| Common Name: | PTG-4012 |
| Manufacturer: | PORTAGAS |
| SDS Revision Date: | 7/1/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 302K91, 49WN10, 60JJ79 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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PORTAGAS BY PRAXAIR
PTG-4012
SAFETY DATA SHEET
PTG-4012
ACCORDING TO U.S. CODE OF FEDERAL REGULATIONS 29 CFR 1910.1200,
HAZARD COMMUNICATION.
DATE OF ISSUE: 05/11/2015
REVISION DATE: 07/01/2015
SUPERSEDES: 06/08/2015
VERSION: 1.1
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
FORMULA:
NON-FLAMMABLE, NON-OXIDIZING GAS MIXTURE CONTAINING ONE OR MORE OF THE
FOLLOWING COMPONENTS: NITRIC OXIDE, NITROGEN DIOXIDE, OXYGEN, NITROGEN.
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: CALIBRATION / REFERENCE
USE OF THE SUBSTANCE/MIXTURE: INDUSTRIAL USE. USE AS DIRECTED.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
PORTAGAS (PRAXAIR, INC.)
1202 E SAM HOUSTON PKWY S
PASADENA, TX 77503
USA
T: +1 713-928-6477
F: +1 713-928-9961
WWW.PRAXAIR.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
ONSITE EMERGENCIES: 1-800-645-4633
CHEMTREC: USA 1-800-424-9300
INTERNATIONAL: 001-703-527-3887 (COLLECT CALLS ACCEPTED, CONTRACT 17729)
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION (GHS-US):
COMPRESSED GAS: H280
ACUTE TOX. 4 (INHALATION: GAS): H332
FULL TEXT OF H-PHRASES: SEE SECTION 16
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS04: GAS CYLINDER
GHS07: EXCLAMATION MARK
SIGNAL WORD (GHS-US): WARNING
HAZARD STATEMENTS (GHS-US):
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H332: HARMFUL IF INHALED
OSHA-H01: MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
PRECAUTIONARY STATEMENTS (GHS-US):
P261: AVOID BREATHING GAS
P271: USE AND STORE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P312: CALL A DOCTOR IF YOU FEEL UNWELL
CGA-PG02:
PROTECT FROM SUNLIGHT WHEN AMBIENT TEMPERATURE EXCEEDS 52 DEG. C
(125 DEG. F).
CGA-PG05: USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING.
CGA-PG06: CLOSE VALVE AFTER EACH USE AND WHEN EMPTY.
CGA-PG10: USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE.
CGA-PG11:
NEVER PUT CYLINDERS INTO UNVENTILATED AREAS OF PASSENGER VEHICLES.
CGA-PG12: DO NOT OPEN VALVE UNTIL CONNECTED TO EQUIPMENT PREPARED FOR USE.
CGA-PG21: OPEN VALVE SLOWLY.
CGA-PG27: READ AND FOLLOW THE SAFETY DATA SHEET (SDS) BEFORE USE.
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
2.4. UNKNOWN ACUTE TOXICITY (GHS-US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % CLASSIFICATION
(GHS-US)
NITROGEN (CAS NO): 7727-37-9 79.1 - 100 COMPRESSED GAS, H280
OXYGEN (CAS NO): 7782-44-7 0 - 20.9 OX. GAS 1, H270
COMPRESSED GAS, H280
NITRIC OXIDE (CAS NO): 10102-43-9 0 - 1 OX. GAS 1, H270
COMPRESSED GAS, H280
ACUTE TOX. 1
(INHALATION: GAS),
H330
SKIN CORR. 1A, H314
EYE DAM. 1, H318
NITROGEN (CAS NO): 10102-44-0 0 - 1 OX. GAS 1, H270
DIOXIDE
LIQUEFIED GAS, H280
ACUTE TOX. 1
(INHALATION: GAS),
H330
FULL TEXT OF H-PHRASES: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO UNCONTAMINATED AREA WEARING SELF CONTAINED BREATHING
APPARATUS. KEEP VICTIM WARM AND RESTED. CALL A DOCTOR. APPLY ARTIFICIAL
RESPIRATION IF BREATHING STOPPED. IMMEDIATELY REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
QUALIFIED PERSONNEL MAY GIVE OXYGEN. CALL A PHYSICIAN.
