| Common Name: | HEAVY DUTY DEGREASER |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 12/16/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 49NW12, 49NW15, 49NW17 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
DATE ISSUED: 06/01/2016
SDS NO:
W.W. GRAINGER INC.
HEAVY DUTY DEGREASER
DATE REVISED: 12/16/2021
REVISION NO: 1
HEAVY DUTY DEGREASER
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: HEAVY DUTY DEGREASER
GENERAL USE: CLEANS MODERATE INDUSTRIAL SOILS AND GREASE.
PRODUCT DESCRIPTION: GENERAL PURPOSE CLEANER
CHEMICAL FAMILY: SOLVENT/DETERGENT BLEND
24 HR. EMERGENCY TELEPHONE NUMBERS:
CHEM-TEL (MEDICAL AND TRANSPORTATION): 800-255-3924
POISON CONTROL CENTER (MEDICAL): 800-222-1222
| 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATIONS:
HEALTH:
EYE IRRITATION, CATEGORY 2A
SKIN IRRITATION, CATEGORY 2
GHS LABEL: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
H319: CAUSES SERIOUS EYE IRRITATION.
H315: CAUSES SKIN IRRITATION.
H303: MAY BE HARMFUL IF SWALLOWED.
PRECAUTIONARY STATEMENT(S):
PREVENTION:
P262: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P102: KEEP OUT OF REACH OF CHILDREN.
P273: AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE:
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P362: TAKE OFF CONTAMINATED CLOTHING.
P301 + P312:
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
STORAGE:
P404: STORE IN A CLOSED CONTAINER.
DISPOSAL:
P501:
DISPOSE OF CONTENTS/CONTAINER ACCORDING TO ALL LOCAL, STATE AND FEDERAL
REGULATIONS.
EMERGENCY OVERVIEW:
PHYSICAL APPEARANCE: ORANGE LIQUID
IMMEDIATE CONCERNS: EYE & SKIN IRRITANT
POTENTIAL HEALTH EFFECTS:
EYES: IRRITATING, AND MAY INJURE EYE TISSUE IF NOT REMOVED PROMPTLY.
SKIN: SKIN IRRITANT WITH PROLONGED OR REPEATED CONTACT.
SKIN ABSORPTION: NONE EXPECTED.
INGESTION:
ALTHOUGH OF MODERATE TO LOW TOXICITY, INGESTION CAN CAUSE GASTROINTESTINAL
IRRITATION, NAUSEA, VOMITING, DIARRHEA, AND POSSIBLE DEATH.
INHALATION: MIST IS IRRITATING TO NOSE, THROAT AND LUNGS.
REPRODUCTIVE TOXICITY:
TERATOGENIC EFFECTS: NONE KNOWN.
CARCINOGENICITY: NO LISTED SUBSTANCE
MUTAGENICITY: NONE KNOWN.
MEDICAL CONDITIONS AGGRAVATED:
PREVIOUS SKIN CONDITIONS SUCH AS DERMATITIS MAY BE AGGREVATED.
ROUTES OF ENTRY: EYE, SKIN, INGESTION.
CANCER STATEMENT: NONE
WARNING CAUTION LABELS: IRRITANT
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
CHEMICAL NAME WT.% CAS
NONOXYNOL 0 - 5 127087-87-0
DIETHYLHEXYL SODIUM SULFOSUCCINATE 0 - 5 577-11-7
DISODIUM LAURYL PHENYL ETHER DISULFONATE 0 - 5 119345-04-9
SODIUM METASILICATE 0 - 2 6834-92-0
DIPROPYLENE GLYCOL METHYL ETHER 0 - 5 34590-94-8
FRAGRANCE 0 - 1 TS
DYE 0 - 0.05 TS
WATER 85 - 90 7732-18-5
COMMENTS:
IF CAS NUMBER IS "TS", THE SPECIFIC CHEMICAL IDENTITY HAS BEEN WITHHELD
AS A TRADE SECRET.
| 4. FIRST AID MEASURES | |
EYES:
IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES, WHILE HOLDING
EYELIDS OPEN. REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST
5 MINUTES, THEN CONTINUE RINSING EYE. SEEK MEDICAL ATTENTION IMMEDIATELY.
SKIN:
WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR
PERSISTS.
