| Common Name: | LPS HDX (AEROSOL), 01020 |
| Manufacturer: | ITW PRO BRANDS |
| SDS Revision Date: | 10/18/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 4KK67 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LPS(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: LPS(R*) HDX (AEROSOL)
OTHER MEANS OF IDENTIFICATION:
PART NUMBER: 01020
RECOMMENDED USE:
A DEGREASER DESIGNED TO REMOVE GREASE, OIL, DIRT AND OTHER RESIDUES FROM
METAL AND OTHER HARD SURFACES NEAR IGNITION SOURCES.
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURER:
COMPANY NAME: ITW PRO BRANDS
ADDRESS:
4647 HUGH HOWELL RD.
TUCKER, GA 30084
COUNTRY: (U.S.A.)
TEL: +1 770-243-8800
IN CASE OF EMERGENCY:
1-800-424-9300 (INSIDE U.S.)
+001 703-527-3887 (OUTSIDE U.S.)
WEBSITE: WWW.LPSLABS.COM
E-MAIL: LPSSDS@ITWPROBRANDS.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
GASES UNDER PRESSURE: COMPRESSED GAS
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
GERM CELL MUTAGENICITY: CATEGORY 2
CARCINOGENICITY: CATEGORY 1B
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED. CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION. SUSPECTED OF CAUSING GENETIC DEFECTS. MAY
CAUSE CANCER. MAY CAUSE DROWSINESS OR DIZZINESS.
PRECAUTIONARY STATEMENT:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING GAS. WASH
THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. CALL A POISON CENTER/DOCTOR IF YOU FEEL
UNWELL.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE REUSE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP. PROTECT FROM SUNLIGHT.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE KNOWN.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
1,1,2-TRICHLOROETHYLENE 79-01-6 90 - 100
CARBON DIOXIDE 124-38-9 1 - 5
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. WASH WITH PLENTY OF SOAP AND WATER. IF SKIN
IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION:
NOT LIKELY, DUE TO THE FORM OF THE PRODUCT. IN THE UNLIKELY EVENT OF
SWALLOWING CONTACT A PHYSICIAN OR POISON CONTROL CENTER. RINSE MOUTH.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
(SHOW THE LABEL WHERE POSSIBLE). ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF
THE MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW
THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE:
STOP LEAK IF SAFE TO DO SO. DO NOT MOVE CARGO OR VEHICLE IF CARGO HAS BEEN
EXPOSED TO HEAT. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT
RISK. CONTAINERS SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE
BUILD UP. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER OR
MONITOR NOZZLES, IF POSSIBLE. IF NOT, WITHDRAW AND LET FIRE BURN OUT.
SPECIFIC METHODS:
COOL CONTAINERS EXPOSED TO FLAMES WITH WATER UNTIL WELL AFTER THE FIRE IS
OUT.
GENERAL FIRE HAZARDS:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY EXPLODE WHEN EXPOSED TO
HEAT OR FLAME.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. MANY GASES ARE HEAVIER THAN AIR AND WILL
SPREAD ALONG GROUND AND COLLECT IN LOW OR CONFINED AREAS (SEWERS,
BASEMENTS, TANKS). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING
DURING CLEAN-UP. AVOID BREATHING GAS. EMERGENCY PERSONNEL NEED
SELF-CONTAINED BREATHING EQUIPMENT. DO NOT TOUCH DAMAGED CONTAINERS OR
SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. VENTILATE
CLOSED SPACES BEFORE ENTERING THEM. LOCAL AUTHORITIES SHOULD BE ADVISED IF
SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. USE PERSONAL PROTECTION
RECOMMENDED IN SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
REFER TO ATTACHED SAFETY DATA SHEETS AND/OR INSTRUCTIONS FOR USE. STOP LEAK
IF YOU CAN DO SO WITHOUT RISK. ISOLATE AREA UNTIL GAS HAS DISPERSED.
