| Common Name: | HEAVY DUTY DEGREASER NO. 03096 (ITEM 1003368) |
| Manufacturer: | CRC INDUSTRIES |
| SDS Revision Date: | 12/19/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 32UN69, 3APN5, 4JB40 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
CRC(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: HEAVY DUTY DEGREASER
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE NO.: 03096 (ITEM# 1003368)
RECOMMENDED USE: HEAVY DUTY DEGREASER
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURED OR SOLD BY:
COMPANY: NAME CRC INDUSTRIES, INC.
ADDRESS:
885 LOUIS DR.
WARMINSTER, PA 18974
US
TELEPHONE:
GENERAL INFORMATION: 215-674-4300
TECHNICAL ASSISTANCE: 800-521-3168
CUSTOMER SERVICE: 800-272-4620
24-HOUR EMERGENCY (CHEMTREC):
800-424-9300 (US)
703-527-3887 (INTERNATIONAL)
WEBSITE: WWW.CRCINDUSTRIES.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS: NOT CLASSIFIED.
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2B
SENSITIZATION, SKIN: CATEGORY 1B
CARCINOGENICITY: CATEGORY 1B
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT, ACUTE HAZARD: CATEGORY 2
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 2
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES EYE
IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. MAY CAUSE CANCER. TOXIC TO
AQUATIC LIFE. TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENT:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. USE WITH ADEQUATE VENTILATION.
OPEN DOORS AND WINDOWS OR USE OTHER MEANS TO ENSURE A FRESH AIR SUPPLY
DURING USE AND WHILE PRODUCT IS DRYING. IF YOU EXPERIENCE ANY SYMPTOMS
LISTED ON THIS LABEL, INCREASE VENTILATION OR LEAVE THE AREA. AVOID
BREATHING MIST OR VAPOR. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK
CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE
GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION. AVOID RELEASE
TO THE ENVIRONMENT.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE REUSE.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION. COLLECT SPILLAGE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL
REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION:
WHEN EXPOSED TO EXTREME HEAT OR HOT SURFACES, VAPORS MAY DECOMPOSE TO
HARMFUL OR FATAL CORROSIVE GASES SUCH AS HYDROGEN FLUORIDE, HYDROGEN
CHLORIDE, AND POSSIBLY PHOSGENE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
TETRACHLOROETHYLENE PERCHLOROETHYLENE 127-18-4 90 - 100
TRANS-1,2-DICHLOROETHYLENE 156-60-5 5 - 10
SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN WITH SOAP AND WATER.
IN CASE OF ECZEMA OR OTHER SKIN DISORDERS: SEEK MEDICAL ATTENTION AND TAKE
ALONG THESE INSTRUCTIONS. WASH CONTAMINATED CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION: RINSE MOUTH. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. IRRITATION
OF EYES. EXPOSED INDIVIDUALS MAY EXPERIENCE EYE TEARING, REDNESS, AND
DISCOMFORT. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN
ALLERGIC SKIN REACTION. DERMATITIS. RASH.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION. ENSURE THAT MEDICAL
PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO
PROTECT THEMSELVES. WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED. WHEN EXPOSED TO
EXTREME HEAT OR HOT SURFACES, VAPORS MAY DECOMPOSE TO HARMFUL OR FATAL
CORROSIVE GASES SUCH AS HYDROGEN FLUORIDE, HYDROGEN CHLORIDE, AND POSSIBLY
PHOSGENE.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS:
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK.
GENERAL FIRE HAZARDS: NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING DURING
CLEAN-UP. AVOID BREATHING MIST OR VAPOR. DO NOT TOUCH DAMAGED CONTAINERS
OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. ENSURE
ADEQUATE VENTILATION. LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT
SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE SECTION 8 OF
THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
THIS PRODUCT IS MISCIBLE IN WATER. THIS MATERIAL IS CLASSIFIED AS A WATER
POLLUTANT UNDER THE CLEAN WATER ACT AND SHOULD BE PREVENTED FROM
CONTAMINATING SOIL OR FROM ENTERING SEWAGE AND DRAINAGE SYSTEMS WHICH LEAD
TO WATERWAYS.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. PUT MATERIAL IN
SUITABLE, COVERED, LABELED CONTAINERS. FOR WASTE DISPOSAL, SEE SECTION 13
OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. INFORM APPROPRIATE MANAGERIAL OR
SUPERVISORY PERSONNEL OF ALL ENVIRONMENTAL RELEASES. PREVENT FURTHER
LEAKAGE OR SPILLAGE IF SAFE TO DO SO. AVOID DISCHARGE INTO DRAINS, WATER
COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING MIST OR VAPOR.
AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID PROLONGED EXPOSURE.
SHOULD BE HANDLED IN CLOSED SYSTEMS, IF POSSIBLE. PROVIDE ADEQUATE
VENTILATION. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. AVOID RELEASE
TO THE ENVIRONMENT. OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES. FOR PRODUCT
USAGE INSTRUCTIONS, SEE THE PRODUCT LABEL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN A COOL, DRY PLACE OUT OF DIRECT SUNLIGHT. KEEP CONTAINER TIGHTLY
CLOSED. STORE AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
THE FOLLOWING CONSTITUENTS ARE THE ONLY CONSTITUENTS OF THE PRODUCT WHICH
HAVE A PEL, TLV OR OTHER RECOMMENDED EXPOSURE LIMIT. AT THIS TIME, THE
OTHER CONSTITUENTS HAVE NO KNOWN EXPOSURE LIMITS.
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
TRANS-1,2-DICHLOROETHYLENE PEL 790 MG/M3
(CAS 156-60-5) 200 PPM
US. OSHA TABLE Z-2 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
TETRACHLOROETHYLENE CEILING 200 PPM
(CAS 127-18-4) TWA 100 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
TETRACHLOROETHYLENE STEL 100 PPM
(CAS 127-18-4) TWA 25 PPM
TRANS-1,2-DICHLOROETHYLENE TWA 200 PPM
(CAS 156-60-5)
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
TRANS-1,2-DICHLOROETHYLENE TWA 790 MG/M3
(CAS 156-60-5) 200 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
TETRACHLOROETHYLENE 0.5 MG/L TETRACHLOROETHYLENE BLOOD *
(CAS 127-18-4)
3 PPM TETRACHLOROETHYLENE END- *
EXHALED
AIR
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
EXPOSURE GUIDELINES:
US - MINNESOTA HAZ SUBS SKIN DESIGNATION APPLIES
TETRACHLOROETHYLENE (CAS 127-18-4) SKIN DESIGNATION APPLIES.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL. EYE WASH FOUNTAIN AND EMERGENCY SHOWERS ARE RECOMMENDED.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION:
WEAR PROTECTIVE GLOVES SUCH AS: POLYVINYL ALCOHOL (PVA). VITON/BUTYL.
OTHER: WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS ARE NOT FEASIBLE OR IF EXPOSURE EXCEEDS THE
APPLICABLE EXPOSURE LIMITS, USE A NIOSH-APPROVED CARTRIDGE RESPIRATOR WITH
AN ORGANIC VAPOR CARTRIDGE. USE A SELF-CONTAINED BREATHING APPARATUS IN
CONFINED SPACES AND FOR EMERGENCIES. AIR MONITORING IS NEEDED TO DETERMINE
ACTUAL EMPLOYEE EXPOSURE LEVELS.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
OBSERVE ANY MEDICAL SURVEILLANCE REQUIREMENTS. WHEN USING DO NOT SMOKE.
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER
HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE
WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL: STATE LIQUID.
FORM: LIQUID.
COLOR: COLORLESS.
ODOR: SOLVENT.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: -119.2 DEG. F (-84 DEG. C) ESTIMATED
INITIAL BOILING POINT AND BOILING RANGE:
119.7 DEG. F (48.7 DEG. C) ESTIMATED
FLASH POINT: NONE (TAG CLOSED CUP)
EVAPORATION RATE: FAST.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 6.7% ESTIMATED
FLAMMABILITY LIMIT - UPPER (%): 18% ESTIMATED
VAPOR PRESSURE: 57.7 HPA ESTIMATED
VAPOR DENSITY: >4 (AIR = 1)
RELATIVE DENSITY: 1.58
SOLUBILITY(IES):
SOLUBILITY (WATER): SLIGHT.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 860 DEG. F (460 DEG. C) ESTIMATED
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
PERCENT VOLATILE: 100 % ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
HEAT, FLAMES AND SPARKS. CONTACT WITH INCOMPATIBLE MATERIALS. WHEN EXPOSED
TO EXTREME HEAT OR HOT SURFACES, VAPORS MAY DECOMPOSE TO HARMFUL OR FATAL
CORROSIVE GASES SUCH AS HYDROGEN FLUORIDE, HYDROGEN CHLORIDE, AND POSSIBLY
PHOSGENE.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
HYDROGEN CHLORIDE. HYDROGEN FLUORIDE. PHOSGENE. CARBON OXIDES.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. PROLONGED
INHALATION MAY BE HARMFUL.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES EYE IRRITATION.
