| Common Name: | PTG-4005 |
| Manufacturer: | PRAXAIR |
| SDS Revision Date: | 5/25/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 49WN08 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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INDUSTRIAL SCIENTIFIC
PTG-4005
SAFETY DATA SHEET
PTG-4005
ACCORDING TO U.S. CODE OF FEDERAL REGULATIONS 29 CFR 1910.1200, HAZARD
COMMUNICATION.
DATE OF ISSUE: 05/25/2015
VERSION: 1.0
| SECTION: 1. PRODUCT AND COMPANY IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
FORMULA:
NON-FLAMMABLE, NON-OXIDIZING GAS MIXTURE CONTAINING ONE OR MORE OF THE
FOLLOWING COMPONENTS: SULFUR DIOXIDE, HYDROGEN SULFIDE, CARBON MONOXIDE,
METHANE, OXYGEN, CARBON DIOXIDE, NITROGEN.
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: CALIBRATION / REFERENCE
USE OF THE SUBSTANCE/MIXTURE: INDUSTRIAL USE. USE AS DIRECTED.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURED FOR:
INDUSTRIAL SCIENTIFIC CORPORATION
1 LIFE WAY
PITTSBURGH, PA 15205-7500
USA
BY:
PORTAGAS(PRAXAIR, INC)
1202 E SAM HOUSTON PKWY S
PASADENA, TX 77503 USA
PHONE: 412-788-4353 1-800-DETECTS (338-3287)
FAX: 412-788-8353
WWW.INDSCI.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
ONSITE EMERGENCIES: 1-800-645-4633
CHEMTREC:
USA 1-800-424-9300, INTERNATIONAL 001-703-527-3887 (COLLECT CALLS ACCEPTED,
CONTRACT 17729)
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION (GHS-US):
COMPRESSED GAS: H280
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS04: GAS CYLINDER
SIGNAL WORD (GHS-US): WARNING
HAZARD STATEMENTS (GHS-US):
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
PRECAUTIONARY STATEMENTS (GHS-US):
P261: AVOID BREATHING GAS
P410+P403:
PROTECT FROM SUNLIGHT WHEN AMBIENT TEMPERATURE EXCEEDS 52 DEG. C (125 DEG.
F). USE AND STORE ONLY OUTDOORS OR IN A WELL-VENTILATED PLACE.
CGA-PG02:
PROTECT FROM SUNLIGHT WHEN AMBIENT TEMPERATURE EXCEEDS 52 DEG. C (125 DEG.
F).
CGA-PG05: USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING.
CGA-PG06: CLOSE VALVE AFTER EACH USE AND WHEN EMPTY.
CGA-PG10: USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE.
CGA-PG11:
NEVER PUT CYLINDERS INTO UNVENTILATED AREAS OF PASSENGER VEHICLES.
CGA-PG12: DO NOT OPEN VALVE UNTIL CONNECTED TO EQUIPMENT PREPARED FOR USE.
CGA-PG21: OPEN VALVE SLOWLY.
CGA-PG27: READ AND FOLLOW THE SAFETY DATA SHEET (SDS) BEFORE USE.
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
2.4. UNKNOWN ACUTE TOXICITY (GHS-US): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER %
NITROGEN (CAS NO) 7727-37-9 <=99.9999
OXYGEN (CAS NO) 7782-44-7 0.0001 - 20.9
CARBON DIOXIDE (CAS NO) 124-38-9 0.0001 - 8.5
METHANE (CAS NO) 74-82-8 0.0001 - 2.5
HYDROGEN SULFIDE (CAS NO) 7783-06-4 0.0001 - 1
SULFUR DIOXIDE (CAS NO) 7446-09-5 0.0001 - 0.9999
CARBON MONOXIDE (CAS NO) 630-08-0 0.0001 - 0.0999
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES AFTER INHALATION:
IMMEDIATELY REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, QUALIFIED PERSONNEL MAY GIVE
OXYGEN. CALL A PHYSICIAN.
FIRST-AID MEASURES AFTER SKIN CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
FIRST-AID MEASURES AFTER EYE CONTACT:
IMMEDIATELY FLUSH EYES THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. HOLD
THE EYELIDS OPEN AND AWAY FROM THE EYEBALLS TO ENSURE THAT ALL SURFACES ARE
FLUSHED THOROUGHLY. CONTACT AN OPHTHALMOLOGIST IMMEDIATELY.
