| Common Name: | DE-ICER WINDSHIELD WASHER ADDITIVE WITH DIRT BLOCKER |
| Manufacturer: | PRESTONE PRODUCTS |
| SDS Revision Date: | 6/11/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 49XW68, 49XW76 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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PRESTONE(R*)
SDS 530
PRESTONE(R*) DE-ICER WINDSHIELD WASHER ADDITIVE WITH DIRT BLOCKER
DATE PREPARED: 06/11/2014
SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
SDS ID: SDS530
PRODUCT NAME:
PRESTONE(R*) DE-ICER WINDSHIELD WASHER ADDITIVE WITH DIRT BLOCKER
PRODUCT NUMBER: AS240, AS240B, 70904
FORMULA NUMBER: 2275-31, 2309-131
MANUFACTURER:
PRESTONE PRODUCTS CORPORATION
DANBURY, CT 06810-5109
CANADIAN OFFICE:
FRAM GROUP (CANADA), INC.
MISSISSAUGA, ONTARIO L5L 3S6
MEDICAL EMERGENCIES AND ALL OTHER INFORMATION PHONE NUMBER:
(800)890-2075 (IN THE US)
(800)668-9349 (IN CANADA)
TRANSPORTATION EMERGENCY PHONE NUMBER (CHEMICAL SPILLS AND TRANSPORT
ACCIDENTS ONLY):
CHEMTREC: 1-800-424-9300 (IN THE US)
CANUTEC: (613)996-6666 (IN CANADA)
SDS DATE OF PREPARATION/REVISION: 06/11/14
PRODUCT USE: AUTOMOBILE WINDSHIELD CLEANER/DEICER - CONSUMER PRODUCT
RESTRICTIONS ON USE: NONE IDENTIFIED
| 2. HAZARDS IDENTIFICATION | |
GHS/HAZCOM 2012 CLASSIFICATION:
HEALTH:
ACUTE TOXICITY CATEGORY 3 (INHALATION, ORAL, DERMAL)
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY - REPEAT EXPOSURE CATEGORY 2
EYE IRRITANT CATEGORY 2A
PHYSICAL: FLAMMABLE LIQUID CATEGORY 2
LABEL ELEMENTS:
FLAME
SKULLS AND CROSSBONES
EXCLAMATION MARK
HEALTH HAZARD
DANGER!
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H301+H311+H331: TOXIC IF SWALLOWED, IN CONTACT WITH SKIN AND IF INHALED.
H319: CAUSES SERIOUS EYE IRRITATION
H370: CAUSES DAMAGE TO EYES.
H373: MAY CAUSE DAMAGE TO KIDNEYS THROUGH PROLONGED OR REPEATED EXPOSURE.
PREVENTION:
P210:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, AND HOT SURFACES. NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND, OR BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, AND LIGHTING EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P260: DO NOT BREATHE VAPORS, OR SPRAY.
P264: WASH EXPOSED SKIN THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280: WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE PROTECTION.
RESPONSE:
P303 + P361 + P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER, OR
SHOWER.
P312: CALL A POISON CENTER OR DOCTOR IF YOU FEEL UNWELL.
P301+ P310:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR.
P330: RINSE MOUTH.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
P304 + P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P308 + P311:
IF EXPOSED OR CONCERNED: CALL A POISON CENTER, OR DOCTOR.
P370 + P378:
IN CASE OF FIRE:
USE WATER FOG, CARBON DIOXIDE, ALCOHOL FOAM OR DRY CHEMICAL TO EXTINGUISH.
STORAGE:
P403 + P233:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P405: STORE LOCKED UP.