INGESTION:
INGESTION OF LARGE AMOUNTS MAY PRODUCE GASTROINTESTINAL DISTURBANCES
INCLUDING IRRITATION, NAUSEA, AND DIARRHEA.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. IRRITATION
OF EYES. EXPOSED INDIVIDUALS MAY EXPERIENCE EYE TEARING, REDNESS, AND
DISCOMFORT. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN
ALLERGIC SKIN REACTION. DERMATITIS. RASH.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT KNOWN.
COMPONENTS SPECIES TEST RESULTS
DECAFLUOROPENTANE (CAS 138495-42-8):
ACUTE:
DERMAL:
LD50 RABBIT >5000 MG/KG
INHALATION:
LC50 RAT 11058 MG/KG,
4 HOURS CALCULATED
ORAL:
LD50 RAT >5000 MG/KG
TETRACHLOROETHYLENE (CAS 127-18-4):
ACUTE:
DERMAL:
LD50 RABBIT >3228 MG/KG
ORAL:
LD50 RAT 2629 MG/KG
TRANS-1,2-DICHLOROETHYLENE (CAS 156-60-5):
ACUTE:
ORAL:
LD50 RAT 1235 MG/KG
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: MAY CAUSE CANCER.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
TETRACHLOROETHYLENE (CAS 127-18-4): 2A PROBABLY CARCINOGENIC TO HUMANS.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS:
TETRACHLOROETHYLENE (CAS 127-18-4):
REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS AND DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET. MAY BE AN
ASPIRATION HAZARD.
CHRONIC EFFECTS:
PROLONGED INHALATION MAY BE HARMFUL. PROLONGED EXPOSURE MAY CAUSE CHRONIC
EFFECTS.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
COMPONENTS SPECIES TEST RESULTS
TETRACHLOROETHYLENE (CAS 127-18-4):
AQUATIC:
FISH LC50 RAINBOW TROUT, DONALDSON TROUT 4.73 - 5.27 MG/L,
(ONCORHYNCHUS MYKISS) 96 HOURS
TRANS-1,2-DICHLOROETHYLENE (CAS 156-60-5):
AQUATIC:
FISH LC50 BLUEGILL (LEPOMIS MACROCHIRUS) 120 - 160 MG/L,
96 HOURS
ACUTE:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 220 MG/L, 48 HOURS
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF ANY INGREDIENTS IN THE
MIXTURE.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
TETRACHLOROETHYLENE: 2.88
TRANS-1,2-DICHLOROETHYLENE: 2.06
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS HAZARDOUS WASTE.
CONSULT AUTHORITIES BEFORE DISPOSAL. DO NOT ALLOW THIS MATERIAL TO DRAIN
INTO SEWERS/WATER SUPPLIES. DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES
WITH CHEMICAL OR USED CONTAINER. DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
REGULATIONS.
HAZARDOUS WASTE CODE:
D039: WASTE TETRACHLOROETHYLENE
F001:
WASTE HALOGENATED SOLVENT - SPENT HALOGENATED SOLVENT USED IN DEGREASING
F002: WASTE HALOGENATED SOLVENT - SPENT HALOGENATED SOLVENT
US RCRA HAZARDOUS WASTE U LIST REFERENCE
TETRACHLOROETHYLENE (CAS 127-18-4) U210
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1897
UN PROPER SHIPPING NAME:
TETRACHLOROETHYLENE MIXTURE (TETRACHLOROETHYLENE RQ = 111 LBS), LIMITED
QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 6.1(PGIII)
SUBSIDIARY RISK:
LABEL(S): 6.1
PACKING GROUP: III
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: IB3, N36, T4, TP1
PACKAGING EXCEPTIONS: 153
PACKAGING NON BULK: 203
PACKAGING BULK: 241
IATA:
UN NUMBER: UN1897
UN PROPER SHIPPING NAME: TETRACHLOROETHYLENE MIXTURE, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 6.1(PGIII)
SUBSIDIARY RISK:
PACKING GROUP: III
ERG CODE: 6L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED WITH RESTRICTIONS.
CARGO AIRCRAFT ONLY: ALLOWED WITH RESTRICTIONS.
IMDG:
UN NUMBER: UN1897
UN PROPER SHIPPING NAME: TETRACHLOROETHYLENE MIXTURE, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 6.1(PGIII)
SUBSIDIARY RISK:
PACKING GROUP: III
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO.
