| Common Name: | METACAULK 835+ |
| Manufacturer: | RECTORSEAL |
| SDS Revision Date: | 9/17/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 49ZY40, 49ZY41 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
SDS 0463
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION |  |
HMIS CODES:
HEALTH 1
FLAMMABILITY 2
REACTIVITY 0
PPI B
PRODUCT NAME: METACAULK 835+
PRODUCT CODES: 66012, 66019, 66645
CHEMICAL FAMILY: ORGANIC/INORGANIC
USE: FIRESTOPPING SEALANT
MANUFACTURER'S NAME:
THE RECTORSEAL CORPORATION
2601 SPENWICK DRIVE
HOUSTON, TEXAS 77055
USA
EMERGENCY TELEPHONE NO.:
CHEMTREC 24 HOURS
(800)424-9300 USA
(703)527-3887 INTERNATIONAL
TECHNICAL SERVICE TELEPHONE NO.: (800)231-3345 OR (713)263-8001
DATE OF VALIDATION: SEPTEMBER 17, 2015
DATE OF PREPARATION: SEPTEMBER 17, 2015
| SECTION 2 - HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
PHYSICAL HAZARDS: NONE
HEALTH HAZARDS:
EYE IRRITATION: CATEGORY 2B
SKIN IRRITATION: CATEGORY 2
SKIN SENSITIZATION: CATEGORY 1B
CARCINOGENICITY: CATEGORY 2
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT: NOT CLASSIFIED
ACUTE AQUATIC TOXICITY: NOT CLASSIFIED
CHRONIC AQUATIC TOXICITY: NOT CLASSIFIED
BIOACCUMULATION POTENTIAL: NOT CLASSIFIED
RAPID DEGRADABILITY: NOT CLASSIFIED
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
PICTOGRAM: GHS 508 HEALTH HAZARD
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
H315: CAUSES SKIN IRRITATION
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H319: CAUSES EYE IRRITATION
H351: SUSPECTED OF CAUSING CANCER
PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P261: AVOID BREATHING DUST, FUME OR VAPORS.
P262: DO NOT GET IN EYES, ON SKIN OR ON CLOTHING.
P264: WASH HANDS AND OTHER SKIN AREAS THOROUGHLY AFTER HANDLING
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P272: CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P302+P352+P333+P313:
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. IF SKIN IRRITATION OR RASH OCCURS, GET
MEDICAL ATTENTION.
P305+P351+P338:
IF IN EYES:
RINSE WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES IF PRESENT AND
EASY TO DO. CONTINUE RINSING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P321:
SPECIFIC TREATMENT: SEEK IMMEDIATE MEDICAL ADVICE. REFER TO PRODUCT LABEL
AND SECTION 4 OF THIS SDS.
P362: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
STORAGE:
P405+P403: STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
P501:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH APPLICABLE LOCAL,
REGIONAL, NATIONAL AND INTERNATIONAL REGULATIONS
SUMMARY OF ACUTE HAZARDS:
MAY CAUSE SKIN/EYE IRRITATION AND AN ALLERGIC SKIN REACTION.
ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS:
INHALATION:
NOT KNOWN TO BE A RESPIRATORY IRRITANT. PROLONGED INHALATION MAY BE
HARMFUL.
EYE CONTACT: CONTACT MAY CAUSE EYE IRRITATION.
SKIN CONTACT: CONTACT MAY CAUSE SKIN IRRITATION.
INGESTION:
POSSIBLE IRRITATION TO MUCOUS MEMBRANES OF THE MOUTH, THROAT, AND STOMACH.
SUMMARY OF CHRONIC HAZARDS: NONE KNOWN.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
PERSONS WITH PRE-EXISTING SKIN CONDITIONS OR CHEMICAL ALLERGIES MAY BE MORE
SUSCEPTIBLE TO CONTACT EFFECTS OF THE CURED ELASTOMER.
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT: AMORPHOUS SILICA
PERCENTAGE BY WEIGHT: 3-7
CAS NUMBER: 7631-86-9
EC#: 231-545-4
INGREDIENT: KETOXIME SILANE
PERCENTAGE BY WEIGHT: 3-7
CAS NUMBER: 22984-54-9
EC#:
INGREDIENT: CALCIUM CARBONATE
PERCENTAGE BY WEIGHT: 15-40
CAS NUMBER: 1317-65-3
EC#: 215-279-6
INGREDIENT: CARBON BLACK
PERCENTAGE BY WEIGHT: 0.1 - 1.0
CAS NUMBER: 1317-65-3
EC#: 215-609-9
INGREDIENT: TITANIUM DIOXIDE
PERCENTAGE BY WEIGHT: 0.1 - 1.0
CAS NUMBER: 13463-67-7
EC#: 236-675-5
| SECTION 4 - FIRST AID MEASURES | |
IF INHALED: NOT A RESPIRATORY IRRITANT.
