| Common Name: | URETHN QT 4PK LOW VOC URETHANE ACTIVATOR, 207243 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 2/16/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 4CY68 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DATE PRINTED: 2/16/2016
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: URETHN QT 4PK LOW VOC URETHANE ACTIVATOR
PRODUCT IDENTIFIER: 207243
PRODUCT USE/CLASS: DTM URETHANE MASTIC/ACTIVATOR
REVISION DATE: 2/16/2016
SUPERCEDES DATE: 9/24/2015
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
| 2. HAZARD IDENTIFICATION | |
CLASSIFICATION:
SYMBOL(S) OF PRODUCT:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL WORD: DANGER
GHS HAZARD STATEMENTS:
FLAMMABLE LIQUID, CATEGORY 3:
H226: FLAMMABLE LIQUID AND VAPOR.
SKIN SENSITIZER, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
ACUTE TOXICITY, INHALATION, CATEGORY 4:
H332: HARMFUL IF INHALED.
RESPIRATORY SENSITIZER, CATEGORY 1:
H334:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
STOT, SINGLE EXPOSURE, CATEGORY 3, RTI:
H335: MAY CAUSE RESPIRATORY IRRITATION.
GHS LABEL PRECAUTIONARY STATEMENTS:
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P261: AVOID BREATHING DUST, FUMES, GASES, MISTS, VAPORS, OR SPRAY.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P285: IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P304+P341:
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A
POSITION COMFORTABLE FOR BREATHING.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P342+P311:
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
GHS SDS PRECAUTIONARY STATEMENTS:
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
RANGE
HEXAMETHYLENE 28182-81-2 75-100 GHS07-GHS08 H317-332-334-335
DIISOCYANATE
POLYMER
N-BUTYL ACETATE 123-86-4 2.5-10 GHS02-GHS07 H226-336
SOLVENT NAPHTHA, 64742-95-6 2.5-10 GHS07-GHS08 H304-332
LIGHT AROMATIC
HEXAMETHYLENE 822-06-0 0.1-1.0 GHS06-GHS08 H311-315-317-
DIISOCYANATE 319-330-334-335
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR
KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS. REMOVE CONTAMINATED CLOTHING.
WASH SKIN WITH SOAP AND WATER. GET MEDICAL ATTENTION.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. IF VICTIM IS CONSCIOUS AND ALERT,
GIVE 2 TO 4 CUPFULS OF WATER OR MILK. CALL A PHYSICIAN OR POISON CONTROL
CENTER IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
TREAT SYMPTOMATICALLY AND SUPPORTIVELY. IF SWALLOWED, GET MEDICAL
ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, DRY SAND
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT DUE TO BUILDUP
OF STEAM. COMBUSTION GENERATES TOXIC FUMES OF CARBON MONOXIDE, CARBON
DIOXIDE AND OTHER GASES. KEEP CONTAINERS TIGHTLY CLOSED. COMBUSTIBLE LIQUID
AND VAPOR. NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
SPECIAL FIREFIGHTING PROCEDURES:
EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE. USE WATER SPRAY TO KEEP
FIRE-EXPOSED CONTAINERS COOL. CONTAINERS MAY EXPLODE WHEN HEATED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS
SUCH AS SAWDUST. ISOLATE THE HAZARD AREA AND DENY ENTRY TO UNNECESSARY AND
UNPROTECTED PERSONNEL. REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA AND
REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. DISPOSE OF ACCORDING TO
LOCAL, STATE (PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED
CONTAINERS.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. USE ONLY WITH ADEQUATE
VENTILATION. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS
EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. AVOID
CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE:
STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN
NOT IN USE. KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL
EQUIPMENT, SPARKS AND OPEN FLAME. DO NOT STORE ABOVE 120 DEG. F. STORE
LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA
CLASS II COMBUSTIBLE LIQUIDS. AVOID EXCESS HEAT.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
HEXAMETHYLENE DIISOCYANATE 28182-81-2 90.0
POLYMER
SOLVENT NAPHTHA, LIGHT AROMATIC 64742-95-6 5.0
N-BUTYL ACETATE 123-86-4 5.0
HEXAMETHYLENE DIISOCYANATE 822-06-0 1.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL-CEILING
HEXAMETHYLENE N.E. N.E. N.E. N.E.
DIISOCYANATE POLYMER
SOLVENT NAPHTHA, LIGHT N.E. N.E. N.E. N.E.
AROMATIC
N-BUTYL ACETATE 150 PPM 200 PPM 150 PPM N.E.
HEXAMETHYLENE DIISOCYANATE 0.005 PPM N.E. N.E. N.E.
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE.