FIRST-AID MEASURES AFTER SKIN CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
FIRST-AID MEASURES AFTER EYE CONTACT:
IMMEDIATELY FLUSH EYES THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. HOLD
THE EYELIDS OPEN AND AWAY FROM THE EYEBALLS TO ENSURE THAT ALL SURFACES
ARE FLUSHED THOROUGHLY. CONTACT AN OPHTHALMOLOGIST IMMEDIATELY.
FIRST-AID MEASURES AFTER INGESTION:
INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NO ADDITIONAL INFORMATION AVAILABLE
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: OBTAIN MEDICAL ASSISTANCE.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
REACTIVITY:
NO REACTIVITY HAZARD OTHER THAN THE EFFECTS DESCRIBED IN SUB-SECTIONS
BELOW.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
EVACUATE ALL PERSONNEL FROM THE DANGER AREA. USE SELF-CONTAINED BREATHING
APPARATUS (SCBA) AND PROTECTIVE CLOTHING. IMMEDIATELY COOL CONTAINERS WITH
WATER FROM MAXIMUM DISTANCE. STOP FLOW OF GAS IF SAFE TO DO SO, WHILE
CONTINUING COOLING WATER SPRAY. REMOVE IGNITION SOURCES IF SAFE TO DO SO.
REMOVE CONTAINERS FROM AREA OF FIRE IF SAFE TO DO SO. ON-SITE FIRE BRIGADES
MUST COMPLY WITH OSHA 29 CFR 1910.156 AND APPLICABLE STANDARDS UNDER
29 CFR 1910 SUBPART L-FIRE PROTECTION.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS:
STANDARD PROTECTIVE CLOTHING AND EQUIPMENT (SELF CONTAINED BREATHING
APPARATUS) FOR FIRE FIGHTERS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
WEAR SELF-CONTAINED BREATHING APPARATUS WHEN ENTERING AREA UNLESS
ATMOSPHERE IS PROVEN TO BE SAFE. ENSURE ADEQUATE AIR VENTILATION. EVACUATE
AREA. TRY TO STOP RELEASE. MONITOR CONCENTRATION OF RELEASED PRODUCT.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS: NO ADDITIONAL INFORMATION AVAILABLE
6.2. ENVIRONMENTAL PRECAUTIONS:
TRY TO STOP RELEASE. PREVENT WASTE FROM CONTAMINATING THE SURROUNDING
ENVIRONMENT. PREVENT SOIL AND WATER POLLUTION. DISPOSE OF CONTENTS/
CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL
REGULATIONS. CONTACT SUPPLIER FOR ANY SPECIAL REQUIREMENTS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
NO ADDITIONAL INFORMATION AVAILABLE
6.4. REFERENCE TO OTHER SECTIONS: SEE ALSO SECTIONS 8 AND 13.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
WEAR LEATHER SAFETY GLOVES AND SAFETY SHOES WHEN HANDLING CYLINDERS.
PROTECT CYLINDERS FROM PHYSICAL DAMAGE; DO NOT DRAG, ROLL, SLIDE OR DROP.
