| Common Name: | SILICONE ULTRA 100% ALL PURPOSE SILICONE SEALANT WHITE |
| Manufacturer: | WHITE LIGHTNING PRODUCTS |
| SDS Revision Date: | 7/2/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 49LX54 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
WL09212
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME:
WHITE LIGHTNING(R*) SILICONE ULTRA 100% ALL PURPOSE SILICONE SEALANT WHITE
PRODUCT CODE: WL09212
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: LIQUID.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NOT APPLICABLE.
MANUFACTURER:
WHITE LIGHTNING PRODUCTS
101 WEST PROSPECT AVENUE
CLEVELAND, OHIO 44115
EMERGENCY TELEPHONE NUMBER OF THE COMPANY: (216) 566-2917
PRODUCT INFORMATION TELEPHONE NUMBER: (800) 241-5295
REGULATORY INFORMATION TELEPHONE NUMBER: (216) 566-2902
TRANSPORTATION EMERGENCY TELEPHONE NUMBER: (800) 424-9300
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
SKIN SENSITIZATION: CATEGORY 1
CARCINOGENICITY: CATEGORY 2
TOXIC TO REPRODUCTION (FERTILITY): CATEGORY 1B
TOXIC TO REPRODUCTION (UNBORN CHILD): CATEGORY 1B
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN TOXICITY:
85.4%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
SUSPECTED OF CAUSING CANCER.
PRECAUTIONARY STATEMENTS:
GENERAL:
READ LABEL BEFORE USE. KEEP OUT OF REACH OF CHILDREN. IF MEDICAL ADVICE IS
NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. USE PERSONAL PROTECTIVE
EQUIPMENT AS REQUIRED. WEAR PROTECTIVE GLOVES. AVOID BREATHING VAPOR.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER. FOR INDUSTRIAL USE ONLY.
PLEASE REFER TO THE SDS FOR ADDITIONAL INFORMATION. DO NOT TRANSFER
CONTENTS TO OTHER CONTAINERS FOR STORAGE.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS NUMBER/OTHER IDENTIFIERS:
INGREDIENT NAME % BY WEIGHT CAS NUMBER
METHYL ETHYL KETOXIME 2.6 96-29-7
TITANIUM DIOXIDE 1.0 13463-67-7
DIBUTYLTIN DILAURATE 0.5 77-58-7
OCTAMETHYLCYCLOTETRASILOXANE 0.5 556-67-2
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION. IF UNCONSCIOUS, PLACE
IN RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN
OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR
WAISTBAND. IN CASE OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE,
SYMPTOMS MAY BE DELAYED. THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER
MEDICAL SURVEILLANCE FOR 48 HOURS.
SKIN CONTACT:
WASH WITH PLENTY OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES.
WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING IT, OR
WEAR GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL
ATTENTION. IN THE EVENT OF ANY COMPLAINTS OR SYMPTOMS, AVOID FURTHER
EXPOSURE. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH
AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL
HAS BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL
QUANTITIES OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS
VOMITING MAY BE DANGEROUS. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO
BY MEDICAL PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO
THAT VOMIT DOES NOT ENTER THE LUNGS. GET MEDICAL ATTENTION. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN
RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN
AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION:
EXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SERIOUS
EFFECTS MAY BE DELAYED FOLLOWING EXPOSURE.
SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT: NO SPECIFIC DATA.
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
IN CASE OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY BE
DELAYED. THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL SURVEILLANCE
FOR 48 HOURS.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
NITROGEN OXIDES
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF THE
INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALISED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH
WATER AND MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE,
ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. APPROACH
RELEASE FROM UPWIND. PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR
CONFINED AREAS. WASH SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED
AS FOLLOWS. CONTAIN AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT
MATERIAL E.G. SAND, EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN
CONTAINER FOR DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13).
DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT
MATERIAL MAY POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). PERSONS
WITH A HISTORY OF SKIN SENSITIZATION PROBLEMS SHOULD NOT BE EMPLOYED IN ANY
PROCESS IN WHICH THIS PRODUCT IS USED. AVOID EXPOSURE - OBTAIN SPECIAL
INSTRUCTIONS BEFORE USE. AVOID EXPOSURE DURING PREGNANCY. DO NOT HANDLE
UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT GET IN
EYES OR ON SKIN OR CLOTHING. DO NOT INGEST. AVOID BREATHING VAPOR OR MIST.
IF DURING NORMAL USE THE MATERIAL PRESENTS A RESPIRATORY HAZARD, USE ONLY
WITH ADEQUATE VENTILATION OR WEAR APPROPRIATE RESPIRATOR. KEEP IN THE
ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE MADE FROM A COMPATIBLE
MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE. EMPTY CONTAINERS RETAIN
PRODUCT RESIDUE AND CAN BE HAZARDOUS. DO NOT REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. STORE
LOCKED UP. KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE.