DISPOSAL:
P501:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH LOCAL AND NATIONAL
REGULATIONS.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENT CAS NO. AMOUNT
METHYL ALCOHOL (METHANOL) 67-56-1 40 - 70%
ETHYLENE GLYCOL 107-21-1 15 - 40%
ISOPROPYL ALCOHOL (ISOPROPANOL) 67-63-0 5 - <20%
NON-HAZARDOUS INGREDIENTS MIXTURE 7 - 14%
SILICONE COPOLYMER PROPRIETARY <2%
THE EXACT CONCENTRATIONS ARE A TRADE SECRET.
| 4. FIRST AID MEASURES | |
INHALATION:
REMOVE THE VICTIM TO FRESH AIR. IF BREATHING HAS STOPPED ADMINISTER
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, HAVE MEDICAL PERSONNEL
ADMINISTER OXYGEN. GET IMMEDIATE MEDICAL ATTENTION.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. IMMEDIATELY WASH CONTACTED AREA THOROUGHLY
WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET
MEDICAL ATTENTION IF IRRITATION PERSISTS.
INGESTION:
SEEK IMMEDIATE MEDICAL ATTENTION. IMMEDIATELY CALL LOCAL POISON CONTROL
CENTER OR GO TO AN EMERGENCY DEPARTMENT. NEVER GIVE ANYTHING BY MOUTH TO OR
INDUCE VOMITING IN AN UNCONSCIOUS OR DROWSY PERSON.
MOST IMPORTANT SYMPTOMS:
INHALATION MAY CAUSE HEADACHE, DIZZINESS, DROWSINESS, NAUSEA, VISUAL
IMPAIRMENT, NARCOSIS AND UNCONSCIOUSNESS. METHYL ALCOHOL MAY BE ABSORBED
THROUGH THE SKIN IN HARMFUL AMOUNTS. POISONOUS IF SWALLOWED.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT, IF NEEDED:
SEEK IMMEDIATE MEDICAL ATTENTION FOR INGESTION; OR PROLONGED OR EXCESSIVE
DERMAL EXPOSURES.
NOTES TO PHYSICIAN:
THE COMBINATION OF VISUAL DISTURBANCES, METABOLIC ACIDOSIS AND AN OSMOL GAP
IS EVIDENCE OF METHANOL POISONING. ETHANOL IS ANTIDOTAL AND ITS EARLY
ADMINISTRATION MAY BLOCK THE FORMATION OF TOXIC METABOLITES OF METHANOL.
THE PRINCIPAL TOXIC EFFECTS OF ETHYLENE GLYCOL, WHEN SWALLOWED, ARE KIDNEY
DAMAGE AND METABOLIC ACIDOSIS. THE COMBINATION OF METABOLIC ACIDOSIS, AN
OSMOL GAP AND OXALATE CRYSTALS IN THE URINE IS EVIDENCE OF ETHYLENE GLYCOL
POISONING. ETHANOL IS ANTIDOTAL AND ITS EARLY ADMINISTRATION MAY BLOCK THE
FORMATION OF NEPHROTOXIC METABOLITES OF ETHYLENE GLYCOL IN THE LIVER. THE
OBJECTIVE IS TO RAPIDLY ACHIEVE AND MAINTAIN A BLOOD ETHANOL LEVEL OF
APPROXIMATELY 100 MG/DL BY GIVING A LOADING DOSE OF ETHANOL FOLLOWED BY A
MAINTENANCE DOSE. INTRAVENOUS ADMINISTRATION OF ETHANOL IS THE PREFERRED
ROUTE. ETHANOL BLOOD LEVELS SHOULD BE CHECKED FREQUENTLY. HEMODIALYSIS MAY
BE REQUIRED.