WHILE MOVING CYLINDER, ALWAYS KEEP IN PLACE REMOVABLE VALVE COVER. NEVER
ATTEMPT TO LIFT A CYLINDER BY ITS CAP; THE CAP IS INTENDED SOLELY TO
PROTECT THE VALVE. WHEN MOVING CYLINDERS, EVEN FOR SHORT DISTANCES, USE A
CART (TROLLEY, HAND TRUCK, ETC.) DESIGNED TO TRANSPORT CYLINDERS. NEVER
INSERT AN OBJECT (E.G., WRENCH, SCREWDRIVER, PRY BAR) INTO CAP OPENINGS;
DOING SO MAY DAMAGE THE VALVE AND CAUSE A LEAK. USE AN ADJUSTABLE STRAP
WRENCH TO REMOVE OVER-TIGHT OR RUSTED CAPS. SLOWLY OPEN THE VALVE. IF THE
VALVE IS HARD TO OPEN, DISCONTINUE USE AND CONTACT YOUR SUPPLIER. CLOSE THE
CONTAINER VALVE AFTER EACH USE; KEEP CLOSED EVEN WHEN EMPTY. NEVER APPLY
FLAME OR LOCALIZED HEAT DIRECTLY TO ANY PART OF THE CONTAINER. HIGH
TEMPERATURES MAY DAMAGE THE CONTAINER AND COULD CAUSE THE PRESSURE RELIEF
DEVICE TO FAIL PREMATURELY, VENTING THE CONTAINER CONTENTS. FOR OTHER
PRECAUTIONS IN USING THIS PRODUCT, SEE SECTION 16.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
STORE IN A COOL, WELL-VENTILATED PLACE. STORE AND USE WITH ADEQUATE
VENTILATION. STORE ONLY WHERE TEMPERATURE WILL NOT EXCEED 125 DEG. F
(52 DEG. C). FIRMLY SECURE CONTAINERS UPRIGHT TO KEEP THEM FROM FALLING OR
BEING KNOCKED OVER. INSTALL VALVE PROTECTION CAP, IF PROVIDED, FIRMLY IN
PLACE BY HAND. STORE FULL AND EMPTY CONTAINERS SEPARATELY. USE A FIRST-IN,
FIRST-OUT INVENTORY SYSTEM TO PREVENT STORING FULL CONTAINERS FOR LONG
PERIODS. OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE:
WHEN HANDLING PRODUCT UNDER PRESSURE, USE PIPING AND EQUIPMENT ADEQUATELY
DESIGNED TO WITHSTAND THE PRESSURES TO BE ENCOUNTERED. NEVER WORK ON A
PRESSURIZED SYSTEM. USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING. GASES
CAN CAUSE RAPID SUFFOCATION BECAUSE OF OXYGEN DEFICIENCY; STORE AND USE
WITH ADEQUATE VENTILATION. IF A LEAK OCCURS, CLOSE THE CONTAINER VALVE AND
BLOW DOWN THE SYSTEM IN A SAFE AND ENVIRONMENTALLY CORRECT MANNER IN
COMPLIANCE WITH ALL INTERNATIONAL, FEDERAL/NATIONAL, STATE/PROVINCIAL,
AND LOCAL LAWS; THEN REPAIR THE LEAK. NEVER PLACE A CONTAINER WHERE IT
MAY BECOME PART OF AN ELECTRICAL CIRCUIT.
7.3. SPECIFIC END USE(S): NONE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
PTG-4012:
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
NITRIC OXIDE (10102-43-9):
ACGIH:
ACGIH TLV-TWA (PPM): 25 PPM
OSHA:
OSHA PEL (TWA) (MG/M3): 30 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 25 PPM
NITROGEN DIOXIDE (10102-44-0):
ACGIH:
ACGIH TLV-TWA (PPM): 0.2 PPM
OSHA:
OSHA PEL (CEILING) (MG/M3): 9 MG/M3
OSHA:
OSHA PEL (CEILING) (PPM): 5 PPM
NITROGEN (7727-37-9):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
OXYGEN (7782-44-7):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION. ALARM DETECTORS
SHOULD BE USED WHEN TOXIC GASES MAY BE RELEASED. PRODUCT TO BE HANDLED IN
A CLOSED SYSTEM. ENSURE EXPOSURE IS BELOW OCCUPATIONAL EXPOSURE LIMITS
(WHERE AVAILABLE).
PERSONAL PROTECTIVE EQUIPMENT: GLOVES. SAFETY GLASSES.
EYE PROTECTION:
WEAR SAFETY GLASSES WHEN HANDLING CYLINDERS; VAPOR-PROOF GOGGLES AND A
FACE SHIELD DURING CYLINDER CHANGEOUT OR WHENEVER CONTACT WITH PRODUCT IS
POSSIBLE. SELECT EYE PROTECTION IN ACCORDANCE WITH OSHA 29 CFR 1910.133.
SKIN AND BODY PROTECTION:
WEAR METATARSAL SHOES FOR CONTAINER HANDLING. WEAR METATARSAL SHOES AND
WORK GLOVES FOR CYLINDER HANDLING, AND PROTECTIVE CLOTHING WHERE NEEDED.
WEAR APPROPRIATE CHEMICAL GLOVES DURING CYLINDER CHANGEOUT OR WHEREVER
CONTACT WITH PRODUCT IS POSSIBLE. SELECT PER OSHA 29 CFR 1910.132,
1910.136, AND 1910.138.
