| Common Name: | OFF DEEP WOODS INSECT REPELLENT V (EPA REG. NO. 4822-167) |
| Manufacturer: | S.C. JOHNSON |
| SDS Revision Date: | 6/13/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 4HK65 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SC JOHNSON
A FAMILY COMPANY
SAFETY DATA SHEET
ACCORDING TO HAZARD COMMUNICATION STANDARD; 29 CFR 1910.1200
OFF DEEP WOODS INSECT REPELLENT V (EPA REG. NO. 4822-167)
VERSION: 2.0
REVISION DATE: 06/13/2016
PRINT DATE: 03/12/2018
SDS NUMBER: 350000004807
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT INFORMATION:
PRODUCT NAME:
OFF DEEP WOODS INSECT REPELLENT V (EPA REG. NO. 4822-167)
RECOMMENDED USE: INSECT REPELLENT
MANUFACTURER, IMPORTER, SUPPLIER:
S.C. JOHNSON & SON, INC.
1525 HOWE STREET
RACINE, WI 53403-2236
TELEPHONE: +18005585252
EMERGENCY TELEPHONE NUMBER:
24 HOUR MEDICAL EMERGENCY PHONE: (866)231-5406
24 HOUR INTERNATIONAL EMERGENCY PHONE: (703)527-3887
24 HOUR TRANSPORT EMERGENCY PHONE: (800)424-9300
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GLOBALLY HARMONIZED SYSTEM (GHS) CLASSIFICATION:
HAZARD CLASSIFICATION HAZARD CATEGORY HAZARDS IDENTIFICATION
AEROSOL CATEGORY 1 EXTREMELY FLAMMABLE AEROSOL.
GASES UNDER PRESSURE LIQUEFIED GAS CONTAINS GAS UNDER PRESSURE;
MAY EXPLODE IF HEATED.
LABELLING:
HAZARD SYMBOLS:
FLAME
GAS CYLINDER
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
PRECAUTIONARY STATEMENTS:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C / 122 DEG. F.
PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
DO NOT PIERCE OR BURN, EVEN AFTER USE.
OTHER HAZARDS: NONE IDENTIFIED
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO. WEIGHT PERCENT
ETHYL ALCOHOL 64-17-5 30.00 - 60.00
N,N-DIETHYL-M-TOLUAMIDE 134-62-3 10.00 - 30.00
BUTANE 106-97-8 1.00 - 5.00
PROPANE 74-98-6 1.00 - 5.00
ISOBUTANE 75-28-5 1.00 - 5.00
THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION)
OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
FOR ADDITIONAL INFORMATION ON PRODUCT INGREDIENTS, SEE
WWW.WHATSINSIDESCJOHNSON.COM.
| 4. FIRST AID MEASURES | |
EYE CONTACT: NO SPECIAL REQUIREMENTS
SKIN CONTACT:
IF YOU SUSPECT A REACTION TO THIS PRODUCT, DISCONTINUE USE AND REMOVE
CONTAMINATED CLOTHING.
INHALATION: NO SPECIAL REQUIREMENTS.
INGESTION: NO SPECIAL REQUIREMENTS
| 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE WATER SPRAY, ALCOHOL-RESISTANT FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIFIC HAZARDS DURING FIREFIGHTING:
AEROSOL PRODUCT - CONTAINERS MAY ROCKET OR EXPLODE IN HEAT OF FIRE. DO NOT
ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
FURTHER INFORMATION:
FIGHT FIRE FROM MAXIMUM DISTANCE OR PROTECTED AREA. COOL AND USE CAUTION
WHEN APPROACHING OR HANDLING FIRE-EXPOSED CONTAINERS. WEAR FULL PROTECTIVE
CLOTHING AND POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS. IN CASE
OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
NFPA CLASSIFICATION: NFPA LEVEL 2 AEROSOL
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
REMOVE ALL SOURCES OF IGNITION.
WEAR PERSONAL PROTECTIVE EQUIPMENT.
WASH THOROUGHLY AFTER HANDLING.
ENVIRONMENTAL PRECAUTIONS:
DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM.
USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
OUTSIDE OF NORMAL USE, AVOID RELEASE TO THE ENVIRONMENT.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
IF DAMAGE OCCURS TO AEROSOL CAN:
CONTAIN SPILLAGE, SOAK UP WITH NON-COMBUSTIBLE ABSORBENT MATERIAL, (E.G.
SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND TRANSFER TO A CONTAINER
FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL REGULATIONS (SEE SECTION 13).
USE ONLY NON-SPARKING EQUIPMENT.
DIKE LARGE SPILLS.
CLEAN RESIDUE FROM SPILL SITE.
| 7. HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
AVOID CONTACT WITH EYES AND LIPS.