EMS: F-A, S-A
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
ALL COMPONENTS ARE ON THE U.S. EPA TSCA INVENTORY LIST.
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
DECAFLUOROPENTANE (CAS 138495-42-8):
1.0% ONE-TIME EXPORT NOTIFICATION ONLY.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED.
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL LISTED SUBSTANCE
TETRACHLOROETHYLENE (CAS 127-18-4)
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
TETRACHLOROETHYLENE (CAS 127-18-4): LISTED.
TRANS-1,2-DICHLOROETHYLENE (CAS 156-60-5): LISTED.
CERCLA HAZARDOUS SUBSTANCES REPORTABLE QUANTITY
TETRACHLOROETHYLENE (CAS 127-18-4) 100 LBS
TRANS-1,2-DICHLOROETHYLENE (CAS 156-60-5) 1000 LBS
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS
RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
TETRACHLOROETHYLENE (CAS 127-18-4)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
CLASSIFIED HAZARD CATEGORIES:
ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
SKIN CORROSION OR IRRITATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
RESPIRATORY OR SKIN SENSITIZATION
CARCINOGENICITY
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
TETRACHLOROETHYLENE 127-18-4 90 - 100
US STATE REGULATIONS:
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
TETRACHLOROETHYLENE (CAS 127-18-4)
TRANS-1,2-DICHLOROETHYLENE (CAS 156-60-5)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
TETRACHLOROETHYLENE (CAS 127-18-4)
TRANS-1,2-DICHLOROETHYLENE (CAS 156-60-5)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
TETRACHLOROETHYLENE (CAS 127-18-4)
TRANS-1,2-DICHLOROETHYLENE (CAS 156-60-5)
US. RHODE ISLAND RTK:
TETRACHLOROETHYLENE (CAS 127-18-4)
TRANS-1,2-DICHLOROETHYLENE (CAS 156-60-5)
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO TETRACHLOROETHYLENE, WHICH IS KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE CANCER. FOR MORE INFORMATION GO TO
WWW.P65WARNINGS.CA.GOV.
CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/CARCINOGENIC SUBSTANCE
TETRACHLOROETHYLENE (CAS 127-18-4) LISTED: APRIL 1, 1988
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
TETRACHLOROETHYLENE (CAS 127-18-4)
TRANS-1,2-DICHLOROETHYLENE (CAS 156-60-5)
VOLATILE ORGANIC COMPOUNDS (VOC) REGULATIONS:
EPA:
VOC CONTENT (40 CFR 51.100(S)): 8%
CONSUMER PRODUCTS (40 CFR 59, SUBPT. C): NOT REGULATED
STATE:
CONSUMER PRODUCTS:
THIS PRODUCT IS NOT FOR RETAIL SALE. IT IS FOR USE IN THE MANUFACTURING
PROCESS ONLY.
VOC CONTENT (CA): 10%
VOC CONTENT (OTC): 8%
INTERNATIONAL INVENTORIES:
COUNTRY(S) INVENTORY NAME ON INVENTORY
OR REGION (YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL YES
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) NO
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) YES
CHINA INVENTORY OF EXISTING CHEMICAL YES
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING COMMERCIAL NO
CHEMICAL SUBSTANCES (EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW CHEMICAL YES
SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS AND YES
CHEMICAL SUBSTANCES (PICCS)
TAIWAN TAIWAN TOXIC CHEMICAL SUBSTANCES (TCS) YES
UNITED STATES TOXIC SUBSTANCES CONTROL ACT (TSCA) INVENTORY YES
& PUERTO RICO
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 06-10-2014
REVISION DATE: 12-19-2017
PREPARED BY: ALLISON YOON
VERSION # 02
FURTHER INFORMATION: CRC # 894A/1002879
HMIS(R*) RATINGS:
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
NFPA RATINGS:
2
1
0
DISCLAIMER
THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC
MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED
IN COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO
THE BEST OF CRC'S KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY CRC TO BE
ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND DIRECTIONS ON THE
LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION CONTAINED ON THIS
(M)SDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY PROFESSIONAL, OR CRC
INDUSTRIES, INC..
REVISION INFORMATION:
THIS DOCUMENT HAS UNDERGONE SIGNIFICANT CHANGES AND SHOULD BE REVIEWED IN
ITS ENTIRETY.
MATERIAL NAME: HEAVY DUTY DEGREASER
SDS: US