| Common Name: | FOOD ZONE SILICONE SEALANT - GRAY (CARTRIDGE) 14087 |
| Manufacturer: | CRC |
| SDS Revision Date: | 4/13/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 49LY05 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CRC(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: FOOD ZONE SILICONE SEALANT - GRAY (CARTRIDGE)
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: 14087
RECOMMENDED USE: SEALANT AND ADHESIVE
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURED OR SOLD BY:
COMPANY NAME: CRC INDUSTRIES, INC.
ADDRESS:
885 LOUIS DR.
WARMINSTER, PA 18974
US
TELEPHONE:
GENERAL INFORMATION: 215-674-4300
TECHNICAL ASSISTANCE: 800-521-3168
CUSTOMER SERVICE: 800-272-4620
24-HOUR EMERGENCY (CHEMTREC):
800-424-9300 (US)
703-527-3887 (INTERNATIONAL)
WEBSITE: WWW.CRCINDUSTRIES.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS: NOT CLASSIFIED.
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2B
CARCINOGENICITY: CATEGORY 2
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT, ACUTE HAZARD: CATEGORY 3
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 3
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENT:
CAUSES SKIN IRRITATION. CAUSES EYE IRRITATION. SUSPECTED OF CAUSING
CANCER. HARMFUL TO AQUATIC LIFE. HARMFUL TO AQUATIC LIFE WITH LONG
LASTING EFFECTS.
PRECAUTIONARY STATEMENT:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. USE WITH ADEQUATE VENTILATION.
OPEN DOORS AND WINDOWS OR USE OTHER MEANS TO ENSURE A FRESH AIR SUPPLY
DURING USE AND WHILE PRODUCT IS DRYING. IF YOU EXPERIENCE ANY SYMPTOMS
LISTED ON THIS LABEL, INCREASE VENTILATION OR LEAVE THE AREA. WASH HANDS
THOROUGHLY AFTER HANDLING. WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE
PROTECTION/FACE PROTECTION. AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE
REUSE.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
STORAGE:
KEEP CONTAINER TIGHTLY CLOSED. STORE IN A DRY PLACE. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL
REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION:
91.97% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN ACUTE HAZARDS TO
THE AQUATIC ENVIRONMENT. 91.97% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF
UNKNOWN LONG-TERM HAZARDS TO THE AQUATIC ENVIRONMENT.
WHEN EXPOSED TO WATER OR HUMID AIR, PRODUCT EVOLVES ACETIC ACID (HOAC).
WHEN HEATED TO TEMPERATURE ABOVE 300 DEG. F/150 DEG. C IN THE PRESENCE OF
AIR, PRODUCT MAY FORM FORMALDEHYDE VAPORS.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
POLYDIMETHYLSILOXANE, 70131-67-8 >=60
HYDROXY-TERMINATED
AMORPHOUS SILICA 7631-86-9 5 - 10
DISTILLATES (PETROLEUM), 64742-46-7 5 - 10
HYDROTREATED MIDDLE
POLYDIMETHYLSILOXANE 63148-62-9 5 - 10
IRON OXIDE 1309-37-1 3 - 5
ETHYLTRIACETOXYSILANE 17689-77-9 1 - 5
METHYLTRIACETOXYSILANE 4253-34-3 1 - 5
ALUMINUM 7429-90-5 1 - 3
TITANIUM DIOXIDE 13463-67-7 1 - 3
CARBON BLACK 1333-86-4 <1
SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION: MOVE TO FRESH AIR. GET MEDICAL ATTENTION IMMEDIATELY.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN WITH SOAP AND
WATER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
GET MEDICAL ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION: RINSE MOUTH. GET MEDICAL ATTENTION.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
IRRITATION OF EYES AND MUCOUS MEMBRANES. EXPOSED INDIVIDUALS MAY EXPERIENCE
EYE TEARING, REDNESS, AND DISCOMFORT. SKIN IRRITATION. MAY CAUSE REDNESS
AND PAIN.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. ENSURE THAT MEDICAL PERSONNEL ARE AWARE
OF THE MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
LARGE FIRES: DRY CHEMICAL, WATER SPRAY OR REGULAR FOAM.