FOR PERSONAL PROTECTION SEE SECTION 8.
USE ONLY AS DIRECTED.
KEEP OUT OF REACH OF CHILDREN AND PETS.
PRESSURIZED CONTAINER.
DO NOT PIERCE OR BURN, EVEN AFTER USE.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
STORAGE:
REQUIREMENTS FOR STORAGE AREAS AND CONTAINERS:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C / 122 DEG. F.
KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDINGSTUFFS.
KEEP IN A DRY, COOL AND WELL-VENTILATED PLACE.
OTHER DATA: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
COMPONENTS CAS-NO. MG/M3 PPM NON- BASIS
STANDARD
UNITS
ETHYL ALCOHOL 64-17-5 1,900 MG/M3 1,000 PPM OSHA TWA
ETHYL ALCOHOL 64-17-5 1,000 PPM ACGIH STEL
BUTANE 106-97-8 1,000 PPM ACGIH STEL
PROPANE 74-98-6 1,800 MG/M3 1,000 PPM OSHA TWA
| PROPANE 74-98-6 ACGIH TWA
ISOBUTANE 75-28-5 1,000 PPM ACGIH STEL
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION: DO NOT SPRAY IN ENCLOSED AREAS.
HAND PROTECTION: NO SPECIAL REQUIREMENTS.
EYE PROTECTION: NO SPECIAL REQUIREMENTS.
SKIN AND BODY PROTECTION: NO SPECIAL REQUIREMENTS.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
WASH THOROUGHLY AFTER HANDLING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
FORM: AEROSOL
FORM: COMPRESSED GAS
COLOR: CLEAR
ODOR: ALCOHOL ODOR
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
INITIAL BOILING POINT AND BOILING RANGE: NO DATA AVAILABLE
FLASH POINT:
-7 DEG. C
19.4 DEG. F
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
VAPOUR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY: 0.84 G/ML AT 21 DEG. C
SOLUBILITY(IES): SLIGHTLY SOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS:
TOTAL VOC (WT. %)*: 64.2% - ADDITIONAL EXEMPTIONS MAY APPLY
*AS DEFINED BY US FEDERAL AND STATE CONSUMER PRODUCT REGULATIONS
OTHER INFORMATION: NONE IDENTIFIED
| 10. STABILITY AND REACTIVITY | |
POSSIBILITY OF HAZARDOUS REACTIONS:
STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID: HEAT, FLAMES AND SPARKS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
HAZARDOUS DECOMPOSITION:
THERMAL DECOMPOSITION CAN LEAD TO RELEASE OF IRRITATING GASES PRODUCTS AND
VAPOURS.
| 11. TOXICOLOGICAL INFORMATION | |
EMERGENCY OVERVIEW: DANGER
ACUTE ORAL TOXICITY:
ACUTE INHALATION TOXICITY:
ACUTE DERMAL TOXICITY:
GHS PROPERTIES CLASSIFICATION ROUTES OF ENTRY
ACUTE TOXICITY NO CLASSIFICATION PROPOSED
SKIN CORROSION/IRRITATION NO CLASSIFICATION PROPOSED
SERIOUS EYE DAMAGE/EYE NO CLASSIFICATION PROPOSED
IRRITATION
SKIN SENSITISATION NO CLASSIFICATION PROPOSED
RESPIRATORY SENSITISATION NO CLASSIFICATION PROPOSED
GERM CELL MUTAGENICITY NO CLASSIFICATION PROPOSED
CARCINOGENICITY NO CLASSIFICATION PROPOSED
REPRODUCTIVE TOXICITY NO CLASSIFICATION PROPOSED
SPECIFIC TARGET ORGAN NO CLASSIFICATION PROPOSED
TOXICITY - SINGLE
EXPOSURE
SPECIFIC TARGET ORGAN NO CLASSIFICATION PROPOSED
TOXICITY - REPEATED
EXPOSURE
ASPIRATION HAZARD NO CLASSIFICATION PROPOSED
AGGRAVATED MEDICAL CONDITION:
| 12. ECOLOGICAL INFORMATION | |
PRODUCT: THE PRODUCT ITSELF HAS NOT BEEN TESTED.
TOXICITY:
THE INGREDIENTS IN THIS FORMULA HAVE BEEN REVIEWED AND NO ADVERSE IMPACT
TO THE ENVIRONMENT IS EXPECTED WHEN USED ACCORDING TO LABEL DIRECTIONS.