IF ON SKIN:
WASH WITH SOAP AND WATER. IF IRRITATION OCCURS, SEEK MEDICAL ATTENTION.
IF IN EYES:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. IF IRRITATION OCCURS, SEEK
MEDICAL ATTENTION.
IF SWALLOWED:
IF SWALLOWED, CALL A PHYSICIAN IMMEDIATELY. ONLY INDUCE VOMITING AT THE
INSTRUCTION OF A PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.
| SECTION 5 - FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
FOAM, DRY CHEMICAL, CARBON DIOXIDE OR WATER FOG.
SPECIAL FIRE FIGHTING PROCEDURES: WEAR SELF-CONTAINED BREATHING APPARATUS
(SCBA) AND OTHER PROTECTIVE CLOTHING. HAZARDOUS DECOMPOSITION PRODUCTS
POSSIBLE (SEE SECTION 10).
UNUSUAL FIRE AND EXPLOSION HAZARDS:
HEAT MAY BUILD UP AND RUPTURE CLOSED CONTAINERS.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
WIPE UP SPILLS TO PREVENT FOOTING HAZARD. AVOID FLUSHING INTO SEWERS,
DRAINS, WATERWAYS AND SOIL. WEAR PROTECTIVE CLOTHING DURING CLEAN UP.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
KEEP CONTAINER CLOSED AND UPRIGHT WHEN NOT IN USE. TO PREVENT FREEZING AND
POSSIBLE RUPTURE OF CONTAINER, DO NOT STORE BELOW 35 F.
OTHER PRECAUTIONS:
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN OR CLOTHING. EMPTY CONTAINERS
MAY CONTAIN RESIDUES AND VAPORS; TREAT AS IF FULL AND OBSERVE ALL PRODUCT
PRECAUTIONS. DO NOT REUSE EMPTY CONTAINERS. KEEP OUT OF REACH OF CHILDREN.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENT UNITS
AMORPHOUS SILICA
ACGIH TLV: N/D PPM
OSHA PEL: N/D PPM
KETOXIME SILANE
ACGIH TLV: N/D PPM
OSHA PEL: N/D PPM
CALCIUM CARBONATE
ACGIH TLV: 10 MG/M3
OSHA PEL: 15 MG/M3
CARBON BLACK:
NIOSH REL: 3.5 MG/M3
OSHA PEL: 3.5 MG/M3
RESPIRATORY PROTECTION (SPECIFY TYPE): NONE REQUIRED.
VENTILATION - LOCAL EXHAUST: ACCEPTABLE
SPECIAL: N/A
MECHANICAL (GENERAL): PREFERABLE
OTHER: N/A
PROTECTIVE GLOVES: WEAR RUBBER GLOVES.
EYE PROTECTION: SAFETY GLASSES (ANSI Z-87.1 OR EQUIVALENT)
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: COVERALLS RECOMMENDED.
WORK/HYGIENIC PRACTICES:
WHERE USE CAN RESULT IN SKIN CONTACT, WASH EXPOSED AREAS THOROUGHLY BEFORE
EATING, DRINKING, SMOKING, OR LEAVING WORK AREA. LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT: NOT AVAILABLE
SPECIFIC GRAVITY (H2O = 1): 1.31 - 1.33
VAPOR PRESSURE (MM Hg): LESS THAN 5 MM Hg
MELTING POINT: N/A
VAPOR DENSITY (AIR = 1): N/A
EVAPORATION RATE (ETHYL ACETATE = 1): >1
APPEARANCE/ODOR: VISCOUS LIQUID, SMOOTH SELF-LEVELLING SEALANT
SOLUBILITY IN WATER: NOT AVAILABLE
VOLATILE ORGANIC COMPOUNDS(VOC)CONTENT 25 GRAMS PER LITER, <3% BY WEIGHT
(CHEMICALLY CURING SEALANTS AND CAULKS - CARB METHOD 310:
VOC LESS WATER, LESS EXEMPT COMPOUNDS AND LVP-VOCS).
FLASH POINT: NONE
LOWER EXPLOSION LIMIT: NONE
UPPER EXPLOSION LIMIT: NONE
| SECTION 10 - STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: NONE
INCOMPATIBILITY (MATERIALS TO AVOID): NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2 AND FRAGMENTED HYDROCARBONS.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| SECTION 11 - TOXICOLOGY INFORMATION | |
CHRONIC HEALTH HAZARDS:
NO INGREDIENT IN THIS PRODUCT IS AN IARC, NTP OR OSHA LISTED CARCINOGEN.