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM
SPILLED MATERIAL. ABSORB IN VERMICULITE, DRY SAND OR EARTH AND PLACE INTO
CONTAINERS. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. PUT MATERIAL IN SUITABLE,
COVERED, LABELED CONTAINERS. FOR WASTE DISPOSAL, SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. PRESSURIZED CONTAINER: DO NOT
PIERCE OR BURN, EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS MISSING OR
DEFECTIVE. DO NOT SPRAY ON A NAKED FLAME OR ANY OTHER INCANDESCENT
MATERIAL. DO NOT SMOKE WHILE USING OR UNTIL SPRAYED SURFACE IS THOROUGHLY
DRY. DO NOT CUT, WELD, SOLDER, DRILL, GRIND, OR EXPOSE CONTAINERS TO HEAT,
FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. GROUND AND BOND CONTAINERS
WHEN TRANSFERRING MATERIAL. DO NOT RE-USE EMPTY CONTAINERS. AVOID BREATHING
GAS. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID PROLONGED EXPOSURE.
SHOULD BE HANDLED IN CLOSED SYSTEMS, IF POSSIBLE. USE ONLY IN
WELL-VENTILATED AREAS. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
LEVEL 1 AEROSOL.
STORE LOCKED UP. CONTENTS UNDER PRESSURE. DO NOT EXPOSE TO HEAT OR STORE AT
TEMPERATURES ABOVE 120 DEG. F/49 DEG. C AS CAN MAY BURST. DO NOT PUNCTURE,
INCINERATE OR CRUSH. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR
OTHER SOURCES OF IGNITION. STORE IN A WELL-VENTILATED PLACE. STORED
CONTAINERS SHOULD BE PERIODICALLY CHECKED FOR GENERAL CONDITION AND
LEAKAGE. STORE AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE
SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
THE FOLLOWING CONSTITUENTS ARE THE ONLY CONSTITUENTS OF THE PRODUCT WHICH
HAVE A PEL, TLV OR OTHER RECOMMENDED EXPOSURE LIMIT. AT THIS TIME, THE
OTHER CONSTITUENTS HAVE NO KNOWN EXPOSURE LIMITS.
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE FORM
BUTANONE (CAS 78-93-3) PEL 590 MG/M3
200 PPM
CAMPHOR USP (CAS 76-22-2) PEL 2 MG/M3
CARBON DIOXIDE (CAS 124-38-9) PEL 9000 MG/M3
5000 PPM
DIPHENYL OXIDE (CAS 101-84-8) PEL 7 MG/M3 VAPOR.
1 PPM VAPOR.
ISO AMYL ACETATE (CAS 123-92-2) PEL 525 MG/M3
100 PPM
TURPENTINE (CAS 8006-64-2) PEL 560 MG/M3
100 PPM
US. OSHA TABLE Z-2 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
1,1,2-TRICHLOROETHYLENE CEILING 200 PPM
(CAS 79-01-6) TWA 100 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE FORM
1,1,2-TRICHLOROETHYLENE STEL 25 PPM
(CAS 79-01-6) TWA 10 PPM
BUTANONE (CAS 78-93-3) STEL 300 PPM
TWA 200 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE FORM
CAMPHOR USP (CAS 76-22-2) STEL 3 PPM
TWA 2 PPM
CARBON DIOXIDE (CAS 124-38-9) STEL 30000 PPM
TWA 5000 PPM
DIPHENYL OXIDE (CAS 101-84-8) STEL 2 PPM VAPOR.
TWA 1 PPM VAPOR.
ISO AMYL ACETATE (CAS 123-92-2) STEL 100 PPM
TWA 50 PPM
TURPENTINE (CAS 8006-64-2) TWA 20 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE FORM
1,1,2-TRICHLOROETHYLENE TWA 25 PPM
(CAS 79-01-6)
BUTANONE (CAS 78-93-3) STEL 885 MG/M3
300 PPM
TWA 590 MG/M3
200 PPM
CAMPHOR USP (CAS 76-22-2) TWA 2 MG/M3
CARBON DIOXIDE STEL 54000 MG/M3
(CAS 124-38-9) 30000 PPM
TWA 9000 MG/M3
5000 PPM
DIPHENYL OXIDE TWA 7 MG/M3 VAPOR.
(CAS 101-84-8) 1 PPM VAPOR.