SMALL FIRES: DRY CHEMICAL, CO2, OR WATER SPRAY.
UNSUITABLE EXTINGUISHING MEDIA: WATER.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED. WHEN HEATED TO
TEMPERATURE ABOVE 300 DEG. F/150 DEG. C IN THE PRESENCE OF AIR, PRODUCT
MAY FORM FORMALDEHYDE VAPORS. WHEN EXPOSED TO WATER OR HUMID AIR, PRODUCT
EVOLVES ACETIC ACID (HOAC).
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
COOL CONTAINERS EXPOSED TO HEAT WITH WATER SPRAY AND REMOVE CONTAINER, IF
NO RISK IS INVOLVED.
GENERAL FIRE HAZARDS: NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. USE A POSITIVE-PRESSURE AIR-SUPPLIED
RESPIRATOR IF THERE IS ANY POTENTIAL FOR AN UNCONTROLLED RELEASE, EXPOSURE
LEVELS ARE NOT KNOWN, OR ANY OTHER CIRCUMSTANCES WHERE AIR-PURIFYING
RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION. WEAR APPROPRIATE
PROTECTIVE EQUIPMENT AND CLOTHING DURING CLEAN-UP. DO NOT TOUCH DAMAGED
CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE
CLOTHING. ENSURE ADEQUATE VENTILATION. LOCAL AUTHORITIES SHOULD BE ADVISED
IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL PROTECTION,
SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS OR FLAMES IN
IMMEDIATE AREA). STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK.
COLLECT SPILLAGE. SHOVEL UP AND PLACE IN A CONTAINER FOR SALVAGE OR
DISPOSAL. PREVENT ENTRY INTO WATERWAYS, SEWER, BASEMENTS OR CONFINED
AREAS. FINAL CLEANING MAY REQUIRE USE OF STEAM, SOLVENTS OR DETERGENTS.
DISPOSE OF SATURATED ABSORBENT OR CLEANING MATERIALS APPROPRIATELY, SINCE
SPONTANEOUS HEATING MAY OCCUR.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. CONTACT LOCAL AUTHORITIES IN CASE OF
SPILLAGE TO DRAIN/AQUATIC ENVIRONMENT. PREVENT FURTHER LEAKAGE OR SPILLAGE
IF SAFE TO DO SO. DO NOT CONTAMINATE WATER. AVOID DISCHARGE INTO DRAINS,
WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING VAPOR. AVOID
CONTACT WITH SKIN. AVOID CONTACT WITH EYES. PROVIDE ADEQUATE VENTILATION.
WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. WASH HANDS THOROUGHLY
AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. DO NOT EMPTY INTO DRAINS.
OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES. FOR PRODUCT USAGE INSTRUCTIONS,
PLEASE SEE THE PRODUCT LABEL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN A COOL, DRY PLACE OUT OF DIRECT SUNLIGHT. STORE AWAY FROM
INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE FORM
ALUMINUM PEL 5 MG/M3 RESPIRABLE DUST.
(CAS 7429-90-5) 15 MG/M3 TOTAL DUST.
CARBON BLACK PEL 3.5 MG/M3
(CAS 1333-86-4)
DISTILLATES (PETROLEUM), PEL 5 MG/M3 MIST.
HYDROTREATED MIDDLE
(CAS 64742-46-7)
IRON OXIDE PEL 10 MG/M3 FUME.
(CAS 1309-37-1)
TITANIUM DIOXIDE PEL 15 MG/M3 TOTAL DUST.
(CAS 13463-67-7)
US. OSHA TABLE Z-3 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
AMORPHOUS SILICA TWA 0.8 MG/M3
(CAS 7631-86-9) 20 MPPCF
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE FORM
ALUMINUM TWA 1 MG/M3 RESPIRABLE FRACTION.
(CAS 7429-90-5)
CARBON BLACK TWA 3 MG/M3 INHALABLE FRACTION.