4-METHYL PYRAZOLE (FOMEPIZOLE(R)), A POTENT INHIBITOR OF ALCOHOL
DEHYDROGENASE, HAS BEEN USED THERAPEUTICALLY TO DECREASE THE METABOLIC
CONSEQUENCES OF METHANOL AND ETHYLENE GLYCOL POISONING. FOMEPIZOLE IS
EASIER TO USE CLINICALLY THAN ETHANOL, DOES NOT CAUSE CNS DEPRESSION OR
HYPOGLYCEMIA AND REQUIRES LESS MONITORING THAN ETHANOL. FOLIC ACID MAY ALSO
BE ADMINISTERED TO ENHANCE THE METABOLISM OF FORMIC ACID, THE TOXIC
METABOLITE OF METHANOL. ADDITIONAL THERAPEUTIC MODALITIES WHICH MAY
DECREASE THE ADVERSE CONSEQUENCES OF ETHYLENE GLYCOL METABOLISM ARE THE
ADMINISTRATION OF BOTH THIAMINE AND PYRIDOXINE.
PULMONARY EDEMA WITH HYPOXIA HAS BEEN DESCRIBED IN A NUMBER OF PATIENTS
FOLLOWING POISONING WITH ETHYLENE GLYCOL. RESPIRATORY SUPPORT WITH
MECHANICAL VENTILATION MAY BE REQUIRED.
THERE MAY BE CRANIAL NERVE INVOLVEMENT IN THE LATE STAGES OF TOXICITY FROM
SWALLOWED ETHYLENE GLYCOL. IN PARTICULAR, EFFECTS HAVE BEEN REPORTED
INVOLVING THE SEVENTH, EIGHTH AND NINTH CRANIAL NERVES, PRESENTING WITH
BILATERAL FACIAL PARALYSIS, DIMINISHED HEARING AND DYSPHAGIA.
AS THERE ARE COMPLICATED AND SERIOUS OVERDOSES, WE RECOMMEND YOU CONSULT
WITH THE TOXICOLOGISTS AT YOUR POISON CONTROL CENTER.
| 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE WATER FOG, CARBON DIOXIDE, ALCOHOL FOAM OR DRY CHEMICAL. COOL FIRE
EXPOSED CONTAINERS WITH WATER.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FLAMMABLE LIQUID. METHANOL-WATER MIXTURES WILL BURN UNLESS VERY DILUTE.
FLAME IS INVISIBLE IN DAYLIGHT. VAPORS ARE HEAVIER THAN AIR AND MAY FLOW
ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASHBACK. BURNING MAY
PRODUCE CARBON MONOXIDE AND CARBON DIOXIDE.
SPECIAL FIRE FIGHTING PROCEDURES:
FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE CLOTHING FOR FIRES IN AREAS WHERE CHEMICALS
ARE USED OR STORED.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ELIMINATE ALL IGNITION SOURCES. VENTILATE AREA. WEAR APPROPRIATE PROTECTIVE
CLOTHING AND EQUIPMENT (SEE SECTION 8).
METHODS AND MATERIALS FOR CONTAINMENT/CLEANUP:
COLLECT WITH ABSORBENT MATERIAL AND PLACE IN A CONTAINER SUITABLE FOR
FLAMMABLE WASTE.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED! DO NOT SWALLOW. AVOID EYE AND
SKIN CONTACT. AVOID BREATHING VAPORS OR MISTS. USE ONLY WITH ADEQUATE
VENTILATION. WASH EXPOSED SKIN THOROUGHLY WITH SOAP AND WATER AFTER USE.
FLAMMABLE LIQUID! KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND ALL OTHER
SOURCES OF IGNITION. DO NOT SMOKE DURING USE.
EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND MAY BE DANGEROUS. DO NOT CUT,
WELD, DRILL, ETC. CONTAINERS, EVEN EMPTY. DO NOT REUSE EMPTY CONTAINERS
UNLESS PROPERLY CLEANED.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND ALL OTHER SOURCES OF IGNITION.
STORE IN A COOL, WELL-VENTILATED AREA.