CONTAINERS THAT HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT
UPRIGHT TO PREVENT LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE
APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
METHYL ETHYL KETOXIME AIHA WEEL (UNITED STATES, 10/2011).
SKIN SENSITIZER.
TWA: 10 PPM 8 HOURS.
TITANIUM DIOXIDE ACGIH TLV (UNITED STATES, 4/2014).
TWA: 10 MG/M3 8 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
DIBUTYLTIN DILAURATE ACGIH TLV (UNITED STATES, 4/2014).
ABSORBED THROUGH SKIN.
TWA: 0.1 MG/M3, (AS Sn) 8 HOURS.
STEL: 0.2 MG/M3, (AS Sn) 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
ABSORBED THROUGH SKIN.
TWA: 0.1 MG/M3, (AS Sn) 10 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 0.1 MG/M3, (AS Sn) 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
IF USER OPERATIONS GENERATE DUST, FUMES, GAS, VAPOR OR MIST, USE PROCESS
ENCLOSURES, LOCAL EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP
WORKER EXPOSURE TO AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY
LIMITS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE THAT
EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: SAFETY GLASSES WITH SIDE-SHIELDS.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A PROPERLY FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH
AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: NOT AVAILABLE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT: NOT AVAILABLE.
BOILING POINT: 305 DEG. C (581 DEG. F)
FLASH POINT:
CLOSED CUP: 94 DEG. C (201.2 DEG. F) [PENSKY-MARTENS CLOSED CUP]
EVAPORATION RATE: 0.24 (BUTYL ACETATE = 1)
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 1%
UPPER: 5%
VAPOR PRESSURE: 0 KPA (0 MMHg) [AT 20 DEG. C]
VAPOR DENSITY: 3 [AIR = 1]
RELATIVE DENSITY: 1.03
SOLUBILITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (ROOM TEMPERATURE): >0.07 CM2/S (>7 CST)
KINEMATIC (40 DEG. C (104 DEG. F)): >0.07 CM2/S (>7 CST)
AEROSOL PRODUCT:
HEAT OF COMBUSTION: 5.856 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
METHYL ETHYL KETOXIME LD50 ORAL RAT 930 MG/KG
DIBUTYLTIN DILAURATE LD50 ORAL RAT 175 MG/KG
OCTAMETHYLCYCLO- LC50 INHALATION RAT 36 G/M3 4 HOURS
TETRASILOXANE VAPOR
LD50 DERMAL RAT 1770 MG/KG
LD50 ORAL RAT 1540 MG/KG
IRRITATION/CORROSION:
PRODUCT/ RESULT SPECIES SCORE EXPOSURE OBSERVATION
INGREDIENT
NAME
METHYL ETHYL EYES: RABBIT 100 MICROLITERS
KETOXIME SEVERE
IRRITANT
TITANIUM SKIN: HUMAN 72 HOURS
DIOXIDE MILD IRRITANT 300 MICROGRAMS
INTERMITTENT
DIBUTYLTIN EYES: RABBIT 24 HOURS
DILAURATE MODERATE 100 MILLIGRAMS
IRRITANT
SKIN: RABBIT 500 MILLIGRAMS
SEVERE
IRRITANT
OCTAMETHYL- EYES: RABBIT 24 HOURS
CYCLOTETRA- MILD IRRITANT 500 MILLIGRAMS
SILOXANE
SKIN: RABBIT 24 HOURS
MILD IRRITANT 500 MILLIGRAMS
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
TITANIUM DIOXIDE 2B
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT AVAILABLE.
ASPIRATION HAZARD: NOT AVAILABLE.
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION:
EXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SERIOUS
EFFECTS MAY BE DELAYED FOLLOWING EXPOSURE.
SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT: NO SPECIFIC DATA.
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL:
ONCE SENSITIZED, A SEVERE ALLERGIC REACTION MAY OCCUR WHEN SUBSEQUENTLY
EXPOSED TO VERY LOW LEVELS.
CARCINOGENICITY:
SUSPECTED OF CAUSING CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL
OF EXPOSURE.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: MAY DAMAGE THE UNBORN CHILD.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: MAY DAMAGE FERTILITY.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 5222.3 MG/KG
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
METHYL ETHYL ACUTE LC50: FISH - PIMEPHALES 96 HOURS
KETOXIME 843000 (MICRO)G/L PROMELAS
FRESH WATER
TITANIUM DIOXIDE ACUTE LC50: FISH - FUNDULUS 96 HOURS
>1000000 (MICRO)G/L HETEROCLITUS
MARINE WATER
DIBUTYLTIN CHRONIC EC10: ALGAE - SCENEDESMUS 96 HOURS
DILAURATE >2 MG/L SUBSPICATUS
FRESH WATER
OCTAMETHYLCYCLO- CHRONIC NOEC: DAPHNIA - DAPHNIA 21 DAYS
TETRASILOXANE 1.7 TO 15 (MICRO)G/L MAGNA
FRESH WATER
CHRONIC NOEC: FISH - ONCORHYNCHUS 93 DAYS
4.4 (MICRO)G/L MYKISS - EGG
FRESH WATER
PERSISTENCE AND DEGRADABILITY: NOT AVAILABLE.