SKIN PROTECTION:
USE GLOVES TO PREVENT PROLONGED SKIN CONTACT. USE IMPERVIOUS GLOVES TO
PREVENT SKIN CONTACT AND ABSORPTION OF THIS MATERIAL THROUGH THE SKIN.
NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE
REGARDING TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
PHYSICAL STATE: LIQUID
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 1.120
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: WATER REACTIVE
PARTITION COEFFICIENT, N-OCTANOL/WATER: N.D.
DECOMPOSITION TEMP., DEG. C: N.D.
BOILING RANGE, DEG. C: 160 - 166
EXPLOSIVE LIMITS, VOL%: 1.2 - 7.5
FLAMMABILITY: SUPPORTS COMBUSTION
FLASH POINT, DEG. C: 53
EVAPORATION RATE: SLOWER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: N.D.
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
AVOID TEMPERATURES ABOVE 120 DEG. F (49 DEG. C). AVOID CONTACT WITH STRONG
ACID AND STRONG BASES. AVOID ALL POSSIBLE SOURCES OF IGNITION.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE. WHEN HEATED TO
DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES. CONTAINS
SOLVENTS WHICH MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, AND FORMALDEHYDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT:
CAUSES EYE BURNS. SUBSTANCE CAUSES MODERATE EYE IRRITATION.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
SUBSTANCE MAY CAUSE SLIGHT SKIN IRRITATION. CONTACT CAUSES SKIN IRRITATION.
CAUSES SKIN IRRITATION. ALLERGIC REACTIONS ARE POSSIBLE. MAY CAUSE SKIN
SENSITIZATION, AN ALLERGIC REACTION, WHICH BECOMES EVIDENT UPON RE-EXPOSURE
TO THIS MATERIAL.
EFFECTS OF OVEREXPOSURE - INHALATION:
HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE HARMFUL IF INHALED.
AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST. HIGH VAPOR CONCENTRATIONS
ARE IRRITATING TO THE EYES, NOSE, THROAT AND LUNGS. PROLONGED OR EXCESSIVE
INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY CAUSE ALLERGIC
RESPIRATORY REACTION.
EFFECTS OF OVEREXPOSURE - INGESTION:
CAN BURN MOUTH, THROAT AND STOMACH. IRRITATING TO THE NOSE, THROAT AND
RESPIRATORY TRACT. HARMFUL IF SWALLOWED. ASPIRATION HAZARD IF SWALLOWED;
CAN ENTER LUNGS AND CAUSE DAMAGE.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
OVEREXPOSURE MAY CAUSE LUNG DAMAGE. HIGH CONCENTRATIONS MAY LEAD TO CENTRAL
NERVOUS SYSTEM EFFECTS (DROWSINESS, DIZZINESS, NAUSEA, HEADACHES,
PARALYSIS, AND BLURRED VISION) AND/OR DAMAGE. REPORTS HAVE ASSOCIATED
REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT
BRAIN AND NERVOUS SYSTEM DAMAGE.
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
28182-81-2 HEXAMETHYLENE N.I. N.I. 18.5 MG/L RAT
DIISOCYANATE
POLYMER
123-86-4 N-BUTYL ACETATE 10768 MG/KG >17600 MG/KG >21 MG/L RAT
RAT RABBIT
64742-95-6 SOLVENT NAPHTHA, 8400 MG/KG >2000 MG/KG N.I.
LIGHT AROMATIC RAT RABBIT
822-06-0 HEXAMETHYLENE N.I. 593 MG/KG 0.06 MG/L RAT
DIISOCYANATE RABBIT
N.I. - NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER N.A. 1263 1263 N.A.
PROPER SHIPPING NOT PAINT PAINT NOT
NAME REGULATED REGULATED
HAZARD CLASS N.A. 3 3 N.A.
PACKING GROUP N.A. III III N.A.
LIMITED QUANTITY NO YES, >5L NO YES, >5L NO NO
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
FIRE HAZARD, REACTIVE HAZARD, ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
HEXAMETHYLENE DIISOCYANATE 822-06-0
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2
FLAMMABILITY 2
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 2
INSTABILITY 1
VOLATILE ORGANIC COMPOUNDS, G/L: 112
SDS REVISION DATE: 2/16/2016
REASON FOR REVISION: PRODUCT COMPOSITION CHANGED
SUBSTANCE AND/OR PRODUCT PROPERTIES CHANGED IN SECTION(S):
02 - HAZARD IDENTIFICATION
STATEMENT(S) CHANGED
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
RUST-OLEUM CORPORATION BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION
AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS
OF THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS OF
HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL, WE
ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM CORPORATION MAKES
NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY OF
THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.