FIRST-AID MEASURES AFTER INGESTION:
INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES:
EFFECTS ARE DUE TO LACK OF OXYGEN. MODERATE CONCENTRATIONS MAY CAUSE
HEADACHE, DROWSINESS, DIZZINESS, EXCITATION, EXCESS SALIVATION, VOMITING,
AND UNCONSCIOUSNESS. PROLONGED EXPOSURE TO LOW CONCENTRATIONS OF CARBON
MONOXIDE CAN KILL. INHALATION.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NONE.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: NOT FLAMMABLE.
EXPLOSION HAZARD:
HEAT MAY BUILD PRESSURE, RUPTURING CLOSED CONTAINERS, SPREADING FIRE AND
INCREASING RISK OF BURNS AND INJURIES.
REACTIVITY:
NO REACTIVITY HAZARD OTHER THAN THE EFFECTS DESCRIBED IN SUB-SECTIONS
BELOW.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
EVACUATE ALL PERSONNEL FROM THE DANGER AREA. USE SELF-CONTAINED BREATHING
APPARATUS (SCBA) AND PROTECTIVE CLOTHING. IMMEDIATELY COOL CONTAINERS WITH
WATER FROM MAXIMUM DISTANCE. STOP FLOW OF GAS IF SAFE TO DO SO, WHILE
CONTINUING COOLING WATER SPRAY. REMOVE IGNITION SOURCES IF SAFE TO DO SO.
REMOVE CONTAINERS FROM AREA OF FIRE IF SAFE TO DO SO. ON-SITE FIRE BRIGADES
MUST COMPLY WITH OSHA 29 CFR 1910.156 AND APPLICABLE STANDARDS UNDER 29 CFR
1910 SUBPART L-FIRE PROTECTION.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS:
STANDARD PROTECTIVE CLOTHING AND EQUIPMENT (SELF CONTAINED BREATHING
APPARATUS) FOR FIRE FIGHTERS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL: NO ADDITIONAL INFORMATION AVAILABLE
6.1.2. FOR EMERGENCY RESPONDERS: NO ADDITIONAL INFORMATION AVAILABLE
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT WASTE FROM CONTAMINATING THE SURROUNDING ENVIRONMENT. PREVENT SOIL
AND WATER POLLUTION. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS. CONTACT SUPPLIER FOR ANY
SPECIAL REQUIREMENTS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
NO ADDITIONAL INFORMATION AVAILABLE
6.4. REFERENCE TO OTHER SECTIONS: SEE ALSO SECTIONS 8 AND 13.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WEAR LEATHER SAFETY GLOVES AND SAFETY SHOES WHEN HANDLING CYLINDERS.
PROTECT CYLINDERS FROM PHYSICAL DAMAGE; DO NOT DRAG, ROLL, SLIDE OR DROP.
WHILE MOVING CYLINDER, ALWAYS KEEP IN PLACE REMOVABLE VALVE COVER. NEVER
ATTEMPT TO LIFT A CYLINDER BY ITS CAP; THE CAP IS INTENDED SOLELY TO
PROTECT THE VALVE. WHEN MOVING CYLINDERS, EVEN FOR SHORT DISTANCES, USE A
CART (TROLLEY, HAND TRUCK, ETC.) DESIGNED TO TRANSPORT CYLINDERS. NEVER
INSERT AN OBJECT (E.G., WRENCH, SCREWDRIVER, PRY BAR) INTO CAP OPENINGS;
DOING SO MAY DAMAGE THE VALVE AND CAUSE A LEAK. USE AN ADJUSTABLE STRAP
WRENCH TO REMOVE OVER-TIGHT OR RUSTED CAPS. SLOWLY OPEN THE VALVE. IF THE
VALVE IS HARD TO OPEN, DISCONTINUE USE AND CONTACT YOUR SUPPLIER. CLOSE THE
CONTAINER VALVE AFTER EACH USE; KEEP CLOSED EVEN WHEN EMPTY. NEVER APPLY
FLAME OR LOCALIZED HEAT DIRECTLY TO ANY PART OF THE CONTAINER. HIGH
TEMPERATURES MAY DAMAGE THE CONTAINER AND COULD CAUSE THE PRESSURE RELIEF
DEVICE TO FAIL PREMATURELY, VENTING THE CONTAINER CONTENTS. FOR OTHER
PRECAUTIONS IN USING THIS PRODUCT, SEE SECTION 16.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES: COMPLY WITH APPLICABLE REGULATIONS.
