
AVOID HEAT, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. AVOID
TEMPERATURES EXCEEDING THE FLASH POINT. CONTACT WITH INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS: STRONG ACIDS. STRONG OXIDIZING AGENTS. HALOGENS.
HAZARDOUS DECOMPOSITION PRODUCTS:
IRRITATING AND/OR TOXIC FUMES AND GASES MAY BE EMITTED UPON THE PRODUCT'S
DECOMPOSITION.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
HARMFUL IF INHALED. MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR
REPEATED EXPOSURE BY INHALATION.
SKIN CONTACT:
HARMFUL IN CONTACT WITH SKIN. CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC
SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
NARCOSIS. BEHAVIORAL CHANGES. DECREASE IN MOTOR FUNCTIONS. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. COUGHING. DISCOMFORT IN THE CHEST. SHORTNESS OF BREATH.
SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN ALLERGIC SKIN
REACTION. DERMATITIS. RASH. EDEMA.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: HARMFUL IF INHALED. HARMFUL IN CONTACT WITH SKIN.
COMPONENTS SPECIES TEST RESULTS
ACETONE (CAS 67-64-1):
ACUTE:
DERMAL:
LD50 RABBIT >20 ML/KG, 24 HOURS
INHALATION:
VAPOR:
LC50 RAT 50.1 MG/L, 4 HOURS
ORAL:
LD50 RAT 9.1 ML/KG
DISTILLATES PETROLEUM, HYDROTREATED LIGHT (CAS 64742-47-8):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG
INHALATION:
VAPOR:
LC50 RAT >4.5 MG/L, 4 HOURS
ORAL:
LD50 RAT >5000 MG/KG
ETHYLBENZENE (CAS 100-41-4):
ACUTE:
DERMAL:
LD50 RABBIT 17.8 ML/KG, 24 HOURS
INHALATION:
VAPOR:
LC50 RAT 4000 PPM, 4 HOURS
ORAL:
LD50 RAT 3500 MG/KG
METALLIC ZINC (CAS 7440-66-6):
ACUTE:
INHALATION:
DUST:
LC50 RAT >5410 MG/M3, 4 HOURS
ORAL:
LD50 RAT 630 MG/KG
NAPHTHA, PETROLEUM, HYDROTREATED HEAVY (CAS 64742-48-9):
ACUTE:
DERMAL:
LD50 RABBIT >1900 MG/KG, 24 HOURS
INHALATION:
VAPOR:
LC50 RAT >4980 MG/M3, 4 HOURS
ORAL:
LD50 RAT 4820 MG/KG
TOLUENE (CAS 108-88-3):
ACUTE:
DERMAL:
LD50 RABBIT 14.1 ML/KG
INHALATION:
LC50 RAT 8000 PPM, 4 HOURS
ORAL:
LD50 RAT 2.6 G/KG
XYLENE (CAS 1330-20-7)
ACUTE:
DERMAL:
LD50 RABBIT >5000 ML/KG, 4 HOURS
INHALATION:
VAPOR:
LC50 RAT 6700 PPM, 4 HOURS
ORAL:
LD50 RAT 10 ML/KG
ZINC OXIDE (CAS 1314-13-2):
ACUTE:
DERMAL:
LD50 RAT >2000 MG/KG, 24 HOURS
INHALATION:
LC50 RAT >5700 MG/M3, 4 HOURS
ORAL:
LD50 RAT >5000 MG/KG
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: SUSPECTED OF CAUSING CANCER.
ACGIH CARCINOGENS:
ACETONE (CAS 67-64-1): A4 NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
ETHYLBENZENE (CAS 100-41-4):
A3 CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS.
TOLUENE (CAS 108-88-3): A4 NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
XYLENE (CAS 1330-20-7): A4 NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
ETHYLBENZENE (CAS 100-41-4): 2B POSSIBLY CARCINOGENIC TO HUMANS.
TOLUENE (CAS 108-88-3): 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
XYLENE (CAS 1330-20-7): 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT REGULATED.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS: NOT LISTED.