MAY CAUSE AN ALLERGIC SKIN REACTION. SUSPECTED OF CAUSING CANCER. ALTHOUGH
THE CARBON BLACK (CAS# 1333-86-4) IS ENCAPSULATED BY THE SILICONE SEALANT,
PROLONGED OVEREXPOSURE TO CARBON BLACK DUST CAUSES LUNG FIBROSIS. ALTHOUGH
THE TITANIUM DIOXIDE (CAS# 13463-67-7) IS ENCAPSULATED BY THE SILICONE
SEALANT, PROLONGED OVEREXPOSURE TO TITANIUM DIOXIDE DUST CAUSES TIGHTNESS
PAIN IN THE CHEST, COUGHING AND DIFFICULTY BREATHING. THE CURING VAPOR,
METHYL ETHYL KETOXIME (CAS# 96-29-7), MAY CAUSE DROWSINESS, INJURE BLOOD,
LIVER AND MAY IRRITATE OR HARM NOSE, THROAT, LUNGS AND EYES. DIRECT CONTACT
WITH EYES WILL IRRITATE. DIRECT CONTACT WITH SKIN MAY IRRITATE.
TOXICOLOGY DATA:
INGREDIENT NAME
AMORPHOUS SILICA:
ORAL-RAT LD50: 22,500 MG/KG
INHALATION-RAT LC50: N/D
KETOXIME SILANE:
ORAL-RAT LD50: N/D
INHALATION-RAT LC50: N/D
CALCIUM CARBONATE:
ORAL-RAT LD50: N/D
INHALATION-RAT LC50: N/D
CARBON BLACK:
ORAL-RAT LD50: >5,000 MG/KG
INHALATION-RAT LC50: >0.0046 MG/L
TITANIUM DIOXIDE:
ORAL-RAT LD50: >5,000 MG/KG
INHALATION-RAT LC50: >6.82 MG/L
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOLOGICAL DATA
INGREDIENT NAME:
KETOXIME SILANE:
TOXICITY TO FISH:
LC50 (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): >120 MG/L, 96 HRS.
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA MAGNA (WATER FLEA)): >120 MG/L, 48 HRS.
CARBON BLACK:
TOXICITY TO FISH:
LC50 (DANIO RERIO (ZEBRA FISH)): >1,000 MG/L, 96 HRS.
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA MAGNA (WATER FLEA)): >5,600 MG/L, 24 HRS.
TOXICITY TO ALGAE:
NOEC (DESMODESMUS SUBSPICATUS (GREEN ALGAE)): 10,000 MG/L, 72 HRS.
TITANIUM DIOXIDE:
TOXICITY TO FISH:
LC50 (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): >100 MG/L, 96 HRS.
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA MAGNA (WATER FLEA)): >100 MG/L, 48 HRS.
TOXICITY TO ALGAE:
EC50 (SKELETONEMA COSTATUM (MARINE DIATOM)): >10,000 MG/L, 72 HRS.
TOXICITY TO BACTERIA:
EC50: >1,000 MG/L, 3 HRS.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE CLASSIFICATION: NON-REGULATED SOLID WASTE
DISPOSAL METHOD: APPROVED LANDFILL
WASTE FROM THIS PRODUCT IS NOT CONSIDERED HAZARDOUS AS DEFINED UNDER THE
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261. DISPOSE OF IN
ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATION REGARDING POLLUTION.
| SECTION 14 - TRANSPORTATION INFORMATION | |
DOT: NON-REGULATED
OCEAN (IMDG): NON-REGULATED
AIR (IATA): NON-REGULATED
WHMIS (CANADA): NON-REGULATED
| SECTION 15 - REGULATORY INFORMATION | |
REGULATORY DATA:
INGREDIENT NAME:
AMORPHOUS SILICA:
SARA 313: N/A
TSCA INVENTORY: YES
CERCLA RQ: N/A
RCRA CODE: N/A
KETOXIME SILANE:
SARA 313: N/A
TSCA INVENTORY: YES
CERCLA RQ: N/A
RCRA CODE: N/A
CARBON BLACK:
SARA 313: N/A
TSCA INVENTORY: YES
CERCLA RQ: N/A
RCRA CODE: N/A
TITANIUM DIOXIDE:
SARA 313: N/A
TSCA INVENTORY: YES
CERCLA RQ: N/A
RCRA CODE: N/A
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS TRACE AMOUNT OF SUBSTANCES, IN THE FORM OF AIRBORNE
OR UNBOUND PARTICLES, KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR
OTHER REPRODUCTIVE HARM.
| SECTION 16 - OTHER INFORMATION | |
THIS DOCUMENT IS PREPARED PURSUANT TO THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200). THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH,
BUT NO WARRANTY, EXPRESSED OR IMPLIED IS MADE. CONSULT RECTORSEAL FOR
FURTHER INFORMATION: (713) 263-8001