| Common Name: | LOCTITE SI 587 HIGH PERFORM RTV SILICONE KNOWN AS LOCTITE 587 BLUE HIGH PERFO, 5 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 5/19/2022 |
| SDS Format: | No Format Specified |
| Item Number(s): | 4KM22 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 009.1
ISSUE DATE: 05/19/2022
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE SI 587 HIGH PERFORM RTV SILICONE KNOWN AS LOCTITE(R) 587 BLUE
HIGH PERFO
IDH NUMBER: 135504
PRODUCT TYPE/USE: SILICONE SEALANT
ITEM NUMBER: 58730
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE CANCER.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
HAZARD CLASS HAZARD CATEGORY
EYE IRRITATION 2A
SKIN SENSITIZATION 1
CARCINOGENICITY 1A
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 2
PICTOGRAM(S):
HEALTH HAZARD
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE DUST OR FUMES.
WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING
SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE GLOVES,
CLOTHING, EYE AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL,
STATE/PROVINCIAL AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE
UNITED NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND
LABELING OF CHEMICALS (GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
LIMESTONE 1317-65-3 30 - 60
AMORPHOUS FUMED SILICA 68611-44-9 5 - 10
BUTAN-2-ONE O,O',O''- 2224-33-1 1 - 5
(VINYLSILYLIDYNE)TRIOXIME
2-BUTANONE OXIME 96-29-7 1 - 5
QUARTZ (SiO2), <1% RESPIRABLE 14808-60-7 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION
RANGE IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR IN CASE OF ACCIDENTAL INHALATION OF VAPOURS OR
DECOMPOSITION PRODUCTS. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
SKIN CONTACT:
WIPE OFF PASTE WITH PAPER TOWEL OR CLOTH. WASH WITH SOAP AND WATER.
IF SKIN IRRITATION PERSISTS, CALL A PHYSICIAN.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF ADVERSE HEALTH EFFECTS DEVELOP SEEK MEDICAL
ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. IN CASE OF ADVERSE HEALTH EFFECTS SEEK MEDICAL
ADVICE.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
PREVENT INHALATION OF FUMES AND GASES. WEAR SELF-CONTAINED BREATHING
APPARATUS.
UNUSUAL FIRE OR EXPLOSION HAZARDS: NOT AVAILABLE.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SILICON. FORMALDEHYDE. IRRITATING ORGANIC
VAPOURS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. MAINTAIN GOOD VENTILATION FOR
LARGE SPILLS. PLACE SCRAP MATERIAL IN A WELL VENTILATED AREA AND ALLOW
TO CURE TO RUBBER.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. DO NOT HANDLE CONTACT LENSES UNTIL
ALL SEALANT HAS BEEN REMOVED FROM HANDS. RESIDUAL SEALANT MAY TRANSFER TO
LENSES AND CAUSE EYE IRRITATION.
STORAGE:
FOR SAFE STORAGE, STORE AT OR BELOW 32 DEG. C (89.6 DEG. F)
KEEP CONTAINER CLOSED.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS ACGIH TLV OSHA PEL AIHA WEEL OTHER
COMPONENT(S)
LIMESTONE 10 MG/M3 TWA 5 MG/M3 PEL NONE NONE
INHALABLE RESPIRABLE
PARTICLES. FRACTION.
3 MG/M3 TWA 15 MG/M3 PEL
RESPIRABLE TOTAL DUST.
PARTICLES.
5 MG/M3 TWA
10 MG/M3 TWA RESPIRABLE
TOTAL DUST. FRACTION.
50 MPPCF TWA
TOTAL DUST.
15 MG/M3 TWA
TOTAL DUST.
15 MPPCF TWA
RESPIRABLE
FRACTION.
AMORPHOUS FUMED 3 MG/M3 TWA 0.8 MG/M3 TWA NONE NONE
SILICA RESPIRABLE
PARTICLES. 20 MPPCF TWA
10 MG/M3 TWA 50 MPPCF TWA
INHALABLE TOTAL DUST.
PARTICLES.
15 MG/M3 TWA
TOTAL DUST.
5 MG/M3 TWA
RESPIRABLE
FRACTION.
15 MPPCF TWA
RESPIRABLE
FRACTION.
BUTAN-2-ONE NONE NONE NONE NONE
O,O',O''-
(VINYLSILYLIDYNE)
TRIOXIME
2-BUTANONE OXIME NONE NONE 10 PPM NONE
(36 MG/M3)
TWA (SKIN
SENSITIZER.)