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. MAY CAUSE
DAMAGE TO ORGANS (AUDITORY ORGAN, LUNG, KIDNEY) THROUGH PROLONGED OR
REPEATED EXPOSURE.
ASPIRATION HAZARD: NOT AN ASPIRATION HAZARD.
CHRONIC EFFECTS:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. MAY CAUSE
DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. PROLONGED
INHALATION MAY BE HARMFUL. PROLONGED EXPOSURE MAY CAUSE CHRONIC EFFECTS.
FURTHER INFORMATION: SYMPTOMS MAY BE DELAYED.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT CLASSIFIED AS ENVIRONMENTALLY HAZARDOUS. HOWEVER, THIS
DOES NOT EXCLUDE THE POSSIBILITY THAT LARGE OR FREQUENT SPILLS CAN HAVE A
HARMFUL OR DAMAGING EFFECT ON THE ENVIRONMENT.
COMPONENTS SPECIES TEST RESULTS
ACETONE (CAS 67-64-1):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 10294 - 17704 MG/L, 48
HOURS
FISH LC50 RAINBOW TROUT, DONALDSON 4740 - 6330 MG/L, 96
TROUT (ONCORHYNCHUS HOURS
MYKISS)
DISTILLATES PETROLEUM, HYDROTREATED LIGHT (CAS 64742-47-8):
AQUATIC:
FISH LC50 RAINBOW TROUT, DONALDSON 2.9 MG/L, 96 HOURS
TROUT (ONCORHYNCHUS
MYKISS)
ETHYLBENZENE (CAS 100-41-4):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 1.37 - 4.4 MG/L, 48 HOURS
FISH LC50 FATHEAD MINNOW (PIMEPHALES 7.5 - 11 MG/L, 96 HOURS
PROMELAS)
METALLIC ZINC (CAS 7440-66-6):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 2.8 MG/L, 48 HOURS
FISH LC50 RAINBOW TROUT, DONALDSON 0.56 MG/L, 96 HOURS
TROUT (ONCORHYNCHUS
MYKISS)
TOLUENE (CAS 108-88-3):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 5.46 - 9.83 MG/L, 48 HOURS
FISH LC50 COHO SALMON, SILVER SALMON 8.11 MG/L, 96 HOURS
(ONCORHYNCHUS KISUTCH)
XYLENE (CAS 1330-20-7):
AQUATIC:
FISH LC50 BLUEGILL (LEPOMIS 7.711 - 9.591 MG/L, 96
MACROCHIRUS) HOURS
ZINC OXIDE (CAS 1314-13-2):
AQUATIC:
FISH LC50 FATHEAD MINNOW 2246 MG/L, 96 HOURS
(PIMEPHALES PROMELAS)
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
ACETONE: -0.24
ETHYLBENZENE: 3.15
MINERAL SPIRITS REGULAR STODDARD SOLVENT: 3.16 - 7.15
TOLUENE: 2.73
XYLENE: 3.12 - 3.2
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS: NONE KNOWN.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1263
UN PROPER SHIPPING NAME:
PAINT INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS, VARNISH,
POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE
TRANSPORT HAZARD CLASS(ES):
CLASS: 3
SUBSIDIARY RISK:
LABEL(S): 3
PACKING GROUP: II
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: 149, B52, IB2, T4, TP1, TP8, TP28
PACKAGING EXCEPTIONS: 150
PACKAGING NON BULK: 173
PACKAGING BULK: 242
IATA:
UN NUMBER: UN1263
UN PROPER SHIPPING NAME:
PAINT INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS, VARNISH,
POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE
TRANSPORT HAZARD CLASS(ES):
CLASS: 3
SUBSIDIARY RISK:
LABEL(S): 3
PACKING GROUP: II
ENVIRONMENTAL HAZARDS: YES
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED WITH RESTRICTIONS.
CARGO AIRCRAFT ONLY: ALLOWED WITH RESTRICTIONS.