INGESTION:
GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING UNLESS INSTRUCTED
TO DO SO BY POISON CENTER OR PHYSICIAN.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND MONITOR. SEEK MEDICAL ADVISE IF IRRITATION
PERSISTS.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
EYES: BURNING SENSATION WITH TEARING, REDNESS.
SKIN:
PROLONGED CONTACT WILL CAUSE IRRITATION MARKED BY REDNESS, BURNING
SENSATION.
SKIN ABSORPTION: NOT ESTABLISHED
INGESTION:
IRRITATION OF MOUTH, THROAT, ALONG WITH STOMACH UPSET, VOMITING.
INHALATION:
IRRITATION OF NOSE, THROAT AND LUNGS WITH COUGHING, SNEEZING, POSSIBLE
DIFFICULTY BREATHING.
ACUTE EFFECTS: NOT ESTABLISHED
| 5. FIRE FIGHTING MEASURES | |
FLAMMABLE CLASS:
NA = NOT APPLICABLE
GENERAL HAZARD:
NA = NOT APPLICABLE
EXTINGUISHING MEDIA: NOT REQUIRED. WATER BASED MATERIAL.
| 6. ACCIDENTAL RELEASE MEASURES | |
SMALL SPILL:
AVOID WALKING IN PRODUCT. WIPE UP OR OTHERWISE FLUSH SMALL SPILLS TO
SANITARY SEWER.
LARGE SPILL:
AVOID WALKING IN MATERIAL. PREVENT PRODUCT FROM ENTERING INTO STREAM,
SOIL, STORM SEWER OR OTHER BODIES OF WATER.
ENVIRONMENTAL PRECAUTIONS:
WATER SPILL:
AVOID DISCHARGES INTO OPEN WATERWAYS AND NOTIFY YOUR LOCAL EMERGENCY
SERVICES IF THIS OCCURS.
LAND SPILL: AVOID DISCHARGE TO SOIL.
GENERAL PROCEDURES:
ISOLATE SPILL OR LEAK AREA IMMEDIATELY. KEEP UNAUTHORIZED PERSONNEL
AWAY. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. PREVENT ENTRY INTO
WATERWAYS, SEWERS, OR CONFINED AREAS. ABSORB WITH DRY EARTH, SAND OR
OTHER NON-COMBUSTIBLE MATERIAL AND TRANSFER TO CONTAINERS.
SPECIAL PROTECTIVE EQUIPMENT:
EYE PROTECTION, RUBBER GLOVES, RUBBER BOOTS TO PROTECT FEET.
| 7. HANDLING AND STORAGE | |
GENERAL PROCEDURES: CLOSE CONTAINER AFTER USE.
HANDLING: WEAR EYE PROTECTION, RUBBER GLOVES WHEN HANDLING CONCENTRATE.
STORAGE: STORE IN AREA INACCESSIBLE TO CHILDREN.
STORAGE TEMPERATURE: STORE AT AMBIENT TEMPERATURES.
STORAGE PRESSURE: STORE AT AMBIENT ATMOSPHERIC PRESSURE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200):
EXPOSURE LIMITS:
CHEMICAL NAME TYPE PPM MG/M3
DIPROPYLENE GLYCOL METHYL ETHER OSHA PEL TWA 100 600
ACGIH TLV TWA 100 606
STEL 150 909
ENGINEERING CONTROLS: NO SPECIAL REQUIREMENTS.
PERSONAL PROTECTIVE EQUIPMENT:
EYES AND FACE: CHEMICAL SPLASH GOGGLES AND FULL FACE-SHIELD.
SKIN: RUBBER OR OTHER CHEMICAL RESISTANT GLOVES.