NFPA CLASSIFICATION: IB
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE GUIDELINES
CHEMICAL EXPOSURE LIMIT
METHYL ALCOHOL (METHANOL) 200 PPM TWA OSHA PEL
200 PPM TWA ACGIH TLV SKIN
250 PPM STEL ACGIH TLV
ETHYLENE GLYCOL NONE ESTABLISHED-OSHA PEL
100 MG/M3 CEILING ACGIH TLV
ISOPROPYL ALCOHOL (ISOPROPANOL) 400 PPM TWA OSHA PEL
200 PPM TWA ACGIH TLV SKIN
400 PPM STEL ACGIH TLV
NON-HAZARDOUS INGREDIENTS NONE ESTABLISHED
SILICONE COPOLYMER NONE ESTABLISHED
APPROPRIATE ENGINEERING CONTROLS:
USE GENERAL VENTILATION OR LOCAL EXHAUST AS REQUIRED TO MAINTAIN EXPOSURES
BELOW THE OCCUPATIONAL EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
FOR OPERATIONS WHERE THE TLV IS EXCEEDED A NIOSH APPROVED SUPPLIED AIR
RESPIRATOR OR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS IS
RECOMMENDED. ORGANIC VAPOR CARTRIDGE RESPIRATORS ARE NOT RECOMMENDED FOR
METHANOL VAPOR EXPOSURES. EQUIPMENT SELECTION DEPENDS ON CONTAMINANT TYPE
AND CONCENTRATION. SELECT AND USE IN ACCORDANCE WITH 29 CFR 1910.134 AND
GOOD INDUSTRIAL HYGIENE PRACTICE. FOR FIREFIGHTING, USE SELF-CONTAINED
BREATHING APPARATUS.
GLOVES:
CHEMICAL RESISTANT GLOVES SUCH AS BUTYL RUBBER OR VITON WHERE CONTACT IS
POSSIBLE.
EYE PROTECTION:
SPLASH PROOF GOGGLES ARE RECOMMENDED TO PREVENT EYE CONTACT.
OTHER PROTECTIVE EQUIPMENT/CLOTHING:
APPROPRIATE PROTECTIVE CLOTHING AS NEEDED TO MINIMIZE SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR LIQUID
ODOR: ALCOHOL
ODOR THRESHOLD: 160 - 690 PPM (METHANOL)
PH: 9.0
MELTING/FREEZING POINT: <-58 DEG. F (<-50 DEG. C)
BOILING POINT/RANGE: 166 DEG. F (74.4 DEG. C)
FLASH POINT: 62 DEG. F (16 DEG. C)
SETAFLASH EVAPORATION RATE (BUTYL ACETATE = 1): >1
FLAMMABILITY (SOLID, GAS): HIGHLY FLAMMABLE LIQUID
FLAMMABILITY LIMITS:
LEL: 2.0% (ISOPROPANOL)
UEL: 36% (METHANOL)
VAPOR PRESSURE: NOT DETERMINED
VAPOR DENSITY: >1
RELATIVE DENSITY: 0.87
SOLUBILITIES WATER: 100%
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED
AUTOIGNITION TEMPERATURE: NOT DETERMINED
DECOMPOSITION TEMPERATURE: NOT DETERMINED
VISCOSITY: NOT DETERMINED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NORMALLY UNREACTIVE
CHEMICAL STABILITY: STABLE
POSSIBILITY OF HAZARDOUS REACTIONS:
REACTION WITH STRONG OXIDIZERS WILL GENERATE HEAT.
CONDITIONS TO AVOID:
HEAT, SPARKS, FLAMES AND ALL OTHER SOURCES OF IGNITION.
INCOMPATIBLE MATERIALS:
STRONG BASES, STRONG ACIDS, STRONG OXIDIZING AGENTS AND MATERIALS REACTIVE
WITH HYDROXYL COMPOUNDS.