STORAGE CONDITIONS:
STORE ONLY WHERE TEMPERATURE WILL NOT EXCEED 125 DEG. F (52 DEG. C). POST
"NO SMOKING OR OPEN FLAMES" SIGNS IN STORAGE AND USE AREAS. THERE MUST BE
NO SOURCES OF IGNITION. SEPARATE PACKAGES AND PROTECT AGAINST POTENTIAL
FIRE AND/OR EXPLOSION DAMAGE FOLLOWING APPROPRIATE CODES AND REQUIREMENTS
(E.G., NFPA 30, NFPA 55, NFPA 70, AND/OR NFPA 221 IN THE U.S.) OR ACCORDING
TO REQUIREMENTS DETERMINED BY THE AUTHORITY HAVING JURISDICTION (AHJ).
ALWAYS SECURE CONTAINERS UPRIGHT TO KEEP THEM FROM FALLING OR BEING KNOCKED
OVER. INSTALL VALVE PROTECTION CAP, IF PROVIDED, FIRMLY IN PLACE BY HAND
WHEN THE CONTAINER IS NOT IN USE. STORE FULL AND EMPTY CONTAINERS
SEPARATELY. USE A FIRST-IN, FIRST-OUT INVENTORY SYSTEM TO PREVENT STORING
FULL CONTAINERS FOR LONG PERIODS. FOR OTHER PRECAUTIONS IN USING THIS
PRODUCT, SEE SECTION 16.
OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE:
WHEN HANDLING PRODUCT UNDER PRESSURE, USE PIPING AND EQUIPMENT ADEQUATELY
DESIGNED TO WITHSTAND THE PRESSURES TO BE ENCOUNTERED. NEVER WORK ON A
PRESSURIZED SYSTEM. USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING. GASES
CAN CAUSE RAPID SUFFOCATION BECAUSE OF OXYGEN DEFICIENCY; STORE AND USE
WITH ADEQUATE VENTILATION. IF A LEAK OCCURS, CLOSE THE CONTAINER VALVE AND
BLOW DOWN THE SYSTEM IN A SAFE AND ENVIRONMENTALLY CORRECT MANNER IN
COMPLIANCE WITH ALL INTERNATIONAL, FEDERAL/NATIONAL, STATE/PROVINCIAL, AND
LOCAL LAWS; THEN REPAIR THE LEAK. NEVER PLACE A CONTAINER WHERE IT MAY
BECOME PART OF AN ELECTRICAL CIRCUIT.
7.3. SPECIFIC END USE(S): NONE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
HYDROGEN SULFIDE (7783-06-4):
ACGIH:
ACGIH TLV-TWA (PPM): 1 PPM
HYDROGEN SULFIDE (7783-06-4):
ACGIH:
ACGIH TLV-STEL (PPM): 5 PPM
USA OSHA:
OSHA PEL (CEILING) (PPM): 20 PPM
CARBON MONOXIDE (630-08-0):
ACGIH:
ACGIH TLV-TWA (PPM): 25 PPM
USA OSHA:
OSHA PEL (TWA) (MG/M3): 55 MG/M3
USA OSHA:
OSHA PEL (TWA) (PPM): 50 PPM
OXYGEN (7782-44-7):
ACGIH: NOT ESTABLISHED
USA OSHA: NOT ESTABLISHED
NITROGEN (7727-37-9):
ACGIH: NOT ESTABLISHED
USA OSHA: NOT ESTABLISHED
CARBON DIOXIDE (124-38-9):
ACGIH:
ACGIH TLV-TWA (PPM): 5000 PPM
ACGIH:
ACGIH TLV-STEL (PPM): 30000 PPM
USA OSHA:
OSHA PEL (TWA) (MG/M3): 9000 MG/M3
USA OSHA:
OSHA PEL (TWA) (PPM): 5000 PPM
METHANE (74-82-8):
ACGIH: NOT ESTABLISHED
USA OSHA: NOT ESTABLISHED
SULFUR DIOXIDE (7446-09-5):
ACGIH:
ACGIH TLV-STEL (PPM): 0.25 PPM
USA OSHA:
OSHA PEL (TWA) (MG/M3): 13 MG/M3
USA OSHA:
OSHA PEL (TWA) (PPM): 5 PPM
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION. ENSURE EXPOSURE IS
BELOW OCCUPATIONAL EXPOSURE LIMITS (WHERE AVAILABLE).