TOXICITY TO FISH:
COMPONENTS END POINT SPECIES VALUE EXPOSURE TIME
ETHYL ALCOHOL LC50 FISH 11,200 MG/L 96 H
N,N-DIETHYL- STATIC TEST ONCORHYNCHUS 71.25 MG/L 96 H
M-TOLUAMIDE LC50 MYKISS
(RAINBOW
TROUT)
BUTANE LC50 FISH 27.98 MG/L 96 H
QSAR
PROPANE LC50 FISH 27.98 MG/L 96 H
ISOBUTANE LC50 FISH 27.98 MG/L 96 H
QSAR
TOXICITY TO AQUATIC INVERTEBRATES:
COMPONENTS END POINT SPECIES VALUE EXPOSURE TIME
ETHYL ALCOHOL STATIC TEST CERIODAPHNIA 5,012 MG/L 48 H
LC50 DUBIA
NOEC DAPHNIA MAGNA 9.6 MG/L 9 D
N,N-DIETHYL- LC50 DAPHNIA MAGNA 75 MG/L 51 H
M-TOLUAMIDE (WATER FLEA)
SEMI- DAPHNIA MAGNA 3.7 MG/L 21 D
STATIC
TEST NOEC
MEASURED
OECD
GUIDELINE
211
(DAPHNIA
MAGNA
REPRODUCT-
ION TEST)
BUTANE NO DATA
AVAILABLE
PROPANE LC50 DAPHNID 14.22 MG/L 48 H
ISOBUTANE LC50 DAPHNID 16.33 MG/L 48 H
QSAR
TOXICITY TO AQUATIC PLANTS:
COMPONENTS END POINT SPECIES VALUE EXPOSURE
TIME
ETHYL ALCOHOL STATIC CHLORELLA VULGARIS 275 MG/L 72 H
EC50 (FRESH WATER ALGAE)
N,N-DIETHYL- NOEC PSEUDOKIRCHNERIELLA 0.521 MG/L 96 H
M-TOLUAMIDE SUBCAPITATA (GREEN
ALGAE)
BUTANE EC50 GREEN ALGAE 7.71 MG/L 96 H
QSAR
PROPANE NO DATA
AVAILABLE
ISOBUTANE EC50 GREEN ALGAE 8.57 MG/L 96 H
QSAR
PERSISTENCE AND DEGRADABILITY:
COMPONENT BIODEGRADATION EXPOSURE TIME SUMMARY
ETHYL ALCOHOL 97% 28 D READILY BIODEGRADABLE
N,N-DIETHYL- 83.8% 28 D READILY BIODEGRADABLE
M-TOLUAMIDE
BUTANE 100% 385.5 H READILY BIODEGRADABLE
PROPANE 70% <10 D READILY BIODEGRADABLE
ISOBUTANE 70% <10 D READILY BIODEGRADABLE
BIOACCUMULATIVE POTENTIAL:
COMPONENT BIOCONCENTRATION PARTITION COEFFICIENT
FACTOR (BCF) N-OCTANOL/WATER (LOG)
ETHYL ALCOHOL 3.2 ESTIMATED -0.35 MEASURED
N,N-DIETHYL-M-TOLUAMIDE 21.9 ESTIMATED 2.4
BUTANE NO DATA AVAILABLE 2.89
PROPANE NO DATA AVAILABLE 2.36
ISOBUTANE 1.57 - 1.97 2.8
MOBILITY:
COMPONENT END POINT VALUE
ETHYL ALCOHOL NO DATA AVAILABLE
N,N-DIETHYL-M-TOLUAMIDE KOC 43.3
BUTANE NO DATA AVAILABLE
PROPANE NO DATA AVAILABLE
ISOBUTANE NO DATA AVAILABLE
PBT AND VPVB ASSESSMENT:
COMPONENT RESULTS
ETHYL ALCOHOL NOT FULFILLING PBT AND VPVB CRITERIA
N,N-DIETHYL-M-TOLUAMIDE NOT FULFILLING PBT AND VPVB CRITERIA
BUTANE NOT FULFILLING PBT AND VPVB CRITERIA
PROPANE NOT FULFILLING PBT AND VPVB CRITERIA
ISOBUTANE NOT FULFILLING PBT AND VPVB CRITERIA
OTHER ADVERSE EFFECTS: NONE KNOWN.
| 13. DISPOSAL CONSIDERATIONS | |
PESTICIDAL WASTE:
FOR DISPOSAL INFORMATION, PLEASE READ AND FOLLOW DISPOSAL INSTRUCTIONS ON
THE PESTICIDE LABEL.
CONSUMER MAY DISCARD EMPTY CONTAINER IN HOUSEHOLD WASTE, OR RECYCLE WHERE
FACILITIES EXIST.