(CAS 1333-86-4)
DISTILLATES (PETROLEUM), TWA 5 MG/M3 INHALABLE FRACTION.
HYDROTREATED MIDDLE
(CAS 64742-46-7)
IRON OXIDE TWA 5 MG/M3 RESPIRABLE FRACTION.
(CAS 1309-37-1)
TITANIUM DIOXIDE TWA 10 MG/M3
(CAS 13463-67-7)
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE FORM
ALUMINUM TWA 5 MG/M3 WELDING FUME OR
(CAS 7429-90-5) PYROPHORIC POWDER.
5 MG/M3 RESPIRABLE.
10 MG/M3 TOTAL
AMORPHOUS SILICA TWA 6 MG/M3
(CAS 7631-86-9)
CARBON BLACK TWA 0.1 MG/M3
(CAS 1333-86-4)
DISTILLATES (PETROLEUM), STEL 10 MG/M3 MIST.
HYDROTREATED MIDDLE
(CAS 64742-46-7) TWA 5 MG/M3 MIST.
IRON OXIDE TWA 5 MG/M3 DUST AND FUME.
(CAS 1309-37-1)
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
EXPOSURE GUIDELINES:
OCCUPATIONAL EXPOSURE LIMITS ARE NOT RELEVANT TO THE CURRENT PHYSICAL FORM
OF THE PRODUCT.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER MUST BE
AVAILABLE WHEN HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION:
WEAR PROTECTIVE GLOVES SUCH AS: NITRILE. BUTYL RUBBER.
OTHER: WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS ARE NOT FEASIBLE OR IF EXPOSURE EXCEEDS THE
APPLICABLE EXPOSURE LIMITS, USE A NIOSH-APPROVED CARTRIDGE RESPIRATOR WITH
AN ORGANIC VAPOR CARTRIDGE. USE A SELF-CONTAINED BREATHING APPARATUS IN
CONFINED SPACES AND FOR EMERGENCIES. AIR MONITORING IS NEEDED TO DETERMINE
ACTUAL EMPLOYEE EXPOSURE LEVELS.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
KEEP AWAY FROM FOOD AND DRINK. ALWAYS OBSERVE GOOD PERSONAL HYGIENE
MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE EATING,
DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND PROTECTIVE
EQUIPMENT TO REMOVE CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: SOLID.
FORM: PASTE.
COLOR: GRAY.
ODOR: ACETIC ACID.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: 680 DEG. F (360 DEG. C) ESTIMATED
FLASH POINT: >212 DEG. F (>100 DEG. C) TAG CLOSED CUP
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE.
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: 405.5 HPA ESTIMATED
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: 1.01
SOLUBILITY (WATER): NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 500 DEG. F (260 DEG. C) ESTIMATED
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY (KINEMATIC): NOT AVAILABLE.
PERCENT VOLATILE: <3%
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
HEAT, FLAMES AND SPARKS. AVOID TEMPERATURES EXCEEDING THE FLASH POINT.
CONTACT WITH INCOMPATIBLE MATERIALS. WHEN EXPOSED TO WATER OR HUMID AIR,
PRODUCT EVOLVES ACETIC ACID (HOAC). WHEN HEATED TO TEMPERATURE ABOVE
300 DEG. F/150 DEG. C IN THE PRESENCE OF AIR, PRODUCT MAY FORM FORMALDEHYDE
VAPORS.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. MOIST AIR. WATER, MOISTURE.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON OXIDES. TRACES OF INCOMPLETELY BURNED CARBON COMPOUNDS. SILICONE
DIOXIDE. FORMALDEHYDE. METAL OXIDES. NITROGEN OXIDES (NOX). SULFUR OXIDES.
CHLORINE COMPOUNDS.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
INHALATION OF FUMES MAY RESULT IN METAL FUME FEVER, A FLU-LIKE ILLNESS
WITH SYMPTOMS OF METALLIC TASTE, FEVER AND CHILLS, ACHES, CHEST TIGHTNESS,
AND COUGH.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES EYE IRRITATION.
INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EXPOSED INDIVIDUALS MAY EXPERIENCE EYE TEARING, REDNESS, AND DISCOMFORT.
SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT AVAILABLE.
PRODUCT SPECIES TEST RESULTS
FOOD ZONE SILICONE SEALANT - GRAY (CARTRIDGE):
ACUTE:
DERMAL:
LD50 RABBIT 28341 MG/KG ESTIMATED
INHALATION:
LC50 RABBIT 370 MG/L, 4 HOURS ESTIMATED
ORAL:
LD50 RAT 22638 MG/KG ESTIMATED
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES EYE IRRITATION.
RESPIRATORY SENSITIZATION: NOT AVAILABLE.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: SUSPECTED OF CAUSING CANCER.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
AMORPHOUS SILICA (CAS 7631-86-9):
3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
CARBON BLACK (CAS 1333-86-4): 2B POSSIBLY CARCINOGENIC TO HUMANS.
IRON OXIDE (CAS 1309-37-1) 3:
NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT LIKELY, DUE TO THE FORM OF THE PRODUCT.
CHRONIC EFFECTS: PROLONGED EXPOSURE MAY CAUSE CHRONIC EFFECTS.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS. ACCUMULATION IN AQUATIC
ORGANISMS IS EXPECTED.
PRODUCT SPECIES TEST RESULTS
FOOD ZONE SILICONE SEALANT - GRAY (CARTRIDGE):
AQUATIC:
FISH LC50 FISH 95.0028 MG/L,
96 HOURS ESTIMATED
COMPONENTS SPECIES TEST RESULTS
ALUMINUM (CAS 7429-90-5):
AQUATIC:
FISH LC50 RAINBOW TROUT, DONALDSON 0.16 MG/L, 96 HOURS
TROUT (ONCORHYNCHUS MYKISS)
POLYDIMETHYLSILOXANE (CAS 63148-62-9):
AQUATIC:
FISH LC50 CHANNEL CATFISH 2.36 - 4.15 MG/L,
(ICTALURUS PUNCTATUS) 96 HOURS
TITANIUM DIOXIDE (CAS 13463-67-7):
ACUTE:
OTHER EC50 PSEUDOKIRCHNERELLA 5.83 MG/L, 72 HOURS
SUBCAPITATA
CHRONIC:
OTHER NOEC PSEUDOKIRCHNERELLA 0.984 MG/L, 72 HOURS
SUBCAPITATA
AQUATIC:
ACUTE:
CRUSTACEA LC50 CERIODAPHNIA DUBIA 3 MG/L, 48 HOURS
WATER FLEA (DAPHNIA MAGNA) 5.5 PPM, 48 HOURS
FISH LC50 FATHEAD MINNOW 1000 MG/L, 96 HOURS
(PIMEPHALES PROMELAS)
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
BIOCONCENTRATION FACTOR (BCF):
TITANIUM DIOXIDE: 352
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL OF WASTE FROM RESIDUES / UNUSED PRODUCTS:
THIS PRODUCT, IN ITS PRESENT STATE, WHEN DISCARDED OR DISPOSED OF, IS NOT
A HAZARDOUS WASTE ACCORDING TO FEDERAL REGULATIONS (40 CFR 261.4 (B)(4)).
UNDER RCRA, IT IS THE RESPONSIBILITY OF THE USER OF THE PRODUCT TO
DETERMINE, AT THE TIME OF DISPOSAL, WHETHER THE PRODUCT MEETS RCRA CRITERIA
FOR HAZARDOUS WASTE. CONSULT AUTHORITIES BEFORE DISPOSAL. DO NOT ALLOW THIS
MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES. DO NOT CONTAMINATE PONDS,
WATERWAYS OR DITCHES WITH CHEMICAL OR USED CONTAINER. DISPOSE IN ACCORDANCE
WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE: NOT REGULATED.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED AS DANGEROUS GOODS.
IATA: NOT REGULATED AS DANGEROUS GOODS.
