| Common Name: | LOCTITE SI 587 KNOWN AS LOCTITE 587 300ML EN, 58775 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 10/14/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 4KM23 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 008.1
ISSUE DATE: 10/14/2019
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE SI 587 KNOWN AS LOCTITE 587 300ML EN
PRODUCT TYPE/USE: SILICONE SEALANT
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 234590
ITEM NUMBER: 58775
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
HAZARD CLASS HAZARD CATEGORY
EYE IRRITATION 2A
SKIN SENSITIZATION 1
REPRODUCTIVE TOXICITY 2
PICTOGRAM(S):
HEALTH HAZARD
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING DUST OR FUMES.
WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING
SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE GLOVES,
CLOTHING, EYE AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED
NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF
CHEMICALS (GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
LIMESTONE 1317-65-3 30 - 60
BUTAN-2-ONE O,O',O''-(VINYLSILYLIDYNE) 2224-33-1 1 - 5
TRIOXIME
OCTAMETHYLCYCLOTETRASILOXANE 556-67-2 0.1 - 1
QUARTZ (SIO2), <1% RESPIRABLE 14808-60-7 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE
IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR IN CASE OF ACCIDENTAL INHALATION OF VAPOURS OR
DECOMPOSITION PRODUCTS. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
SKIN CONTACT:
WIPE OFF PASTE WITH PAPER TOWEL OR CLOTH. WASH WITH SOAP AND WATER. IF
SKIN IRRITATION PERSISTS, CALL A PHYSICIAN.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF ADVERSE HEALTH EFFECTS DEVELOP SEEK MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. IN CASE OF ADVERSE HEALTH EFFECTS SEEK MEDICAL
ADVICE.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
PREVENT INHALATION OF FUMES AND GASES. WEAR SELF-CONTAINED BREATHING
APPARATUS.
UNUSUAL FIRE OR EXPLOSION HAZARDS: NOT AVAILABLE.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SILICON. FORMALDEHYDE. IRRITATING ORGANIC
VAPOURS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. MAINTAIN GOOD VENTILATION FOR LARGE
SPILLS. PLACE SCRAP MATERIAL IN A WELL VENTILATED AREA AND ALLOW TO CURE TO
RUBBER.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. DO NOT HANDLE CONTACT LENSES UNTIL
ALL SEALANT HAS BEEN REMOVED FROM HANDS. RESIDUAL SEALANT MAY TRANSFER TO
LENSES AND CAUSE EYE IRRITATION.
STORAGE:
FOR SAFE STORAGE, STORE AT OR BELOW 32 DEG. C (89.6 DEG. F)
KEEP CONTAINER CLOSED.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL
LIMESTONE 10 MG/M3 TWA 5 MG/M3 PEL
TOTAL DUST. RESPIRABLE FRACTION.
15 MG/M3 PEL
TOTAL DUST.
BUTAN-2-ONE O,O',O''- NONE NONE
(VINYLSILYLIDYNE)TRIOXIME
OCTAMETHYLCYCLOTETRASILOXANE NONE NONE
QUARTZ (SIO2), <1% RESPIRABLE 0.025 MG/M3 TWA 0.05 MG/M3 TWA
RESPIRABLE FRACTION. (RESPIRABLE DUST.)
0.025 MG/M3 OSHA_ACT
(RESPIRABLE DUST.)
0.05 MG/M3 PEL
RESPIRABLE DUST.
2.4 MPPCF TWA
RESPIRABLE.
0.1 MG/M3 TWA
RESPIRABLE.
HAZARDOUS COMPONENT(S) AIHA WEEL OTHER
LIMESTONE NONE NONE
BUTAN-2-ONE O,O',O''-(VINYLSILYLIDYNE)TRIOXIME NONE NONE
OCTAMETHYLCYCLOTETRASILOXANE 10 PPM TWA NONE
QUARTZ (SIO2), <1% RESPIRABLE NONE NONE
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE A NIOSH APPROVED AIR-PURIFYING RESPIRATOR IF THE POTENTIAL TO EXCEED
ESTABLISHED EXPOSURE LIMITS EXISTS.
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. SAFETY SHOWERS AND
EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT
SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE
COLOR: BLUE
ODOR: MILD, PETROLEUM
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: <5 MMHg (20 DEG. C (68 DEG. F))
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.31 AT 20 DEG. C (68 DEG. F)
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: >93 DEG. C (>199.4 DEG. F) TAGLIABUE CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: POLYMERISES IN PRESENCE OF WATER.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 3.33%; 43.09 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE AT NORMAL CONDITIONS.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SILICON. METHYL ETHYL KETOXIME FORMED DURING
CURE. FORMALDEHYDE.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS. ACIDS AND BASES.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: EXPOSURE TO MOISTURE.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION. WHEN HEATED TO TEMPERATURES
EXCEEDING 300 DEG. F (150 DEG. C) IN THE PRESENCE OF AIR, SILICONES MAY
FORM FORMALDEHYDE VAPORS. FORMALDEHYDE IS A POTENTIAL CANCER HAZARD AND A
KNOWN SKIN AND RESPIRATORY SENSITIZER. VAPORS IRRITATE THE EYES, NOSE AND
THROAT. SAFE HANDLING CONDITIONS MAY BE MAINTAINED BY KEEPING FORMALDEHYDE
VAPOR CONCENTRATIONS BELOW THE OSHA PERMISSIBLE LIMIT. ABRASION OF CURED
MATERIAL SUCH AS BY SANDING OR GRINDING COULD RELEASE RESPIRABLE PARTICLES
OF SILICA QUARTZ, A CANCER HAZARD BY INHALATION. NORMAL USE OF THIS
PRODUCT CAUSES NO SUCH RELEASE.
SKIN CONTACT: MAY CAUSE SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
NOT EXPECTED UNDER NORMAL CONDITIONS OF USE. INGESTION MAY CAUSE
GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
LIMESTONE NONE NUISANCE DUST
BUTAN-2-ONE O,O',O''- NONE IRRITANT, ALLERGEN
(VINYLSILYLIDYNE)TRIOXIME
OCTAMETHYLCYCLOTETRASILOXANE NONE IRRITANT
QUARTZ (SIO2), <1% RESPIRABLE NONE IMMUNE SYSTEM, LUNG,
SOME EVIDENCE OF
CARCINOGENICITY
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN SPECIFICALLY
REGULATED)
LIMESTONE NO NO NO
BUTAN-2-ONE O,O',O''- NO NO NO
(VINYLSILYLIDYNE)TRIOXIME
OCTAMETHYLCYCLOTETRASILOXANE NO NO NO
QUARTZ (SIO2), <1% RESPIRABLE KNOWN TO GROUP 1 YES
BE HUMAN
CARCINOGEN.
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
CURED RUBBER CAN BE INCINERATED OR LANDFILLED FOLLOWING EPA AND LOCAL
REGULATIONS. FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS
FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
EXCEPTIONS: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 2, 3, 8, 11
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 10/14/2019
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN
ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION OF
ANY KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF ANY
OTHER JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION PROVIDED
HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY OTHER
JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY AND
REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.