RESPIRATORY PROTECTION:
WHEN WORKPLACE CONDITIONS WARRANT RESPIRATOR USE, FOLLOW A RESPIRATORY
PROTECTION PROGRAM THAT MEETS OSHA 29 CFR 1910.134, ANSI Z88.2, OR MSHA
30 CFR 72.710 (WHERE APPLICABLE). USE AN AIR-SUPPLIED OR AIR-PURIFYING
CARTRIDGE IF THE ACTION LEVEL IS EXCEEDED. ENSURE THAT THE RESPIRATOR HAS
THE APPROPRIATE PROTECTION FACTOR FOR THE EXPOSURE LEVEL. IF CARTRIDGE
TYPE RESPIRATORS ARE USED, THE CARTRIDGE MUST BE APPROPRIATE FOR THE
CHEMICAL EXPOSURE (E.G., AN ORGANIC VAPOR CARTRIDGE). FOR EMERGENCIES OR
INSTANCES WITH UNKNOWN EXPOSURE LEVELS, USE A SELF-CONTAINED BREATHING
APPARATUS (SCBA).
THERMAL HAZARD PROTECTION:
WEAR COLD INSULATING GLOVES WHEN TRANSFILLING OR BREAKING TRANSFER
CONNECTIONS.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: GAS
APPEARANCE:
COLORLESS GAS. TURNS YELLOW TO REDDISH BROWN ON EXPOSURE TO LIGHT AND AIR.
COLOR: COLORLESS RED BROWN
ODOR: PUNGENT ACRID
ODOR THRESHOLD: <=0.11 PPM
PH: NOT APPLICABLE.
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (ETHER=1): NOT APPLICABLE.
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NOT APPLICABLE.
OXIDIZING PROPERTIES: NONE.
VAPOR PRESSURE: NOT APPLICABLE.
RELATIVE DENSITY: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
SOLUBILITY:
WATER: NO DATA AVAILABLE
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NOT APPLICABLE.
VISCOSITY, DYNAMIC: NOT APPLICABLE.
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
NO REACTIVITY HAZARD OTHER THAN THE EFFECTS DESCRIBED IN SUB-SECTIONS
BELOW.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
NO ADDITIONAL INFORMATION AVAILABLE
10.4. CONDITIONS TO AVOID: NO ADDITIONAL INFORMATION AVAILABLE
10.5. INCOMPATIBLE MATERIALS: NO ADDITIONAL INFORMATION AVAILABLE
10.6. HAZARDOUS DECOMPOSITION PRODUCTS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
INHALATION:
GAS: HARMFUL IF INHALED.
PTG-4012:
ATE US (GASES): 2875.000 PPMV/4H
NITRIC OXIDE (10102-43-9):
LC50 INHALATION RAT (MG/L): 1068 MG/M3 (EXPOSURE TIME: 4 H)
LC50 INHALATION RAT (PPM): 57.5 PPM/4H
ATE US (GASES): 57.500 PPMV/4H
NITROGEN DIOXIDE (10102-44-0):
LC50 INHALATION RAT (PPM): 57.5 PPM/4H
ATE US (GASES): 57.500 PPMV/4H
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE.
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY: NO ADDITIONAL INFORMATION AVAILABLE
12.2. PERSISTENCE AND DEGRADABILITY:
PTG-4012:
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
NITRIC OXIDE (10102-43-9):
PERSISTENCE AND DEGRADABILITY: NOT APPLICABLE FOR INORGANIC GASES.
NITROGEN DIOXIDE (10102-44-0):
PERSISTENCE AND DEGRADABILITY: NOT APPLICABLE FOR INORGANIC GASES.
NITROGEN (7727-37-9):
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
OXYGEN (7782-44-7):
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
12.3. BIOACCUMULATIVE POTENTIAL:
PTG-4012:
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
NITRIC OXIDE (10102-43-9):
LOG POW: NOT APPLICABLE FOR INORGANIC GASES.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
NITROGEN DIOXIDE (10102-44-0):
LOG POW: NOT APPLICABLE FOR INORGANIC GASES.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
NITROGEN (7727-37-9):
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
OXYGEN (7782-44-7):
LOG POW: NOT APPLICABLE.