ISO AMYL ACETATE TWA 525 MG/M3
(CAS 123-92-2) 100 PPM
TURPENTINE TWA 560 MG/M3
(CAS 8006-64-2) 100 PPM
US. WORKPLACE ENVIRONMENTAL EXPOSURE LEVEL (WEEL) GUIDES:
COMPONENTS TYPE VALUE
1,2 BUTYLENE OXIDE (CAS 106-88-7) TWA 5.9 MG/M3
2 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING
TIME
1,1,2-TRICHLOROETHYLENE 15 MG/L TRICHLOROACETIC URINE *
(CAS 79-01-6) ACID
0.5 MG/L TRICHLOROETHANO BLOOD *
L, WITHOUT
HYDROLYSIS
BUTANONE (CAS 78-93-3) 2 MG/L MEK URINE *
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE
PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER MUST BE
AVAILABLE WHEN HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION: WEAR APPROPRIATE CHEMICAL RESISTANT GLOVES.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON IS
RECOMMENDED.
RESPIRATORY PROTECTION:
IF PERMISSIBLE LEVELS ARE EXCEEDED USE NIOSH MECHANICAL FILTER / ORGANIC
VAPOR CARTRIDGE OR AN AIR-SUPPLIED RESPIRATOR.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
OBSERVE ANY MEDICAL SURVEILLANCE REQUIREMENTS. WHEN USING DO NOT SMOKE.
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER
HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: GAS.
FORM: AEROSOL.
COLOR: CLEAR. COLORLESS.
ODOR: SWEET. SPICE.
ODOR THRESHOLD: NOT ESTABLISHED
PH: NOT APPLICABLE
MELTING POINT/FREEZING POINT: NOT ESTABLISHED
INITIAL BOILING POINT AND BOILING RANGE: 188.6 DEG. F (87 DEG. C)
FLASH POINT: TAG CLOSED CUP (NONE)
EVAPORATION RATE: 0.3 (ETHYL ETHER = 1)
FLAMMABILITY (SOLID, GAS): NON FLAMMABLE GAS.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 8%
FLAMMABILITY LIMIT - UPPER (%): 10.5%
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: 58 MMHg @ 20 DEG. C
VAPOR DENSITY: 4.5
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES):
SOLUBILITY (WATER): 0.1%
PARTITION COEFFICIENT (N-OCTANOL/WATER): 2.4
AUTO-IGNITION TEMPERATURE: >788 DEG. F (>420 DEG. C)
DECOMPOSITION TEMPERATURE: NOT ESTABLISHED
VISCOSITY: 0.53 CP @ 25 DEG. C
OTHER INFORMATION:
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
HEAT OF COMBUSTION: <20 KJ/G
OXIDIZING PROPERTIES: NOT OXIDIZING.
PERCENT VOLATILE: 100%
SPECIFIC GRAVITY: 1.41 - 1.47 @ 20 DEG. C
VOC: 97.8%
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID: HEAT. CONTACT WITH INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. PROLONGED
INHALATION MAY BE HARMFUL.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NARCOTIC EFFECTS.
COMPONENTS SPECIES TEST RESULTS
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6):
ACUTE:
DERMAL:
LD50 RABBIT 20 ML/KG
INHALATION:
LC50 RAT 12500 PPM, 4 HOURS
ORAL:
LD50 RAT 4920 MG/KG
1,2 BUTYLENE OXIDE (CAS 106-88-7):
ACUTE:
DERMAL:
LD50 RABBIT 1.77 ML/KG, 24 HOURS
INHALATION:
VAPOR:
LC50 RAT >6.3 MG/L, 4 HOURS
ORAL:
LD50 RAT 1100 (MICRO)L/KG
BUTANONE (CAS 78-93-3):
ACUTE:
DERMAL:
LD50 RABBIT >10 ML/KG
ORAL:
LD50 RAT 2054 MG/KG
DIPHENYL OXIDE (CAS 101-84-8):
ACUTE:
ORAL:
LD50 RAT 2.83 G/KG
TURPENTINE (CAS 8006-64-2):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG, 24 HOURS
INHALATION:
VAPOR:
LC50 RAT 13.7 MG/L, 4 HOURS
ORAL:
LD50 RAT 4.6 ML/KG
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
ACGIH SENSITIZATION:
TURPENTINE (CAS 8006-64-2): DERMAL SENSITIZATION
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY: SUSPECTED OF CAUSING GENETIC DEFECTS.