HAZARDOUS DECOMPOSITION PRODUCTS:
COMBUSTION WILL PRODUCE CARBON MONOXIDE, CARBON DIOXIDE.
| 11. TOXICOLOGICAL INFORMATION | |
POTENTIAL HEALTH EFFECTS:
ACUTE HAZARDS:
INHALATION:
MAY CAUSE IRRITATION OF THE NOSE AND THROAT WITH HEADACHE, PARTICULARLY
FROM MISTS. HIGH VAPOR CONCENTRATIONS MAY PRODUCE NAUSEA, VOMITING,
HEADACHE, DIZZINESS, DROWSINESS, TINGLING, NUMBNESS AND SHOOTING PAINS IN
THE HANDS AND FOREARMS, AND VISUAL DISTURBANCES.
SKIN CONTACT:
PROLONGED CONTACT WITH THE SKIN MAY CAUSE REDNESS AND DEFATTING OF THE SKIN
AND ABSORPTION OF HARMFUL AMOUNTS OF METHANOL.
EYE CONTACT:
LIQUID, VAPORS OR MIST MAY CAUSE DISCOMFORT IN THE EYE WITH PERSISTENT
CONJUNCTIVITIS, SEEN AS SLIGHT EXCESS REDNESS OR CONJUNCTIVA. SERIOUS
CORNEAL INJURY IS NOT ANTICIPATED.
INGESTION:
CONTAINS METHANOL AND ETHYLENE GLYCOL. MAY CAUSE ABDOMINAL DISCOMFORT OR
PAIN, NAUSEA, VOMITING, DIZZINESS, DROWSINESS, HEADACHE, MALAISE, BLURRING
OF VISION, IRRITABILITY, BACK PAIN, DECREASE IN URINE OUTPUT, KIDNEY
FAILURE, AND CENTRAL NERVOUS SYSTEM EFFECTS, INCLUDING IRREGULAR EYE
MOVEMENTS, CONVULSIONS AND COMA. VISUAL EFFECTS FROM METHANOL INCLUDE
BLURRED VISION, DOUBLE VISION, CHANGES IN COLOR PERCEPTION, RESTRICTION OF
VISUAL FIELDS AND COMPLETE BLINDNESS. CARDIAC FAILURE AND PULMONARY EDEMA
MAY DEVELOP. SEVERE KIDNEY DAMAGE WHICH MAY BE FATAL FOLLOWS THE SWALLOWING
OF LARGE VOLUMES OF ETHYLENE GLYCOL. SIGNS OF RENAL INSUFFICIENCY MAY BE
DELAYED 36 TO 48 HOURS POST INGESTION. A FEW REPORTS HAVE BEEN PUBLISHED
DESCRIBING THE DEVELOPMENT OF WEAKNESS OF THE FACIAL MUSCLES, DIMINISHING
HEARING, AND DIFFICULTY WITH SWALLOWING, DURING THE LATE STAGES OF SEVERE
POISONING. CARDIOGENIC PULMONARY EDEMA CAN ALSO OCCUR FROM ETHYLENE GLYCOL
POISONING.
WITH MASSIVE OVERDOSES OF METHANOL, LIVER, KIDNEY AND HEART MUSCLE INJURY
HAVE BEEN DESCRIBED. THERE MAY BE A DELAY OF 6-12 HOURS BETWEEN SWALLOWING
METHANOL AND THE ONSET OF SIGNS AND SYMPTOMS. INGESTION OF MODERATE
QUANTITIES OF METHANOL ALSO PRODUCES METABOLIC ACIDOSIS. 60-200 ML OF
METHANOL IS A FATAL DOSE FOR MOST ADULTS INGESTION OF AS LITTLE AS 10 ML
MAY CAUSE BLINDNESS.
CHRONIC EFFECTS:
PROLONGED OR REPEATED INHALATION EXPOSURE MAY PRODUCE SIGNS OF CENTRAL
NERVOUS SYSTEM INVOLVEMENT, INCLUDING NAUSEA, VOMITING, HEADACHE, RINGING
IN THE EARS, DIZZINESS, VERTIGO, CLOUDY AND DOUBLE VISION. PROLONGED
OVEREXPOSURE AT LEVELS OF 800-1000 PPM MAY RESULT AND IN SEVERE EYE DAMAGE.