LOG KOW: NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
12.4. MOBILITY IN SOIL:
PTG-4012:
MOBILITY IN SOIL: NO DATA AVAILABLE.
NITRIC OXIDE (10102-43-9):
MOBILITY IN SOIL: NO DATA AVAILABLE.
ECOLOGY - SOIL:
BECAUSE OF ITS HIGH VOLATILITY, THE PRODUCT IS UNLIKELY TO CAUSE GROUND OR
WATER POLLUTION.
NITROGEN DIOXIDE (10102-44-0):
ECOLOGY - SOIL:
BECAUSE OF ITS HIGH VOLATILITY, THE PRODUCT IS UNLIKELY TO CAUSE GROUND
OR WATER POLLUTION.
NITROGEN (7727-37-9):
MOBILITY IN SOIL: NO DATA AVAILABLE.
ECOLOGY - SOIL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
OXYGEN (7782-44-7):
MOBILITY IN SOIL: NO DATA AVAILABLE.
ECOLOGY - SOIL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON OZONE LAYER: NONE.
EFFECT ON THE GLOBAL WARMING:
NO KNOWN ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE TREATMENT METHODS:
REFER TO THE EIGA CODE OF PRACTICE DOC.30 "DISPOSAL OF GASES", DOWNLOADABLE
AT HTTP://WWW.EIGA.ORG FOR MORE GUIDANCE ON SUITABLE DISPOSAL METHODS.
WASTE DISPOSAL RECOMMENDATIONS:
DO NOT ATTEMPT TO DISPOSE OF RESIDUAL OR UNUSED QUANTITIES. RETURN
CONTAINER TO SUPPLIER.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION: UN1956 COMPRESSED GAS, N.O.S., 2.2
UN-NO.(DOT): UN1956
PROPER SHIPPING NAME (DOT): COMPRESSED GAS, N.O.S.
TRANSPORT HAZARD CLASS(ES) (DOT):
2.2 - CLASS 2.2 - NON-FLAMMABLE COMPRESSED GAS 49 CFR 173.115
HAZARD LABELS (DOT): 2.2 - NON-FLAMMABLE GAS
DOT PACKAGING NON BULK (49 CFR 173.XXX): 302;305
DOT PACKAGING BULK (49 CFR 173.XXX): 314;315
DOT SYMBOLS:
G - IDENTIFIES PROPER SHIPPING NAME (PSN) REQUIRING THE ADDITION OF
TECHNICAL NAME(S) IN PARENTHESES FOLLOWING THE PSN.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 306;307
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 172.101 HMT,
COLUMN 9A): 75 KG
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 172.101 HMT,
COLUMN 9B): 150 KG
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
ADDITIONAL INFORMATION:
EMERGENCY RESPONSE GUIDE (ERG) NUMBER: 126
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
SPECIAL TRANSPORT PRECAUTIONS:
AVOID TRANSPORT ON VEHICLES WHERE THE LOAD SPACE IS NOT SEPARATED FROM THE
DRIVER'S COMPARTMENT. ENSURE VEHICLE DRIVER IS AWARE OF THE POTENTIAL
HAZARDS OF THE LOAD AND KNOWS WHAT TO DO IN THE EVENT OF AN ACCIDENT OR AN
EMERGENCY.
BEFORE TRANSPORTING PRODUCT CONTAINERS:
ENSURE THERE IS ADEQUATE VENTILATION.
ENSURE THAT CONTAINERS ARE FIRMLY SECURED.
ENSURE CYLINDER VALVE IS CLOSED AND NOT LEAKING.
ENSURE VALVE OUTLET CAP NUT OR PLUG (WHERE PROVIDED) IS CORRECTLY FITTED.
ENSURE VALVE PROTECTION DEVICE (WHERE PROVIDED) IS CORRECTLY FITTED.