RESPIRATORY:
A RESPIRATOR IS NOT NEEDED UNDER NORMAL AND INTENDED CONDITIONS OF PRODUCT
USE.
PROTECTIVE CLOTHING:
CHEMICAL RESISTANT OUTERWEAR (TYVEK) IF CONTACT WITH SPRAY OR MIST IS
ANTICIPATED.
WORK HYGIENIC PRACTICES:
WASH WITH SOAP AND WATER AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHILE
USING PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
ODOR: CITRUS
COLOR: ORANGE
PH: 11.5 TO 12.0
PERCENT VOLATILE: 85+
FLASH POINT AND METHOD: NONE
LOWER EXPLOSION LIMIT: N/A
AUTOIGNITION TEMPERATURE:
NA = NOT APPLICABLE
VAPOR PRESSURE: </=20 MMHg AT (68 DEG. F)
VAPOR DENSITY: </=1 AIR = 1
BOILING POINT: APPROX. 100 DEG. C (212 DEG. F)
FREEZING POINT: APPROX. 0 DEG. C (32 DEG. F)
MELTING POINT: NOT AVAILABLE
SOLUBILITY IN WATER: COMPLETE
EVAPORATION RATE: (WATER = 1) 1.0
DENSITY: 8.41 AT (68 DEG. F)
SPECIFIC GRAVITY: 1.008 GRAMS/ML.
VISCOSITY: WATER THIN.
(VOC): 4.75% BY WEIGHT
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: STABLE
HAZARDOUS POLYMERIZATION: NO
CONDITIONS TO AVOID: NOT ESTABLISHED
POSSIBILITY OF HAZARDOUS REACTIONS: NONE EXPECTED.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN.
INCOMPATIBLE MATERIALS: STRONG ACIDS, OXIDIZERS.
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
CHEMICAL NAME ORAL LD50 (RAT) DERMAL LD50 (RABBIT)
NONOXYNOL 960 TO 3980 MG/KG (RAT) 4490 MG/KG (RABBIT)
DISODIUM LAURYL PHENYL >2000 MG/KG (RAT) >2000 MG/KG (RABBIT)
ETHER DISULFONATE
SODIUM METASILICATE 1500 TO 3200 MG/KG (RAT)
DIPROPYLENE GLYCOL >5000 MG/KG (RAT) 9510 MG/KG (RABBIT)
METHYL ETHER
DERMAL LD50: NOT ESTABLISHED
ORAL LD50: NOT ESTABLISHED
INHALATION LC50: NOT ESTABLISHED
SERIOUS EYE DAMAGE/IRRITATION: IRRITANT
RESPIRATORY OR SKIN SENSITISATION:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
GERM CELL MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY
IARC: NO LISTED SUBSTANCE
REPRODUCTIVE TOXICITY:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS NOTED.
AQUATIC TOXICITY (ACUTE):
96-HOUR LC50: >100 MG/L (FISH)
48-HOUR EC50: >100 MG/L (DAPHNIA MAGNA)
NOTES: ACUTE TOXICITY DERIVED FROM MAJOR COMPONENT INFORMATION.
CHEMICAL FATE INFORMATION: THIS PRODUCT IS BIODEGRADABLE.
BIOACCUMULATION/ACCUMULATION: NONE EXPECTED.
ENVIRONMENTAL DATA: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DISTRIBUTION: NOT ESTABLISHED
GENERAL COMMENTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION,
PHOTOCHEMICAL OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION,
GLOBAL WARMING POTENTIAL) ARE EXPECTED FROM THIS PRODUCT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHOD:
SMALL AMOUNTS (LESS THAN 5 GALLONS) MAY BE DISPOSED OF IN SANITARY
SEWER. CONSULT LOCAL AUTHORITIES FOR ADDITIONAL DISPOSAL INFORMATION.
FOR LARGE SPILLS:
CONSULT WITH LOCAL AND STATE AUTHORITIES FOR LARGE VOLUME DISPOSAL.