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE SKIN SENSITIZATION AND AN
ASSOCIATED DERMATITIS IN SOME INDIVIDUALS. ETHYLENE GLYCOL HAS BEEN FOUND
TO CAUSE BIRTH DEFECTS IN LABORATORY ANIMALS. THE SIGNIFICANCE OF THIS
FINDING TO HUMANS HAS NOT BEEN DETERMINED.
CARCINOGENICITY LISTING:
NONE OF THE COMPONENTS OF THESE PRODUCTS IS LISTED AS A CARCINOGEN OR
SUSPECTED CARCINOGEN BY IARC, NTP, ACGIH OR OSHA.
ACUTE TOXICITY VALUES:
CALCULATED ATE FOR PRODUCT:
ATE ORAL: 142 MG/KG
ATE DERMAL: 428 MG/KG
ATE INHALATION: 4.3 MG/L
METHANOL:
LD50 ORAL RAT: 5,628 MG/KG
LC50 INHALATION RAT: 64,000 PPM/4 HR.
LD50 DERMAL RABBIT: 15,800 MG/KG
ETHYLENE GLYCOL:
LD50 ORAL RAT: 4,700 MG/KG
LD50 SKIN RABBIT: 9,530 MG/KG
ISOPROPYL ALCOHOL:
LD50 ORAL RAT: 5045 MG/KG
LD50 SKIN RABBIT: 12,800 MG/KG
LC50 INHALATION RAT: 72.6 MG/L/4H
SILICONE COPOLYMER:
LD50 ORAL RAT: >5000 MG/KG
LD50 SKIN RABBIT: >2000 MG/KG
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
METHANOL:
LC50 FATHEAD MINNOWS: 29,400 MG/L/96 HR.
EC50 DAPHNIA MAGNA: >10,000 MG/L/24 HR.
ETHYLENE GLYCOL:
LC50 FATHEAD MINNOW: <10,000 MG/L/96 HR.
EC50 DAPHNIA MAGNA: 100,000 MG/L/48 HR.
BACTERIAL (PSEUDOMONAS PUTIDA): 10,000 MG/L
PROTOZOA (ENTOSIPHON SULCATUM AND URONEMA PARDUCZI; CHATTON-LWOFF):
>10,000 MG/L
ALGAE (MICROCYSTIS AERUGINOSA): 2,000 MG/L
GREEN ALGAE (SCENEDESMUS QUANDRICAUDA): >10,000 MG/L
ISOPROPYL ALCOHOL:
LC50 FATHEAD MINNOW: 6550 MG/L/96 HR
PERSISTENCE AND DEGRADABILITY:
METHANOL: READILY BIODEGRADABLE.
ETHYLENE GLYCOL IS READILY BIODEGRADABLE (97-100% IN 2-12 DAYS).
ISOPROPYL ALCOHOL IS READILY BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL:
METHANOL:
ESTIMATED BCF OF 3 - POTENTIAL FOR BIOCONCENTRATION IN AQUATIC ORGANISMS IS
LOW.
ETHYLENE GLYCOL:
A BCF OF 10, REPORTED FOR ETHYLENE GLYCOL IN FISH, GOLDEN IDE (LEUCISCUS
IDUS MELANOTUS), AFTER 3 DAYS OF EXPOSURE SUGGESTS THE POTENTIAL FOR
BIOCONCENTRATION IN AQUATIC ORGANISMS IS LOW.
ISOPROPYL ALCOHOL:
IN ADULTS, THE ELIMINATION HALF LIFE RANGES FROM 2.9 TO 16.2 HOURS.
MOBILITY IN SOIL:
METHANOL: VERY HIGH
ETHYLENE GLYCOL IS HIGHLY MOBILE IN SOIL.