ADR:
TRANSPORT DOCUMENT DESCRIPTION:
UN 1956 COMPRESSED GAS, N.O.S. (NITROGEN, NITRIC OXIDE), 2.2, (E)
CLASS (ADR): 2 - GASES
HAZARD IDENTIFICATION NUMBER (KEMLER NO.): 20
CLASSIFICATION CODE (ADR): 1A
HAZARD CLASS LABELS (ADR): 2.2 - NON-FLAMMABLE COMPRESSED GAS
CLASS 2.2, NON-FLAMMABLE AND NON-TOXIC GASES
ORANGE PLATES: 20/1956
TUNNEL RESTRICTION CODE (ADR): E
LIMITED QUANTITIES (ADR): 120ML
EXCEPTED QUANTITIES (ADR): E1
TRANSPORT BY SEA:
UN-NO. (IMDG): 1956
PROPER SHIPPING NAME (IMDG): COMPRESSED GAS, N.O.S.
CLASS (IMDG): 2.2 - NON-FLAMMABLE, NON-TOXIC GASES
LIMITED QUANTITIES (IMDG): 120ML
EMS-NO. (1): F-C
MFAG-NO: 620
EMS-NO. (2): S-V
AIR TRANSPORT:
UN-NO. (IATA): 1956
PROPER SHIPPING NAME (IATA): COMPRESSED GAS, N.O.S.
CLASS (IATA): 2
INSTRUCTION "CARGO" (ICAO): 200
INSTRUCTION "PASSENGER" (ICAO): 200
INSTRUCTION "PASSENGER" - LIMITED QUANTITIES (ICAO): FORBIDDEN
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
NITRIC OXIDE (10102-43-9):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
LISTED ON THE UNITED STATES SARA SECTION 302
SARA SECTION 302 THRESHOLD PLANNING QUANTITY (TPQ): 100
NITROGEN DIOXIDE (10102-44-0):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
LISTED ON THE UNITED STATES SARA SECTION 302
SARA SECTION 302 THRESHOLD PLANNING QUANTITY (TPQ): 100
NITROGEN (7727-37-9):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
OXYGEN (7782-44-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
NITRIC OXIDE (10102-43-9):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS C - OXIDIZING MATERIAL
CLASS D DIVISION 1 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING IMMEDIATE
AND SERIOUS TOXIC EFFECTS
CLASS E - CORROSIVE MATERIAL
NITROGEN DIOXIDE (10102-44-0):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS C - OXIDIZING MATERIAL
CLASS D DIVISION 1 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING IMMEDIATE
AND SERIOUS TOXIC EFFECTS
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
CLASS E - CORROSIVE MATERIAL
NITROGEN (7727-37-9): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION: CLASS A - COMPRESSED GAS
OXYGEN (7782-44-7): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS C - OXIDIZING MATERIAL
EU-REGULATIONS:
NITRIC OXIDE (10102-43-9):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
NITROGEN DIOXIDE (10102-44-0):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
NITROGEN (7727-37-9):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
OXYGEN (7782-44-7):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]:
COMPRESSED GAS: H280
ACUTE TOX. 4 (INHALATION: GAS): H332
SKIN IRRIT. 2: H315
EYE IRRIT. 2: H319
STOT SE 3: H335
FULL TEXT OF H-PHRASES: SEE SECTION 16
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC [DSD] OR 1999/45/EC [DPD]:
NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS:
NITRIC OXIDE (10102-43-9):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICAL SUBSTANCES) INVENTORY
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
NITROGEN DIOXIDE (10102-44-0):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICAL SUBSTANCES) INVENTORY
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
NITROGEN (7727-37-9):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
OXYGEN (7782-44-7):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
15.3. US STATE REGULATIONS:
NITRIC OXIDE (10102-43-9):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
NITROGEN DIOXIDE (10102-44-0):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
NITROGEN (7727-37-9):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
OXYGEN (7782-44-7):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 07/01/2015
TRAINING ADVICE: USERS OF BREATHING APPARATUS MUST BE TRAINED.