CARCINOGENICITY: MAY CAUSE CANCER.
ACGIH CARCINOGENS:
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6): A2 SUSPECTED HUMAN CARCINOGEN.
CAMPHOR USP (CAS 76-22-2): A4 NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
TURPENTINE (CAS 8006-64-2): A4 NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6): 1 CARCINOGENIC TO HUMANS.
1,2 BUTYLENE OXIDE (CAS 106-88-7): 2B POSSIBLY CARCINOGENIC TO HUMANS.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050);
NOT REGULATED.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS:
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6):
REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS AND DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT AN ASPIRATION HAZARD.
CHRONIC EFFECTS:
PROLONGED INHALATION MAY BE HARMFUL. PROLONGED EXPOSURE MAY CAUSE CHRONIC
EFFECTS.
FURTHER INFORMATION: SYMPTOMS MAY BE DELAYED.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT CLASSIFIED AS ENVIRONMENTALLY HAZARDOUS. HOWEVER, THIS
DOES NOT EXCLUDE THE POSSIBILITY THAT LARGE OR FREQUENT SPILLS CAN HAVE A
HARMFUL OR DAMAGING EFFECT ON THE ENVIRONMENT.
COMPONENTS SPECIES TEST RESULTS
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6):
AQUATIC:
FISH LC50 FLAGFISH (JORDANELLA 3.1 MG/L, 96 HOURS
FLORIDAE)
BUTANONE (CAS 78-93-3):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA 4025 - 6440 MG/L,
MAGNA) 48 HOURS
FISH LC50 SHEEPSHEAD MINNOW >400 MG/L, 96 HOURS
(CYPRINODON
VARIEGATUS)
DIPHENYL OXIDE (CAS 101-84-8):
AQUATIC:
FISH LC50 SHEEPSHEAD MINNOW 1.8 - 3.2 MG/L,
(CYPRINODON 96 HOURS
VARIEGATUS)
PERSISTENCE AND DEGRADABILITY: NOT INHERENTLY BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
LPS(R*) HDX (AEROSOL): 2.4
1,1,2-TRICHLOROETHYLENE: 2.61
BUTANONE: 0.29
DIPHENYL OXIDE: 4.21
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS: NONE KNOWN.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE OR
CRUSH. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
D003: WASTE REACTIVE MATERIAL
D040: WASTE TRICHLOROETHYLENE
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL. DO NOT RE-USE EMPTY
CONTAINERS.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME:
AEROSOLS, NON-FLAMMABLE, (EACH NOT EXCEEDING 1 L CAPACITY)
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.2
SUBSIDIARY RISK: 6.1(PGIII)
LABEL(S): 2.2
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: NONE
PACKAGING BULK: NONE
IATA:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, NON-FLAMMABLE
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.2
SUBSIDIARY RISK: 6.1(PGIII)
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS: NO
ERG CODE: 2L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED WITH RESTRICTIONS.
CARGO AIRCRAFT ONLY: ALLOWED WITH RESTRICTIONS.
IMDG:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.2
SUBSIDIARY RISK: 6.1(PGIII)
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
EMS: F-D, S-U
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE.
DOT:
NON-FLAMMABLE GAS, CLASS/DIVISION 2.2
POISION, CLASS/DIVISION 6.1 PACKING GROUP I OR II
IATA; IMDG:
CLASS 2.1 - FLAMMABLE GASES
CLASS 6.1 - TOXIC
GENERAL INFORMATION:
AVOID TRANSPORT ON VEHICLES WHERE THE LOAD SPACE IS NOT SEPARATED FROM THE
DRIVER'S COMPARTMENT. ENSURE VEHICLE DRIVER IS AWARE OF THE POTENTIAL
HAZARDS OF THE LOAD AND KNOWS WHAT TO DO IN THE EVENT OF AN ACCIDENT OR AN
EMERGENCY. BEFORE TRANSPORTING PRODUCT CONTAINERS: ENSURE THAT CONTAINERS
ARE FIRMLY SECURED. ENSURE CYLINDER VALVE IS CLOSED AND NOT LEAKING. ENSURE
VALVE OUTLET CAP NUT OR PLUG (WHERE PROVIDED) IS CORRECTLY FITTED. ENSURE
VALVE PROTECTION DEVICE (WHERE PROVIDED) IS CORRECTLY FITTED. ENSURE
ADEQUATE VENTILATION. ENSURE COMPLIANCE WITH APPLICABLE REGULATIONS.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6):
0.1% ONE-TIME EXPORT NOTIFICATION ONLY.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6): LISTED.