ISOPROPYL ALCOHOL IS HIGHLY MOBILE IN SOIL.
OTHER ADVERSE EFFECTS: NONE
| 13. DISPOSAL CONSIDERATIONS | |
RECYCLE, INCINERATE, TREAT OR LANDFILL IN ACCORDANCE WITH ALL LOCAL,
STATE/PROVINCIAL AND FEDERAL REGULATIONS.
| 14. TRANSPORT INFORMATION | |
U.S. DOT HAZARD CLASSIFICATION (FOR GROUND SHIPMENTS ONLY):
CONTAINERS NOT OVER 1 LITER (0.3 GAL.):
PROPER SHIPPING NAME:
UN1993, FLAMMABLE LIQUID, N.O.S., (METHANOL, ISOPROPANOL), 3, PG II LIMITED
QUANTITIES
TECHNICAL NAME: FLAMMABLE LIQUID, N.O.S., (METHANOL, ISOPROPANOL)
UN NUMBER: UN1993
HAZARD CLASS/PACKING GROUP: 3, II
LABELS REQUIRED: LIMITED QUANTITY MARK
CONTAINERS OVER 1 LITER:
UN1993, FLAMMABLE LIQUID, N.O.S., (METHANOL, ISOPROPANOL), 3, PG II
DOT MARINE POLLUTANTS:
THIS PRODUCT DOES NOT CONTAIN MARINE POLLUTANTS AS DEFINED IN 49 CFR 171.8.
IMDG CODE SHIPPING CLASSIFICATION:
ONLY CONTAINERS NOT OVER 1 LITER CAN BE SHIPPED AS LIMITED QUANTITIES:
DESCRIPTION:
UN1992, FLAMMABLE LIQUID, TOXIC, N.O.S. (METHANOL, ISOPROPANOL) 3 (6.1), PG
II, FP 16 C, LTD QTY
ID NUMBER: UN1992
HAZARD CLASS: 3 (6.1)
PACKING GROUP: II
LABELS REQUIRED: LIMITED QUANTITY MARK
PLACARDS REQUIRED: LIMITED QUANTITIES MARK ON CARGO TRANSPORT CONTAINERS
NOTE:
THIS PRODUCT IS EXEMPTED FROM MARKING THE UN NUMBER (SEE IMDG CODE 3.4.7)
CANADIAN TDG CLASSIFICATION (FOR GROUND SHIPMENTS ONLY):
CONTAINERS NOT OVER 1 LITER (0.3 GAL.):
PROPER SHIPPING NAME: CONSUMER COMMODITY (LIMITED QUANTITY)
TECHNICAL NAME: NONE
UN NUMBER: NONE
HAZARD CLASS: NONE
PACKING GROUP: NONE
CONTAINERS OVER 1 LITER:
UN1992, FLAMMABLE LIQUID, TOXIC, N.O.S., (METHANOL, ISOPROPANOL), 3 (6.1),
PG II
IATA/ICAO SHIPPING CLASSIFICATION:
THESE PRODUCTS ARE NOT SUITABLE FOR SHIPMENT BY AIR.
| 15. REGULATORY INFORMATION | |
EPA SARA 311/312 HAZARD CLASSIFICATION:
ACUTE HEALTH, CHRONIC HEALTH, FIRE HAZARD
EPA SARA 313:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS SUBJECT TO ANNUAL RELEASE
REPORTING REQUIREMENTS UNDER SARA TITLE LLL, SECTION 313 (40 CFR 372):
METHANOL 67-56-1 40-70%
ETHYLENE GLYCOL 107-21-1 15-40%
PROTECTION OF STRATOSPHERIC OZONE:
THIS PRODUCT IS NOT KNOWN TO CONTAIN OR TO HAVE BEEN MANUFACTURED WITH
OZONE DEPLETING SUBSTANCES AS DEFINED IN 40 CFR PART 82, APPENDIX A TO
SUBPART A.