PESTICIDAL WASTE:
OBSERVE ALL APPLICABLE FEDERAL, PROVINCIAL AND STATE REGULATIONS AND
LOCAL/MUNICIPAL ORDINANCES REGARDING DISPOSAL.
| 14. TRANSPORT INFORMATION | |
PLEASE REFER TO THE BILL OF LADING/RECEIVING DOCUMENTS FOR UP-TO-DATE
SHIPPING INFORMATION.
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT
UN NUMBER 1950 1950 1950
UN PROPER SHIPPING AEROSOLS, AEROSOLS, AEROSOLS,
NAME FLAMMABLE FLAMMABLE FLAMMABLE
TRANSPORT HAZARD 2.1 2 2.1
CLASS(ES)
PACKING GROUP
ENVIRONMENTAL
HAZARDS
SPECIAL PRECAUTIONS LIMITED LIMITED LIMITED
FOR USER QUANTITIES QUANTITIES QUANTITIES
DEROGATION DEROGATION DEROGATION
MAY BE MAY BE MAY BE
APPLICABLE TO APPLICABLE TO APPLICABLE TO
THIS PRODUCT, THIS PRODUCT, THIS PRODUCT,
PLEASE CHECK PLEASE CHECK PLEASE CHECK
TRANSPORT TRANSPORT TRANSPORT
DOCUMENTS. DOCUMENTS. DOCUMENTS.
| 15. REGULATORY INFORMATION | |
FIFRA LABELING:
THIS CHEMICAL IS A PESTICIDE PRODUCT REGISTERED BY THE ENVIRONMENTAL
PROTECTION AGENCY AND IS SUBJECT TO CERTAIN LABELING REQUIREMENTS UNDER
FEDERAL PESTICIDE LAW. THESE REQUIREMENTS DIFFER FROM THE CLASSIFICATION
CRITERIA AND HAZARD INFORMATION REQUIRED FOR SAFETY DATA SHEETS, AND FOR
WORKPLACE LABELS OF NON-PESTICIDE CHEMICALS.
FOLLOWING IS THE HAZARD INFORMATION AS REQUIRED ON THE PESTICIDE LABEL:
CAUTION:
CAUSES MODERATE EYE IRRITATION.
HARMFUL IF SWALLOWED.
USE OF THIS PRODUCT MAY CAUSE SKIN REACTIONS IN RARE CASES.
FLAMMABLE.
CONTENTS UNDER PRESSURE.
EXPOSURE TO TEMPERATURES ABOVE 120 DEG. F MAY CAUSE BURSTING.
NOTIFICATION STATUS:
ALL INGREDIENTS OF THIS PRODUCT ARE LISTED OR ARE EXCLUDED FROM LISTING ON
THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCE INVENTORY.
NOTIFICATION STATUS:
ALL INGREDIENTS OF THIS PRODUCT COMPLY WITH THE NEW SUBSTANCES NOTIFICATION
REQUIREMENTS UNDER THE CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA).
CALIFORNIA PROP. 65:
THIS PRODUCT IS NOT SUBJECT TO THE REPORTING REQUIREMENTS UNDER
CALIFORNIA'S PROPOSITION 65.
REGISTRATION # / AGENCY: 4822-167/US/EPA
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2
FLAMMABILITY 4
REACTIVITY 0
NFPA RATINGS:
HEALTH 2
FIRE 4
REACTIVITY 0
SPECIAL
THIS INFORMATION IS BEING PROVIDED IN ACCORDANCE WITH THE OCCUPATIONAL
SAFETY AND HEALTH ADMINISTRATION (OSHA) REGULATION (29 CFR 1910.1200).
THE INFORMATION SUPPLIED IS DESIGNED FOR WORKPLACES WHERE PRODUCT USE AND
FREQUENCY OF EXPOSURE EXCEEDS THAT ESTABLISHED FOR THE LABELED CONSUMER
USE.
FURTHER INFORMATION:
THIS DOCUMENT HAS BEEN PREPARED USING DATA FROM SOURCES CONSIDERED TO BE
TECHNICALLY RELIABLE. IT DOES NOT CONSTITUTE A WARRANTY, EXPRESSED OR
IMPLIED, AS TO THE ACCURACY OF THE INFORMATION CONTAINED HEREIN. ACTUAL
CONDITIONS OF USE ARE BEYOND THE SELLER'S CONTROL. USER IS RESPONSIBLE TO
EVALUATE ALL AVAILABLE INFORMATION WHEN USING PRODUCT FOR ANY PARTICULAR
USE AND TO COMPLY WITH ALL FEDERAL, STATE, PROVINCIAL AND LOCAL LAWS AND
REGULATIONS.
PREPARED BY:
SC JOHNSON GLOBAL SAFETY ASSESSMENT & REGULATORY AFFAIRS (GSARA)