PERSONAL PROTECTIVE EQUIPMENT: SAFETY GLASSES. GLOVES.
EYE PROTECTION:
WEAR SAFETY GLASSES WHEN HANDLING CYLINDERS; VAPOR-PROOF GOGGLES AND A FACE
SHIELD DURING CYLINDER CHANGEOUT OR WHENEVER CONTACT WITH PRODUCT IS
POSSIBLE. SELECT EYE PROTECTION IN ACCORDANCE WITH OSHA 29 CFR 1910.133.
SKIN AND BODY PROTECTION:
WEAR METATARSAL SHOES FOR CONTAINER HANDLING. WEAR METATARSAL SHOES AND
WORK GLOVES FOR CYLINDER HANDLING, AND PROTECTIVE CLOTHING WHERE NEEDED.
WEAR APPROPRIATE CHEMICAL GLOVES DURING CYLINDER CHANGEOUT OR WHEREVER
CONTACT WITH PRODUCT IS POSSIBLE. SELECT PER OSHA 29 CFR 1910.132,
1910.136, AND 1910.138.
RESPIRATORY PROTECTION:
WHEN WORKPLACE CONDITIONS WARRANT RESPIRATOR USE, FOLLOW A RESPIRATORY
PROTECTION PROGRAM THAT MEETS OSHA 29 CFR 1910.134, ANSI Z88.2, OR MSHA 30
CFR 72.710 (WHERE APPLICABLE). USE AN AIR-SUPPLIED OR AIR-PURIFYING
CARTRIDGE IF THE ACTION LEVEL IS EXCEEDED. ENSURE THAT THE RESPIRATOR HAS
THE APPROPRIATE PROTECTION FACTOR FOR THE EXPOSURE LEVEL. IF CARTRIDGE TYPE
RESPIRATORS ARE USED, THE CARTRIDGE MUST BE APPROPRIATE FOR THE CHEMICAL
EXPOSURE (E.G., AN ORGANIC VAPOR CARTRIDGE). FOR EMERGENCIES OR INSTANCES
WITH UNKNOWN EXPOSURE LEVELS, USE A SELF-CONTAINED BREATHING APPARATUS
(SCBA). SELF CONTAINED BREATHING APPARATUS (SCBA) OR POSITIVE PRESSURE
AIRLINE WITH MASK ARE TO BE USED IN OXYGEN-DEFICIENT ATMOSPHERES.
THERMAL HAZARD PROTECTION:
WEAR COLD INSULATING GLOVES WHEN TRANSFILLING OR BREAKING TRANSFER
CONNECTIONS.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: GAS
APPEARANCE: COLORLESS GAS.
COLOR: COLORLESS
ODOR: ROTTEN EGGS
ODOR THRESHOLD: >3 PPM HYDROGEN SULFIDE
PH: NOT APPLICABLE.
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (ETHER=1): NOT APPLICABLE.
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOR PRESSURE: NOT APPLICABLE.
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SOLUBILITY:
WATER: NO DATA AVAILABLE
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
VISCOSITY, KINEMATIC: NOT APPLICABLE.
VISCOSITY, DYNAMIC: NOT APPLICABLE.
EXPLOSIVE PROPERTIES: NOT APPLICABLE.
OXIDIZING PROPERTIES: NONE.
EXPLOSION LIMITS: NO DATA AVAILABLE
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
NO REACTIVITY HAZARD OTHER THAN THE EFFECTS DESCRIBED IN SUB-SECTIONS
BELOW.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NONE.
