| Common Name: | PERMWH 1-GL 4PK EXTERIOR SATIN, 3101 |
| Manufacturer: | RUST-OLEUM CANADA |
| SDS Revision Date: | 8/6/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 4FZX6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DATE PRINTED: 8/18/2015
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: PERMWH 1-GL 4PK EXTERIOR SATIN
PRODUCT IDENTIFIER: 3101
PRODUCT USE/CLASS: TOPCOAT/ACRYLIC
REVISION DATE: 8/6/2015
SUPERCEDES DATE: 5/20/2015
SUPPLIER:
RUST-OLEUM CONSUMER BRANDS CANADA (RCBC)
200 CONFEDERATION PARKWAY
CONCORD, ON L4K 4T8
CANADA
MANUFACTURER:
RUST-OLEUM CONSUMER BRANDS CANADA (RCBC)
200 CONFEDERATION PARKWAY
CONCORD, ON L4K 4T8
CANADA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
| 2. HAZARD IDENTIFICATION | |
CLASSIFICATION:
SYMBOL(S) OF PRODUCT: HEALTH HAZARD
SIGNAL WORD: DANGER
GHS HAZARD STATEMENTS:
CARCINOGENICITY, CATEGORY 1B:
H350:
MAY CAUSE CANCER. CLASSIFIED AS CARCINOGENIC CATEGORY 1 ON THE BASIS OF
EPIDEMIOLOGICAL AND/OR ANIMAL DATA. MIXTURES ARE CLASSIFIED AS CARCINOGENIC
WHEN AT LEAST 1 INGREDIENT HAS BEEN CLASSIFIED AS CARCINOGENIC AND IS
PRESENT AT 0.1% OR ABOVE ROUTES OF EXPOSURE ARE DEPENDENT ON INGREDIENT
FORM.
GHS LABEL PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
RANGE
TITANIUM DIOXIDE 13463-67-7 10-25 NO INFORMATION NO INFORMATION
ETHYLENE GLYCOL 107-21-1 2.5-10 NO INFORMATION NO INFORMATION
ZINC OXIDE 1314-13-2 1.0-2.5 NO INFORMATION NO INFORMATION
2,2,4-TRIMETHYL- 25265-77-4 1.0-2.5 NO INFORMATION NO INFORMATION
1,3-PENTANEDIOL
ISOBUTYRATE
AMORPHOUS SILICA 7631-86-9 0.1-1.0 GHS06 H331
DISTILLATES 64742-65-0 0.1-1.0 GHS08 H350
(PETROLEUM)
SOLVENT-DEWAXED
HEAVY PARAFFINIC
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR
KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION.
IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION.
DO NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION:
IF SWALLOWED, RINSE MOUTH WITH WATER. IF FEELING UNWELL, GET MEDICAL
ATTENTION. SWALLOWING LESS THAN AN OUNCE WILL NOT CAUSE SIGNIFICANT HARM.
FOR LARGER AMOUNTS, DO NOT INDUCE VOMITING, BUT GIVE ONE OR TWO GLASSES OF
WATER TO DRINK AND GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
KEEP CONTAINERS TIGHTLY CLOSED. FLASH POINT IS TESTED TO BE GREATER THAN
200 DEGREES F. NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
SPECIAL FIREFIGHTING PROCEDURES:
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT BUILDUP OF STEAM.
IF WATER IS USED, FOG NOZZLES ARE PREFERRED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
IF SPILLED, CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT.
DISPOSE OF CONTAMINATED ABSORBENT, CONTAINER, AND UNUSED CONTENTS IN
ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO NOT INCINERATE
CLOSED CONTAINERS DISPOSE OF ACCORDING TO LOCAL, STATE (PROVINCIAL) AND
FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. USE ONLY WITH ADEQUATE
VENTILATION. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS
EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID CONTACT
WITH EYES.
STORAGE:
STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN
NOT IN USE. KEEP FROM FREEZING. KEEP CONTAINER CLOSED WHEN NOT IN USE.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
TITANIUM DIOXIDE 13463-67-7 20.0
ETHYLENE GLYCOL 107-21-1 5.0
ZINC OXIDE 1314-13-2 5.0
2,2,4-TRIMETHYL-1,3-PENTANEDIOL 25265-77-4 5.0
ISOBUTYRATE
AMORPHOUS SILICA 7631-86-9 1.0
DISTILLATES (PETROLEUM) SOLVENT- 64742-65-0 1.0
DEWAXED HEAVY PARAFFINIC
CHEMICAL NAME ACGIH ACGIH OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL-CEILING
TITANIUM DIOXIDE 10 MG/M3 N.E. 15 MG/M3 N.E.
ETHYLENE GLYCOL N.E. N.E. N.E. N.E.
ZINC OXIDE 2 MG/M3 10 MG/M3 5 MG/M3 N.E.
2,2,4-TRIMETHYL- N.E. N.E. N.E. N.E.
1,3-PENTANEDIOL
ISOBUTYRATE
AMORPHOUS SILICA N.E. N.E. N.E. N.E.
DISTILLATES (PETROLEUM) N.E. N.E. N.E. N.E.
SOLVENT-DEWAXED HEAVY
PARAFFINIC
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE.