1,2 BUTYLENE OXIDE (CAS 106-88-7): LISTED.
BUTANONE (CAS 78-93-3): LISTED.
ISO AMYL ACETATE (CAS 123-92-2): LISTED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: NO
PRESSURE HAZARD: YES
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 311/312 HAZARDOUS CHEMICAL: YES
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
TRICHLOROETHYLENE 79-01-6 97.25
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6)
1,2 BUTYLENE OXIDE (CAS 106-88-7)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 2, ESSENTIAL CHEMICALS (21 CFR
1310.02(B) AND 1310.04(F)(2) AND CHEMICAL CODE NUMBER:
BUTANONE (CAS 78-93-3): 6714
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 1 & 2 EXEMPT CHEMICAL MIXTURES
(21 CFR 1310.12(C)):
BUTANONE (CAS 78-93-3): 35%WV
DEA EXEMPT CHEMICAL MIXTURES CODE NUMBER:
BUTANONE (CAS 78-93-3): 6714
FEMA PRIORITY SUBSTANCES RESPIRATORY HEALTH AND SAFETY IN THE FLAVOR
MANUFACTURING WORKPLACE:
BUTANONE (CAS 78-93-3): LOW PRIORITY
DIPHENYL OXIDE (CAS 101-84-8): LOW PRIORITY
ISO AMYL ACETATE (CAS 123-92-2): LOW PRIORITY
US STATE REGULATIONS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/CARCINOGENIC SUBSTANCE
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6):
LISTED: APRIL 1, 1988
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/DEVELOPMENTAL TOXIN
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6):
LISTED: JAN 31, 2014
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/MALE REPRODUCTIVE TOXIN
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6):
LISTED: JAN 31, 2014
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
1,1,2-TRICHLOROETHYLENE (CAS 79-01-6)
1,2 BUTYLENE OXIDE (CAS 106-88-7)
BUTANONE (CAS 78-93-3)
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR INVENTORY NAME ON INVENTORY
REGION (YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF YES
CHEMICAL SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST NO
(NDSL)
CHINA INVENTORY OF EXISTING CHEMICAL YES
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING YES
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED NO
CHEMICAL SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW YES
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF YES
CHEMICALS AND CHEMICAL
SUBSTANCES (PICCS)
UNITED STATES TOXIC SUBSTANCES CONTROL ACT YES
& PUERTO RICO (TSCA) INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY (S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF | |
PREPARATION OR LAST REVISION
ISSUE DATE: 10-18-2016
VERSION #: 01
DISCLAIMER:
ITW PRO BRANDS CANNOT ANTICIPATE ALL CONDITIONS UNDER WHICH THIS
INFORMATION AND ITS PRODUCT, OR THE PRODUCTS OF OTHER MANUFACTURERS IN
COMBINATION WITH ITS PRODUCT, MAY BE USED. IT IS THE USER'S RESPONSIBILITY
TO ENSURE SAFE CONDITIONS FOR HANDLING, STORAGE AND DISPOSAL OF THE
PRODUCT, AND TO ASSUME LIABILITY FOR LOSS, INJURY, DAMAGE OR EXPENSE DUE TO
IMPROPER USE. THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT
TO THE BEST OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS
PUBLICATION. THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE
HANDLING, USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE
AND IS NOT TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE
INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE
VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN
ANY PROCESS, UNLESS SPECIFIED IN THE TEXT.
REVISION INFORMATION:
THIS DOCUMENT HAS UNDERGONE SIGNIFICANT CHANGES AND SHOULD BE REVIEWED IN
ITS ENTIRETY.
MATERIAL NAME: LPS(R*) HDX (AEROSOL)
SDS: US