IMDG: NOT REGULATED AS DANGEROUS GOODS.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
ALL COMPONENTS ARE ON THE U.S. EPA TSCA INVENTORY LIST.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL LISTED SUBSTANCE
NOT LISTED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4): NOT LISTED.
CERCLA HAZARDOUS SUBSTANCES REPORTABLE QUANTITY
NOT LISTED.
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS
RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
SECTION 311/312 HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
US STATE REGULATIONS:
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
CARBON BLACK (CAS 1333-86-4)
TITANIUM DIOXIDE (CAS 13463-67-7)
ALUMINUM (CAS 7429-90-5)
DISTILLATES (PETROLEUM), HYDROTREATED MIDDLE (CAS 64742-46-7)
US. CALIFORNIA CONTROLLED SUBSTANCES. CA DEPARTMENT OF JUSTICE
(CALIFORNIA HEALTH AND SAFETY CODE SECTION 11100): NOT LISTED.
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
CARBON BLACK (CAS 1333-86-4)
IRON OXIDE (CAS 1309-37-1)
TITANIUM DIOXIDE (CAS 13463-67-7)
ALUMINUM (CAS 7429-90-5)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
ALUMINUM (CAS 7429-90-5)
AMORPHOUS SILICA (CAS 7631-86-9)
TITANIUM DIOXIDE (CAS 13463-67-7)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
ALUMINUM (CAS 7429-90-5)
AMORPHOUS SILICA (CAS 7631-86-9)
CARBON BLACK (CAS 1333-86-4)
DISTILLATES (PETROLEUM), HYDROTREATED MIDDLE (CAS 64742-46-7)
IRON OXIDE (CAS 1309-37-1)
TITANIUM DIOXIDE (CAS 13463-67-7)
US. RHODE ISLAND RTK: NONE.
US. CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
US - CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/CARCINOGENIC SUBSTANCE
CARBON BLACK (CAS 1333-86-4) LISTED: FEBRUARY 21, 2003
VOLATILE ORGANIC COMPOUNDS (VOC) REGULATIONS:
EPA:
VOC CONTENT (40 CFR 51.100(S)): <3%
CONSUMER PRODUCTS (40 CFR 59, SUBPT. C): NOT REGULATED
STATE:
CONSUMER PRODUCTS:
THIS PRODUCT IS REGULATED AS A SEALANT AND CAULKING COMPOUND (CHEMICALLY
CURING, NON-AEROSOL).
THIS PRODUCT IS COMPLIANT FOR USE IN ALL 50 STATES.
VOC CONTENT (CA): <3%
VOC CONTENT (OTC): <3%
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL YES
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL YES
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING NO
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW NO
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS YES
AND CHEMICAL SUBSTANCES (PICCS)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 04-13-2015
PREPARED BY: ALLISON CHO
VERSION #: 01
FURTHER INFORMATION: NOT AVAILABLE.
HMIS(R*) RATINGS:
HEALTH 1*
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
NFPA RATINGS:
HEALTH 1
FLAMMABILITY 1
INSTABILITY 0
NFPA RATINGS:
1
1
0
DISCLAIMER:
CRC CANNOT ANTICIPATE ALL CONDITIONS UNDER WHICH THIS INFORMATION AND ITS
PRODUCT, OR THE PRODUCTS OF OTHER MANUFACTURERS IN COMBINATION WITH ITS
PRODUCT, MAY BE USED. IT IS THE USER'S RESPONSIBILITY TO ENSURE SAFE
CONDITIONS FOR HANDLING, STORAGE AND DISPOSAL OF THE PRODUCT, AND TO ASSUME
LIABILITY FOR LOSS, INJURY, DAMAGE OR EXPENSE DUE TO IMPROPER USE. THE
INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC MATERIAL
AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED IN
COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO THE
BEST OF CRC INDUSTRIES' KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY CRC
TO BE ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND DIRECTIONS
ON THE LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION CONTAINED ON
THIS (M)SDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY PROFESSIONAL, OR
CRC INDUSTRIES.
MATERIAL NAME: FOOD ZONE SILICONE SEALANT - GRAY (CARTRIDGE)
SDS US