SKIN PROTECTION:
USE GLOVES TO PREVENT PROLONGED SKIN CONTACT. NITRILE OR NEOPRENE GLOVES
MAY AFFORD ADEQUATE SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE
REGARDING TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
PHYSICAL STATE: LIQUID
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 1.335
PH: 8.0 - 10.0
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: MISCIBLE
PARTITION COEFFICIENT, N-OCTANOL/WATER: N.D.
DECOMPOSITION TEMP., DEG. C: N.D.
BOILING RANGE, DEG. C: -18 - 244
EXPLOSIVE LIMITS, VOL%: 0.6 - 15.3
FLAMMABILITY: DOES NOT SUPPORT COMBUSTION
FLASH POINT, DEG. C: 94
EVAPORATION RATE: SLOWER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: N.D.
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID: AVOID CONTACT WITH STRONG ACID AND STRONG BASES.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE. WHEN HEATED TO
DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT:
CAUSES EYE IRRITATION. IRRITATING, AND MAY INJURE EYE TISSUE IF NOT REMOVED
PROMPTLY.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
SUBSTANCE MAY CAUSE SLIGHT SKIN IRRITATION. LOW HAZARD FOR USUAL INDUSTRIAL
HANDLING OR COMMERCIAL HANDLING BY TRAINED PERSONNEL.
EFFECTS OF OVEREXPOSURE - INHALATION:
HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE HARMFUL IF INHALED.
AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST. LOW HAZARD FOR USUAL
INDUSTRIAL HANDLING OR COMMERCIAL HANDLING BY TRAINED PERSONNEL.
EFFECTS OF OVEREXPOSURE - INGESTION: SUBSTANCE MAY BE HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
CONTAINS TITANIUM DIOXIDE. TITANIUM DIOXIDE IS LISTED AS A GROUP
2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY IARC. NO SIGNIFICANT EXPOSURE TO
TITANIUM DIOXIDE IS THOUGHT TO OCCUR DURING THE USE OF PRODUCTS IN WHICH
TITANIUM DIOXIDE IS BOUND TO OTHER MATERIALS, SUCH AS IN PAINTS DURING
BRUSH APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND
LEVEL OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST
AND THE ACTUAL CONCENTRATION OF TITANIUM DIOXIDE IN THE FORMULA. (REF: IARC
MONOGRAPH, VOL. 93, 2010)
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
13463-67-7 TITANIUM DIOXIDE >10000 MG/KG N.I. N.I.
RAT
107-21-1 ETHYLENE GLYCOL 4000 MG/KG RAT N.I. N.I.
1314-13-2 ZINC OXIDE >5000 MG/KG RAT N.I. N.I.
25265-77-4 2,2,4-TRIMETHYL- 3200 MG/KG RAT >15200 MG/KG N.I.
1,3-PENTANEDIOL RAT
ISOBUTYRATE
7631-86-9 AMORPHOUS SILICA >5000 MG/KG RAT >2000 MG/KG >2.2 MG/L
RABBIT RAT
N.I. - NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER N.A. N.A. N.A. N.A.
PROPER SHIPPING NAME NOT NOT NOT NOT
REGULATED REGULATED REGULATED REGULATED
HAZARD CLASS N.A. N.A. N.A. N.A.
PACKING GROUP N.A. N.A. N.A. N.A.
LIMITED QUANTITY NO NO NO NO
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
ETHYLENE GLYCOL 107-21-1
ZINC OXIDE 1314-13-2
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
CHEMICAL NAME CAS-NO.
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE 26172-55-4
METHYL-4-ISOTHIAZOLIN-3-ONE 2682-20-4
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS, G/L: 149
SDS REVISION DATE: 8/6/2015
REASON FOR REVISION:
SUBSTANCE AND/OR PRODUCT PROPERTIES CHANGED IN SECTION(S):
01 - IDENTIFICATION
02 - HAZARD IDENTIFICATION
03 - COMPOSITION/INFORMATION ON INGREDIENTS
05 - FIRE-FIGHTING MEASURES
09 - PHYSICAL & CHEMICAL PROPERTIES
11 - TOXICOLOGICAL INFORMATION
15 - REGULATORY INFORMATION
16 - OTHER INFORMATION
SUBSTANCE HAZARD THRESHOLD % CHANGED
SUBSTANCE REGULATORY CAS NUMBER CHANGED
SUBSTANCE HAZARDOUS FLAG CHANGED
PRODUCT COMPOSITION CHANGED
STATEMENT(S) CHANGED
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
RUST-OLEUM CONSUMER BRANDS CANADA BELIEVES, TO THE BEST OF ITS KNOWLEDGE,
INFORMATION AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND
RELIABLE AS OF THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE
CONDITIONS OF HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR
CONTROL, WE ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR
PROPERTY DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM CONSUMER
BRANDS CANADA MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE
ACCURACY OR RELIABILITY OF THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL
MATERIALS MAY PRESENT UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE
INFORMATION AND RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE
OFFERED FOR THE USERS' CONSIDERATION AND EXAMINATION. IT IS THE
RESPONSIBILITY OF THE USER TO DETERMINE THE FINAL SUITABILITY OF THIS
INFORMATION AND TO COMPLY WITH ALL APPLICABLE INTERNATIONAL, FEDERAL,
STATE, AND LOCAL LAWS AND REGULATIONS.