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
METHYL ETHYL KETOXIME 2.5 TO 5.8 LOW
TITANIUM DIOXIDE 352 LOW
DIBUTYLTIN DILAURATE 2.91 LOW
OCTAMETHYLCYCLOTETRASILOXANE 13400 HIGH
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING
EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. AVOID DISPERSAL OF
SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND
SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER NOT REGULATED. NOT REGULATED. NOT REGULATED.
UN PROPER SHIPPING NAME
TRANSPORT HAZARD
CLASS(ES)
PACKING GROUP
ENVIRONMENTAL HAZARDS NO. NO. NO.
ADDITIONAL INFORMATION SPECIAL SPECIAL SPECIAL
PROVISIONS: PROVISIONS: PROVISIONS:
NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
IATA IMDG
UN NUMBER NOT REGULATED. NOT REGULATED.
UN PROPER SHIPPING NAME
TRANSPORT HAZARD CLASS(ES)
PACKING GROUP
ENVIRONMENTAL HAZARDS NO. NO.
ADDITIONAL INFORMATION SPECIAL PROVISIONS: EMERGENCY SCHEDULES
NOT APPLICABLE (EMS): NOT APPLICABLE
SPECIAL PRECAUTIONS FOR USER:
MULTI-MODAL SHIPPING DESCRIPTIONS ARE PROVIDED FOR INFORMATIONAL PURPOSES
AND DO NOT CONSIDER CONTAINER SIZES. THE PRESENCE OF A SHIPPING DESCRIPTION
FOR A PARTICULAR MODE OF TRANSPORT (SEA, AIR, ETC.), DOES NOT INDICATE THAT
THE PRODUCT IS PACKAGED SUITABLY FOR THAT MODE OF TRANSPORT. ALL PACKAGING
MUST BE REVIEWED FOR SUITABILITY PRIOR TO SHIPMENT, AND COMPLIANCE WITH THE
APPLICABLE REGULATIONS IS THE SOLE RESPONSIBILITY OF THE PERSON OFFERING
THE PRODUCT FOR TRANSPORT. PEOPLE LOADING AND UNLOADING DANGEROUS GOODS
MUST BE TRAINED ON ALL OF THE RISKS DERIVING FROM THE SUBSTANCES AND ON ALL
ACTIONS IN CASE OF EMERGENCY SITUATIONS.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
STATE REGULATIONS:
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 3*
FLAMMABILITY 1
PHYSICAL HAZARDS 0
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON SDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK OF
THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS MAY BE
PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
NOTICE TO READER:
IT IS RECOMMENDED THAT EACH CUSTOMER OR RECIPIENT OF THIS SAFETY DATA SHEET
(SDS) STUDY IT CAREFULLY AND CONSULT RESOURCES, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THIS INFORMATION IS
PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE DATE
HEREIN. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. THE INFORMATION
PRESENTED HERE APPLIES ONLY TO THE PRODUCT AS SHIPPED. THE ADDITION OF ANY
MATERIAL CAN CHANGE THE COMPOSITION, HAZARDS AND RISKS OF THE PRODUCT.
REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN
VARIOUS LOCATIONS AND JURISDICTIONS. THE CUSTOMER/BUYER/USER IS RESPONSIBLE
TO ENSURE THAT HIS ACTIVITIES COMPLY WITH ALL COUNTRY, FEDERAL, STATE,
PROVINCIAL OR LOCAL LAWS. THE CONDITIONS FOR USE OF THE PRODUCT ARE NOT
UNDER THE CONTROL OF THE MANUFACTURER; THE CUSTOMER/BUYER/USER IS
RESPONSIBLE TO DETERMINE THE CONDITIONS NECESSARY FOR THE SAFE USE OF THIS
PRODUCT. THE CUSTOMER/BUYER/USER SHOULD NOT USE THE PRODUCT FOR ANY PURPOSE
OTHER THAN THE PURPOSE SHOWN IN THE APPLICABLE SECTION OF THIS SDS WITHOUT
FIRST REFERRING TO THE SUPPLIER AND OBTAINING WRITTEN HANDLING
INSTRUCTIONS. DUE TO THE PROLIFERATION OF SOURCES FOR INFORMATION SUCH AS
MANUFACTURER-SPECIFIC SDS, THE MANUFACTURER CANNOT BE RESPONSIBLE FOR SDSS
OBTAINED FROM ANY OTHER SOURCE.
DATE OF ISSUE/DATE OF REVISION: 7/2/2015.
DATE OF PREVIOUS ISSUE: 3/13/2015.
VERSION: 1.01