OTHER INFORMATION:
WHEN YOU MIX TWO OR MORE CHEMICALS, YOU CAN CREATE ADDITIONAL, UNEXPECTED
HAZARDS. OBTAIN AND EVALUATE THE SAFETY INFORMATION FOR EACH COMPONENT
BEFORE YOU PRODUCE THE MIXTURE. CONSULT AN INDUSTRIAL HYGIENIST OR OTHER
TRAINED PERSON WHEN YOU EVALUATE THE END PRODUCT. BEFORE USING ANY
PLASTICS, CONFIRM THEIR COMPATIBILITY WITH THIS PRODUCT. PRAXAIR ASKS USERS
OF THIS PRODUCT TO STUDY THIS SDS AND BECOME AWARE OF THE PRODUCT HAZARDS
AND SAFETY INFORMATION. TO PROMOTE SAFE USE OF THIS PRODUCT, A USER SHOULD
(1) NOTIFY EMPLOYEES, AGENTS, AND CONTRACTORS OF THE INFORMATION IN THIS
SDS AND OF ANY OTHER KNOWN PRODUCT HAZARDS AND SAFETY INFORMATION,
(2) FURNISH THIS INFORMATION TO EACH PURCHASER OF THE PRODUCT, AND (3) ASK
EACH PURCHASER TO NOTIFY ITS EMPLOYEES AND CUSTOMERS OF THE PRODUCT HAZARDS
AND SAFETY INFORMATION. THE OPINIONS EXPRESSED HEREIN ARE THOSE OF
QUALIFIED EXPERTS WITHIN PRAXAIR, INC. WE BELIEVE THAT THE INFORMATION
CONTAINED HEREIN IS CURRENT AS OF THE DATE OF THIS SAFETY DATA SHEET. SINCE
THE USE OF THIS INFORMATION AND THE CONDITIONS OF USE ARE NOT WITHIN THE
CONTROL OF PRAXAIR, INC., IT IS THE USER'S OBLIGATION TO DETERMINE THE
CONDITIONS OF SAFE USE OF THE PRODUCT. PRAXAIR SDSS ARE FURNISHED ON SALE
OR DELIVERY BY PRAXAIR OR THE INDEPENDENT DISTRIBUTORS AND SUPPLIERS WHO
PACKAGE AND SELL OUR PRODUCTS. TO OBTAIN CURRENT SDSS FOR THESE PRODUCTS,
CONTACT YOUR PRAXAIR SALES REPRESENTATIVE, LOCAL DISTRIBUTOR, OR SUPPLIER,
OR DOWNLOAD FROM WWW.PRAXAIR.COM. IF YOU HAVE QUESTIONS REGARDING PRAXAIR
SDSS, WOULD LIKE THE DOCUMENT NUMBER AND DATE OF THE LATEST SDS, OR WOULD
LIKE THE NAMES OF THE PRAXAIR SUPPLIERS IN YOUR AREA, PHONE OR WRITE THE
PRAXAIR CALL CENTER (PHONE: 1-800-PRAXAIR/1-800-772-9247; ADDRESS: PRAXAIR
CALL CENTER, PRAXAIR, INC., P.O. BOX 44, TONAWANDA, NY 14151-0044). PRAXAIR
AND THE FLOWING AIRSTREAM DESIGN ARE TRADEMARKS OR REGISTERED TRADEMARKS OF
PRAXAIR TECHNOLOGY, INC. IN THE UNITED STATES AND/OR OTHER COUNTRIES.
FULL TEXT OF H-PHRASES:
ACUTE TOX. 1 (INHALATION: GAS): ACUTE TOXICITY (INHALATION:GAS) CATEGORY 1
ACUTE TOX. 4 (INHALATION: GAS): ACUTE TOXICITY (INHALATION:GAS) CATEGORY 4
COMPRESSED GAS: GASES UNDER PRESSURE COMPRESSED GAS
EYE DAM. 1: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 1
LIQUEFIED GAS: GASES UNDER PRESSURE LIQUEFIED GAS
OX. GAS 1: OXIDIZING GASES CATEGORY 1
SKIN CORR. 1A: SKIN CORROSION/IRRITATION CATEGORY 1A
H270: MAY CAUSE OR INTENSIFY FIRE; OXIDIZER
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H318: CAUSES SERIOUS EYE DAMAGE
H330: FATAL IF INHALED
H332: HARMFUL IF INHALED
SDS US (GHS HAZCOM 2012)
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
DESCRIBE THE PRODUCT FOR THE PURPOSES OF HEALTH, SAFETY AND ENVIRONMENTAL
REQUIREMENTS ONLY. IT SHOULD NOT THEREFORE BE CONSTRUED AS GUARANTEEING
ANY SPECIFIC PROPERTY OF THE PRODUCT.
EN (ENGLISH US)
SDS ID: PTG-4012