10.4. CONDITIONS TO AVOID: NONE.
10.5. INCOMPATIBLE MATERIALS: NONE.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: NONE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
HYDROGEN SULFIDE (7783-06-4):
LC50 INHALATION RAT (MG/L): 0.99 MG/L (EXPOSURE TIME: 1 H)
LC50 INHALATION RAT (PPM): 356 PPM/4H
ATE US (GASES): 356.000 PPMV/4H
ATE US (VAPORS): 0.990 MG/L/4H
ATE US (DUST, MIST): 0.990 MG/L/4H
CARBON MONOXIDE (630-08-0):
LC50 INHALATION RAT (PPM): 3760 PPM/1H
ATE US (GASES): 1880.000 PPMV/4H
SULFUR DIOXIDE (7446-09-5):
LC50 INHALATION RAT (PPM): 1260 PPM/4H
ATE US (GASES): 1260.000 PPMV/4H
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE.
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
SULFUR DIOXIDE (7446-09-5):
IARC GROUP: 3 - NOT CLASSIFIABLE
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
HYDROGEN SULFIDE (7783-06-4):
LC50 FISH 1:
0.0448 MG/L (EXPOSURE TIME: 96 H - SPECIES: LEPOMIS MACROCHIRUS
[FLOW-THROUGH])
LC50 FISH 2:
0.016 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[FLOW-THROUGH])
12.2. PERSISTENCE AND DEGRADABILITY:
PTG-4005:
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
HYDROGEN SULFIDE (7783-06-4):
PERSISTENCE AND DEGRADABILITY: NOT APPLICABLE FOR INORGANIC GASES.
OXYGEN (7782-44-7):
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
NITROGEN (7727-37-9):
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
CARBON DIOXIDE (124-38-9):
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
METHANE (74-82-8):
PERSISTENCE AND DEGRADABILITY:
THE SUBSTANCE IS BIODEGRADABLE. UNLIKELY TO PERSIST.
SULFUR DIOXIDE (7446-09-5):
PERSISTENCE AND DEGRADABILITY: NOT APPLICABLE FOR INORGANIC GASES.
12.3. BIOACCUMULATIVE POTENTIAL:
PTG-4005:
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
HYDROGEN SULFIDE (7783-06-4):
BCF FISH 1: (NO BIOACCUMULATION EXPECTED)
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
CARBON MONOXIDE (630-08-0):
LOG KOW: NOT APPLICABLE.
OXYGEN (7782-44-7):
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL:
NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
NITROGEN (7727-37-9):
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
CARBON DIOXIDE (124-38-9):
BCF FISH 1: (NO BIOACCUMULATION)
LOG POW: 0.83
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
METHANE (74-82-8):
LOG POW: 1.09
BIOACCUMULATIVE POTENTIAL:
NOT EXPECTED TO BIOACCUMULATE DUE TO THE LOW LOG KOW (LOG KOW <4). REFER TO
SECTION 9.
SULFUR DIOXIDE (7446-09-5):
BCF FISH 1: (NO BIOACCUMULATION EXPECTED)
LOG POW: NOT APPLICABLE FOR INORGANIC GASES.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
12.4. MOBILITY IN SOIL:
PTG-4005:
MOBILITY IN SOIL: NO DATA AVAILABLE.
HYDROGEN SULFIDE (7783-06-4):
MOBILITY IN SOIL: NO DATA AVAILABLE.
ECOLOGY - SOIL:
BECAUSE OF ITS HIGH VOLATILITY, THE PRODUCT IS UNLIKELY TO CAUSE GROUND OR
WATER POLLUTION.
CARBON MONOXIDE (630-08-0):
MOBILITY IN SOIL: NO DATA AVAILABLE.
OXYGEN (7782-44-7):
MOBILITY IN SOIL: NO DATA AVAILABLE.
ECOLOGY - SOIL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
NITROGEN (7727-37-9):
MOBILITY IN SOIL: NO DATA AVAILABLE.
ECOLOGY - SOIL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
CARBON DIOXIDE (124-38-9):
MOBILITY IN SOIL: NO DATA AVAILABLE.
ECOLOGY - SOIL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
METHANE (74-82-8):
ECOLOGY - SOIL:
BECAUSE OF ITS HIGH VOLATILITY, THE PRODUCT IS UNLIKELY TO CAUSE GROUND OR
WATER POLLUTION.
SULFUR DIOXIDE (7446-09-5):
ECOLOGY - SOIL:
BECAUSE OF ITS HIGH VOLATILITY, THE PRODUCT IS UNLIKELY TO CAUSE GROUND OR
WATER POLLUTION.