QUARTZ (SiO2), 0.025 MG/M3 TWA 0.05 MG/M3 TWA NONE NONE
<1% RESPIRABLE RESPIRABLE (RESPIRABLE
FRACTION. DUST.)
0.025 MG/M3
OSHA_ACT
(RESPIRABLE
DUST.)
0.05 MG/M3 PEL
RESPIRABLE
DUST.
2.4 MPPCF TWA
RESPIRABLE.
0.1 MG/M3 TWA
RESPIRABLE.
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE A NIOSH APPROVED AIR-PURIFYING RESPIRATOR IF THE POTENTIAL TO EXCEED
ESTABLISHED EXPOSURE LIMITS EXISTS.
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. SAFETY SHOWERS AND EYE
WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT
SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE
COLOR: BLUE
ODOR: MILD, PETROLEUM
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: <5 MM Hg (20 DEG. C (68 DEG. F))
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.31 AT 20 DEG. C (68 DEG. F)
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: >93 DEG. C (>199.4 DEG. F) TAGLIABUE CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: POLYMERISES IN PRESENCE OF WATER.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0.44 %
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE AT NORMAL CONDITIONS.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SILICON. METHYL ETHYL KETOXIME FORMED DURING
CURE. FORMALDEHYDE.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS. ACIDS AND BASES.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: EXPOSURE TO MOISTURE.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION. WHEN HEATED TO TEMPERATURES
EXCEEDING 300 DEG. F (150 DEG. C) IN THE PRESENCE OF AIR, SILICONES
MAY FORM FORMALDEHYDE VAPORS. FORMALDEHYDE IS A POTENTIAL CANCER HAZARD
AND A KNOWN SKIN AND RESPIRATORY SENSITIZER. VAPORS IRRITATE THE EYES,
NOSE AND THROAT. SAFE HANDLING CONDITIONS MAY BE MAINTAINED BY KEEPING
FORMALDEHYDE VAPOR CONCENTRATIONS BELOW THE OSHA PERMISSIBLE LIMIT.
ABRASION OF CURED MATERIAL SUCH AS BY SANDING OR GRINDING COULD RELEASE
RESPIRABLE PARTICLES OF SILICA QUARTZ, A CANCER HAZARD BY INHALATION.
NORMAL USE OF THIS PRODUCT CAUSES NO SUCH RELEASE.
SKIN CONTACT: MAY CAUSE SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
NOT EXPECTED UNDER NORMAL CONDITIONS OF USE. INGESTION MAY CAUSE
GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
LIMESTONE NONE NUISANCE DUST
AMORPHOUS FUMED SILICA NONE NO TARGET ORGANS
BUTAN-2-ONE O,O',O''- NONE IRRITANT, ALLERGEN
(VINYLSILYLIDYNE)TRIOXIME
2-BUTANONE OXIME INHALATION LC50 ALLERGEN, BLOOD,
(RAT, 4 H): CENTRAL NERVOUS
>4.83 MG/L SYSTEM, EYES,
IRRITANT, SOME
EVIDENCE OF
CARCINOGENICITY
QUARTZ (SiO2), NONE IMMUNE SYSTEM, LUNG,
<1% RESPIRABLE SOME EVIDENCE OF
CARCINOGENICITY
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY
REGULATED)
LIMESTONE NO NO NO
AMORPHOUS FUMED SILICA NO NO NO
BUTAN-2-ONE O,O',O''- NO NO NO
(VINYLSILYLIDYNE)TRIOXIME
2-BUTANONE OXIME NO NO NO
QUARTZ (SiO2), KNOWN TO GROUP 1 YES
<1% RESPIRABLE BE HUMAN
CARCINOGEN.
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
CURED RUBBER CAN BE INCINERATED OR LANDFILLED FOLLOWING EPA AND LOCAL
REGULATIONS. FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS
FOR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
EXCEPTIONS: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED AS ACTIVE OR ARE EXEMPT FROM LISTING ON THE
TOXIC SUBSTANCES CONTROL ACT (TSCA) INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. THIS PRODUCT CONTAINS A CHEMICAL
KNOWN IN THE STATE OF CALIFORNIA TO CAUSE CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 9
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 05/19/2022
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR
ANY PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND
TO ADOPT SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF
PROPERTY AND PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE
HANDLING AND USE OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING,
HENKEL SPECIFICALLY DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED,
INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR
PURPOSE, ARISING FROM SALE OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER
DISCLAIMS ANY LIABILITY FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY
KIND, INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN
ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION
OF ANY KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF
ANY OTHER JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION
PROVIDED HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY
OTHER JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY
AND REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.