IMDG:
UN NUMBER: UN1263
UN PROPER SHIPPING NAME:
PAINT INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS, VARNISH,
POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE (METALLIC ZINC), MARINE
POLLUTANT
TRANSPORT HAZARD CLASS(ES):
CLASS: 3
SUBSIDIARY RISK:
LABEL(S): 3
PACKING GROUP: II
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: YES
EMS: F-E, S-E
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT ESTABLISHED.
DOT: FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
IATA; IMDG: CLASS 3 - FLAMMABLE LIQUIDS
MARINE POLLUTANT: ENVIRONMENT
GENERAL INFORMATION: IMDG REGULATED MARINE POLLUTANT.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
ACETONE (CAS 67-64-1): LISTED.
ETHYLBENZENE (CAS 100-41-4): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
XYLENE (CAS 1330-20-7): LISTED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: YES
REACTIVITY HAZARD: YES
PRESSURE HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 311/312 HAZARDOUS CHEMICAL: YES
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
ETHYLBENZENE 100-41-4 2.56
XYLENE (MIXED ISOMERS) 1330-20-7 9.46
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
ETHYLBENZENE (CAS 100-41-4)
TOLUENE (CAS 108-88-3)
XYLENE (CAS 1330-20-7)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 2, ESSENTIAL CHEMICALS (21 CFR
1310.02(B) AND 1310.04(F)(2) AND CHEMICAL CODE NUMBER:
ACETONE (CAS 67-64-1): 6532
TOLUENE (CAS 108-88-3): 6594
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 1 & 2 EXEMPT CHEMICAL MIXTURES
(21 CFR 1310.12(C)):
ACETONE (CAS 67-64-1): 35%WV
TOLUENE (CAS 108-88-3): 35%WV
DEA EXEMPT CHEMICAL MIXTURES CODE NUMBER:
ACETONE (CAS 67-64-1): 6532
TOLUENE (CAS 108-88-3): 594
FEMA PRIORITY SUBSTANCES RESPIRATORY HEALTH AND SAFETY IN THE FLAVOR
MANUFACTURING WORKPLACE:
ACETONE (CAS 67-64-1): LOW PRIORITY
US STATE REGULATIONS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/CARCINOGENIC SUBSTANCE
ETHYLBENZENE (CAS 100-41-4):
LISTED: JUNE 11, 2004
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/DEVELOPMENTAL TOXIN
TOLUENE (CAS 108-88-3):
LISTED: JANUARY 1, 1991
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
ACETONE (CAS 67-64-1)
ETHYLBENZENE (CAS 100-41-4)
MINERAL SPIRITS REGULAR STODDARD SOLVENT (CAS 8052-41-3)
NAPHTHA, PETROLEUM, HYDROTREATED HEAVY (CAS 64742-48-9)
TOLUENE (CAS 108-88-3)
XYLENE (CAS 1330-20-7)
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 09-08-2016
VERSION #: 01
DISCLAIMER:
ITW PRO BRANDS CANNOT ANTICIPATE ALL CONDITIONS UNDER WHICH THIS
INFORMATION AND ITS PRODUCT, OR THE PRODUCTS OF OTHER MANUFACTURERS IN
COMBINATION WITH ITS PRODUCT, MAY BE USED. IT IS THE USER'S RESPONSIBILITY
TO ENSURE SAFE CONDITIONS FOR HANDLING, STORAGE AND DISPOSAL OF THE
PRODUCT, AND TO ASSUME LIABILITY FOR LOSS, INJURY, DAMAGE OR EXPENSE DUE TO
IMPROPER USE. THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT
TO THE BEST OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS
PUBLICATION. THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE
HANDLING, USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE
AND IS NOT TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE
INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE
VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN
ANY PROCESS, UNLESS SPECIFIED IN THE TEXT.
REVISION INFORMATION:
THIS DOCUMENT HAS UNDERGONE SIGNIFICANT CHANGES AND SHOULD BE REVIEWED IN
ITS ENTIRETY.
MATERIAL NAME: LPS(R*) COLD GALVANIZE
SDS: US