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON OZONE LAYER: NONE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DO NOT ATTEMPT TO DISPOSE OF RESIDUAL OR UNUSED QUANTITIES. RETURN
CONTAINER TO SUPPLIER.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH DOT TRANSPORT DOCUMENT DESCRIPTION:
UN1956 COMPRESSED GAS, N.O.S., 2.2
UN-NO.(DOT): UN1956
PROPER SHIPPING NAME (DOT): COMPRESSED GAS, N.O.S.
TRANSPORT HAZARD CLASS(ES) (DOT):
2.2 - CLASS 2.2 - NON-FLAMMABLE COMPRESSED GAS 49 CFR 173.115
HAZARD LABELS (DOT): 2.2 - NON-FLAMMABLE GAS
DOT SYMBOLS:
G - IDENTIFIES PROPER SHIPPING NAME (PSN) REQUIRING THE ADDITION OF
TECHNICAL NAME(S) IN PARENTHESES FOLLOWING THE PSN.
ADDITIONAL INFORMATION:
EMERGENCY RESPONSE GUIDE (ERG) NUMBER: 126
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
SPECIAL TRANSPORT PRECAUTIONS:
AVOID TRANSPORT ON VEHICLES WHERE THE LOAD SPACE IS NOT SEPARATED FROM THE
DRIVER'S COMPARTMENT. ENSURE VEHICLE DRIVER IS AWARE OF THE POTENTIAL
HAZARDS OF THE LOAD AND KNOWS WHAT TO DO IN THE EVENT OF AN ACCIDENT OR AN
EMERGENCY. BEFORE TRANSPORTING PRODUCT CONTAINERS: - ENSURE THERE IS
ADEQUATE VENTILATION. - ENSURE THAT CONTAINERS ARE FIRMLY SECURED. - ENSURE
CYLINDER VALVE IS CLOSED AND NOT LEAKING. - ENSURE VALVE OUTLET CAP NUT OR
PLUG (WHERE PROVIDED) IS CORRECTLY FITTED. - ENSURE VALVE PROTECTION DEVICE
(WHERE PROVIDED) IS CORRECTLY FITTED.
TRANSPORT BY SEA:
UN-NO. (IMDG): 1956
PROPER SHIPPING NAME (IMDG): COMPRESSED GAS, N.O.S.
CLASS (IMDG): 2.2 - NON-FLAMMABLE, NON-TOXIC GASES
LIMITED QUANTITIES (IMDG): 120ML
EMS-NO. (1): F-C
MFAG-NO: 620
EMS-NO. (2): S-V
AIR TRANSPORT:
UN-NO.(IATA): 1956
PROPER SHIPPING NAME (IATA): COMPRESSED GAS, N.O.S.
CLASS (IATA): 2
INSTRUCTION "CARGO" (ICAO): 200
INSTRUCTION "PASSENGER" (ICAO): 200
INSTRUCTION "PASSENGER" - LIMITED QUANTITIES (ICAO): FORBIDDEN
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
HYDROGEN SULFIDE (7783-06-4):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
LISTED ON THE UNITED STATES SARA SECTION 302
LISTED ON UNITED STATES SARA SECTION 313
SARA SECTION 302 THRESHOLD PLANNING QUANTITY (TPQ): 500
SARA SECTION 313 - EMISSION REPORTING: 1.0%
SULFUR DIOXIDE (7446-09-5):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
LISTED ON THE UNITED STATES SARA SECTION 302
SARA SECTION 302 THRESHOLD PLANNING QUANTITY (TPQ): 500
15.2. INTERNATIONAL REGULATIONS:
CANADA:
HYDROGEN SULFIDE (7783-06-4):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
CARBON MONOXIDE (630-08-0):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
OXYGEN (7782-44-7): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
NITROGEN (7727-37-9): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
CARBON DIOXIDE (124-38-9):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
METHANE (74-82-8): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
SULFUR DIOXIDE (7446-09-5):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS:
HYDROGEN SULFIDE (7783-06-4):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
SULFUR DIOXIDE (7446-09-5):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
15.2.2. NATIONAL REGULATIONS:
HYDROGEN SULFIDE (7783-06-4):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICAL SUBSTANCES) INVENTORY
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
SULFUR DIOXIDE (7446-09-5):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICAL SUBSTANCES) INVENTORY
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
PTG-4005():