CERCLA SECTION 103:
SPILLS OF THIS PRODUCT OVER THE RQ (REPORTABLE QUANTITY) MUST BE REPORTED
TO THE NATIONAL RESPONSE CENTER. THE RQ FOR THE PRODUCT, BASED ON THE RQ
FOR METHANOL (70% MAXIMUM) OF 5,000 LBS, IS 7,140 LBS. MANY STATES HAVE
MORE STRINGENT RELEASE REPORTING REQUIREMENTS. REPORT SPILLS REQUIRED UNDER
FEDERAL, STATE AND LOCAL REGULATIONS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS REGULATED UNDER CALIFORNIA
PROPOSITION 65: METHANOL (CAS # 67-56-1) 40-70% (DEVELOPMENTAL TOXICITY)
EPA TSCA INVENTORY:
ALL OF THE COMPONENTS OF THIS MATERIAL ARE LISTED ON THE TOXIC SUBSTANCES
CONTROL ACT (TSCA) CHEMICAL SUBSTANCES INVENTORY.
CANADIAN ENVIRONMENTAL PROTECTION ACT:
ALL OF THE INGREDIENTS ARE LISTED ON THE CANADIAN DOMESTIC SUBSTANCES LIST
OR EXEMPT FROM NOTIFICATION.
CANADIAN WHMIS CLASSIFICATION:
CLASS D - DIVISION 2 - SUBDIVISION A - (A VERY TOXIC MATERIAL CAUSING OTHER
TOXIC EFFECTS), CLASS B - DIVISION 2 (FLAMMABLE LIQUID)
CANADIAN WHMIS HAZARD SYMBOLS:
D2 - MATERIALS CAUSING OTHER TOXIC EFFECTS
B - FLAMMABLE AND COMBUSTIBLE MATERIAL
THIS SDS HAS BEEN PREPARED ACCORDING TO THE CRITERIA OF THE CONTROLLED
PRODUCTS REGULATION (CPR) AND THE SDS CONTAINS ALL OF THE INFORMATION
REQUIRED BY THE CPR.
EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES (EINECS):
ALL OF THE INGREDIENTS ARE LISTED ON THE EINECS INVENTORY.
| 16. OTHER INFORMATION | |
NFPA RATING:
HEALTH 2
FIRE 3
INSTABILITY 0
REVISION SUMMARY:
SECTION 2: CORRECTION TO P PHRASES.
SDS DATE OF PREPARATION/REVISION: JUNE 11, 2014
THIS SDS IS DIRECTED TO PROFESSIONAL USERS AND BULK HANDLERS OF THE
PRODUCT. CONSUMER PRODUCTS ARE LABELED IN ACCORDANCE WITH FEDERAL HAZARDOUS
SUBSTANCES ACT REGULATIONS.
WHILE PRESTONE PRODUCTS CORPORATION BELIEVES THAT THE DATA CONTAINED HEREIN
ARE FACTUAL AND THE OPINIONS EXPRESSED ARE THOSE OF QUALIFIED EXPERTS
REGARDING THE RESULTS OF TESTS CONDUCTED, THE DATA ARE NOT TO BE TAKEN AS A
WARRANTY OR REPRESENTATION FOR WHICH PRESTONE PRODUCTS CORPORATION ASSUMES
LEGAL RESPONSIBILITY. THEY ARE OFFERED FOR YOUR CONSIDERATION,
INVESTIGATION AND VERIFICATION. ANY USE OF THESE DATA AND INFORMATION MUST
BE DETERMINED BY THE USER TO BE IN ACCORDANCE WITH APPLICABLE FEDERAL,
STATE AND LOCAL LAWS AND REGULATIONS.
IF MORE INFORMATION IS NEEDED, PLEASE CONTACT:
PRESTONE PRODUCTS CORPORATION
69 EAGLE ROAD
DANBURY CT 06810
(800)-890-2075