PRODUCT DISPOSAL: SEE ABOVE.
EMPTY CONTAINER:
RINSE CONTAINER WITH CLEAR WATER. OFFER CONTAINER FOR RECYCLING, OR
DISPOSE OF IN TRASH.
RCRA/EPA WASTE INFORMATION:
NA = NOT APPLICABLE
| 14. TRANSPORT INFORMATION | |
DOT (DEPARTMENT OF TRANSPORTATION):
PROPER SHIPPING NAME: NOT REGULATED.
ROAD AND RAIL (ADR/RID):
PROPER SHIPPING NAME: CLEANING COMPOUND, NOT REGULATED.
AIR (ICAO/IATA):
SHIPPING NAME: NOT REGULATED.
VESSEL (IMO/IMDG):
SHIPPING NAME: NOT REGULATED.
| 15. REGULATORY INFORMATION | |
UNITED STATES:
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT):
311/312 HEALTH HAZARDS: HEALTH - ACUTE
313 REPORTABLE INGREDIENTS: NONE
EPCRA SECTION 313 SUPPLIER NOTIFICATION:
CHEMICAL NAME WT.% CAS COMMENTS
NONOXYNOL 0 - 5 127087-87-0 N535 NONYLPHENOL ETHOXYLATES
302/304 EMERGENCY PLANNING:
EMERGENCY PLAN:
NA = NOT APPLICABLE
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT):
CERCLA REGULATORY:
NA = NOT APPLICABLE
TSCA (TOXIC SUBSTANCE CONTROL ACT):
TSCA REGULATORY:
ALL INGREDIENTS ARE LISTED ON THE TSCA CHEMICAL INVENTORY.
STATES WITH SPECIAL REQUIREMENTS:
CHEMICAL NAME REQUIREMENTS
NONOXYNOL MASSACHUSETTS RIGHT TO KNOW SUBSTANCE
NEW JERSEY RIGHT TO KNOW SUBSTANCE
PENNSYLVANIA RIGHT TO KNOW SUBSTANCE
SODIUM METASILICATE PENNSYLVANIA RIGHT TO KNOW SUBSTANCE
NEW JERSEY RIGHT TO KNOW SUBSTANCE
DIPROPYLENE GLYCOL METHYL ETHER MASSACHUSETTS RIGHT TO KNOW SUBSTANCE
NEW JERSEY RIGHT TO KNOW SUBSTANCE
PENNSYLVANIA RIGHT TO KNOW SUBSTANCE
CALIFORNIA PROPOSITION 65: NONE
CARCINOGEN: NO LISTED SUBSTANCE
| 16. OTHER INFORMATION | |
PREPARED BY: REG
DATE REVISED: 12/16/2021
REVISION SUMMARY: THIS SDS REPLACES THE 06/01/2016 SDS.
REVISED:
SECTION 2: GHS CLASSIFICATIONS, GHS LABEL, PRECAUTIONARY STATEMENT(S).
HMIS RATING:
HEALTH 2
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
NFPA CODES:
2
0
0
MANUFACTURER DISCLAIMER:
THIS COMPANY CANNOT ANTICIPATE ALL CONDITIONS OF HANDLING AND USE OF THIS
PRODUCT. THEREFORE, THIS COMPANY ACCEPTS NO RESPONSIBILITY FOR RESULTS
OBTAINED BY THE APPLICATION OF THIS INFORMATION, OR THE SAFETY AND
SUITABILITY OF THE PRODUCT EITHER ALONE OR IN COMBINATION WITH OTHER
PRODUCTS. IT IS THE RESPONSIBILITY OF THE EMPLOYER AND/OR USER TO PROVIDE
A SAFE WORKPLACE, USING HEALTH AND SAFETY INFORMATION CONTAINED HEREIN AS
A GUIDE. THIS COMPANY WILL ACCEPT NO LIABILITY FOR DAMAGES OR LOSSES
INCURRED FROM THE IMPROPER HANDLING AND USE OF THIS PRODUCT.