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
HYDROGEN SULFIDE (7783-06-4):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANCE RISK LEVEL (NSRL):
CARBON MONOXIDE (630-08-0):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANCE RISK LEVEL (NSRL):
OXYGEN (7782-44-7):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANCE RISK LEVEL (NSRL):
NITROGEN (7727-37-9):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANCE RISK LEVEL (NSRL):
CARBON DIOXIDE (124-38-9):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANCE RISK LEVEL (NSRL):
METHANE (74-82-8):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANCE RISK LEVEL (NSRL):
SULFUR DIOXIDE (7446-09-5):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NO SIGNIFICANCE RISK LEVEL (NSRL):
HYDROGEN SULFIDE (7783-06-4):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
CARBON MONOXIDE (630-08-0):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
OXYGEN (7782-44-7):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
NITROGEN (7727-37-9):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
CARBON DIOXIDE (124-38-9):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
METHANE (74-82-8):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
SULFUR DIOXIDE (7446-09-5):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
| SECTION 16: OTHER INFORMATION | |
OTHER INFORMATION:
WHEN YOU MIX TWO OR MORE CHEMICALS, YOU CAN CREATE ADDITIONAL, UNEXPECTED
HAZARDS. OBTAIN AND EVALUATE THE SAFETY INFORMATION FOR EACH COMPONENT
BEFORE YOU PRODUCE THE MIXTURE. CONSULT AN INDUSTRIAL HYGIENIST OR OTHER
TRAINED PERSON WHEN YOU EVALUATE THE END PRODUCT. BEFORE USING ANY
PLASTICS, CONFIRM THEIR COMPATIBILITY WITH THIS PRODUCT.
PRAXAIR ASKS USERS OF THIS PRODUCT TO STUDY THIS SDS AND BECOME AWARE OF
THE PRODUCT HAZARDS AND SAFETY INFORMATION. TO PROMOTE SAFE USE OF THIS
PRODUCT, A USER SHOULD (1) NOTIFY EMPLOYEES, AGENTS, AND CONTRACTORS OF THE
INFORMATION IN THIS SDS AND OF ANY OTHER KNOWN PRODUCT HAZARDS AND SAFETY
INFORMATION, (2) FURNISH THIS INFORMATION TO EACH PURCHASER OF THE PRODUCT,
AND (3) ASK EACH PURCHASER TO NOTIFY ITS EMPLOYEES AND CUSTOMERS OF THE
PRODUCT HAZARDS AND SAFETY INFORMATION.
THE OPINIONS EXPRESSED HEREIN ARE THOSE OF QUALIFIED EXPERTS WITHIN
PRAXAIR, INC. WE BELIEVE THAT THE INFORMATION CONTAINED HEREIN IS CURRENT
AS OF THE DATE OF THIS SAFETY DATA SHEET. SINCE THE USE OF THIS INFORMATION
AND THE CONDITIONS OF USE ARE NOT WITHIN THE CONTROL OF PRAXAIR, INC., IT
IS THE USER'S OBLIGATION TO DETERMINE THE CONDITIONS OF SAFE USE OF THE
PRODUCT.
PRAXAIR SDSS ARE FURNISHED ON SALE OR DELIVERY BY PRAXAIR OR THE
INDEPENDENT DISTRIBUTORS AND SUPPLIERS WHO PACKAGE AND SELL OUR PRODUCTS.
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PRAXAIR AND THE FLOWING AIRSTREAM DESIGN ARE TRADEMARKS OR REGISTERED
TRADEMARKS OF PRAXAIR TECHNOLOGY, INC. IN THE UNITED STATES AND/OR OTHER
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SDS US (GHS HAZCOM 2012) - PRAXAIR
ISC PART NUMBERS:
1810-9237, 1810-9231, 1810-9232, 1810-9233, 1810-9234, 1810-9390,
1810-9179, 1810-6799, 1810-9167, 1810-6807, 1810-9220, 1810-9221,
1810-9222, 1810-9224
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
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REQUIREMENTS ONLY. IT SHOULD NOT THEREFORE BE CONSTRUED AS GUARANTEEING ANY
SPECIFIC PROPERTY OF THE PRODUCT.
EN (ENGLISH US)
SDS ID: PTG-4005
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